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118 | null | Коллектив исследователей из Сингапура создал новый материал на основе оксида графена и хитозана, формирующийся методом самосборки и позволяющий эффективно извлекать золото из отходов электроники. Благодаря использованию этого материала удается исключить сразу несколько стадий переработки отходов, что делает весь процесс более выгодным с экономической точки зрения.
https://www.pnas.org/doi/10.1073/pnas.2414449121
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118 | null | #органика #природное
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118 | null | #органика #природное
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| [{"ner":"07-12","lemma":"07-12","label":"DATE","start_pos":88,"end_pos":93},{"ner":"12","lemma":"12","label":"NUM","start_pos":91,"end_pos":93}] | NEUTRAL | eng | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | Актуально для студентов медиков 2 курса :)
😇
На самом деле биохимия хоть и объемная, но очень логичная, понятная и доступная наука, которая дает ответ на многие вопросы и формирует понимание работы нашего организма, и причины развития патологических состояний.
❗️
Главный принцип, чтобы разобраться в биохимии сформулирован в названии канала -
говорить просто о сложном!
Поэтому все посты, лекции и курсы рассказываются максимально просто и понятно, с переводом на «русский человеческий язык»
😂 | https://t.me/simplebestbiochemistry/480?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,500 | 0 | 1,729,928,808 | 1,736,456,931 | 1,147 | 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| [{"ner":"2","lemma":"2","label":"NUM","start_pos":32,"end_pos":33}] | NEUTRAL | rus | NOT SPAM | 73 | 0 | 0 | 1 | 0 | 0 | 13 | 6 | 1 | 1 | 25 | 4 | 13 | true |
118 | null | КУРС ПО БЕЛКАМ, НАЧИНАЕМ!
Коллеги, с радостью вам сообщаю, что мы открываем продажи нашего большого курса по обмену белков и аминокислот!
🔥
Ключевая цель
- сформировать прочный фундамент понимания метаболизма белков и аминокислот, и научиться интегрировать его в свою практическую деятельность.
✅
Первый модуль уже готов и вы можете приступать к изучению прямо сегодня!
Ознакомиться с содержанием, ценами, ключевыми организационными вопросами вы можете на сайте
⤵️
http://simplebiochemistry.tilda.ws/menu
🔬
Как принять участие?
Напишите моему ассистенту
@ysavnin
, которая ответит на все вопросы и поможет с приобретение. Или заполняйте анкету участника на сайте и мы свяжемся с вами!
Возможна покупка в рассрочку
😉
До встречи! | https://t.me/simplebestbiochemistry/481?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,500 | 0 | 1,730,089,863 | 1,736,456,931 | 1,146 | 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| [{"ner":"КУРС ПО БЕЛКАМ","lemma":"курс по белкам","label":"ORG","start_pos":0,"end_pos":14},{"ner":"НАЧИНАЕМ!\n","lemma":"начинаем!","label":"ORG","start_pos":16,"end_pos":26},{"ner":"⤵️\nhttp://simplebiochemistry.tilda.ws/menu\n🔬","lemma":"⤵️\nhttp://simplebiochemistry.tilda.ws/menu\n🔬","label":"ORG","start_pos":462,"end_pos":506}] | NEUTRAL | rus | SPAM | 103 | 0 | 4 | 0.985075 | 0.014925 | 0 | 9 | 16 | 8 | 0 | 30 | 4 | 17 | true |
118 | null | 🙆
Когда закрывается запись на курс?
Вопрос, который часто нам задают
⤴️
Коллеги, обратите внимание, продажи будут открыты по текущим ценам
ровно неделю
: с 28 октября по 4 ноября.
Не упустите возможность углубить свои знания и освоить важные аспекты биохимии обмена белков и аминокислот!
http://simplebiochemistry.tilda.ws/menu | https://t.me/simplebestbiochemistry/483?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,730,118,358 | 1,736,456,931 | 1,140 | 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| [{"ner":"28 октября","lemma":"28 октября","label":"DATE","start_pos":156,"end_pos":166},{"ner":"4","lemma":"4","label":"NUM","start_pos":170,"end_pos":171}] | NEUTRAL | rus | NOT SPAM | 46 | 0 | 0 | 0.983333 | 0.016667 | 0 | 4 | 7 | 2 | 0 | 18 | 3 | 7 | true |
118 | null | Простой эксперимент «Волшебное молоко»
Понадобятся:
- Молоко 3,25%
- Средство для мытья посуды
- Пищевой краситель (лучше взять несколько разных цветов)
- Ватные палочки
1. Молоко налейте в неглубокое блюдце или миску.
2. Добавить несколько капель красителя.
3. Окунуть ватную палочку в средство для мытья посуды, а затем в капельку пищевого красителя, который мы уже добавили в молоко. | https://t.me/ychemistry/988?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,800 | 0 | 1,725,253,945 | 1,736,456,931 | 1,143 | 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| [{"ner":"Волшебное молоко","lemma":"волшебный молоко","label":"ORG","start_pos":21,"end_pos":37},{"ner":"3","lemma":"3","label":"NUM","start_pos":61,"end_pos":62},{"ner":"25","lemma":"25","label":"NUM","start_pos":63,"end_pos":65},{"ner":"1","lemma":"1","label":"NUM","start_pos":170,"end_pos":171},{"ner":"2","lemma":"2","label":"NUM","start_pos":219,"end_pos":220},{"ner":"3","lemma":"3","label":"NUM","start_pos":259,"end_pos":260}] | NEUTRAL | rus | NOT SPAM | 58 | 0 | 0 | 1 | 0 | 0 | 11 | 6 | 2 | 6 | 23 | 2 | 13 | true |
118 | null | Залипательный эксперимент с мощным магнитом и магнитными шариками. | https://t.me/ychemistry/989?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,700 | 0 | 1,725,433,364 | 1,736,456,931 | 1,145 | 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| null | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 3 | 0 | 0 | 0 | 3 | 0 | 1 | true |
118 | null | Ракета, на создание которой ушло несколько десятков тысяч спичек. | https://t.me/ychemistry/990?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,700 | 0 | 1,725,608,842 | 1,736,456,931 | 1,139 | 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| null | NEUTRAL | rus | NOT SPAM | 12 | 0 | 0 | 1 | 0 | 0 | 3 | 0 | 0 | 0 | 5 | 0 | 1 | true |
118 | null | Апофиллит, а также рыбий глаз или каменный рыбий глаз — минерал, силикат натрия и кальция сложного состава.
Термин «апофиллит» применим для целой группы сходных минералов, включающих в себя флуорапофиллит, гидроксиапофиллит и натроапофиллит. Название камня указывает на свойство апофиллита расслаиваться при нагревании, когда минерал теряет воду. | https://t.me/chemistrytg2021/9484?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,870,000 | 1,736,456,932 | 1,143 | 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| null | NEUTRAL | rus | NOT SPAM | 45 | 0 | 0 | 1 | 0 | 0 | 7 | 5 | 1 | 0 | 20 | 1 | 11 | true |
118 | null | Вулкан в тарелке
Мелкоизмельченный порошок серы и железа смешивается и «зажигается» с помощью горячего стеклянного стержня. Эта реакция производит безумное количество тепла, оставляя после себя твердый сульфид железа (II) (FeS). | https://t.me/chemistrytg2021/9486?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,891,600 | 1,736,456,932 | 1,148 | 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| null | NEUTRAL | rus | NOT SPAM | 30 | 0 | 1 | 0.95 | 0.05 | 0 | 6 | 4 | 1 | 0 | 12 | 0 | 9 | true |
118 | null | Увлекательный научный опыт с глицерином и пищевым красителем | https://t.me/chemistrytg2021/9487?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,100 | 0 | 1,734,934,800 | 1,736,456,932 | 1,149 | 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| null | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 3 | 0 | 0 | 0 | 3 | 0 | 0 | true |
118 | null | Норадреналин иногда называют гормоном ярости. При выбросе его в кровь возникает агрессивная реакция, увеличивается мышечная сила. Его уровень возрастает при страхе, шоке, травмах и нервном напряжении - ситуациях, когда требуется немедленная перестройка организма. Сосудорасширяющий эффект норадреналина сильнее, но более короткий по времени и играет роль при регуляции объема и скорости кровотока. | https://t.me/incredible_chemistry/308?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,688,533,201 | 1,736,456,932 | 1,143 | 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| [{"ner":"Норадреналин","lemma":"норадреналин","label":"PER","start_pos":0,"end_pos":12}] | NEUTRAL | rus | NOT SPAM | 51 | 0 | 0 | 1 | 0 | 0 | 6 | 7 | 1 | 0 | 22 | 2 | 9 | true |
118 | null | Нонаконтатриктан
- самый длинный синтетический углеводород. Был синтезирован в 1985 году химиками Айлиш Бидд и Марком Уайтингом. При нормальных условиях представляет собой бесцветные кристаллы с температурой плавления 132°C, нерастворимые в воде. | https://t.me/incredible_chemistry/309?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,200 | 0 | 1,688,619,600 | 1,736,456,932 | 1,143 | 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| [{"ner":"Айлиш Бидд","lemma":"айлиш бидд","label":"PER","start_pos":98,"end_pos":108},{"ner":"Марком Уайтингом","lemma":"марк уайтингом","label":"PER","start_pos":111,"end_pos":127},{"ner":"1985","lemma":"1985","label":"NUM","start_pos":79,"end_pos":83},{"ner":"132","lemma":"132","label":"NUM","start_pos":219,"end_pos":222}] | NEUTRAL | rus | NOT SPAM | 31 | 0 | 1 | 0.974359 | 0.025641 | 0 | 7 | 3 | 1 | 1 | 10 | 0 | 4 | true |
118 | null | 𝙼𝚎𝚖𝚎𝚗𝚝𝚘 𝚖𝚘𝚛𝚒:
Этот яд мы едим каждый день
💀
Сильнейший канцероген и яд регулярно отравляет нас по малу, он накапливается в организме и убивает его, вызывая
рак
,
синдром Альцгеймера
и другие болезни. Так что никогда не ешь эти продукты...
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https://t.me/TrueChmsry/182 | https://t.me/incredible_chemistry/310?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,688,631,243 | 1,736,456,932 | 1,143 | 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| [{"ner":"182","lemma":"182","label":"NUM","start_pos":278,"end_pos":281}] | NEUTRAL | rus | NOT SPAM | 44 | 0 | 0 | 0.948276 | 0.017241 | 0.034483 | 2 | 7 | 4 | 1 | 11 | 4 | 6 | true |
118 | null | «КЕДА»
- удобное мнемоническое правило, чтобы запомнить жирорастворимые витамины
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| [{"ner":"КЕДА","lemma":"кеда","label":"ORG","start_pos":1,"end_pos":5}] | NEUTRAL | rus | NOT SPAM | 10 | 0 | 1 | 1 | 0 | 0 | 3 | 2 | 0 | 0 | 3 | 0 | 3 | true |
118 | null | 🔥
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| [{"ner":"28 октября","lemma":"28 октября","label":"DATE","start_pos":194,"end_pos":204}] | NEUTRAL | rus | NOT SPAM | 50 | 0 | 0 | 0.968254 | 0.031746 | 0 | 2 | 7 | 3 | 0 | 16 | 1 | 6 | true |
118 | null | ОБЕЗВРЕЖИВАНИЕ НЕЙРОМЕДИАТОРОВ
С точки
зрения биохимии и физиологии нервной системы, важной задачей является не только синтезировать нейромедиаторы, но еще при этом их быстро обезвреживать и утилизировать.
Почему это важно? Потому что избыток нейромедиатора в синаптической щели приведет к чрезмерному возбуждению нейрона и его повреждению.
За обезвреживание и утилизацию отвечают два ключевых фермента:
1️⃣
Моноаминооксидаза (МАО)
Фермент МАО отщепляет от нейромедиатора аминогруппу -NH2, в результате чего нейромедиатор превращается в другое соединение - альдегид, который уже не возбуждает синаптические рецепторы. А аминогруппа выделяется в виде аммиака NH3.
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Поэтому нервная ткань сама является поставщиком продуктов азотистого обмена - аммиака!
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Метил-трансфераза (КОМТ)
Особенностью данного фермента является способность присоединять к нейромедиатору метильную группу - CH3, в результате чего метилированый нейромедиатор уже не выполняет своей функции.
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Кстати донором метильной группы является активная форма метионина -
S аденозин метионин (SAM).
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У всех этих ферментов есть свои коферменты, определенные особенности работы, но их сложно кратко сформулировать в одном посте,
поэтому более подробно и основательно будем разбирать эту тему на большом курсе по обмену белков и аминокислот.
А вам интересна эта тема? | https://t.me/simplebestbiochemistry/478?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,729,833,440 | 1,736,456,932 | 1,147 | 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| [{"ner":"ОБЕЗВРЕЖИВАНИЕ","lemma":"обезвреживание","label":"ORG","start_pos":0,"end_pos":14},{"ner":"НЕЙРОМЕДИАТОРОВ","lemma":"нейромедиаторов","label":"ORG","start_pos":15,"end_pos":30},{"ner":"Фермент МАО","lemma":"фермент мао","label":"PER","start_pos":432,"end_pos":443},{"ner":"1","lemma":"1","label":"NUM","start_pos":404,"end_pos":405},{"ner":"2","lemma":"2","label":"NUM","start_pos":487,"end_pos":488},{"ner":"3","lemma":"3","label":"NUM","start_pos":660,"end_pos":661},{"ner":"2","lemma":"2","label":"NUM","start_pos":753,"end_pos":754},{"ner":"3","lemma":"3","label":"NUM","start_pos":884,"end_pos":885}] | NEUTRAL | rus | NOT SPAM | 177 | 0 | 14 | 0.97807 | 0.02193 | 0 | 21 | 18 | 9 | 2 | 60 | 13 | 30 | true |
118 | null | Как защитить себя от солнца?
🌞
Когда до конца календарной зимы остаётся
меньше недели,
мы всё больше и больше ждём яркого согревающего солнца
🗓
Но с приходом солнечных дней у многих возникает вопрос —
как правильно защитить кожу от УФ-излучения?
Поэтому давайте выясним,
какие бывают солнцезащитные средства, по какому принципу они работают и что такое SPF?
Озоновый слой
, конечно, защищает нас от
самого опасного
спектра солнечного излучения, но до поверхности Земли доходят два типа УФ-лучей: малая часть
UVB-
и практически полностью
UVA-лучи.
Под воздействием первых наша кожа краснеет и даже может получить солнечный ожог, а вторые проникают в кожу глубже, ускоряя процесс
старения и разрушая её изнутри
💥
Существует два типа солнцезащитных фильтров, используемых в косметике:
физический и химический.
В кремах на основе
физических фильтров
частицы минералов действуют
как зеркало
на поверхности кожи, отражая UVB- и UVA-лучи. Самые распространённые физические фильтры это диоксид титана
TiO₂
(
Titanium Dioxide
) и оксид цинка
ZnO
(
Zinc Oxide
). Средства на их основе редко вызывают раздражение и подходят для чувствительной и детской кожи. Но к сожалению, они часто оставляют
белый налёт
после нанесения
👻
В средствах на основе
химических фильтров
специальные вещества проникают в поверхностный слой кожи и
преобразуют
солнечное излучение в безопасную тепловую энергию. В составе эти компоненты вы сможете встретить под названиями авобензон (
avobenzone
), мексорил (
ecamsule/mexoryl SX
), тиносорб (
tinosorb
), оксибензон (
oxybenzone
) и другие.
Такие фильтры отлично работают даже в небольшой концентрации,
равномерно
распределяются по коже и не оставляют следов. Но их недостатками являются возможные
аллергические реакции
и недостаточная эффективность против всего спектра УФ-излучения
🌤
Поэтому для максимальной защиты от солнца лучше использовать средства, в которых
сочетаются
физические и химические фильтры — именно такие сейчас встречаются всё чаще и чаще
👍🏻
А теперь о том, что такое SPF?
Фактор защиты от солнца —
SPF
— рассчитывается на основании того, сколько времени мы можем провести на солнце, когда наша кожа
защищена кремом,
до первых признаков загара (покраснения) по сравнению
с кожей без крема.
Если санскрин имеет SPF 30, то кожа покраснеет
в 30 раз медленнее,
чем если бы на ней вообще не было средства
👙
Важно отметить, что SPF разных средств
не складываются,
а считаются по высшему. Например, если вы нанесли сначала SPF 50, а потом SPF 30, то фактор защиты так и останется на отметке 50.
Но большой SPF нам в
большинстве случаев и не нужен.
Средство с SPF 30 уже блокирует
97%
солнечного излучения. Но ни один крем
не защищает на 100%.
Так что разница между SPF 15, SPF 30 и SPF 50 в целом не такая уж большая
☀️
Главная ошибка, которую допускают при использовании солнцезащитных средств, — это
недостаточное количество
наносимого крема. Рекомендуемая плотность покрытия — 2 мг средства на см² кожи (около
половины чайной ложки на лицо
). И не забывайте обязательно смывать его в конце дня
🙌🏻
А если вам кажется, что защита от солнца — это бесполезное занятие, то уточню, что помимо фотостарения УФ-излучение значительно повышает риск развития
меланомы и других злокачественных образований на коже
👁
Наслаждайтесь солнечными днями без риска для здоровья
😌 | https://t.me/ychemistry/984?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,724,655,938 | 1,736,456,932 | 1,150 | 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| NEUTRAL | rus | NOT SPAM | 508 | 0 | 27 | 0.958641 | 0.041359 | 0 | 56 | 56 | 19 | 19 | 138 | 30 | 83 | true |
118 | null | О рафинированном масле
🌻
Мало кто знает, но наша страна является
не только одним из лидеров по добыче нефти
, но и крупнейшим производителем
подсолнечного масла
— на долю России приходится около
25%
от всего мирового производства
🌏
В кулинарии у растительных масел особое применение — заправка салатов и жарка горячих блюд. Причём мы чётко понимаем, что
нельзя жарить
на масле прямого отжима, а добавлять рафинированное масло в греческий салат —
бессмысленная затея
. Но задумывались ли вы,
в чем разница
между рафинированными и нерафинированными маслами?
