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Открытие ампулы с калием под водой.
https://t.me/chemistrytg2021/9543?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
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Максимальное приближение чайного пакетика.
https://t.me/chemistrytg2021/9544?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
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Фильм «Оригинальные молекулы Дмитрия Ямбулатова» Старший научный сотрудник Института общей и неорганической химии им. Н.С. Курнакова РАН, к.х.н. Дмитрий Ямбулатов стал главным героем новой премьерной серии цикла «Российский код. Суверенное будущее», посвященного молодым талантливым учёным и изобретателям, создающим в России реальные технологии будущего. Исследования, которые Дмитрий выполняет в ИОНХ РАН, имеют потрясающие перспективы. Он разрабатывает специальные химические соединения для интеллектуальных устройств с молекулярной памятью. Молекулярная электроника недалёкого будущего – это многократное, в сотни и даже тысячи раз, увеличение мощности компьютера при существенном снижении энергозатрат плюс «миниатюризация» устройства. В основе таких «супергаджетов» - специальные молекулярные магнетики. #российскиеученые #ионх
https://t.me/chemrussia/5171?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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[{"ner":"Дмитрия Ямбулатова","lemma":"дмитрий ямбулатова","label":"PER","start_pos":29,"end_pos":47},{"ner":"Института общей и неорганической химии им. Н.С. Курнакова","lemma":"институт общий и неорганический химия им. н.с. курнакова","label":"ORG","start_pos":75,"end_pos":132},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":133,"end_pos":136},{"ner":"Дмитрий Ямбулатов","lemma":"дмитрий ямбулатов","label":"PER","start_pos":145,"end_pos":162},{"ner":"России","lemma":"россия","label":"LOC","start_pos":319,"end_pos":325},{"ner":"Дмитрий","lemma":"дмитрий","label":"PER","start_pos":378,"end_pos":385},{"ner":"ИОНХ","lemma":"ионх","label":"ORG","start_pos":398,"end_pos":402},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":403,"end_pos":406}]
NEUTRAL
rus
NOT SPAM
97
0
5
1
0
0
26
6
2
0
35
0
25
true
118
null
Напоминаем, что Научный совет по неорганической химии РАН и Научно-образовательный центр ИОНХ РАН приглашают аспирантов и молодых ученых принять участие в работе Первой ежегодной зимней школы по физическим методам исследования неорганических веществ и материалов, которая пройдет с 17 по 21 февраля 2025 г. в Институте общей и неорганической химии им. Н. С. Курнакова РАН в очном формате. У вас появится уникальная возможность расширить свои знания в передовых методах рентгеноструктурного и рентгенодифракционного анализа, сканирующей электронной микроскопии, молекулярной спектроскопии. Основное внимание будет уделено современным достижениям в области исследования характеристик неорганических веществ и перспективных материалов применительно к их использованию в различных отраслях – от микроэлектроники до биомедицины. Число участников ограничено. Стоимость участия в мероприятии – 20 000 рублей с человека. По завершении школы всем участникам с высшим образованием и средним профессиональным образованием выдаётся удостоверение о повышении квалификации установленного образца. Для участия необходимо подать заявку в свободной форме в Образовательный центр ИОНХ РАН по e-mail: [email protected] #ионх #обучение
https://t.me/chemrussia/5172?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
1,800
0
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Новые биоактивные нанокомпозитные гидрогели на основе глицеролатов кремния, цинка, бора и железа Ученые из Института органического синтеза им. И.Я. Постовского УрО РАН, Уральского государственного аграрного университета, Уральского государственного медицинского университета, Уральского федерального университета им. первого Президента России Б.Н. Ельцина и Уральского научно-исследовательского института дерматовенерологии и иммунопатологии с помощью золь-гель метода синтеза получили новые биоактивные нанокомпозитные гидрогели на основе глицеролатов кремния, цинка, бора и железа. Выявлены структурные особенности гидрогелей и их связь с медико-биологическими свойствами. Первичные токсикологические исследования позволили обнаружить, что Si-Fe-Zn-, Si-Fe-B- и Si-Fe-Zn-B-гели нетоксичны. Гемостатическая активность гидрогелей изучена в экспериментах in vivo и показано, что они проявляют кровоостанавливающее действие, сопоставимое с коммерческим препаратом Капрамин. При этом антимикробная активность более выражена для Si-Fe-Zn-B- и Si-Fe-B-гелей. Полученные исследователями глицерогдрогели являются потенциальными гемостатическими и антимикробными агентами местного применения для заживления ран в медицине и ветеринарии. Результаты работы опубликованы в журнале «Gels». Khonina, T.; Alekseenko, S.; Shadrina, E.; Ganebnykh, I.; Mekhaev, A.; Larionov, L.; Dobrinskaya, M.; Izmozherova, N.; Antropova, I.; Karabanalov, M.; et al. Hemostatic Antimicrobial Hydrogels Based on Silicon, Iron, Zinc, and Boron Glycerolates for Wound Healing Applications. Gels 2024, 10, 795. https://doi.org/10.3390/gels10120795 Источник: ИОС УрО РАН #российскаянаука