Какие этапы проходит то самое «масло для жарки», прежде чем попасть на сковородку?
Из сырья масло можно получить несколькими способами. Самое очевидное — это
холодный отжим
. Берём семена подсолнечника, очищаем от кожуры и под прессом выдавливаем масло, в котором сохраняются все полезные природные вещества. Более продвинутый вариант —
горячее прессование
. Чтобы более эффективно извлечь масло из семян, их предварительно обжаривают, при этом усиливается аромат, но часть натуральных компонентов утрачивается
🍳
И самое полное извлечение достигается наиболее
распространённым и дешёвым методом
—
экстракцией
. Сырьё после первичного прессования обрабатывается растворителями — бензином особой марки или гексаном. При этом масло из жмыха практически
полностью переходит в органические растворители
🧪
Но не стоит переживать, что на полках в продуктовых магазинах нам продают бензин в бутылках. После экстракции растворители полностью удаляются путём вакуумной отгонки.
Перечисленными способами получают
нерафинированные
масла, то есть такие, в которых в зависимости от исходного сырья сохранён запах, вкус, цвет и природные вещества. Их принято добавлять в готовые блюда для улучшения вкусовых качеств
🥗
Чтобы получить такое масло, которое сохранило
лишь консистенцию и смазывающий эффект
, его подвергают дальнейшим стадиям очистки
👀
На первом этапе проводят
гидратацию
— обработку небольшим количеством горячей (до 70 °С) воды. Содержащиеся в масле фосфолипиды при это выпадают в осадок, после чего отделяются на центрифугах. Эти вещества хоть и полезны, но не стабильны в масле. При длительном хранении они склонны выпадать в осадок, а при жарке на сковороде — гореть
🔥
На следующем этапе масло
обрабатывают фосфорной кислотой и щелочью
, чтобы нейтрализовать свободные жирные кислоты и отделить то, что не до конца ушло вместе с водой. Этот процесс по сути представляет собой
омыление
масла.
Натриевые соли жирных кислот
, образующиеся на данной стадии, являются основой хозяйственного мыла и напрямую продаются соответствующим компаниям-производителям бытовой химии
🧼
Третий этап —
отбеливание
. Масло пропускают через
адсорбенты
природного происхождения (специальные глины), которые поглощают красящие компоненты. Природная насыщенная окраска сменяется на бледно-жёлтую.
После отбеливания масло
вымораживают
для удаления
воска
, которым покрыто большинство масличных культур
🕯
При охлаждении воск образует осадок, который удаляют с помощью фильтра, получая на выходе прозрачное масло.
Завершающая стадия —
дезодорация
. В условиях вакуума масло обрабатывают струей горячего пара (230—240°С), при этом извлекаются последние пахучие вещества.
💨
И только пройдя все
круги ада
, растительное масло становится
обезличенным — без цвета, вкуса и запаха
. Но пригодным для жарки и приготовления продукции, где привкус растительного масла нежелателен, — майонез, маргарин и кондитерский жир
👩🏻🔬 | https://t.me/ychemistry/985?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,800 | 0 | 1,724,741,356 | 1,736,456,932 | 1,150 | 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| [{"ner":"России","lemma":"россия","label":"LOC","start_pos":171,"end_pos":177},{"ner":"30—24","lemma":"30—24","label":"DATE","start_pos":3142,"end_pos":3147},{"ner":"25","lemma":"25","label":"NUM","start_pos":195,"end_pos":197},{"ner":"70","lemma":"70","label":"NUM","start_pos":1972,"end_pos":1974},{"ner":"230","lemma":"230","label":"NUM","start_pos":3141,"end_pos":3144},{"ner":"240","lemma":"240","label":"NUM","start_pos":3145,"end_pos":3148}] | NEUTRAL | rus | NOT SPAM | 488 | 0 | 7 | 1 | 0 | 0 | 73 | 63 | 23 | 5 | 162 | 17 | 84 | true |
118 | null | Веселящий газ. Как работает наркоз?
😷
В настоящее время почти невозможно представить даже незначительное хирургическое вмешательство без применения
анестезии
. Она необходима
не только
для того, чтобы
пациент не чувствовал боли
, но и
чтобы убрать напряжение мышц и других тканей
, мешающее работе хирурга. Только мало кто знает, что применение современных анестезирующих препаратов
начиналось с открытия самых простых химических веществ
👩🏻🔬
Каким образом анестезия блокирует боль?
Если совсем просто, то сами по себе болевые ощущения
формируются в головном или спинном мозге
в ответ на
болевые импульсы
, идущие от специальных рецепторов по всему телу
🧠
Анестезия блокирует нервные окончания
, нарушая цепочку специальных биохимических реакций, — из-за этого болевой импульс не доходит до центральной нервной системы.
Местная анестезия
нарушает передачу импульса в определенном участке, а
общая
(именно её называют
наркозом
) полностью угнетает ЦНС, убирая болевую чувствительность по всему телу.
Одним из самых популярных веществ для ингаляционного наркоза является
оксид азота (I) N₂O (закись азота)
. Вскоре после его открытия на рубеже 17-18 веков было обнаружено, что вдыхание небольших количеств закиси азота сопровождается эффектом
опьянения, эйфории и появлением приступов смеха
. За эту особенность закиси азота дали еще одно название —
веселящий газ
.
Смекалистые умельцы уже на том этапе исторического развития нашли открытому газу альтернативное применение, вдыхая его на светских вечеринках.
Впрочем, мало что изменилось.
Воздушные шары с веселящим газом по-прежнему продают в клубах и на вечеринках. Но я настаиваю на том, чтобы вы не злоупотребляли закисью азота без медицинской необходимости
🤔
В
высоких концентрациях
оксид азота применяется в медицине для обеспечения хирургического наркоза во время мелких и крупных операций.
Другим популярным летучим веществом для ингаляционной анестезии является
диэтиловый эфир
. Вещество с простой химической формулой получило широкое распространение в анестезиологии благодаря
сильному эффекту и безопасности применения
. Выдающийся отечественный хирург
Н.И.Пирогов
первым в истории медицины начал оперировать в полевых условиях раненых с использованием диэтилового эфира в качестве обезболивающего.
В современной медицине используются различные комбинации анестезирующих веществ для достижения эффективного и безопасного наркоза. Помимо веществ
ингаляционного типа
, то есть тех, что вводятся через дыхательные пути (+ к упомянутым выше:
хлороформ, фторотан, изофлуран
), распространены
инъекционные вещества
— кетамин, производные барбитуровой кислоты и др.
🧪
Выбор
типа анестезии и препаратов
осуществляется
анестезиологом
на основе предварительных исследований. Именно он контролирует как состояние организма во время операции, так и режим подачи анестезирующих веществ.
Поэтому ни одно оперативное вмешательство не может обойтись без врача-анестезиолога
😉 | https://t.me/ychemistry/986?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 3,500 | 0 | 1,724,930,259 | 1,736,456,932 | 1,143 | 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| [{"ner":"2","lemma":"2","label":"NUM","start_pos":26,"end_pos":27}] | NEUTRAL | rus | NOT SPAM | 3 | 0 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | Если над свечой включить лазер, можно увидеть, как выглядит дым в разрезе. | https://t.me/chemistrytg2021/9481?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,805,200 | 1,736,456,933 | 1,124 | 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| null | NEUTRAL | rus | NOT SPAM | 12 | 0 | 0 | 1 | 0 | 0 | 0 | 3 | 0 | 0 | 4 | 2 | 3 | true |
118 | null | Реакция взаимодействия марганца окиси (IV) и перекиси водорода. | https://t.me/chemistrytg2021/9482?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,700 | 0 | 1,734,848,400 | 1,736,456,933 | 1,125 | 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| [{"ner":"2","lemma":"2","label":"NUM","start_pos":29,"end_pos":30}] | POSITIVE | rus | NOT SPAM | 4 | 0 | 0 | 0.75 | 0.25 | 0 | 1 | 1 | 0 | 0 | 1 | 0 | 0 | true |
118 | null | День в истории химии: Яков Сыркин
Ровно 130 лет назад в Минске родился
Яков Кивович Сыркин
(1894-1974) – советский физико-химик, академик АН СССР, специалист в области природы химической связи. В 1950-х в рамках «борьбы с идеологическими извращениями в вопросах химической теории» вместе с ученицей
Миррой Ефимовной Дяткиной
был изгнан из нескольких организаций, но в итоге пришел в ИОНХ АН СССР и был избран в академики АН СССР.
#деньвисториихимии
Материал подготовлен ИОНХ РАН для Виртуального музея химии при грантовой поддержке Минобрнауки России в рамках федерального проекта «Популяризация науки и технологий» | https://t.me/chemrussia/5104?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,400 | 0 | 1,733,398,176 | 1,736,456,933 | 1,124 | 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118 | null | Открыта регистрация для участия в юбилейной XV Конференции молодых учёных по общей о неорганической химии, организованной Советом молодых учёных Института общей и неорганической химии им. Н.С. Курнакова РАН
Приглашаем для участия студентов, аспирантов и молодых учёных, работающих в области общей и неорганической химии. Организационный взнос за участие в Конференции и публикацию в сборнике тезисов Конференции не взимается.
Секции конференции:
1. Новые неорганические материалы: методы получения, химическая диагностика и области применения;
2. Синтез, свойства и применение неорганических и координационных соединений;
3. Химическая технология: теоретические основы и процессы.
Основные даты:
- Регистрация и прием тезисов до 20 февраля 2025 г.
- Проведение Конференции 07-11 апреля 2025 г.
Лучшие доклады участников будут награждены дипломами Научного совета РАН по неорганической химии, а также редакций журналов: «Журнал неорганической химии», «Координационная химия» и «Теоретические основы химической технологии».
С более подробной информацией можно ознакомиться на официальном сайте Конференции:
https://kurnakov-conf.ru/
По всем возникающим организационным вопросам, а также по вопросам сотрудничества писать на e-mail: [email protected]
#конференция #ионх | https://t.me/chemrussia/5105?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 3,700 | 0 | 1,733,464,830 | 1,736,456,933 | 1,126 | 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118 | null | Директор ИОНХ РАН, чл.-к. РАН В.К. Иванов вошел в состав Комиссии РАН по экспертизе федеральных государственных образовательных стандартов и учебников в качестве председателя соответствующей группы при ОХНМ РАН.
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118 | null | Улучшение восстановления спектра в ультраскоростной ЯМР с использованием SPEN
В журнале Analytica Chimica Acta опубликована статья, посвященная улучшенному методу восстановления спектра для ультраскоростной "спатиотемпоральной" кодировки (SPEN) в двухмерной ЯМР спектроскопии. Статья, автором которой является группа ученых из Китая и Израиля, обсуждает проблему шума, возникающего при использовании метода переплетенной Фурье-преобразования (FT) для реконструкции спектра, а также предлагает новый метод для его устранения. Предложенный метод реконструкции эффективно использует данные SPEN и значительно улучшает чувствительность спектра. Экспериментальные результаты показывают, что это решение позволяет существенно улучшить качество данных ЯМР, делая их более четкими и легко интерпретируемыми. Это открывает новые возможности для более точного анализа молекулярных структур и компонентных составов в сложных смесях, особенно в исследованиях быстрых реакций.
https://doi.org/10.1016/j.aca.2024.343430 | https://t.me/chemrussia/5107?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,800 | 0 | 1,733,464,890 | 1,736,456,933 | 1,143 | 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118 | null | Лютефиск- скандинавское рыбное блюдо, которое готовится с помощью едкого натра. Сушеная треска или другая рыба 5 - 6 дней вымачивается в растворе гидроксида натрия, благодаря чему становится мягкой и нежной. Потом ее несколько дней вымачивают в воде и запекают.
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| [{"ner":"5","lemma":"5","label":"NUM","start_pos":111,"end_pos":112},{"ner":"6","lemma":"6","label":"NUM","start_pos":116,"end_pos":117}] | NEUTRAL | rus | NOT SPAM | 40 | 0 | 0 | 1 | 0 | 0 | 7 | 5 | 3 | 4 | 12 | 1 | 6 | true |
118 | null | Средняя летальная доза никотина для людей составляет 0,5 - 1,0 мг/кг, то есть при среднем весе 70 кг смертельная доза составит 35 - 70 мг. В одной сигарете содержится от 0,7 до 1,4 мг никотина, значит 35 - 60 сигарет могут убить, если их выкурить одну за другой. Однако стоит учесть, что не весь никотин попадает в легкие, и для гарантированной смерти придется выкурить больше. Если же стоит задача убиться каплей никотина, то расчет следующий: одна капля содержит приблизительно 50 мг никотина, значит 1 - 1,5 капель вполне будет достаточно для того, чтобы убить человека. А чтобы убить лошадь понадобится 2 - 6 капель никотина (100 - 300 мг). Любите животных и помните, что никотин - это яд.
Подробнее про никотин можно прочитать здесь
https://t.me/incredible_chemistry/32 | https://t.me/incredible_chemistry/305?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,800 | 0 | 1,688,360,400 | 1,736,456,933 | 1,124 | 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| NEUTRAL | rus | SPAM | 125 | 0 | 2 | 0.993197 | 0.006803 | 0 | 8 | 23 | 2 | 25 | 33 | 7 | 20 | true |
118 | null | Друзья, наша подписчица ведет свой канал по химии и это прекрасно! Если Вам зайдет, подпишитесь и поддержите девушку! | https://t.me/incredible_chemistry/306?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 1,900 | 0 | 1,688,445,515 | 1,736,456,933 | 1,124 | 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| null | POSITIVE | rus | NOT SPAM | 18 | 0 | 0 | 1 | 0 | 0 | 1 | 4 | 2 | 0 | 5 | 0 | 4 | true |
118 | null | БЕЛКИ КРОВИ. Глобулины
Итак, на прошлой неделе мы поговорили с вами про альбумины и узнали про их особенности и функции!
Но в плазме крови существует еще одна большая группа белков -
глобулины
.
Какими свойствами обладают глобулины?
1️⃣
Имеют более высокую молекулярную массу, около 100 кДа (килодальтон) по сравнению с альбуминами (69 кДа).
2️⃣
Имеют слабый отрицательный или нейтральный заряд.
Именно поэтому глобулины вносят слабый вклад в поддержание онкотического давления (слабо притягивают воду), хуже растворяются в воде и проще выпадают в осадок.
❗️
Именно на свойстве глобулинов легко выпадать в осадок основаны многие диагностические пробы, например, Тимоловая - маркер повреждения печени.
Глобулинов чрезвычайно много, они делятся на 4 фракции, и каждый конкретный белок выполняет специфическую функцию, например, транспортирует витамин D, ион железа, формирует тромб и так далее.
👨⚕️
А теперь ответ на вопрос, что будет с действием лекарства, если снижено количество альбумина в крови?
Если у пациента низкое количество альбуминов в крови, то свободная, несвязанная фракция препарата оказывается в более высокой концентрации, а соответственно оказывает более активное фармакологическое действие.
Это обязательно нужно учитывать у пациентов со сниженным белком в крови!
Вот такая вот арифметика
😇
🩸
А что вы знаете про глобулины крови? | https://t.me/simplebestbiochemistry/473?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,729,493,219 | 1,736,456,933 | 1,124 | 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| [{"ner":"БЕЛКИ КРОВИ","lemma":"белки крови","label":"ORG","start_pos":0,"end_pos":11},{"ner":"Глобулинов","lemma":"глобулинов","label":"PER","start_pos":701,"end_pos":711},{"ner":"1","lemma":"1","label":"NUM","start_pos":233,"end_pos":234},{"ner":"100","lemma":"100","label":"NUM","start_pos":283,"end_pos":286},{"ner":"69","lemma":"69","label":"NUM","start_pos":333,"end_pos":335},{"ner":"2","lemma":"2","label":"NUM","start_pos":342,"end_pos":343},{"ner":"4","lemma":"4","label":"NUM","start_pos":746,"end_pos":747}] | NEUTRAL | rus | NOT SPAM | 193 | 0 | 5 | 0.996032 | 0.003968 | 0 | 22 | 22 | 7 | 4 | 63 | 17 | 38 | true |
118 | null | АМИНОКИСЛОТЫ И НЕЙРОМЕДИАТОРЫ
Мы все с вами прекрасно знаем, что аминокислоты являются структурным материалом для синтеза белков, но кроме этого аминокислоты имеют индивидуальные специфические пути метаболизма, и один из них -
превращение в нейромедиаторы
.
Ключевые примеры:
✅
триптофан превращается в серотонин;
✅
тирозин превращается в дофамин и норадреналин;
✅
глутамат метаболизируется в в ГАМК;
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При этом для работы ферментов, катализирующих данные процессы, обязательно требуется витамин B6 -
пиридоксальфосфат
.
⚠️
Как именно работает этот механизм мы будем разбирать на большом курсе по обмену белков и аминокислот, участие в котором открывается в понедельник - 28 октября!