https://t.me/chemrussia/5174?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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NEUTRAL
rus
NOT SPAM
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https://telegra.ph/Pochemu-uglekislyj-gaz-ne-yavlyaetsya-organicheskim-soedineniem-01-02
https://t.me/incredible_chemistry/358?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,700
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https://telegra.ph/Mify-i-realnost-sahar-v-benzobake-avtomobilya-01-06
https://t.me/incredible_chemistry/359?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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https://telegra.ph/Kak-nasha-lyubov-k-prirode-prevratilas-v-strah-pered-himiej-01-09
https://t.me/incredible_chemistry/360?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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[{"ner":"01-09","lemma":"01-09","label":"DATE","start_pos":79,"end_pos":84},{"ner":"09","lemma":"09","label":"NUM","start_pos":82,"end_pos":84}]
NEUTRAL
eng
NOT SPAM
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ГГТП. Что это такое? Поскольку мы говорим про глутатион, то нельзя пропустить тему и про ГГТП - гамма-глутамил транспептидазу (или трансферазу), для которой глутатион важнейший субстрат. А что вообще такое ГГТП ❓ Многие знают, что повышается он при поражении желчных путей, печени, поджелудочной, но какую роль в целом выполняет этот фермент и зачем он нужен? Давайте разберемся ⤵️ 👨‍⚕️ Транспорт аминокислот через мембраны клеток - задача непростая. Сами аминокислоты не могут «протиснуться», как иногда кажется ученикам, сквозь фосфолипиды мембран клеток, поэтому на помощь приходят специальные белки транспортеры. А вот ГГТП - как раз яркий представитель белка транспортера, ответственного за перенос аминокислот через мембраны клеток по направлению внутрь клетки. ⚙️ Гамма-глутамил транспептидаза «хватает» снаружи клетки свободную аминокислоту и «прикрепляет» ее к глутатиону, а именно к ее фрагменту - гамма-глутамилу. Посмотри рисунок выше, как именно это работает ⤴️ Далее такой комплекс проникает внутрь клетки, аминокислота отсоединяется, а глутатион восстанавливается. 😉 Поэтому нужно четко понимать, что ГГТП в норме - важнейший белок транспортер, который располагается на мембране клеток и ответственен за перенос или «всасывание» аминокислот в цитоплазму клетки. ❓ ГГТП имеется во всех тканях, но у меня вопрос к вам, а в каких тканях количество ГГТП наибольшее и почему? Жду ваши ответы в комментариях, а завтра мы обсудим и этот вопрос.
https://t.me/simplebestbiochemistry/526?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,600
0
1,733,976,548
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rus
NOT SPAM
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ГГТП. Печень, почки, поджелудочная Итак, вчера вопрос о том, почему транспортер аминокислот ГГТП наиболее активно локализуется в печени, почках и поджелудочной железе вызвал активный интерес. В целом, многие правильно сказали в комментариях о важной синтетической функции данных желез. Но давайте ответим на этот вопрос подробно! 1️⃣ Реадсорбция аминокислот обратно в клетку 👨‍⚕️ Печень активно вырабатывает желчь (до 1,5 л в сутки), почки выделяют мочу (до 10 л первичной мочи), поджелудочная железа секретирует панкреатический сок (до 500-700 мл в сутки). Когда клетки секретируют в просвет протоков данные жидкости, то вместе с ними выходит большое количество аминокислот. Но ведь это было бы очень не выгодно, сливать ценные аминокислоты с мочей, желчью и панкреатическим соком. ❗️ Поэтому клетки эпителия активно реадсорбируют из протоков печени, поджелудочной и канальцев почек аминокислоты с помощью ГГТП обратно в клетку, тем самым не допуская их потерю. Именно поэтому при воспалении и повреждении желчных, панкреатических протоков повышается фермент ГГТП. Клетки разрушаются и данный транспортер оказывается в крови. 2️⃣ Поставка аминокислот для синтеза Данная роль особенно актуальная для печени и ПЖ, которые очень активно секретируют различные белки. Поэтому для того, чтобы активно поставлять субстрат в виде аминокислот в клетку, ГГТП находится на мембранах в больших количествах. 😉 По этим двум причинам ГГТП маркер повреждений именно данных органов!