Буду рад вашим реакциям и обратной связи!
😇 | https://t.me/simplebestbiochemistry/475?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,729,575,534 | 1,736,456,933 | 1,128 | 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| [{"ner":"АМИНОКИСЛОТЫ","lemma":"аминокислоты","label":"ORG","start_pos":0,"end_pos":12},{"ner":"28 октября","lemma":"28 октября","label":"DATE","start_pos":672,"end_pos":682},{"ner":"6","lemma":"6","label":"NUM","start_pos":497,"end_pos":498}] | NEUTRAL | rus | NOT SPAM | 105 | 0 | 5 | 0.992647 | 0.007353 | 0 | 8 | 12 | 8 | 1 | 34 | 3 | 15 | true |
118 | null | Как сделать бомбы для ванны своими руками?
🛁
Если вы любите устраивать домашние спа-процедуры, принимать расслабляющие ванны, или просто фанатеете от
бомбочек
из Lush, но не готовы выкладывать за них предложенную цену, то данный пост будет для вас
актуальным
.
Он в любом случае будет полезным, потому что всё, что связано с химией — это интересно
👩🏻🔬
Прогуливаясь в торговом центре мимо стендов со средствами для душа, я обратила внимание на
бомбы для ванны
. Вернее, на ту
цену
, за которую предлагают приобрести довольно-таки
примитивную химическую смесь
, учитывая, что её можно приготовить из
«кухонных»
реактивов. Хотя поспорить не могу,
пахнут они
потрясающе и в воде выглядят эффектно
✨
Основа любой бомбочки для ванны — это два компонента.
Пищевая сода и лимонная кислота
. Именно благодаря их взаимодействию получается тот самый
бурлящий и пузырящийся эффект
🌊
Пищевая сода — это кислая соль угольной кислоты с формулой NaHCO₃
. В составах ей приписывают разные наименования:
бикарбонат натрия, гидрокарбонат натрия, натрий двууглекислый
или пищевая добавка под номером
E500 (ii)
. Это всё названия одного и того же вещества
🤔
Лимонная кислота — это слабая органическая кислота
, используемая как
консервант
и
регулятор кислотности
в пищевой промышленности. При взаимодействии с пищевой содой она вытесняет гидрокарбонат-ион в виде
угольной кислоты
, которая
не устойчива
в растворе и мгновенно распадается на
углекислый газ CO₂ и воду H₂O
. Наверное, это один из самых простых типов взаимодействия, который только можно представить. Выделяющийся
углекислый газ как раз и образует мелкие пузырьки и шипение
💨
На этой реакции основано использовании бикарбоната натрия в пищевой промышленности в качестве
разрыхлителя
🍞
Хозяйки добавляют соду в тесто, а содержащиеся в нём кислые компоненты (
уксус и молочная кислота
) аналогичным образом взаимодействуют с гидрокарбонатом натрия.
Выделяющийся углекислый газ вспучивает тесто и делает его пористым и воздушным
🍰
А теперь к методике изготовления бомбочек для ванны
. В качестве базы используем смесь
2 частей пищевой соды и 1 части лимонной кислоты
(можно перемолоть сухие компоненты, чтобы избежать попадания крупных кусков).
А дальше включаем фантазию
🧙🏻♀️
Можно добавить к смеси несколько капель
пищевых красителей
, создавая узоры на самой бомбочке. Тогда непосредственно во время использования мы получим цветную пену и окрашенную воду
🌈
Приятным дополнением будет несколько капель
эфирных масел
с вашим любимым ароматом. Какую-то глобальную пользу для кожи они вряд ли принесут, но приятный запах в ванной уж точно обеспечат
🌺
За ароматическое сопровождение спа-процедуры могут отвечать сухие измельченные травы или натуральные компоненты: мёд, цедра лимона или апельсина, масло какао, молотый кофе, сухое молоко или сливки
🍯
После создания неповторимой рецептуры смесь стоит
утрамбовать в шарообразные формочки
, при необходимости сбрызнуть водой из пульверизатора для лучшего склеивания и
оставить на 4-5 часов в сухом месте
. После полного затвердевания бомбы можно отложить на пару дней или использовать сразу по назначению
🛀🏻
Уверена, бомбы для ванны у вас получатся не хуже, чем на полках в магазине, а сам процесс принесет удовольствие и позволит почувствовать себя в роли химика-технолога, разрабатывающего рецептуру нового средства для ухода за телом
⚗️ | https://t.me/ychemistry/978?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,723,706,701 | 1,736,456,933 | 1,124 | 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| [{"ner":"Lush","lemma":"lush","label":"ORG","start_pos":162,"end_pos":166},{"ner":"цедра лимона","lemma":"цедра лимон","label":"PER","start_pos":2711,"end_pos":2723},{"ner":"₃","lemma":"₃","label":"NUM","start_pos":936,"end_pos":937},{"ner":"500","lemma":"500","label":"NUM","start_pos":1082,"end_pos":1085},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1438,"end_pos":1439},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1448,"end_pos":1449},{"ner":"2","lemma":"2","label":"NUM","start_pos":2059,"end_pos":2060},{"ner":"1","lemma":"1","label":"NUM","start_pos":2083,"end_pos":2084},{"ner":"4","lemma":"4","label":"NUM","start_pos":2969,"end_pos":2970},{"ner":"5","lemma":"5","label":"NUM","start_pos":2971,"end_pos":2972}] | NEUTRAL | rus | NOT SPAM | 495 | 0 | 7 | 0.990566 | 0.009434 | 0 | 66 | 57 | 23 | 10 | 167 | 23 | 73 | true |
118 | null | Чем опасны инертные газы?
🎈
Думаю, многие из вас хотя бы раз в жизни вдыхали
шары с гелием
, чтобы наложить на свой голос весёлый звуковой эффект.
Надеюсь, что после прочтения сегодняшнего поста вам будет, о чём задуматься, прежде чем сделать это снова
🤔
Еще со школы мы знаем об
элементах восьмой группы таблицы Менделеева — благородных или инертных газах,
— которые ни с чем не реагируют и ассоциируются у нас в голове с
безопасными
. Есть ряд так называемых
физиологически инертных газов
, которые не вступают в химические реакции со средой нашего организма. Если
угарный газ CO
прочно связывается с гемоглобином в крови,
хлор Cl₂ и фосген COCl₂
вызывают сильнейший ожог лёгочной ткани и разрушают алвьеолы, то
азот N₂, благородные газы
(гелий He, неон Ne, аргон Ar, криптон Kr) и другие инертные при обычных условиях соединения (например,
гексафторид серы SF₆
)
не вызовут такого разрушающего эффекта
.
Их опасность скрывается в другом
👀
Вдыхаемый нами воздух в норме содержит
78% азота N₂, 21% кислорода O₂ и 1% составляют все остальные газы
— углекислый CO₂, аргон Ar и другие. Когда мы вдыхаем избыток инертного газа, он выступает в роли
«разбавителя»
, уменьшая содержание кислорода в воздухе и, соответственно, в крови.
Развивается гипоксия
😨
Вдыхая воздух, в котором кислорода содержится
в два раза меньше
, человек чувствует сильное головокружение, он теряет возможность объективно оценивать происходящее, возрастает пульс и частота дыхания, синеют губы
🥴
При концентрации кислорода в воздухе
от 4 до 6% потеря сознания наступает через 40 секунд
, а
минуты
будет достаточно, чтобы наступила смерть
⏳
Всё коварство заключается в том, что физиологически инертные газы
не имеют запаха или вкуса и не вызывают болезненных ощущений при вдыхании
. Когда наступает дискомфорт, связанный с недостатком кислорода, человек
не успевает понять, с чем это связано
.
Из-за недостаточной информированности об удушающих свойствах азота и других инертных газов происходят
несчастные случаи
. От массовой потери сознания на вечеринке с жидким азотом до смерти в ходе криотерапии с использованием того же жидкого азота. Удушье гелием случается реже и в основном связано с его промышленным использованием.
Удушье азотом
является одним из методов
смертной казни
и используется для безболезненного оглушения животных на фермах.
Сегодняшний текст
не является
призывом отказаться от использования шаров с гелием и
не написан
с целью напугать вас.
Я хотела лишь напомнить, что понятие техники безопасности применимо к большинству ситуаций, даже когда мы имеем дело с безобидными на первый взгляд веществами
👩🏻🔬 | https://t.me/ychemistry/979?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,723,880,332 | 1,736,456,933 | 1,127 | 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| [{"ner":"Менделеева","lemma":"менделеев","label":"PER","start_pos":313,"end_pos":323},{"ner":"N₂","lemma":"n₂","label":"ORG","start_pos":719,"end_pos":721},{"ner":"CO₂","lemma":"co₂","label":"ORG","start_pos":1060,"end_pos":1063},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":632,"end_pos":633},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":647,"end_pos":648},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":720,"end_pos":721},{"ner":"₆","lemma":"₆","label":"NUM","start_pos":862,"end_pos":863},{"ner":"78","lemma":"78","label":"NUM","start_pos":981,"end_pos":983},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":992,"end_pos":993},{"ner":"21","lemma":"21","label":"NUM","start_pos":995,"end_pos":997},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1010,"end_pos":1011},{"ner":"1","lemma":"1","label":"NUM","start_pos":1014,"end_pos":1015},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":1062,"end_pos":1063},{"ner":"4","lemma":"4","label":"NUM","start_pos":1507,"end_pos":1508},{"ner":"6","lemma":"6","label":"NUM","start_pos":1512,"end_pos":1513},{"ner":"40","lemma":"40","label":"NUM","start_pos":1547,"end_pos":1549}] | NEUTRAL | rus | NOT SPAM | 399 | 0 | 7 | 0.97451 | 0.02549 | 0 | 45 | 58 | 20 | 9 | 120 | 11 | 61 | true |
118 | null | Почему вино игристое?
Считается, что пузырьки шампанского образуются вокруг небольших загрязнений на бокале. Однако эти естественные загрязнения обычно слишком малы, чтобы стать такими центрами образования пузырьков,
пузырьки же формируются
на
волокнах целлюлозы
, которые либо присутствуют в окружающей
воздушной пыли
, либо остаются после
натирания бокала
.
🍾
В ста миллилитрах шампанского, содержится около 20 миллионов пузырьков углекислого газа. Только
20% углекислого газа выходит из шампанского в виде пузырьков
. Остальное теряется при прямой диффузии из жидкости.
🥂
Когда пузырьки шампанского идут на поверхность
, с собой они несут
вкус и аромат соединений
, входящих в состав шампанского. Вот некоторые из них:
— Гамма-Декалактон - фруктовый, персиковый, сладкий;
— Метилдегидрожасмонат - сладкий, фруктовый, цветочный;
— Декановая кислота - согревающий, кислый;
— Этилмиристат - сладкий, восковатый;
— Пальмитолеиновая кислота - маслянистый, восковатый.
Приблизительно в
0,75 литровой бутылке шампанского
содержиться около
5 литров углекислого газа
. А давление в бутылке составляет 5-6 атмосфер. Для сравнения в большинстве автомобильных шин приблизительное давление от 1,5 до 2,5 атмосфер.
💨
Количество сахара
, добавляемого после вторичного брожения и выдержки, варьируют, получая
сорта
:
— doux - сладкое;
— demi-sec - полусухое;
— sec - сухое;
— extra sec - экстра-сухое;
— brut - самое сухое;
— extra brut/brut nature/brut zero - чрезмерно сухое (сахар или ликёр не добавляется вовсе).
⚡️ | https://t.me/ychemistry/980?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,724,055,246 | 1,736,456,933 | 1,124 | 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| [{"ner":"20","lemma":"20","label":"NUM","start_pos":410,"end_pos":412},{"ner":"20","lemma":"20","label":"NUM","start_pos":458,"end_pos":460},{"ner":"0","lemma":"0","label":"NUM","start_pos":983,"end_pos":984},{"ner":"75","lemma":"75","label":"NUM","start_pos":985,"end_pos":987},{"ner":"5","lemma":"5","label":"NUM","start_pos":1035,"end_pos":1036},{"ner":"5","lemma":"5","label":"NUM","start_pos":1095,"end_pos":1096},{"ner":"6","lemma":"6","label":"NUM","start_pos":1097,"end_pos":1098},{"ner":"1","lemma":"1","label":"NUM","start_pos":1183,"end_pos":1184},{"ner":"5","lemma":"5","label":"NUM","start_pos":1185,"end_pos":1186},{"ner":"2","lemma":"2","label":"NUM","start_pos":1190,"end_pos":1191},{"ner":"5","lemma":"5","label":"NUM","start_pos":1192,"end_pos":1193}] | NEUTRAL | rus | NOT SPAM | 215 | 0 | 2 | 0.957096 | 0.042904 | 0 | 31 | 21 | 4 | 10 | 63 | 7 | 58 | true |
118 | null | Химия изобразительного искусства
🎨
Если, глядя на картины известных художников, вы задумываетесь не только о том, какую мысль автор хотел донести до зрителя, но и о том,
из чего состоят живые мазки на полотне
, то нам определенно есть
о чем поговорить
. Даже если вы не увлекаетесь живописью — уроки ИЗО в школьные годы не обходят никого мимо, и
коробочка гуаши или медовой акварели
была у каждого.
Так что же входит в состав красок?
👩🏻🎨
Все художественные краски — масляные, акриловые, гуашевые, акварельные и др. —
состоят из пигмента и связующих компонентов
.
Начнём со
связующих веществ
— они необходимы для того, чтобы
скреплять частички сухого пигмента и образовывать надежный плотный слой краски
. Можно сказать, что именно
связующее вещество отличает один вид красок от других
, потому что оно отвечает за текстуру, плотность и другие характеристики материала
🧪
Например, в
художественной акварели
связующим веществом является водорастворимая
смола
растительного происхождения —
гуммиарабик
🌿
. К полученной клееобразной смеси добавляют
консервант
— фенол, — чтобы краски не покрывались плесенью, и пластификаторы. При растворении в воде акварель образует
взвесь мельчайшего пигмента
, который переносится на бумагу и создает эффект лёгкости и воздушности.
В
медовой акварели
(что очевидно из названия) в качестве связующего вещества используют продукты переработки мёда
🍯
Это позволяет избежать использования фенола, делает краски
безопасными для детского творчества
, но сказывается на цветопередаче и способности красок смешиваться и наслаиваться друг на друга.
Гуашь
по своему составу близка к акварели и относится к
водорастворимым краскам на клеевой основе
— камеди или декстрине. От акварели гуашь
отличается добавкой белил
в основу каждого цвета. Примесь белил придаёт гуаши высокую кроющую способность и матовую бархатистость, но при высыхании её
цвета выбеливаются
и заметно отличаются от еще влажной краски.
Совсем иначе ведут себя
акриловые краски
, которые при высыхании
темнеют
и представляют смесь пигмента, воды и полимеров акриловой кислоты. Акриловая краска
не просто высыхает
— в её слое проходит химическая реакция полимеризации по мере испарения воды
💧
Благодаря этому образуется
прочная плёнка
, которую после нанесения можно смыть только специальным растворителем.
И, наконец,
масляные краски
, связующим веществом в которых являются
специальные высыхающие масла
. Обычно используют
льняное масло
или
олифы
— плёнкообразующие вещества на основе растительных масел. Под влиянием воздуха, света и тепла такие масла густеют и в тонком слое
превращаются в твёрдую массу
. Так масляные краски прочно закрепляются на холсте, но на это им нужно гораздо больше времени, чем тем же акриловым
🖼
Все перечисленные выше виды красок
объединяет одно — пигменты
. Именно они отвечают за
цвет
🎨
Еще в древние времена человек научился
перетирать минералы
с целью получения красящих веществ. Так и по сей день —
большинство пигментов в художественных красках состоят из натуральных природных соединений
.
Здесь можно начать совсем другой разговор, потому что между различными пигментами возникают особые взаимодействия вплоть до того, что одни красящие вещества могут
разрушать
другие и
менять
их цвет.
Это почти отдельная химия
👩🏻🔬 | https://t.me/ychemistry/981?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,724,222,335 | 1,736,456,933 | 1,127 | 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| [{"ner":"ИЗО","lemma":"изо","label":"ORG","start_pos":300,"end_pos":303}] | NEUTRAL | rus | NOT SPAM | 480 | 0 | 4 | 1 | 0 | 0 | 60 | 69 | 27 | 3 | 139 | 25 | 73 | true |
118 | null | Почему нельзя выбрасывать батарейки в мусорку?
Наверняка вы слышали о том, что батарейки ни в коем случае нельзя выбрасывать в обычную мусорку и уж тем более на улицу. Говорят об этом не ради красного словца.
В любой батарейке содержаться такие элементы, как свинец, никель, кадмий, литий и ртуть. Самыми опасными для жизни человека является ртуть и кадмий. Второй элемент очень токсичен. Кадмий негативно влияет на работу почечной системы, костных тканей и печени.
Большинство людей считают, что ничего страшного не произойдёт, если они выбросят 1-2 батарейки. Действительно, уровень угрозы будет минимальный. Но что если кроме вас так же подумает ещё 10000 людей?
Согласно Гринпис, на свалках одной Москвы было обнаружено около 15 миллионов батареек, а радиус загрязнения окружающей среды равен одному квадратному метру на каждую. Не маленькая цифра, правда?
Итак, чем же грозит выброс батареек в мусорку? Батарейки или аккумуляторы в процессе коррозии начинают разрушаться и все токсичные вещества проникают прямиком в почву и грунтовые воды. Если батарейки сжечь
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вместе с прочим мусором, то токсины добираются до атмосферы.
Что происходит дальше — очевидно. Распространившись в почве, водоёмах и воздухе, токсичные вещества наносят серьёзный ущерб всему живому на планете. Они замедляют рост растений, попадают в организмы животных и, конечно, человека — вместе с водой, пищей животного и растительного происхождения и даже из вдыхаемого нами воздуха. Это всё может привести к раку и прочим болезням.
Помни, забота о планете начинается с тебя, начни прямо сейчас
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А я говорю вам спасибо за то, что дочитали, хорошей вам недели! | https://t.me/ychemistry/982?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,724,392,796 | 1,736,456,933 | 1,127 | 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| [{"ner":"Кадмий","lemma":"кадмий","label":"LOC","start_pos":389,"end_pos":395},{"ner":"Гринпис","lemma":"гринпис","label":"PER","start_pos":675,"end_pos":682},{"ner":"Москвы","lemma":"москва","label":"LOC","start_pos":701,"end_pos":707},{"ner":"10000","lemma":"10000","label":"DATE","start_pos":653,"end_pos":658},{"ner":"1","lemma":"1","label":"NUM","start_pos":547,"end_pos":548},{"ner":"2","lemma":"2","label":"NUM","start_pos":549,"end_pos":550},{"ner":"15","lemma":"15","label":"NUM","start_pos":730,"end_pos":732}] | NEUTRAL | rus | NOT SPAM | 246 | 0 | 2 | 1 | 0 | 0 | 24 | 31 | 17 | 7 | 77 | 17 | 46 | true |
118 | null | Несгораемая купюра
Спирты, такие как этиловый, легко воспламеняются. Этанол сгорает с образованием углекислого газа и воды:
C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O
Когда мы поджигаем купюру, горит на самом деле не она, а этиловый спирт. Хлорид натрия придает пламени желто-оранжевый цвет. Вода, которой смочена купюра, поглощает выделяющееся тепло. Но этого тепла недостаточно, чтобы полностью испарить воду. В результате весь спирт прогорает, пламя гаснет, а слегка влажная денежная купюра остается неповрежденной. | https://t.me/chemistrytg2021/9475?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,708,001 | 1,736,456,934 | 1,113 | 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| [{"ner":"Этанол","lemma":"этанол","label":"PER","start_pos":69,"end_pos":75},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":125,"end_pos":126},{"ner":"₅","lemma":"₅","label":"NUM","start_pos":127,"end_pos":128},{"ner":"3","lemma":"3","label":"NUM","start_pos":133,"end_pos":134},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":135,"end_pos":136},{"ner":"2","lemma":"2","label":"NUM","start_pos":139,"end_pos":140},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":142,"end_pos":143},{"ner":"3","lemma":"3","label":"NUM","start_pos":146,"end_pos":147},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":148,"end_pos":149}] | NEUTRAL | rus | NOT SPAM | 71 | 0 | 5 | 0.956522 | 0.043478 | 0 | 12 | 12 | 3 | 2 | 22 | 3 | 17 | true |
118 | null | Реакцию калия с соляной кислотой следует проводить при низких температурах, при комнатной - может произойти взрыв. Уравнение реакции 2K + 2HCl = KCl + H2. | https://t.me/chemistrytg2021/9476?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,718,801 | 1,736,456,934 | 1,128 | 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118 | null | Сила удара воды падающей с пожарного самолета.
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| null | NEUTRAL | rus | NOT SPAM | 8 | 0 | 0 | 1 | 0 | 0 | 1 | 1 | 0 | 0 | 5 | 0 | 2 | true |
118 | null | Coca - Cola на все случаи жизни | https://t.me/chemistrytg2021/9478?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,772,800 | 1,736,456,934 | 1,128 | 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| [{"ner":"Coca - Cola","lemma":"Coca - Cola","label":"ORG","start_pos":0,"end_pos":11}] | NEUTRAL | other | NOT SPAM | 7 | 0 | 0 | 0.714286 | 0.285714 | 0 | 0 | 0 | 0 | 0 | 2 | 0 | 0 | true |
118 | null | Умный болт
Индикатор цветом покажет насколько хорошо затянута гайка. Красиво, полезно, но слабо применимо из-за экономических факторов. | https://t.me/chemistrytg2021/9479?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,783,600 | 1,736,456,934 | 1,128 | 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| null | NEUTRAL | rus | NOT SPAM | 17 | 0 | 0 | 1 | 0 | 0 | 4 | 2 | 0 | 0 | 5 | 4 | 4 | true |
118 | null | Новые асимметричные фторированные хиноксалины
Ученые из Уральского федерального университета и Института органического синтеза им. И.Я. Постовского УрО РАН синтезировали серию новых 6-фтор- и 6-трифторметил-2,3-бис(5-арилтиофен-2-ил)хиноксалинов с помощью Pd-катализируемых реакций кросс-сочетания. Фотофизические свойства соединений были изучены в трех растворителях и в твердом состоянии. Установлено, что V-образные хиноксалины поглощают свет в видимом диапазоне и излучают в широкой области (от зеленого до оранжевого в толуоле). При этом полосы поглощения и испускания 6-CF₃-замещенных хиноксалинов смещены в красную область по сравнению с их 6-фтор-аналогами. Полярность растворителя незначительно влияет на полосу поглощения, в то время как полоса эмиссии претерпевает выраженный красный сдвиг и ослабление интенсивности. Химикам также удалось определить характер влияние внешних факторов, включая кислотность, присутствие воды и нитроароматических соединений, на поведение поглощения и испускания. Эксперименты были дополнены расчетом электронной структуры на основе квантово-химических методов.
Результаты исследования опубликованы в Journal of Photochemistry & Photobiology, A: Chemistry и могут быть использованы при разработке различных устройств органической электроники и хемосенсоров на основе хиноксалинов.
A.E. Kopotilova, M.A. Ivan’kina, E.S. Starnovskaya, T.N. Moshkina, D.A. Gazizov, I.N. Ganebnykh, E.V. Nosova, V.N. Charushin. Asymmetric fluorinated 2,3-bis(5-arylthiophen-2-yl)quinoxalines: Synthesis and photophysical properties. Journal of Photochemistry and Photobiology A: Chemistry. V. 461, 2025, 116161.
https://doi.org/10.1016/j.jphotochem.2024.116161
Источник:
ИОС УрО РАН
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118 | null | На сайте Научной электронной библиотеки
Elibrary.ru
опубликован очередной номер журнала «Теоретические основы химической технологии» (том 58, № 3, 2024 г.)
Содержание выпуска со ссылками на статьи:
XXV Международная конференция по химическим реакторам ХИМРЕАКТОР-25.
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Кук Х.Г., Шишанов М.В., Досов К.А., Яшунин Д.В., Большаков И.А., Морозов Н.В.
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Экспериментальное исследование гидродинамики и массообмена в микроканалах для проектирования микрореакторов и микроэкстракторов.
Ягодницына А.А., Ковалев А.В., Бильский А.В.
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Двухуровневое моделирование кинетики фазообразования при синтезе композита из порошков Ti-Al-Fe2O3 в SD-технологии.
Князева А.Г., Крюкова О.Н.
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Ивашкина Е.Н., Назарова Г.Ю., Дементьев А.Ю., Чузлов В.А., Сладков Д.Ю., Самойлов Е.Р., Григораш М.С.
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Кривцова Н.И., Герасимова Н.Н., Туралин К.Н., Кривцов Е.Б., Судаков Д.О.
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Флисюк О.М., Марцулевич Н.А., Мешалкин В.П., Лихачев И.Г.
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Гидрофобные эвтектические растворители на основе спиртов и камфоры в экстракции Fe(III) из солянокислых растворов.
Кожевникова А.В., Зиновьева И.В., Заходяева Ю.А., Вошкин А.А.
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Модели Навье-Стокса и Дарси-Бринкмана для синтеза микронных частиц магний-цинкового феррита.
Марков А.А.
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Гаспарян М.Д., Грунский В.Н., Мочалов Ю.С., Суханов Л.П., Титов А.В., Тищенко С.В., Обухов Е.О.
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https://elibrary.ru/item.asp?id=74503451
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118 | null | Трансформация диоксида церия в фосфатных растворах
Ученые из Московского государственного университета им. М.В. Ломоносова, Института общей и неорганической химии им. Н.С. Курнакова РАН и Национального исследовательского центра «Курчатовский институт» подробно изучили взаимодействие диоксида церия с растворами фосфатов – солей, имеющих важнейшее промышленное и биохимическое значение. Более двух лет исследователи наблюдали за трансформациями оксида церия и тщательно фиксировали концентрацию церия в растворе. Выявлено, что некоторые фосфатные соединения церия (IV), которые ранее синтезировали искусственным образом и исключительно при высоких температурах, могут образовываться и в условиях, приближенных к природным. Химикам также удалось обнаружить, что в присутствии фосфат-ионов в растворе диоксид церия способен превращаться в новое, ранее неизвестное соединение, причем скорость этого превращения зависит от размера частиц оксида. Полученный новый двойной фосфат натрия-церия(IV) обладает высокой термодинамической устойчивостью.
Результаты работы, выполненной при поддержке РНФ (грант № 22-73-10056), опубликованы в высокорейтинговом журнале Chemosphere, открывают новые возможности неорганической химии соединений церия и способствуют пониманию поведения в природных условиях химических аналогов церия – радиоактивных тория, урана, нептуния и плутония.
Tatiana V. Plakhova, Maria A. Vyshegorodtseva, Irina F. Seregina, Roman D. Svetogorov, Alexander L. Trigub, Daniil A. Kozlov, Alexander V. Egorov, Maria D. Shaulskaya, Dmitry M. Tsymbarenko, Anna Yu. Romanchuk, Vladimir K. Ivanov, Stepan N. Kalmykov. Unexpected nanoscale CeO2 structural transformations induced by ecologically relevant phosphate species. Chemosphere. V. 368, 2024, 143664.
https://doi.org/10.1016/j.chemosphere.2024.143664
Пресс-релиз опубликован на сайте
Научная Россия
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118 | null | #органика #природное
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| [{"ner":"06-25","lemma":"06-25","label":"DATE","start_pos":49,"end_pos":54},{"ner":"25","lemma":"25","label":"NUM","start_pos":52,"end_pos":54}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | Природа химических веществ непосредственно влияет на скорость химической реакции. Реакция окисления железа (образование ржавчины) длится годами, а, например, нейтрализация соляной кислоты гидроксидом натрия протекает практически мгновенно. | https://t.me/incredible_chemistry/301?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,687,842,355 | 1,736,456,934 | 1,129 | 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| null | NEUTRAL | rus | NOT SPAM | 26 | 0 | 0 | 1 | 0 | 0 | 3 | 3 | 0 | 0 | 14 | 4 | 7 | true |
118 | null | 📌
Учебная программа курса по обмену белков и аминокислот
Коллеги, публикуем для вас готовую учебную программу, состоящую из трех основных и одного дополнительного практического модуля.
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⤵️ | https://t.me/simplebestbiochemistry/467?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,729,225,117 | 1,736,456,934 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 42 | 0 | 0 | 1 | 0 | 0 | 7 | 6 | 4 | 2 | 10 | 0 | 5 | true |
118 | null | ЦЕНЫ НА КУРС
Подготовили
два тарифа:
✔️
Стандартный
Цена: 9900 ₽
Входят:
три модуля + ответы на вопросы в формате личных сообщений;
✔️
Расширенный
Цена: 12900 ₽
Входят:
три модуля + практический модуль + ответы на вопросы в формате личных сообщений;
* В
индивидуальном порядке
обсуждение оплаты в рассрочку; | https://t.me/simplebestbiochemistry/469?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,800 | 0 | 1,729,241,944 | 1,736,456,934 | 1,128 | 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| [{"ner":"ЦЕНЫ","lemma":"цены","label":"ORG","start_pos":0,"end_pos":4},{"ner":"12900","lemma":"12900","label":"DATE","start_pos":153,"end_pos":158},{"ner":"9900","lemma":"9900","label":"NUM","start_pos":58,"end_pos":62}] | NEUTRAL | rus | NOT SPAM | 49 | 0 | 4 | 1 | 0 | 0 | 7 | 3 | 0 | 5 | 19 | 1 | 14 | true |
118 | null | «Люблю я пышное природы увяданье,
В багрец и в золото одетые леса…»
🍂 | https://t.me/simplebestbiochemistry/471?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,500 | 0 | 1,729,334,134 | 1,736,456,934 | 1,124 | 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| [{"ner":"🍂","lemma":"🍂","label":"ORG","start_pos":68,"end_pos":69}] | POSITIVE | rus | NOT SPAM | 13 | 0 | 1 | 1 | 0 | 0 | 0 | 4 | 1 | 0 | 5 | 0 | 4 | true |
118 | null | Зачем лёд посыпают солью?
❄️
Каждую зиму мы наблюдаем, как на утро после ночных заморозков сотрудники коммунальных служб усиленно
посыпают реагентами застывшие дороги и тротуары
. Интуитивно мы понимаем, для чего они это делают, но химические процессы, стоящие за методом борьбы с гололёдом, вряд ли были известны... До настоящего момента
👩🏻🔬
В свойствах многокомпонентных систем есть интересная закономерность:
температура плавления смеси веществ ниже, чем температура плавления каждого из чистых компонентов по отдельности
. Мы знаем, что температура плавления льда 0℃. Температура, при которой плавится твердый хлорид натрия NaCl около 800℃. А если к воде постепенно добавлять соль, то
вода начнёт превращаться в лёд при температуре заметно ниже 0℃
. И достигнув определенной пропорции мы получим раствор, который превращается в лёд
только при -21℃
(смотри диаграмму).
Ощутимо, правда?
На этом и основан метод борьбы с гололёдом
💡
Если посыпать лёд солью, температура его плавления понизится, и он начнёт таять
. Стоит учитывать, что если температура воздуха ниже -21℃, то лёд так и останется в твёрдом состоянии, ведь даже в смеси с солью он находится при температуре ниже точки замерзания.
Поэтому, если вы видите, как в лютые заморозки кто-то посыпает лёд солью, то знайте, что он делает это зря
. Данный способ работает в мягких зимних условиях, когда столбик термометра не опускается ниже определенной температуры
🌡
Точка на диаграмме, которая отражает минимум температуры замерзания смеси, называется
точкой эвтектики
, а сама температура —
криогидратной
. Необходимым условием существования эвтектической точки является
наличие трёх фаз
: твердая соль, лёд и раствор данного состава. Поэтому температура не будет достигать минимального значения, если исчезнет одна из фаз (растворится вся соль или растает весь лёд)
🤔
Помимо поваренной соли в качестве добавки можно использовать другие вещества, причём криогидратная температура будет меняться. Смесь в определенных пропорциях воды с
калиевой селитрой KNO₃
замерзает при -10,9℃, с
хлоридом магния MgCl₂
— почти при -34℃, а с
хлоридами кальция CaCl₂ и железа FeCl₂
— при -55℃.
Вы можете себе представить водный раствор, который замерзает при такой температуре?
❄️
На этом основано действие
охлаждающих смесей
— смесей льда с солями. Они буквально высасывают тепло из окружения. Их используют для поддержания низких температур в условиях эксперимента, или чтобы быстро охладить напитки
🍸
При работе с такими смесями можно получить холодовые травмы, поэтому нужно быть осторожным
.
К сожалению, использование зимой соляных реагентов
отрицательно
сказывается как на нашей жизни, так и на экологической обстановке. Соль вызывает коррозию многих поверхностей (автомобили, мосты, исторические памятники), портит обувь и сильно раздражает подушечки лап домашних любимцев во время прогулок
🐾
Хлориды в большом количестве попадают в сточные воды и почву, что оказывает
токсичное влияние
на растения и другие организмы. | https://t.me/ychemistry/975?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,723,185,781 | 1,736,456,934 | 1,128 | 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| 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| NEUTRAL | rus | NOT SPAM | 432 | 0 | 5 | 0.990991 | 0.009009 | 0 | 44 | 57 | 26 | 6 | 149 | 25 | 82 | true |
118 | null | Как производят серную кислоту?
H₂SO₄
— эта формула прекрасно вам знакома. Серную кислоту используют повсеместно:
для обработки руд
редких элементов и металлов,
в качестве электролита
в свинцовых аккумуляторах, для производства химических
волокон и взрывчатых веществ
🧨
Причём
бóльшее
количество получаемой серной кислоты уходит на производство
минеральных удобрений
— около 50% от мирового объема
🍂
Но откуда H₂SO₄ берётся в таких количествах?