https://t.me/simplebestbiochemistry/527?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,700
0
1,734,071,487
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[{"ner":"ГГТП","lemma":"ггтп","label":"ORG","start_pos":0,"end_pos":4},{"ner":"ГГТП","lemma":"ггтп","label":"ORG","start_pos":92,"end_pos":96},{"ner":"00-70","lemma":"00-70","label":"DATE","start_pos":538,"end_pos":543},{"ner":"1","lemma":"1","label":"NUM","start_pos":330,"end_pos":331},{"ner":"1","lemma":"1","label":"NUM","start_pos":418,"end_pos":419},{"ner":"5","lemma":"5","label":"NUM","start_pos":420,"end_pos":421},{"ner":"10","lemma":"10","label":"NUM","start_pos":458,"end_pos":460},{"ner":"500","lemma":"500","label":"NUM","start_pos":537,"end_pos":540},{"ner":"700","lemma":"700","label":"NUM","start_pos":541,"end_pos":544},{"ner":"2","lemma":"2","label":"NUM","start_pos":1127,"end_pos":1128}]
NEUTRAL
rus
NOT SPAM
207
2
8
1
0
0
24
19
6
6
73
19
39
true
118
null
Отличная демонстрация 🔥 того, как гломерулярный фильтр здоровой почки сохраняет белки в плазме крови, поскольку последние большие и крупные! ❗️ А вот появление белка в моче - грозный признак повреждения почечного фильтра!
https://t.me/simplebestbiochemistry/528?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,700
0
1,734,241,379
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​​ Метастабильные состояния ⚗️ Все мы знаем, что вода встречается в трёх привычных нам агрегатных состояниях: твёрдом, жидком и газообразном. Но сегодня я хочу поделиться чем-то более экзотичным — рассказать вам о метастабильных состояниях 🌊 Химические и физические системы в природе встречаются в нескольких типах состояний: стабильное, нестабильное и метастабильное . Каждая система из нестабильного состояния непременно стремится перейти в стабильное . В стабильном состоянии она может находиться сколь угодно долго 🕰 Метастабильное состояние — это «псевдоустойчивое» равновесие, устойчивость которого нарушается при появлении внешнего воздействия ⏳ Представьте себе сани, которые катятся с горки 🛷 На её вершине у самого спуска сани находятся в нестабильном состоянии — они непременно начинают съезжать вниз. Но если посреди горки есть небольшое плато , скорее всего, сани остановятся на нём. Эту точку можно ассоциировать с метастабильным состоянием. Если подтолкнуть сани, они поедут дальше вниз по склону, пока не спустятся до конца и не остановятся, достигнув стабильного состояния 🗻 А теперь к химии. Будем проводить мысленные эксперименты. Возьмём сосуд с водой и будем его нагревать. Мы знаем, что при атмосферном давлении вода закипает при 100℃ и немедленно превращается в пар. Но далеко не всегда бывает так. Из-за трудности фазового перехода — превращения жидкости в пар — мы можем получить перегретую жидкость , то есть такую, которая нагрета выше температуры кипения. В лабораторных условиях можно получать жидкую воду, нагретую до 200℃ . Как только вода в этом метастабильном состоянии сталкивается с внешним возмущением, она немедленно и взрывообразно закипает. Перегретую жидкость можно получить, нагревая воду в микроволновой печи. Это становится частой причиной ожогов: вода кажется некипящей, но после легкого толчка мгновенно вскипает 💨 Теперь представим себе большой сосуд с поршнем , под которым находится водяной пар (вода в газообразном состоянии). Интуитивно понятно, что при высоком давлении, то есть при опускании поршня, газ будет сжиматься и превращаться в жидкость. Но если в сосуде отсутствуют посторонние частицы — центры конденсации — образование новой фазы будет затруднено, и мы не будем наблюдать капель воды 💧 Полученный пар называется пересыщенным . Его еще называют переохлажденным , потому что в другом способе его получают путем охлаждения ❄️ Пересыщенный пар применяют в камере Вильсона — устройстве для наблюдения траектории заряженных частиц. Когда в камеру, заполненную пересыщенным паром, влетает заряженная частица, она сталкивается с молекулами газа и вызывает их ионизацию. Полученные ионы становятся центрами конденсации — вдоль пути полёта частицы образуются мельчайшие капельки жидкости, которые фиксируются