Подземных источников серной кислоты в чистом виде вы
не обнаружите
на нашей планете — её не выкачивают из недр Земли, как в случае с нефтью и газом. Поэтому сегодня мы рассмотрим
промышленное производство серной кислоты
🏭
Природным сырьем для получения H₂SO₄ сейчас в основном служит
самородная сера
, меньшая доля приходится на другие минералы (сульфиды и сульфаты металлов) и газ — сероводород. Также используются
газы от переработки неочищенной нефти
, так как в ней содержится большое количество органических примесей серы
💨
На первой стадии сырье окисляют до диоксида серы SO₂
. Рассмотрим на примере обжига минерала
пирита
(дисульфида железа FeS₂), названного
«золотом дураков»
из-за внешнего сходства с драгоценным металлом
⭐️
FeS₂ + O₂ → Fe₂O₃ + SO₂
Полученный печной газ помимо интересующего нас диоксида серы содержит
кучу примесей
. Поэтому газ пропускают через серьезную
систему очистки
: крупную пыль удаляют с помощью устройства, подобного
центрифуге
, мелкую пыль отделяют с помощью
электрофильтра
, а от примесей воды избавляются в
сушильной башне
. Причём последняя представляет интересную конструкцию: диоксид серы в башню подаётся снизу, а сверху
распыляется концентрированная серная кислота
, которая, проходя через газ, беспощадно поглощает воду
💧
Далее необходимо еще сильнее окислить сернистый газ SO₂ до серного ангидрида SO₃
:
SO₂ + O₂ → SO₃
Причём этот процесс протекает
не так эффективно
, как сгорание пирита, поэтому для его ускорения применяют катализатор —
высший оксид ванадия V₂O₅
— наиболее экономичный и удобный вариант. Также очень важно поддерживать
оптимальную температуру и давление
🧭
При слишком низкой температуре реакция будет идти очень медленно, а слишком высокая вызовет разложение целевого продукта
🌡
И последняя стадия — поглощение серного ангидрида
. Но ни в коем случае не водой, как вы могли подумать.
Мы уже разбирали, что будет, если добавить концентрированную H₂SO₄ к воде.
В промышленных масштабах ситуация аналогичная: если добавлять серный ангидрид к воде, будет выделяться
колоссальное количество тепла
и вместо жидкости образуется
сернокислый туман
🔥
Поэтому серный газ поглощают уже готовой концентрированной серной кислотой
, получая
олеум — раствор серного ангидрида в серной кислоте
. Это очень едкая дымящая жидкость, которую в стальных цистернах транспортируют до места назначения.
И уже из олеума путём аккуратного разбавления получают растворы серной кислоты необходимой концентрации
⚗️ | https://t.me/ychemistry/976?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,500 | 0 | 1,723,353,899 | 1,736,456,934 | 1,129 | 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118 | null | Игра в конструктор. Как построить молекулу?
🧬
Со школы мы знаем, что молекулы образуются за счёт возникновения
химических связей
между атомами. Например, молекула воды H₂O существует благодаря ковалентным связям между атомами водорода H и кислорода O, в кристаллы поваренной соли NaCl сформированы за счет ионной связи между хлорид-ионами и натрием.
Но можно ли построить молекулу без химических связей?
Неожиданный ответ — отчасти
да, можно
. Этой идеей загорелись ученые еще в прошлом веке — и у них получилось синтезировать молекулы, разные части которых удерживаются исключительно
механически
. Давайте посмотрим, что это за молекулы.
Первыми были получены
катенаны
. Представьте себе звенья цепи — кольца, соединенные друг с другом
⛓
А теперь представьте молекулу, которая имеет аналогичное строение —
две циклические структуры, продетые друг в друга.
Длинная органическая цепочка состоит из атомов, соединенных химической связью, но между собой кольца соединены лишь
механически
— как два обруча, продетых друг в друга
🔗
На картинке молекула катенана схематически изображена
слева
.
Первые синтезы катенанов опирались на принципы вероятности. Бралась реакционная смесь из длинных молекул, которые могли при определенных условиях образовывать кольцо, и надеялись:
вдруг какая-то из них во время замыкания окажется продетой в уже существующий цикл и получится два звена, соединенных между собой
. Чисто статистически катенаны действительно образовывались — их удавалось зафиксировать, но содержание было чрезвычайно
мало
(около 0,0001%).
Другой тип молекул —
ротаксаны
— представляет собой структуры, состоящие из гантели и надетного на нее обруча
⭕️
В данном случае соскользнуть с перекладины кольцу мешают массивные группы на концах
📍
На картинке модель молекулы ротаксана находится
справа
.
Первые синтезы ротаксана так же были предложены на основе статистики: какая-то доля циклических молекул в смеси могла замкнуться вокруг гантелевидных молекул.
Существуют катенаны с большим числом звеньев и ротаксаны с большим числом надетых колец, а так же другие типы молекул с механическим взаимодействием:
узлы и молекулярные кольца
. Синтез подобных веществ представляет собой интересную задачу. В настоящее время никто не надеется на авось — разработаны новые методы направленного синтеза.
Также хочу сказать пару слов о применении полученных экзотических соединений. Ротаксаны стали объектом внимания и биологов, и нанотехнологов. Современные ученые рассматривают такие структуры как элементы молекулярных машин — уже построены ротаксановые молекулярные переключатели, «молекулярные мышцы» и нанороботы.
Наука не стоит на месте
👩🔬 | https://t.me/ychemistry/977?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,723,531,670 | 1,736,456,934 | 1,128 | 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| [{"ner":"NaCl","lemma":"nacl","label":"ORG","start_pos":280,"end_pos":284},{"ner":"Наука","lemma":"наука","label":"PER","start_pos":2608,"end_pos":2613},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":169,"end_pos":170},{"ner":"0","lemma":"0","label":"NUM","start_pos":1532,"end_pos":1533},{"ner":"0001","lemma":"0001","label":"NUM","start_pos":1534,"end_pos":1538}] | NEUTRAL | rus | NOT SPAM | 368 | 0 | 6 | 0.991379 | 0.008621 | 0 | 41 | 57 | 21 | 5 | 121 | 24 | 63 | true |
118 | null | Необыкновенная Bluetooth-колонка с ферромагнитной жидкостью, которая двигается и меняет форму в такт музыке. | https://t.me/chemistrytg2021/9470?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,621,600 | 1,736,456,935 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 13 | 0 | 0 | 0.941177 | 0.058824 | 0 | 2 | 2 | 1 | 0 | 5 | 0 | 2 | true |
118 | null | Эксперимент «Клеточка Траубе»
Биология и химия тесно связаны между собой. В этом познавательном опыте мы научимся с помощью химической реакции создавать искусственные клетки! | https://t.me/chemistrytg2021/9471?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,632,400 | 1,736,456,935 | 1,113 | 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118 | null | Искусство | https://t.me/chemistrytg2021/9472?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,675,600 | 1,736,456,935 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 1 | 0 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 0 | true |
118 | null | Золотые сталактиты
Очень красочный эксперимент, который, по сути, является разновидностью опытов «химические водоросли». Налейте в стакан раствор ацетата или нитрата свинца (концентрация около 10%), подкисленный азотной или муравьиной кислотой. На поверхность раствора аккуратно поместите пол шпателя кристаллов KI. Постарайтесь, чтобы кристаллики плавали на поверхности, а не падали на дно. Для этого хорошо использовать кристаллики пластинчатой формы. KI добавляют такое количество, чтобы его кристаллы покрыли 50-80% поверхности раствора. Необходимо тщательно избегать даже небольших сотрясений стакана и стола, на котором он стоит. Иначе опыт может не получиться. Кристаллики, которые попали на поверхность раствора моментально окрашиваются в желтый цвет – вследствие образования иодида свинца:
2KI + Pb(NO3)2 = РbI2 + 2KNO3 | https://t.me/chemistrytg2021/9473?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,686,400 | 1,736,456,935 | 1,113 | 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118 | null | Химический метод снятия краски с садовой лопатки. | https://t.me/chemistrytg2021/9474?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,700 | 0 | 1,734,697,200 | 1,736,456,935 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 7 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 0 | 4 | 0 | 1 | true |
118 | null | Президент России на встрече с участниками IV Конгресса молодых ученых заявил, что основное научное оборудование должно быть отечественным. В ходе встречи аспирант Института общей и неорганической химии им. Н.С. Курнакова
@chemrussia
Лев Краснов представил платформу
CoLab.ws
для коммуникации между исследователями и научными группами. Он также рассказал о совместном цифровом сервисе, дающем ученым доступ в режиме
«единого окна»
к трем платформам – Science-ID,
Colab.ws
и НАША ЛАБА. Объединение систем позволяет им подбирать решение под необходимый запрос – от мероприятий до оборудования.
«Все, кто работает по этому направлению, добились хороших результатов. У нас сегодня 1800 предприятий предлагают чуть ли не 12 тысяч изделий, реактивов и так далее, отечественных. Между иностранными производителями и продуктами для научного инструментария и отечественными резко изменилось соотношение», – сказал Владимир Путин.
#ионх #инфраструктуранауки | https://t.me/chemrussia/5097?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,800 | 0 | 1,733,203,854 | 1,736,456,935 | 1,114 | 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118 | null | Научный совет по неорганической химии РАН и Научно-образовательный центр ИОНХ РАН приглашают аспирантов и молодых ученых принять участие в работе Первой ежегодной зимней школы по физическим методам исследования неорганических веществ и материалов, которая пройдет с 17 по 21 февраля 2025 г. в Институте общей и неорганической химии им. Н. С. Курнакова РАН в очном формате.
У вас появится уникальная возможность расширить свои знания в передовых методах рентгеноструктурного и рентгенодифракционного анализа, сканирующей электронной микроскопии, молекулярной спектроскопии.
Основное внимание будет уделено современным достижениям в области исследования характеристик неорганических веществ и перспективных материалов применительно к их использованию в различных отраслях – от микроэлектроники до биомедицины.
Число участников ограничено. Стоимость участия в мероприятии – 20 000 рублей с человека.
По завершении школы всем участникам с высшим образованием и средним профессиональным образованием выдаётся удостоверение о повышении квалификации установленного образца.
Для участия необходимо подать заявку в свободной форме в Образовательный центр ИОНХ РАН по e-mail: [email protected]
#ионх #обучение | https://t.me/chemrussia/5098?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 2,700 | 0 | 1,733,203,859 | 1,736,456,935 | 1,114 | 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118 | null | #органика #парфюм
https://telegra.ph/Vse-vse-vse-o-nogotkah-06-12 | https://t.me/incredible_chemistry/295?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,686,632,400 | 1,736,456,935 | 1,115 | 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| [{"ner":"06-12","lemma":"06-12","label":"DATE","start_pos":60,"end_pos":65},{"ner":"12","lemma":"12","label":"NUM","start_pos":63,"end_pos":65}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | 👋
Привет, друзья! Мы рады представить вам фотоблог Александра Шрайфеля. Он не только виртуозный химик, но и талантливый фотограф, который умело улавливает красоту дикой природы и запечатлевает ее во всех ее проявлениях.
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Когда химия искусно переплетается с хобби, результаты бывают просто ошеломляющими. Александр, будучи настоящим химиком, находит вдохновение в красочных молекулах и разнообразных элементах природы. Он способен увидеть красоту, которую многие упускают из виду, и воплотить ее в своих фотографиях.
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На страницах фотоблога вы найдете потрясающие пейзажи, волшебные закаты, уникальные растения и животных в их естественной среде обитания. Эти снимки переносят нас в мир, где природа является настоящим произведением искусства, а каждая фотография - его неповторимым шедевром.
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Подготовьтесь к визуальному путешествию по прекрасному миру дикой природы, исполненному ярких красок и захватывающих моментов.
Подписывайтесь и наслаждайтесь:
https://t.me/shraifell | https://t.me/incredible_chemistry/296?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,900 | 0 | 1,686,645,791 | 1,736,456,935 | 1,113 | 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| [{"ner":"Александра Шрайфеля","lemma":"александр шрайфеля","label":"PER","start_pos":51,"end_pos":70},{"ner":"Александр","lemma":"александр","label":"PER","start_pos":307,"end_pos":316}] | NEUTRAL | rus | NOT SPAM | 130 | 0 | 0 | 0.993865 | 0.006135 | 0 | 19 | 17 | 10 | 0 | 45 | 3 | 24 | true |
118 | null | #природное #органика
https://telegra.ph/Krasitel-iz-chlenistonogogo-zhuka-06-14 | https://t.me/incredible_chemistry/298?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 3,300 | 0 | 1,686,805,200 | 1,736,456,935 | 1,115 | 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| [{"ner":"06-14","lemma":"06-14","label":"DATE","start_pos":74,"end_pos":79},{"ner":"14","lemma":"14","label":"NUM","start_pos":77,"end_pos":79}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.833333 | 0.166667 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | АЛЬБУМИНЫ. Транспортная функция
На прошлой неделе мы начали разговор про белки альбумины и
узнали,
что они ответственны за формирование онкотического давления плазмы крови.
❗️
Но есть и вторая важная функция -
транспортная!
Альбумины имеют в своем составе большое количество аминокислот глутамата, которые формируют отрицательный заряд и способны притягивать положительно заряженные молекулы.
Хоть белки альбумины и не являются крупными, но за счет их большого количества, в сумме, они формируют очень большую площадь поверхности, в которую встраиваются транспортирующиеся вещества.
❓
Что именно транспортирует альбумин?
✔️
пигмент билирубин
- одна молекула альбумина может одновременно связать 25-50 молекул билирубина;
✔️
длинноцепочечные жирные кислоты
– ключевая физиологическая функция, 6-8 штук на одну молекулу альбумина;
✔️
катионы
-
в основном Ca2+ и Mg2+, и другие металлы, например Hg+, благодаря большому количеству глутамата;
✔️
ж
елчные кислоты;
✔️
витамины;
✔️
гормоны
- альдостерон, прогестерон, гидрокортизон;
✔️
органические красители;
✔️
лекарственные вещества
- например, дигоксин, барбитураты, пенициллин, ацетилсалициловая кислота,
сердечные гликозиды;
Вот такие вот «белки-таксисты»
🔥 | https://t.me/simplebestbiochemistry/461?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,700 | 0 | 1,728,971,881 | 1,736,456,935 | 1,116 | 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| [{"ner":"АЛЬБУМИНЫ","lemma":"альбумины","label":"ORG","start_pos":0,"end_pos":9},{"ner":"молекулу альбумина","lemma":"молекула альбумин","label":"PER","start_pos":809,"end_pos":827},{"ner":"25-50","lemma":"25-50","label":"DATE","start_pos":695,"end_pos":700},{"ner":"50","lemma":"50","label":"NUM","start_pos":698,"end_pos":700},{"ner":"6","lemma":"6","label":"NUM","start_pos":792,"end_pos":793},{"ner":"8","lemma":"8","label":"NUM","start_pos":794,"end_pos":795},{"ner":"2","lemma":"2","label":"NUM","start_pos":855,"end_pos":856},{"ner":"2","lemma":"2","label":"NUM","start_pos":862,"end_pos":863}] | NEUTRAL | rus | NOT SPAM | 158 | 0 | 1 | 0.987805 | 0.012195 | 0 | 31 | 14 | 6 | 8 | 57 | 6 | 45 | true |
118 | null | СВЯЗЫВАНИЕ ЛЕКАРСТВ С БЕЛКАМИ ПЛАЗМЫ
Как мы узнали с вами в предыдущем уроке, альбумины - ключевые транспортные белки, которые связывают и перемещают в том числе и лекарственные препараты!
👨⚕️
Препараты, которые попадают в кровь, находятся соответственно в плазме в двух формах:
связанной
с белками альбуминами и
несвязанной
, т.е. свободной. При этом их отношение всегда индивидуально для конкретного лекарства.
❗️
При этом важно знать, что именно
несвязанная доля
лекарства будет оказывать терапевтический эффект. Чем меньше препарат связывается с альбумином, тем больший он оказывает эффект и наоборот.
💊
Например, парацетамол связывается с белками всего на 15%, а аспирин (ацетилсалициловая кислота) на 80%. В зависимости от этого и подбирается дозировка.
Если хотите узнать степень связывания с белками плазмы, читайте в аннотации к конкретному препарату в разделе фармакокинетика.
Та часть препарата, которая связалась с альбумином, будет в дальнейшем постепенно отщепляться от него.
❓
А теперь вопрос к вам, как будет распределяться лекарство, если количество белка в крови снижено? | https://t.me/simplebestbiochemistry/462?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,729,151,855 | 1,736,456,935 | 1,116 | 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| [{"ner":"15","lemma":"15","label":"NUM","start_pos":662,"end_pos":664},{"ner":"80","lemma":"80","label":"NUM","start_pos":708,"end_pos":710}] | NEUTRAL | rus | NOT SPAM | 155 | 0 | 7 | 1 | 0 | 0 | 16 | 19 | 12 | 4 | 42 | 9 | 30 | true |
118 | null | Разбираем с учениками обмен аминокислот, а также роль ферментов и коферментов в их метаболизме!
🔥
Кстати будем говорить об этом в предстоящем курсе по обмену белков и аминокислот! | https://t.me/simplebestbiochemistry/463?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,500 | 0 | 1,729,167,717 | 1,736,456,935 | 1,116 | 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| null | NEUTRAL | rus | NOT SPAM | 28 | 0 | 0 | 1 | 0 | 0 | 0 | 3 | 1 | 0 | 11 | 2 | 4 | true |
118 | null | Из чего делают пигменты?
Об
одном из двух основных компонентов
, входящих в состав красок, мы уже поговорили в
этом сочном посте
. Настало время окунуться в яркую палитру цветов. Только начнём с
ахроматических
, то есть чёрного, белого и всех оттенков серого между ними и, как всегда, с
точки зрения химии
👩🏻🔬
Думаю, вы с легкостью догадаетесь, из чего состоит
черный пигмент
🔳
Да, это одна из модификаций углерода —
сажа
. Она образуется в ходе
неполного сгорания
или
термического разложения
углеводородов и представляет собой
чистый углерод C
🔥
Почему неполного?