прибором. Мы наблюдаем траекторию её движения 🌠 Если мы возьмём кристально-чистую воду, поместим её в не менее чистый сосуд и охладим до температуры ниже 0℃ , то можем получить другое метастабильное состояние — переохлаждённую жидкость 🌡 . Казалось бы, при отрицательной температуре вода превращается в лёд, но в нашем случае отсутствуют центры кристаллизации , и данный переход затруднен. Экспериментально установлено, что воду можно переохладить до −48℃ . Очередные фокусы : как только мы потревожим нашу переохлаждённую жидкость, просто взболтнув её или бросив песчинку, она мгновенно начнёт замерзать и превращаться в лёд 🥶 С переохлаждённой водой проводят эффектные эксперименты — струя жидкой воды превращается в лёд пока вытекает из бутылки 💦
https://t.me/ychemistry/1034?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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​​ Какие бывают ткани? 🧶 Текстильная промышленность является ярким примером использования химических знаний для решения бытовых проблем. Сегодня мы разберёмся вместе с вами, из чего шьют одежду 👚 Все текстильные волокна делятся на три большие группы : Натуральные волокна используются с древнейших времён и хорошо нам знакомы. Из растительного сырья производят хлопок, лён, пеньку и джут 🌿 Волокна животного происхождения представлены шерстью и натуральным шёлком 🐏 И существуют минеральные волокна, к которым относится асбест — собирательное название нескольких минералов, образующих тончайшие гибкие нити. Из асбеста изготавливают огнеупорные ткани, кровельные и строительные материалы 🔥 К сожалению, асбестовая пыль является сильнейшим канцерогеном — она повышает вероятность появления злокачественных опухолей при попадании в дыхательные пути. Поэтому изделия из асбеста в разных странах запрещены или частично, или полностью . В России разрешено около трёх тысяч видов продукции из наиболее безопасного асбестового минерала — хризотила . В них асбест находится в связанном состоянии с полимерами, цементом или смолой, поэтому безопасен 👩🏻‍🔬 К химическим волокнам относят волокна, получаемые в заводских условиях. Из разделяют на искусственные и синтетические . К искусственным относят волокна на основе целлюлозы и ее производных. Например, вискозу вырабатывают из целлюлозы, полученной из древесины ели, пихты или сосны. После химической обработки целлюлозы ( обработка сероуглеродом в щелочной среде ) из неё формируют тонкие нити, пропуская через специальные аппараты со множеством мелких отверстий — фильеры . Из вязкой жидкости мы получаем тонкие нити вискозы. Ткани из вискозы хорошо впитывают воду и пропускают воздух, отличаются высокой прочностью и мягкостью, а благодаря характерному блеску порой ассоциируются с искусственным шёлком 👗 К искусственным также относятся ацетатные и триацетатные волокна , получаемые из обработанного уксусной кислотой хлопка. Ацетатные волокна менее распространены из-за ряда недостатков: высокая электризуемость, низкая устойчивость к истиранию и высоким температурам 🌡 Синтетические волокна получают путём синтеза из низкомолекулярных продуктов переработки нефти, каменного угля и природного газа ( фенол, этилен, ацетилен, метан ). На выходе образуются длинные цепочки полимеров 🧬 К тканям из синтетических волокон относятся нейлон, капрон, лавсан, акрил, лайкра, спандекс и многие другие 🧵 Капрон обладает высокой прочностью, эластичностью и, в отличие от натурального шёлка , не гниёт и не слёживается. Благодаря этому капрон пришёл на смену шёлку в производстве парашютов . Нейлон и лавсан используются не только в качестве тканей — модифицированные волокна используются в машиностроении, производстве техники и пластиковой тары ⚗️ Большинство синтетических волокон зарегистрировано под своими торговыми названиями . Каждый вид представлен несколькими модификациями для устранения определенных недостатков и решения конкретных производственных задач 👀 Поэтому не стоит пугаться непривычных названий в составе ткани при выборе одежды. Как мы выяснили, многие химические волокна по своим свойствам превосходят натуральные . Надпись «хлопок 100%» уже давно не является гарантом высочайшего качества . Большинство дешёвых хлопковых изделий изготавливается из низкокачественных продуктов переработки 🧦 Только правильное сочетание натуральных, искусственных и синтетических волокон оправдает ваши ожидания от новой одежды 👍🏻