Если горение будет протекать в
избытке кислорода O₂
, то, как мы знаем, углеводороды сгорают с образованием
углекислого газа CO₂ и воды H₂O
. Но если процесс горения поддерживать при
недостатке кислорода
, то образуется ядовитый угарный газ CO и сажа С, которую осаждают из
коптящего пламени
на специальных охлаждаемых поверхностях. Например, много сажи образуется при сжигании
бензола
, который горит характерным коптящим пламенем
⚗️
Выбор пигмента
белого цвета
уже шире
🔲
. Вы наверняка слышали об одном из древнейших белых пигментов —
свинцовых белилах
(основный карбонат свинца
2PbCO₃·Pb(OH)₂
). Сейчас этот пигмент
запрещен
для использования в малярных работах из-за его
высокой токсичности
, но несколько веков назад люди не знали об опасности соединений свинца и добавляли его даже в косметику
☠️
. С помощью свинцовых белил дамы из высшего света добивались ровного и белоснежного цвета лица, нанося при этом
непоправимый вред коже и своему здоровью
.
Существенным недостатком свинцовых белил также было
взаимодействие с сероводородом H₂S
, содержащимся в небольших количествах в воздухе. При реакции свинца с серой образуется очень прочное соединение
черного цвета
—
сульфид свинца PbS
. В ходе необратимого процесса белый цвет на картинах постепенно темнел.
На смену свинцовым белилам пришли
цинковые белила
—
оксид цинка ZnO
. Благодаря своему
противовоспалительному
действию он вам может быть известен как основной компонент
цинковой мази
, которая как раз имеет белоснежный цвет.
В современных эмалях используют
титановые белила
—
диоксид титана TiO₂
, — которые по многим свойствам обыгрывают цинковые. Титановые белила обладают более сильной
кроющей
способностью и
не меняют
своего цвета со временем и при нагревании.
Но между цинковыми и титановыми белилами есть отличия помимо кроющей способности, существенные в работе художника
👩🏻🎨
Цинковые обладают
более холодным
слегка голубоватым оттенком, а титановые наоборот —
более теплым
и желтоватым. Поэтому в профессиональных наборах масляных красок так и сохранились эти два «оттенка» белого
🤷🏻♀️
Диоксид титана
не является
токсичным соединением и используется в качестве зарегистрированной
пищевой добавки E171
. В качестве
абразивного вещества
его добавляют, например, в зубную пасту
🦷
Оттенки серого
, очевидно, получают смешением белого и черного. Но известны и пигменты серого цвета, приготовленные из
металлического порошка
или графита. Например,
измельченный цинк или алюминий
.
О пигментах
хроматических
цветов, то есть оттенков цветового круга (красный, желтый, синий и др.) поговорим в следующий раз
🎨
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😉 | https://t.me/ychemistry/969?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,722,334,937 | 1,736,456,935 | 1,117 | 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118 | null | Как очищается водопроводная вода
У каждого в доме есть водопровод
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. Из него в наш дом поступает вода, которую мы очень часто используем не только для мытья посуды
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, но и для утоления жажды. Однако большинство людей не знают как очищается водопроводная вода. Поэтому сегодня об этом.
Сначала воду отбирают из рек, озер, водохранилищ или подземных резервуаров
⛲️
. Вся эта вода находится в заборе. После этого наступает механическая очистка воды. С помощью пропускания через крупную сетку из воды удаляют загрязнения большого размера
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. Механическая очистка делает воду безопаснее для других систем водоподготовки.
Следующий этап это добавление коагулянтов. Они способствуют слипанию дисперсных частиц, взвешенных в воде. В результате образуются частицы, от которых можно избавиться отстаиванием.
При медленном перемешивании небольшие частицы слипаются. При достижении определенного размера они оседают на дно, и от них можно избавиться отстаиванием.Не опавшие на дно частицы, отделяют фильтрованием через слои углерода, песка
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и гравия. Фильтрующий материал очищается током воды и прокачкой воздуха.
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Кислая вода может вызывать коррозию водопровода. Её пропускают через известковый фильтр до понижения кислотности. К воде с щелочной реакцией добавляют кислоты. Эта часть называется корректировка рН.
Далее следует стадия осаждения. В ней вода обрабатывается ортофосфатами
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, которые дают нерастворимые осадки с катионами кальция, магния и ряда тяжелых металлов, удаляя их из воды.
Затем вода обрабатывается хлором, который убивает микроорганизмы и вирусы, что препятствует распространению болезней, передающихся с питьевой водой(холера, тиф).
Хлор в воде из под крана остаётся для угнетения роста патогенов. Иногда вводят фторид-ионы для защиты от кариеса. После этого вода поступает из кранов в наш дом.
🚰 | https://t.me/ychemistry/970?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,722,496,299 | 1,736,456,935 | 1,117 | 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| [{"ner":"Хлор","lemma":"хлор","label":"PER","start_pos":1650,"end_pos":1654}] | NEUTRAL | rus | NOT SPAM | 259 | 0 | 5 | 1 | 0 | 0 | 19 | 38 | 15 | 1 | 104 | 11 | 42 | true |
118 | null | Водный баланс
Все мы знаем, что человек на 70-80% состоит из воды. Практически каждый наш орган содержит воду, где-то больше её, где-то меньше. Например, в крови – 83%, в костях – 15 — 20%, мозг, сердце, мышцы – 76%. Благодаря воде все биохимические реакции в нашем организме происходят в растворе. Если верить медицинским исследованиям, то нам нужно около 40 грамм воды на каждый килограмм нашего веса. Из-за этих данных многие считают, что если превысить суточную норму воды, то могут возникнуть не только отеки, но и хроническая усталость из-за недостатка солей. Но правда ли всё это? Сейчас расскажу.
Миф про 3 литра в день?
🤔
Это, действительно, рекомендуемое врачами суммарное количество воды при заболеваниях, требующих обильного питья.Почему популярные блогеры часто исключают из этого количества не только воду в супе, но даже чай и кофе? Как обычно, поверхностное знание хуже незнания. Есть такое понятие - осмотическое давление. Оно связано с мембранными процессами (в т.ч. в клетках организма) и зависит от количества растворенных в воде веществ. В организме оно почти постоянно. Чтобы разбавить кровь и другие жидкости осмотическое давление у поступающей воды должно быть меньше, чем в самом организме. Только такой водой можно нормально напиться.
💧
Если взять во внимание содержание веществ в чаях и прочем, то оказывается, что врачи правы, а блогеры - врут. 95% известных всем напитков имеют подходящий для регулярного питья состав.
Если солёность вашего бульона меньше, чем у морской воды, а чай - не 10% раствор сахара, то пейте на здоровье! Такая вода усваивается и нормально разбавляет жидкость в организме.
🍹
Единственное, что стоит избегать - это сладкую воду, особенно колу. Такой водой сложно напиться, хочется еще. Много сахара, около десяти чайных ложек на один литр жидкости. Пользы от такого напитка никакой.
Не забудьте, что лайк = спасибо за пост. Хорошей всем недели! | https://t.me/ychemistry/971?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,722,581,038 | 1,736,456,935 | 1,117 | 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| [{"ner":"70-80","lemma":"70-80","label":"DATE","start_pos":43,"end_pos":48},{"ner":"80","lemma":"80","label":"NUM","start_pos":46,"end_pos":48},{"ner":"83","lemma":"83","label":"NUM","start_pos":164,"end_pos":166},{"ner":"15","lemma":"15","label":"NUM","start_pos":180,"end_pos":182},{"ner":"20","lemma":"20","label":"NUM","start_pos":185,"end_pos":187},{"ner":"76","lemma":"76","label":"NUM","start_pos":212,"end_pos":214},{"ner":"40","lemma":"40","label":"NUM","start_pos":357,"end_pos":359},{"ner":"3","lemma":"3","label":"NUM","start_pos":613,"end_pos":614},{"ner":"95","lemma":"95","label":"NUM","start_pos":1374,"end_pos":1376},{"ner":"10","lemma":"10","label":"NUM","start_pos":1518,"end_pos":1520}] | NEUTRAL | rus | NOT SPAM | 294 | 0 | 1 | 1 | 0 | 0 | 28 | 33 | 8 | 16 | 92 | 23 | 64 | true |
118 | null | Как делали первые фотографии?
📸
Сейчас мы
не можем представить свою жизнь
без новых
селфи
в инстаграме*,
фотографий
с друзьями во время редких встреч и
фотосессий
на рекламных постерах. Но путь к цифровой фотографии и её массовому распространению
был очень сложен и интересен
.
А начиналось всё, как и положено, с химии
👩🏻🔬
Еще в
1727
году немецкий химик
Шульце
обнаружил
чувствительность солей серебра к свету
— они темнели на свету и оставались без изменений в темноте
💡
Например,
белый хлорид серебра
темнел под действием света за счёт образования
металлического серебра
:
AgCl + свет → Ag + Cl₂
Вскоре был предложен способ
закрепить
полученное изображение с помощью
раствора аммиака NH₃
, который
растворял
не засвеченный хлорид серебра:
AgCl + NH₃ → Ag(NH₃)₂Cl
Поскольку хлорид серебра удалялся, дальнейшее
действие света никак не влияло на изображение
🙅♀️
Следующим этапом в развитии фотографии стало появление
дагеротипии
— фотопроцесса на основе светочувствительности
йодида серебра AgI
. В качестве основы под фотографию использовалась
серебряная пластинка, обработанная парами йода
. Её помещали в прототип фотоаппарата —
камеру-обскура
🎥
Что из себя представляла камера-обскура?
Простой светонепроницаемый ящик с маленьким отверстием (от 0,1 до 5 мм в зависимости от фокусного расстояния), через которое внутрь проникали лучи света и попадали на экран с противоположной стороны
🎇
Свет
, падая на пластинку, покрытую йодидом серебра,
вызывал его разложение
по уже знакомой нам схеме:
AgI + свет → Ag + I₂
Полученное изображение было настолько слабым и незаметным, что человеческий глаз не мог его разглядеть, поэтому его называли
скрытым
🔍
Чтобы проявить скрытое изображение
пластинку помешали в камеру, наполненную
парами ртути Hg
, которые образовывали
амальгаму серебра
. Изображение усиливалось за счёт увеличения массы, то есть происходило его
проявление
👁
Чтобы
«закрепить»
изображение, нужно было
удалить светочувствительный йодид серебра
с поверхности. Для этого со временем стали применять
тиосульфат натрия Na₂S₂O₃
, который быстро растворял йодид серебра:
AgI + Na₂S₂O₃ → Na₃Ag(S₂O₃)₂ + NaI
В результате засвеченные места пластинки, покрытые сплавом ртути и серебра, рассеивали отражённый свет, а в теневых участках отражались окружающие предметы, как в зеркале
. Расположив готовый
дагерротип
напротив чёрного бархата, получали
позитивное
изображение — чёрно-белую картинку, где тени, как и положено, были черные, а светлые участки — белыми
🔘
В дальнейшем была изобретена
калотипия
— способ получения изображения с использованием
бумаги
, пропитанной йодидом серебра. А уже потом стали использовать
фотоэмульсии
—
смеси галогенидов серебра и фотографического желатина
🎞
Дальнейшие открытий позволили ускорить и упростить процесс получения изображений, что в итоге привело к
тиражированию
и появлению
моментальных фотографий
🖨
Такие снимки не требовали манипуляций в лаборатории, а светочувствительное покрытие обрабатывалось встроенными химреактивами
📷
После
«полароидных»
снимком наступила
эра цифровой фотографии
, развитие которой мы наблюдаем по сей день
👀
И это лишь очень малая часть всей предыстории, скрытой за миниатюрными мощнейшими фотокамерами в наших смартфонах
📱
*Instagram принадлежит Meta, которая признана экстремисткой организацией и запрещена в России. | https://t.me/ychemistry/972?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,400 | 0 | 1,722,672,544 | 1,736,456,935 | 1,113 | 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| 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| NEUTRAL | rus | NOT SPAM | 470 | 0 | 9 | 0.969937 | 0.030063 | 0 | 59 | 62 | 18 | 2 | 157 | 15 | 69 | true |
118 | null | Оловянная чума
☠
По мнению учёных, этот недуг сыграл решающую роль в нескольких особо важных исторических моментах.
Звучит интригующе?
Давай внимательно изучим причины и симптомы
оловянной чумы
, чтобы избежать её последствий
👩🔬
Начнём с понятия
аллотропии — способности одного химического элемента образовывать два и более простых веществ, отличающихся друг от друга по свойствам
. На примерах проще, поэтому сразу перейдем к ним.
Вам хорошо известны два вещества —
графит и алмаз
. Одно из них довольно-таки мягкое, блестяще-чёрного цвета и находится в грифеле карандаша
✏️
а другое является самым твёрдым кристалльно-прозрачным веществом и используется в роскошных ювелирных изделиях
💍
Несмотря на такие отличия, графит и алмаз образованы
одним химическим элементом
—
углеродом
— и являются его аллотропными модификациями. Разница обусловлена различным строением кристаллической решётки.
Аллотропия характерна для многих химических элементов, в том числе и для
олова
. При обычных условиях олово представлено
белой модификацией
— серебристый, мягкий и пластичный металл. Но если охладить белое олово до температуры ниже 13℃, то оно перейдёт в другую модификацию —
серое олово
. Из-за различий в кристаллической структуре данный переход сопровождается необычными явлениями —
металл рассыпается и крошится, теряя пластичность и мягкость
. И чем ниже температура, тем быстрее процесс
🌡
Соприкосновение серого олова и белого приводит к
«заражению»
последнего, то есть к ускорению аллотропного превращения. Совокупность этих явлений и была названа
«оловянной чумой»
💀
Оловянная чума — одна из причин
гибели экспедиции Скотта к Южному полюсу в 1912 году
. Путешественники осталась без горючего из-за того, что топливо просочилось из заянных оловом баков, поражённых «оловянной чумой»
⛵️
Некоторые историки указывают на оловянную чуму как на одну из причин
поражения армии Наполеона в России в 1812 году
— сильные морозы привели к превращению оловянных пуговиц на солдатских мундирах в порошок
💂♀
Кроме того, оловянная чума превратила в труху многие коллекции оловянных солдатиков
😧
Со временем учёные разработали способы борьбы с чумой — были найдены вещества, стабилизирующие белое олово, например,
висмут Bi
.
Вот так, зная химическую природу заболевания, можно найти эффективные методы борьбы с ним
👩🔬 | https://t.me/ychemistry/973?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,300 | 0 | 1,722,853,720 | 1,736,456,935 | 1,113 | 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| [{"ner":"Скотта","lemma":"скотт","label":"PER","start_pos":1617,"end_pos":1623},{"ner":"Южному полюсу","lemma":"южный полюс","label":"LOC","start_pos":1626,"end_pos":1639},{"ner":"Наполеона","lemma":"наполеон","label":"PER","start_pos":1870,"end_pos":1879},{"ner":"России","lemma":"россия","label":"LOC","start_pos":1882,"end_pos":1888},{"ner":"13","lemma":"13","label":"NUM","start_pos":1124,"end_pos":1126},{"ner":"1912","lemma":"1912","label":"NUM","start_pos":1642,"end_pos":1646},{"ner":"1812","lemma":"1812","label":"NUM","start_pos":1891,"end_pos":1895}] | NEUTRAL | rus | NOT SPAM | 333 | 0 | 1 | 0.997727 | 0.002273 | 0 | 55 | 41 | 9 | 10 | 108 | 15 | 54 | true |
118 | null | Блестящий Ванадинит
Pb5[VO4]3Cl — минерал, ванадат свинца с дополнительными анионами Cl- из надгруппы апатита. | https://t.me/chemistrytg2021/9466?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,546,001 | 1,736,456,936 | 1,128 | 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| [{"ner":"Ванадинит\nPb5[VO4]3Cl","lemma":"ванадинит\npb5[vo4]3cl","label":"ORG","start_pos":10,"end_pos":31},{"ner":"5","lemma":"5","label":"NUM","start_pos":22,"end_pos":23},{"ner":"4","lemma":"4","label":"NUM","start_pos":26,"end_pos":27},{"ner":"3","lemma":"3","label":"NUM","start_pos":28,"end_pos":29}] | NEUTRAL | rus | NOT SPAM | 14 | 0 | 0 | 0.882353 | 0.117647 | 0 | 1 | 1 | 0 | 0 | 6 | 0 | 3 | true |
118 | null | Парень собрал «тяговый луч» из мусора, найденного у себя дома, и теперь может заставлять левитировать небольшие предметы. | https://t.me/chemistrytg2021/9467?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 2,900 | 0 | 1,734,589,200 | 1,736,456,936 | 1,128 | 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| null | NEUTRAL | rus | NOT SPAM | 17 | 0 | 0 | 1 | 0 | 0 | 2 | 5 | 1 | 0 | 4 | 2 | 5 | true |
118 | null | Очищенная вода может охлаждаться до температуры ниже точки замерзания, но при взбалтывании немедленно замерзает. | https://t.me/chemistrytg2021/9468?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,600,001 | 1,736,456,936 | 1,120 | 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| null | NEUTRAL | rus | NOT SPAM | 14 | 0 | 0 | 1 | 0 | 0 | 2 | 3 | 0 | 0 | 5 | 1 | 2 | true |
118 | null | Шерл или чёрный турмалин - минерал подкласса кольцевых боросиликатов; разновидность турмалина, отличающаяся наличием в кристаллической решётке натрия и двухвалентного железа. | https://t.me/chemistrytg2021/9469?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,200 | 0 | 1,734,610,800 | 1,736,456,936 | 1,113 | 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| null | NEUTRAL | rus | NOT SPAM | 20 | 0 | 0 | 1 | 0 | 0 | 4 | 1 | 0 | 0 | 12 | 0 | 3 | true |
118 | null | Новые синтетически доступные и эффективные одноатомные электрокатализаторы получения высокочистого водорода
Учеными из Института общей и неорганической химии им. Н.С. Курнакова РАН, Института элементоорганических соединений им. А.Н. Несмеянова РАН, Института нефтехимического синтеза им. А.В. Топчиева РАН, Института органической и физической химии им. А.Е. Арбузова Казанского научного центра РАН и НИЦ «Курчатовский институт» были получены новые эффективные электрокатализаторы реакции выделения водорода, которые не содержат производные серы, известные как «каталитические яды». Полученные соединения с инкапсулированными ионами широко распространенных биометаллов – кобальта и железа – являются химически-устойчивыми моноатомными катализаторами (т.е. достигается максимальная эффективность использования металла, что соответствует принципам «экономии атомов»), перспективными для электрокаталитического получения высокочистого «зеленого» водорода для его использования в водородной и атомной энергетике, высокотехнологическом транспорте и передовой химической технологии.