https://t.me/ychemistry/1035?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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Определение характера среды водных растворов + индикаторы: Различают три вида сред водных растворов: кислая, щелочная и нейтральная. Для характеристики среды раствора используют водородный показатель pH, определить среду можно при помощи индикаторов: Фенолфталеина, лакмуса и метилоранжа. В разных средах они окрашиваются в различные цвета. Запомнить цвета индикаторов просто) 1. Фенолфталеин - индикатор щелочной среды, в ней он окрашивается в малиновый. В остальных средах он безцветный. 2. Лакмус и метилоранж, в Кислой среде - Красные. ( Запоминаем по первой букве К) 3. В щелочной среде лакмус синий . Нейтральную же среду можно вывести, представив, что мы смешиваем цвета в палитре: - (Кислая) красный + (щелочная) синий = Нейтральная - фиолетовый 💜 4. С метилоранжем можно сделать все то же самое. В щелочной среде - он желтый, следовательно: - (Кислая) красный + (щелочная) желтый = нейтральная - оранжевый 🧡
https://t.me/ychemistry/1037?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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[{"ner":"Фенолфталеина","lemma":"фенолфталеин","label":"PER","start_pos":251,"end_pos":264},{"ner":"Лакмус","lemma":"лакмус","label":"PER","start_pos":493,"end_pos":499},{"ner":"Кислая","lemma":"кислый","label":"LOC","start_pos":692,"end_pos":698},{"ner":"Кислая","lemma":"кислый","label":"LOC","start_pos":853,"end_pos":859},{"ner":"1","lemma":"1","label":"NUM","start_pos":377,"end_pos":378},{"ner":"2","lemma":"2","label":"NUM","start_pos":490,"end_pos":491},{"ner":"3","lemma":"3","label":"NUM","start_pos":572,"end_pos":573},{"ner":"4","lemma":"4","label":"NUM","start_pos":756,"end_pos":757}]
NEUTRAL
rus
NOT SPAM
136
0
6
0.99495
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null
Стибнит (трисульфид сурьмы Sb2S3) — токсичный сульфидный минерал сурьмы, один из важных источников этого элемента-неметалла. Также стибнит — одно из самых древних косметических средств.
https://t.me/chemistrytg2021/9535?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
1,735,820,401
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[{"ner":"2","lemma":"2","label":"NUM","start_pos":29,"end_pos":30},{"ner":"3","lemma":"3","label":"NUM","start_pos":31,"end_pos":32}]
NEUTRAL
rus
NOT SPAM
24
0
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0.969697
0.030303
0
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2
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true
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null
Золотой рутил Несмотря на красивое название, к золоту данный образец не имеет никакого отношения. Рутил (TiO2) который вырос первым, охватили кристаллы кварца (SiO2), которые выросли поверх его. Вот и получается такая красота. Из-за особенностей кристаллографии и условий роста: у рутила игольчатые кристаллы
https://t.me/chemistrytg2021/9536?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,500
0
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Моющее средство+молоко
https://t.me/chemistrytg2021/9537?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
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null
NEUTRAL
rus
NOT SPAM
2
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true
118
null
Реакция взаимодействия ванадия и азотной кислоты. 3V + 5HNO3 → 3HVO3 + 5NO + H2O
https://t.me/chemistrytg2021/9538?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
1,735,884,004
1,736,456,921
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NEUTRAL
rus
SPAM
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Растворение монеты в азотной кислоте! В результате реакции образуется красно-коричневый газообразный диоксид азота и горячий концентрированный раствор нитрата меди (II).