Результаты работы, поддержанной грантом РНФ (№ 24-13-00230), опубликованы в журнале Process Safety and Environmental Protection (статья выбрана для Gold Open Access).
I.P. Limarev, S.A. Belova, A.V. Vologzhanina, P.V. Dorovatovskii, Y.H. Budnikova, V.V. Khrizanforova, G.K. Sterligov, S.A. Grigoriev, S.Yu. Kottsov, M.A. Teplonogova, V.K. Ivanov, A.G. Dedov, Y.Z. Voloshin. In a search of the single-atom electrocatalysts for hydrogen production: The first sulfur-free mono- and diphenanthrenyl-terminated iron and cobalt(II) clathrochelates versus their thioanalogs. Process Safety and Environmental Protection, 2024, 192, 285–299.
https://doi.org/10.1016/j.psep.2024.10.030
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Научный микроблог Минобрнауки России
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118 | null | На сайте Научной электронной библиотеки
Elibrary.ru
опубликован очередной номер Журнала неорганической химии (том 69, № 5, 2024 г.)
Содержание выпуска со ссылками на статьи:
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Замещенное производное клозо-додекаборатного аниона на основе пара-йод-L-фенилаланина - новое соединение для БНЗТ с возможностью визуализации методом КТ.
Рябчикова М.Н., Нелюбин А.В., Финогенова Ю.А., Скрибицкий В.А., Жданов А.П., Липенгольц А.А., Григорьева Е.Ю., Жижин К.Ю., Кузнецов Н.Т.
https://elibrary.ru/item.asp?id=74510498
Синтез и свойства неорганических соединений
Исследование фотокаталитической активности наноразмерного порошка и волокон на основе никель-цинкового феррита.
Иванин С.Н., Бузько В.Ю., Якупов Р.П., Сухно И.В.
https://elibrary.ru/item.asp?id=74510499
Координационные соединения
Структурное разнообразие комплексов бромидов редкоземельных элементов с ацетилмочевиной.
Акулинин П.В., Савинкина Е.В., Григорьев М.С., Белоусов Ю.А.
https://elibrary.ru/item.asp?id=74510500
Увеличение водорастворимости эфиров N-ацилзамещенных аминокислот как ингибиторов репликации современных штаммов вируса гриппа А in vitro за счет комплексообразования с цинком (II).
Гараев Т.М., Юдин И.И., Бреслав Н.В., Савочкина Т.Е., Крепкая А.С., Гребенникова Т.В., Никифорова С.Е., Мышлецов И.И., Авдеева В.В., Малинина Е.А.
https://elibrary.ru/item.asp?id=74510501
Теоретическая неорганическая химия
Квантово-химическое моделирование супертетраэдрических кристаллических структур, содержащих тетраэдры C4 И X4 (X = B, Al, Ga).
Гетманский И.В., Зайцев С.А., Коваль В.В., Миняев Р.М.
https://elibrary.ru/item.asp?id=74510502
Компьютерное моделирование свойств и структуры кристаллического 1,6-клозо-карборана (С2В4)N.
Зайцев С.А., Зайцева Ю.И., Гетманский И.В., Миняев Р.М.
https://elibrary.ru/item.asp?id=74510504
Спиновые свойства кремний-германиевых нанотрубок.
Дьячков Е.П., Меринов В.Б., Дьячков П.Н.
https://elibrary.ru/item.asp?id=74510505
#российскаянаука #ионх | https://t.me/chemrussia/5095?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemrussia | 1,100 | 0 | 1,733,203,839 | 1,736,456,936 | 1,118 | 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| NEUTRAL | rus | SPAM | 357 | 0 | 88 | 0.939623 | 0.060377 | 0 | 61 | 2 | 2 | 6 | 113 | 0 | 91 | true |
118 | null | Продолжение
Физические методы исследования
Термодинамические характеристики перфторциклогексаноата меди(1) C6F11COOCu.
Малкерова И.П., Каюмова Д.Б., Ямбулатов Д.С., Хорошилов А.В., Сидоров А.А., Алиханян А.С.
https://elibrary.ru/item.asp?id=74510506
Физико-химический анализ неорганических систем
Взаимодействие в системе Li+,Na+,K+||F-,Cr и 3D-модель стабильного треугольника LiF-NaCl-KCl.
Бурчаков А.В., Гаркушин И.К., Егорова Е.М., Емельянова У.А., Финогенов А.А.
https://elibrary.ru/item.asp?id=74510507
Физикохимия растворов
Исследование спин-кроссовера в комплексе перрената железа(II) с 2,6-бис(бензимидазол-2-ил)пиридином в растворах диметилсульфоксида.
Коковкин В.В., Миронов И.В., Коротаев Е.В., Лавренова Л.Г.
https://elibrary.ru/item.asp?id=74510508
Экстракция ионов металлов в системе сульфат аммония-оксиэтилированный нонилфенол-вода в присутствии органических комплексообразователей.
Шилыковская Д.О., Куимова Д.Ю., Елохов А.М.
https://elibrary.ru/item.asp?id=74510509
Неорганические материалы и наноматериалы
Термическая стабильность гетеронаноструктур (ZnS)(Ag2S)X сульфидов цинка и серебра.
Садовников С.И., Сергеева С.В., Гусев А.И.
https://elibrary.ru/item.asp?id=74510510
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118 | null | #неорганика
https://telegra.ph/Vodorod-ne-prosto-pervyj-ehlement-06-04 | https://t.me/incredible_chemistry/291?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,300 | 0 | 1,685,941,201 | 1,736,456,936 | 1,130 | 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| [{"ner":"06-04","lemma":"06-04","label":"DATE","start_pos":65,"end_pos":70},{"ner":"04","lemma":"04","label":"NUM","start_pos":68,"end_pos":70}] | NEUTRAL | eng | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | 💪
Фторид
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Фторид!
Что такое фторид? Ну, если мы заглянем в справочник по химии (или просто в Google), мы увидим, что фторид - это название, данное отрицательно заряженному иону атома фтора (F). Но не все так просто! Фторид также может быть названием соединения, содержащего этот элемент. И если мы будем действовать по научному, то любое соединение, будь то органическое или неорганическое, содержащее ион фторида, также известно как фторид. Примеры включают CaF2 (фторид кальция) и NaF (фторид натрия). Ионы, содержащие ион фторида, аналогично называются фторидами.
Если у вас есть туба зубной пасты под рукой, шансы встретить его там довольно высоки. Фториды добавляют в зубные пасты и даже в питьевую воду в некоторых странах, чтобы предотвратить кариес. Это процесс обычно осуществляется путем добавления фторида натрия (NaF), фторокремниевой кислоты (H2SiF6) или фторокремниевого натрия (Na2SiF6) в воду. Однако в других странах фторид считается токсичным соединением и их стараются избегать в питьевой воде. | https://t.me/incredible_chemistry/292?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,700 | 0 | 1,686,027,600 | 1,736,456,936 | 1,128 | 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118 | null | #органика #природное
https://telegra.ph/D-galakturonovaya-kislota-v-tvoem-varene-06-07 | https://t.me/incredible_chemistry/293?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,600 | 0 | 1,686,200,400 | 1,736,456,936 | 1,117 | 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| [{"ner":"06-07","lemma":"06-07","label":"DATE","start_pos":82,"end_pos":87},{"ner":"07","lemma":"07","label":"NUM","start_pos":85,"end_pos":87}] | NEUTRAL | other | NOT SPAM | 3 | 0 | 0 | 0.857143 | 0.142857 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 2 | true |
118 | null | #неорганика
https://telegra.ph/Prochnee-almaza-06-09 | https://t.me/incredible_chemistry/294?embed=1&mode=tme | https://t.me/ | https://t.me/s/incredible_chemistry | 2,700 | 0 | 1,686,286,801 | 1,736,456,936 | 1,115 | 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| [{"ner":"06-09","lemma":"06-09","label":"DATE","start_pos":47,"end_pos":52},{"ner":"09","lemma":"09","label":"NUM","start_pos":50,"end_pos":52}] | NEUTRAL | other | NOT SPAM | 2 | 0 | 0 | 0.75 | 0.25 | 0 | 0 | 0 | 0 | 0 | 1 | 0 | 1 | true |
118 | null | ❗️
Коллеги, хотел бы анонсировать активную подготовку к
большому курсу по обмену белков и аминокислот!
Ключевой целью
мы ставим простым
и понятным языком
сформировать прочный фундамент
понимания обмена белков и аминокислот и научиться применять теоретические знания на практике!
🔥
Готовим для вас четыре модуля.
1️⃣
Первый модуль направлен на разбор
общей биохимии белков
.
Поговорим о структуре, простых и сложных белках, альбуминах, глобулинах, гемоглобине, а также о многих других вопросах.
2️⃣
Второй будет охватывать
общий обмен аминокислот.
Вы узнаете про дезаминирование и трансаминирование, роль ферментов АСТ и АЛТ, синтез нейромедиаторов, роль витамина Б6 и многое другое.
3️⃣
Третий модуль посвящен
обмену отдельных аминокислот
.
Фенилаланин и тирозин, триптофан, метионин и гомоцистеин, креатин и креатинин. Разберем их практическую роль и пути превращения.
4️⃣
Также готовится четвертый практический модуль, посвященный разбору маркеров метаболизма аминокислот в анализе на органические кислоты.
😊
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Также предлагайте свои темы в комментариях, и задавайте вопросы! | https://t.me/simplebestbiochemistry/455?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,200 | 0 | 1,728,461,864 | 1,736,456,936 | 1,131 | 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| [{"ner":"АСТ","lemma":"аст","label":"ORG","start_pos":614,"end_pos":617},{"ner":"АЛТ","lemma":"алт","label":"ORG","start_pos":620,"end_pos":623},{"ner":"1","lemma":"1","label":"NUM","start_pos":312,"end_pos":313},{"ner":"2","lemma":"2","label":"NUM","start_pos":494,"end_pos":495},{"ner":"6","lemma":"6","label":"NUM","start_pos":664,"end_pos":665},{"ner":"3","lemma":"3","label":"NUM","start_pos":683,"end_pos":684},{"ner":"4","lemma":"4","label":"NUM","start_pos":870,"end_pos":871}] | NEUTRAL | rus | NOT SPAM | 155 | 0 | 3 | 1 | 0 | 0 | 28 | 18 | 4 | 2 | 60 | 3 | 31 | true |
118 | null | МЕТАБОЛИЧЕСКАЯ КАРТА В ВЫСОКОМ РАЗРЕШЕНИИ
Друзья, нашел самую полную и большую метаболическую карту в максимально высоком качестве! Посмотрите и удивитесь, насколько сложен и удивителен наш организм!
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| [{"ner":"ВЫСОКОМ РАЗРЕШЕНИИ","lemma":"высоком разрешении","label":"ORG","start_pos":23,"end_pos":41}] | NEUTRAL | rus | NOT SPAM | 38 | 0 | 5 | 1 | 0 | 0 | 7 | 6 | 0 | 0 | 7 | 4 | 6 | true |
118 | null | АЛЬБУМИНЫ. Онкотическое давление
Продолжим тему, которую
подняли
на этой неделе, и поясним, а какие же именно функции выполняют самые распространенные белки сыворотки крови - альбумины.
❗️
Кстати на
большом курсе по обмену белков и аминокислот
мы будем подробно говорить и о белках крови!
Итак, многие из вас ответили совершенно верно
🔥
, когда я попросил перечислить функции в комментариях. И давайте остановимся на самой первой из них:
Поддержание коллоидно-осмотического давления крови
Как мы уже говорили, альбумины чрезвычайно гидрофильны - хорошо растворяются в воде
💦
и обладают способностью удерживать вокруг себя воду. Тем самым, альбумины сыворотки удерживают жидкую часть плазмы в сосудистом русле и препятствуют ее миграции в ткани с развитием отеков.
❗️
Именно поэтому при снижении количества альбуминов мы будем наблюдать
гипоонкотические отеки
- вода не удерживается в сосудистом русле и проникает в ткани.
В таком случае мы говорим, что онкотическое давление плазмы крови снижено. У пациентов начинают отекать нижние конечности, появляется свободная жидкость в брюшной полости.
👨⚕️
Как правило такие отеки начинают появляться при снижении общего белка менее 50 г/л, при этом особое значение имеет дефицит альбуминов - менее 25 г/л - обладающих значительно большей осмотической активностью, чем глобулины.
А вы знали об этом?
😊 | https://t.me/simplebestbiochemistry/458?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 2,000 | 0 | 1,728,720,880 | 1,736,456,936 | 1,116 | 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| [{"ner":"АЛЬБУМИНЫ","lemma":"альбумины","label":"ORG","start_pos":0,"end_pos":9},{"ner":"50","lemma":"50","label":"NUM","start_pos":1175,"end_pos":1177},{"ner":"25","lemma":"25","label":"NUM","start_pos":1241,"end_pos":1243}] | NEUTRAL | rus | NOT SPAM | 196 | 0 | 5 | 1 | 0 | 0 | 25 | 28 | 13 | 3 | 61 | 13 | 31 | true |
118 | null | Всем доброго утра! Отличного дня и продуктивной недели! Берегите свое здоровье и преумножайте его
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Картинка заимствована на просторах интернета
🤣 | https://t.me/simplebestbiochemistry/459?embed=1&mode=tme | https://t.me/ | https://t.me/s/simplebestbiochemistry | 1,600 | 0 | 1,728,881,444 | 1,736,456,936 | 1,113 | 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| null | POSITIVE | rus | NOT SPAM | 21 | 0 | 0 | 1 | 0 | 0 | 3 | 3 | 2 | 0 | 7 | 0 | 5 | true |
118 | null |
Разрушители
озонового слоя
🌎
Раз уж мы обсудили
принципы, на основе которых работают холодильники
, нельзя пройти мимо связанной с использованием хладагентов
проблемы разрушения озонового слоя
. О том, как формируется озоновой слой, из-за чего появляются озоновые дыры и какую роль в этом процессе играют
фреоны
, предлагаю узнать прямо сейчас
👁
Озоновый слой
— это слой атмосферы Земли с наибольшим содержанием озона. Молекула озона O₃ образуется в результате действия
ультрафиолетового излучения
Солнца на привычный для нас молекулярный кислород
🌤
O₂ + УФ-излучение → 2O:
(образуется высокоактивный
атомарный кислород
)
O₂ + O: → O₃
(который затем реагирует с другой молекулой кислорода, образуя озон)
В равновесии с реакцией получения озона находится процесс его разрушения под действием того же солнечного излучения:
O₃ + УФ-излучение → O₂ + O:
O₃ + O: → 2O₂
(озон разрушается, превращаясь в две молекулы кислорода)
В ходе реакций образования и распада озона
поглощаются самые опасные типы УФ-излучения
, благодаря чему
возможно существование живых организмов
на поверхности нашей планеты
🐸
Существует несколько механизмов разрушения озонового слоя, один из которых упомянут выше. В природе
процессы образования-разрушения сбалансированы
— сколько озона погибает в ходе одной реакции, столько образуется в ходе другой.
Но деятельность человека внесла свои коррективы, сместив баланс, как чашу весов, в сторону разрушения
⚖️
И одну из ключевых ролей в этом процессе сыграли
фреоны
.
Фреоны
— производные метана CH₄ (реже этана С₂Н₆), в которых атомы водорода заменены на
фтор F, хлор Cl или бром Br
. Они были получены американским химиком
То́масом Ми́джли
с целью сделать холодильники безопасными, поскольку ранее в них использовались ядовитые и горючие вещества
👨🏻🔬
Помимо уникальных термических свойств, фреоны
инертны, невзрывоопасны и нетоксичны
, что способствовало их распространению не только в холодильных установках, но и в качестве основы аэрозолей, газовых баллончиков и огнетушителей
🧯
К сожалению, некоторые фреоны (
не все!
), попадая в атмосферу и достигая озонового слоя, вступают в реакцию с озоном,
ускоряя его разрушение
, что и приводит к образованию
озоновых дыр
. Массовое использование фреонов во второй половине прошлого века сильно отразилось на толщине озонового слоя в отдельных регионах. Это наглядно можно проследить на ежегодном мониторинге
🌍
Мировое сообщество не оставило эту проблему без внимания,
ограничив использование
тех фреонов, которые оказывают озоноразрушающее влияние, но в отдельных странах до сих пор производится часть из них (
R-12 и R-22
). И пока организации стараются перейти на безопасные для озонового слоя фреоны,
над Антарктидой
еще долго будет зиять
огромнейшая озоновая дыра
, в образовании которой важную роль сыграло их накопление
☁️
Конечно, в одном ряду с фреонами истончают озоновый слой и другие результаты деятельности человека.
Но вы только задумайтесь, какой огромный вклад в этот процесс внесло небольшое открытие, сделанное одним человеком
🤔 | https://t.me/ychemistry/964?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 1,900 | 0 | 1,721,807,028 | 1,736,456,936 | 1,128 | 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118 | null | Какую соль выбрать?
🧂
Соль
— самая распространённая пищевая добавка, без которой не обходится ни одно блюдо в ресторане или на кухне
🥗
При этом, химический состав её предельно прост и знаком каждому.
Откуда тогда на полках в магазине берётся такое разнообразие хлорида натрия? И почему стоимость одной упаковки может быть в десять раз больше, чем другой?
Начнём с того,
как добывают пищевую соль
.
ГОСТ выделяет четыре способа производства
, которые указывают на упаковке:
Каменная соль
добывается в шахтах или карьерах из соляных залежей, не подвергаясь тепловой и водной обработке
⛏
Выварочную соль
выпаривают из соляных растворов. Бывает так, что строить целую шахту для добычи соли невыгодно. Тогда бурят небольшие скважины, заливают их водой, которая растворяет соль, затем рассол выкачивают, фильтруют и вываривают
💨
Встречаются также естественные подземные рассолы, с которыми поступают аналогичным образом.
Садочную соль
осаждают из соленой воды в специальных бассейнах. В теплый сезон в местностях с подходящим климатом вода испаряется из искусственных плоских водоёмов, оставляя следы соли
🏝
И, наконец,
самосадочная соль
— это та, которая оседает естественным образом на дне водоема. Чаще всего это озерная соль. На самом известном в России соляном озере —
Баскунчак
— получают до 80 % от общей добычи соли в стране
🗻
Согласно одному из основных законов химии —
закону постоянства состава
— определенное химически чистое соединение,
независимо от способа получения
, состоит из одних и тех же химических элементов. Вне зависимости от того,
как был получен хлорид натрия
, он будет иметь однозначную формулу NaCl и обладать одинаковыми химическими свойствами
👁
Другая сторона вопроса —
сорт соли
, который определяет внешний вид, цвет, вкус, запах и состав продукта.
ГОСТ выделяет четыре сорта
, для каждого из которых указано минимальное содержание содержание чистого хлорида натрия: экстра —
99,7%
, высший —
98,4%
, первый —
97,7%
, второй —
97%
.
Остальные проценты — это следование содержания
других минералов
, характерных для места добычи соли (кальций, магний, калий, железо и т.д.). Эти элементы необходимы для нормальной работы нашего организма, правда получаем мы их в основном из другой пищи
🍎
Как можно заметить,
соль ЭКСТРА
— это практически химически чистый реактив, подходящий для экспериментов в лаборатории
🧪
А соль
первого и второго сорта
может иметь тёмные вкрапления соединений железа и других минералов, которые никак не сказываются на её вкусовых качествах.
И другая характеристика соли — это
помол
. Занятно, что при использовании крупной соли блюдо
сложнее пересолить
, потому что в щепотке крупного помола хлорида натрия на самом деле меньше, чем в щепотке мелкого из-за наличия
пустот между кристалликами
💎
Вывод
. Как бы ни старался
современный маркетинг
, вкус дорогой морской соли ничем
не будет отличаться
от дешёвой каменной. Чем ниже сорт, тем больше содержание других
полезных элементов
, а чем крупнее помол, тем лучше соль ведёт себя
при готовке
. И не стоит
бояться
тёмных частиц — это лишь вкрапления
других минералов
.
Но обращайте внимание
на состав
😉
Иногда в соль добавляют компоненты
против слёживания и комкования
. Если вы желаете купить
натуральный продукт
, выбирайте упаковку с
наиболее кратким и лаконичным составом
👩🏻🔬 | https://t.me/ychemistry/965?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,000 | 0 | 1,721,889,760 | 1,736,456,936 | 1,129 | 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| [{"ner":"🧂\nСоль","lemma":"🧂\nсоль","label":"ORG","start_pos":20,"end_pos":26},{"ner":"России","lemma":"россия","label":"LOC","start_pos":1245,"end_pos":1251},{"ner":"NaCl","lemma":"nacl","label":"ORG","start_pos":1618,"end_pos":1622},{"ner":"80","lemma":"80","label":"NUM","start_pos":1292,"end_pos":1294},{"ner":"99","lemma":"99","label":"NUM","start_pos":1904,"end_pos":1906},{"ner":"7","lemma":"7","label":"NUM","start_pos":1907,"end_pos":1908},{"ner":"98","lemma":"98","label":"NUM","start_pos":1921,"end_pos":1923},{"ner":"4","lemma":"4","label":"NUM","start_pos":1924,"end_pos":1925},{"ner":"97","lemma":"97","label":"NUM","start_pos":1938,"end_pos":1940},{"ner":"7","lemma":"7","label":"NUM","start_pos":1941,"end_pos":1942},{"ner":"97","lemma":"97","label":"NUM","start_pos":1955,"end_pos":1957}] | NEUTRAL | rus | NOT SPAM | 506 | 0 | 9 | 0.998471 | 0.001529 | 0 | 84 | 49 | 20 | 16 | 151 | 22 | 88 | true |
118 | null | Метастабильные состояния
⚗️
Все мы знаем, что вода встречается в трёх
привычных
нам агрегатных состояниях: твёрдом, жидком и газообразном. Но сегодня я хочу поделиться чем-то более
экзотичным
— рассказать вам о
метастабильных состояниях
🌊
Химические и физические системы в природе встречаются в нескольких типах состояний:
стабильное, нестабильное и метастабильное
. Каждая система из
нестабильного
состояния непременно стремится перейти в
стабильное
. В стабильном состоянии она может находиться сколь угодно долго
🕰
Метастабильное состояние
— это
«псевдоустойчивое»
равновесие, устойчивость которого нарушается при появлении внешнего воздействия
⏳
Представьте себе сани, которые катятся с горки
🛷
На её вершине у самого спуска сани находятся в нестабильном состоянии — они непременно начинают съезжать вниз. Но если посреди горки есть небольшое
плато
, скорее всего, сани остановятся на нём. Эту точку можно ассоциировать с метастабильным состоянием. Если подтолкнуть сани, они поедут дальше вниз по склону, пока не спустятся до конца и не остановятся, достигнув стабильного состояния
🗻
А теперь к химии. Будем проводить мысленные эксперименты.
Возьмём сосуд с водой и будем его нагревать. Мы знаем, что при атмосферном давлении
вода закипает при 100℃
и немедленно превращается в пар. Но далеко не всегда бывает так. Из-за
трудности фазового перехода
— превращения жидкости в пар — мы можем получить
перегретую жидкость
, то есть такую, которая нагрета
выше
температуры кипения. В лабораторных условиях можно получать жидкую воду, нагретую до
200℃
. Как только вода в этом метастабильном состоянии сталкивается с внешним возмущением, она немедленно и взрывообразно закипает. Перегретую жидкость можно получить, нагревая воду в микроволновой печи. Это становится частой причиной ожогов: вода кажется некипящей, но после легкого толчка мгновенно вскипает
💨
Теперь представим себе
большой сосуд с поршнем
, под которым находится
водяной пар
(вода в газообразном состоянии). Интуитивно понятно, что при высоком давлении, то есть при опускании поршня, газ будет сжиматься и превращаться в жидкость. Но если в сосуде
отсутствуют посторонние частицы
—
центры конденсации
— образование новой фазы будет затруднено, и мы не будем наблюдать капель воды
💧
Полученный пар называется пересыщенным
. Его еще называют
переохлажденным
, потому что в другом способе его получают путем охлаждения
❄️
Пересыщенный пар применяют в
камере Вильсона
— устройстве для наблюдения траектории заряженных частиц. Когда в камеру, заполненную пересыщенным паром, влетает заряженная частица, она сталкивается с молекулами газа и вызывает их ионизацию. Полученные ионы становятся
центрами конденсации
— вдоль пути полёта частицы образуются мельчайшие капельки жидкости, которые фиксируются прибором.
Мы наблюдаем траекторию её движения
🌠
Если мы возьмём кристально-чистую воду, поместим её в не менее чистый сосуд и охладим до температуры
ниже 0℃
, то можем получить другое метастабильное состояние —
переохлаждённую жидкость
🌡
. Казалось бы, при отрицательной температуре вода превращается в лёд, но в нашем случае
отсутствуют центры кристаллизации
, и данный переход затруднен. Экспериментально установлено, что воду можно переохладить
до −48℃
.
Очередные фокусы
: как только мы потревожим нашу переохлаждённую жидкость, просто взболтнув её или бросив песчинку, она мгновенно начнёт замерзать и превращаться в лёд
🥶
С переохлаждённой водой проводят эффектные эксперименты — струя жидкой воды превращается в лёд пока вытекает из бутылки
💦 | https://t.me/ychemistry/966?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,721,977,959 | 1,736,456,936 | 1,119 | 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| [{"ner":"Вильсона","lemma":"вильсон","label":"PER","start_pos":2421,"end_pos":2429},{"ner":"100","lemma":"100","label":"NUM","start_pos":1249,"end_pos":1252},{"ner":"200","lemma":"200","label":"NUM","start_pos":1545,"end_pos":1548},{"ner":"0","lemma":"0","label":"NUM","start_pos":2915,"end_pos":2916},{"ner":"48","lemma":"48","label":"NUM","start_pos":3213,"end_pos":3215}] | NEUTRAL | rus | NOT SPAM | 500 | 0 | 4 | 1 | 0 | 0 | 62 | 86 | 33 | 4 | 137 | 34 | 81 | true |
118 | null | Какие бывают углеводы?
🍭
Вы наверняка слышали о
«быстрых»
и
«медленных»
углеводах, они же
простые
и
сложные
. Одни люди целенаправленно выбирают в супермаркете продукты с медленными углеводами, другие ищут что-то сладенькое в кондитерском отделе. В любом случае, отрицать удовольствие от съеденного лакомства не имеет смысла.
Давайте рассмотрим химические аспекты, скрывающиеся за надписью
«углеводы»
в строке пищевой ценности
👩🏻🔬
Углеводы
— это название целого класса органических соединений, содержащих определенные функциональные группы (карбонильную
=С=O
и гидроксильную
—ОН
группы, если быть точным). Представители этого класса сильно отличаются друг от друга по свойствам, но объединяет их важный факт — углеводы содержатся в клетках и тканях
всех живых организмов
и выполняют в них
множество функций
☘️
Все углеводы состоят из отдельных единиц —
мономеров
. Их них, как их звеньев цепи, складываются длинные молекулы полимеров, имеющих сложное разветвлённое строение
⛓
Простейшие углеводы называются моносахаридами
. К ним относятся, например,
глюкоза
и
фруктоза
, которые представляют самые простые формы сахаров и не дают при разложении других молекул. Попадая в кровь, глюкоза становится основным источником энергии для обеспечения процессов в нашем организме
🍫
Когда молекула глюкозы соединяется с молекулой фруктозы, мы получаем
дисахарид
, получивший название
сахароза
. Это тот самый сахар, который мы добавляем в чай, получаемый из сахарной свёклы или тростника
☕️
Другим дисахаридом является
молочный сахар
—
лактоза
. Как уже понятно из названия, он содержится в молоке и молочных продуктах. В нашем организме расщеплением лактозы занимается особый фермент, и в ситуациях, когда он отсутствует или его производится недостаточно, возникает
непереносимость лактозы
🥛
Когда десятки, сотни или тысячи моносахаридов объединяются в одну молекулу, образуется
полисахарид
. Самыми яркими представителями таких сложных углеводных структур являются
крахмал, гликоген и целлюлоза
(она же
клетчатка
). Первый накапливается в растениях в результате фотосинтеза, второй запасается в мышцах и печени животных и людей, из третьего состоит хлопок, древесина и другие механические ткани растений
🌿
Как можно заметить, с изменением числа структурных единиц
кардинально меняются свойства углеводов
. И если моносахариды и дисахариды могут обладать ярко-выраженным сладким вкусом, то вряд ли вы почувствуете его, попробовав крахмал или бумагу
🤔
Моносахариды и дисахариды легко усваиваются
— организму почти не нужно прикладывать усилий, чтобы
«развалить»
сахар на две простые молекулы. Такие углеводы называют
«быстрыми»
— они быстро всасываются в кровь, повышая в ней содержание глюкозы. Съев сладкий кусочек торта, шоколадки или печенья, мы почти сразу чувствуем насыщение из-за попадания сахара в кровь, но это насыщение так же быстро сходит на нет
🍰
Чтобы усвоить длинные полимерные структуры, нашему организму требуется больше времени и энергии
. Поэтому полисахариды относят к
«медленным»
углеводам. Продукты, богатые сложными углеводами, постепенно повышают содержание глюкозы и дают более длительное чувство насыщения.
К ним относятся крупы, большинство овощей и зелени, макароны из твёрдых сортов пшеницы
🥦 | https://t.me/ychemistry/967?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,722,063,007 | 1,736,456,936 | 1,119 | 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| [{"ner":"🥛","lemma":"🥛","label":"ORG","start_pos":1781,"end_pos":1782}] | NEUTRAL | rus | NOT SPAM | 448 | 0 | 8 | 0.998333 | 0.001667 | 0 | 60 | 63 | 26 | 3 | 151 | 20 | 90 | true |
118 | null | Чем мы чистим зубы?
С детства нас учили тому, что утром и вечером нужно чистить зубы
👄
. Следуя правилам и привычкам, ежедневно два раза в день, мы это делаем. При этом мало кто из нас обращает внимание на состав зубной пасты. Мы слепо верим рекламе и даже не пытаемся выяснить, действительно ли данное средство защищает зубы от налёта, кариеса и прочих проблем.
Интересный факт. Наши далекие предки
🐵
, которые даже не знали про существование "быстрых" углеводов, жили без кариеса до 30-40 лет. Сегодня же кариес появляется даже у детей
👶
до 5 лет.
🔬
Любая зубная паста состоит из четырех видов компонентов: абразивные, поверхностно-активные, связующие и вспомогательные. Абразивные вещества - одни из самых главных, они убирают налёт, в котором обычно размножаются бактерии. Когда-то для этих целей использовали зубной порошок, однако из-за того, что у большинства людей чувствительная эмаль, его запретили.
Сегодня эффект своеобразной "терки" создаётся благодаря полимерным силикатам. Секрет "отбеливающих" паст заключается в обыкновенной пищевой соде. Поэтому если вы любитель отбеливающей пасты, рекомендую использовать её не чаще трёх раз в неделю. Кристаллы соды довольно твёрдые, поэтому могут повредить эмаль.
Содержащиеся в зубных пастах ПАВ отвечают за пенообразование
🌊
, чистящий эффект и уменьшение вероятности появления микроцарапин на эмали. По статистике, люди больше любят пенящиеся зубные пасты. Поэтому практически в каждом тюбике есть ПАВ.
Связующие компоненты, вроде карбоксиметилцеллюлозы, нужны для того, чтобы паста была именно пастой, а не жидкостью
💧
. Так что можем считать данный ингредиент своего рода загустителем.
У любой зубной пасты есть 2 главные задачи - стерилизация полости рта
👅
и реминерализация зубов. За первое отвечают различные экстракты трав
🌿
, за второе - соединения кальция и фтора. По последним исследованиям, кальций в зубной пасте бесполезен, а вот ионы фтора, действительно, успевают проникнуть в эмаль и ее укрепить.
Лучше не использовать пасты с антибиотиками, часть всегда попадает в желудок и убивает наших симбионтов. Кроме того, бесконтрольное использование бактерицидов ускоряет эволюцию бактерий, а так можно вывести совсем неубиваемого микроба. Прямо у себя во рту
😕
.
Поэтому стоматологи и химики рекомендуют использоваться зубные пасты с экстрактами трав
🌿
. Помимо запаха они могут обладать противовоспалительным и бактериостатичным эффектом: десны быстрее успокаиваются и бактерии хуже размножаются. | https://t.me/ychemistry/968?embed=1&mode=tme | https://t.me/ | https://t.me/s/ychemistry | 2,200 | 0 | 1,722,237,177 | 1,736,456,936 | 1,117 | 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118 | null | Смесь порошка железа и серы начинает вступать в реакцию при прикосновении к чему-то горячему. | https://t.me/chemistrytg2021/9461?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,000 | 0 | 1,734,459,600 | 1,736,456,937 | 1,133 | 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| null | NEUTRAL | rus | NOT SPAM | 14 | 0 | 0 | 1 | 0 | 0 | 1 | 2 | 3 | 0 | 6 | 0 | 1 | true |
118 | null | Невероятные свойства ферромагнитной жидкости: завораживающее видео
⠀
Ферромагнитная жидкость представляет собой коллоидные системы, состоящие из ферромагнитных частиц нанометровых размеров, находящихся во взвешенном состоянии в несущей жидкости, в качестве которой обычно выступает органический растворитель или вода. Она способна сильно поляризоваться в присутствии магнитного поля, а для обеспечения устойчивости такой жидкости ферромагнитные частицы связываются с поверхностно-активным веществом, образующим защитную оболочку вокруг частиц и препятствующим их слипанию. | https://t.me/chemistrytg2021/9462?embed=1&mode=tme | https://t.me/ | https://t.me/s/chemistrytg2021 | 3,300 | 0 | 1,734,502,800 | 1,736,456,937 | 1,131 | 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| null | NEUTRAL | rus | NOT SPAM | 64 | 0 | 0 | 1 | 0 | 0 | 16 | 9 | 3 | 0 | 22 | 2 | 8 | true |