https://t.me/chemistrytg2021/9539?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,100
0
1,735,896,000
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NEUTRAL
rus
NOT SPAM
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Распоряжением Правительства РФ № 3903-р от 20.12.2024 ликвидирована автономная некоммерческая организация "Научно-образовательный центр "Большая российская энциклопедия" (АНО БРЭ), отвечавшая за создание цифровой версии Большой российской энциклопедии. http://publication.pravo.gov.ru/document/0001202412200080 #инфраструктуранауки
https://t.me/chemrussia/5167?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
1,600
0
1,734,847,307
1,736,456,921
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Экскурсия для московских химических классов в ИОНХ РАН «Московские химические классы» - городской образовательный проект, разработанный Департаментом образования и науки города Москвы с целью обеспечить конкурентоспособность выпускников школ при поступлении в московские вузы на приоритетные специальности, связанные с владением прикладными и аналитическими методами в области химии. 19 декабря 2024 г. химические классы Школы им. Маршала В. И. Чуйкова посетили ИОНХ РАН. Мероприятие состоялось при поддержке Института развития профильного обучения ГАОУ ВО «Московский городской педагогический университет». Во время экскурсий по лабораториям учащиеся и учителя получили возможность познакомиться с профессией ученого и направлениями деятельности ведущих лабораторий института. Научные сотрудники продемонстрировали школьникам как изучаются вещества и материалы с помощью электронной микроскопии, спектроскопии ядерного магнитного резонанса и рентгеноструктурного анализа, каким образом происходит получение кристаллов координационных полимеров, с помощью каких методов синтеза удается получать соединения, перспективные для электроники и медицины. Гости также узнали какие исследования проводятся в Центре цвета, Платиновом центре и Центре масштабирования химических технологий. Участники экскурсии увлеченно общались с учеными и смогли задать все интересующие их вопросы. #ионх
https://t.me/chemrussia/5169?embed=1&mode=tme
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NEUTRAL
rus
NOT SPAM
165
0
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1
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0
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0
69
2
19
true
118
null
Вышло в свет интервью директора ИСПМ РАН чл.-к. РАН С.А. Пономаренко, посвященное органическим полупроводникам: https://zanauku.mipt.ru/2024/12/19/tonshe-legche-deshevle/ #российскаянаука #российскиеученые
https://t.me/chemrussia/5170?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
2,400
0
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NEUTRAL
rus
NOT SPAM
17
0
4
0.956522
0.043478
0
2
2
0
0
6
0
4
true
118
null
Итак, вы решили заняться виноделием на домашней кухне? Отлично, но будьте готовы к неожиданностям. Вместо ароматного вина вы рискуете получить... уксус. Все дело в кислороде, , который, кстати, не просто так входит в состав воздуха. Когда он проникает в ваше вино, начинается веселье. Уксуснокислые бактерии, которые, к слову, витают везде вокруг нас и обожают тепло и влажность, словно магнитом притягиваются к вашему напитку. И тут они начинают свою работу, превращая вкусный алкоголь в уксусную кислоту. Чем больше кислорода, тем сильнее вечеринка для бактерий и тем больше у вас шансов на уксус, а не вино. Так что, если вы не хотите превратить свою винодельню в уксусоварню, следите за герметичностью емкостей и за чистотой оборудования. Ведь, как говорится, дьявол кроется в деталях – и в бактериях.
https://t.me/incredible_chemistry/353?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,800
0
1,700,715,601
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null
NEUTRAL
rus
NOT SPAM
124
0
1
1
0
0
7
17
10
2
35
7
30
true
118
null
Октановое число - ключ к эффективности двигателя Октановое число – это показатель, который оценивает, как топливо справляется с самовоспламенением при сжатии в двигателе внутреннего сгорания. Этот показатель особенно важен, потому что он указывает на способность топлива противостоять детонации – явлению, которое может проявляться в виде стука или щелчков в двигателе при ускорении. Октановое число определяется сравнением, в стандартных условиях, интенсивности детонации топлива с детонацией эталонных веществ – изооктана и н-гептана. Изооктан (2,2,4-триметилпентан) имеет октановое число 100, означающее высокую устойчивость к детонации даже при сильном сжатии. В контрасте с ним, н-гептан, с октановым числом 0, имеет низкую устойчивость к детонации. Транспортные средства с высокой производительностью требуют топлива с более высоким октановым числом, чтобы обеспечить оптимальную работу двигателя и предотвратить детонацию.
https://t.me/incredible_chemistry/355?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
4,300
0
1,701,061,200
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rus
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https://telegra.ph/Mozhno-li-umeret-ot-pereizbytka-povarennoj-soli-12-06
https://t.me/incredible_chemistry/356?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
4,200
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https://telegra.ph/CHto-budet-esli-vypit-otbelivatel-12-18
https://t.me/incredible_chemistry/357?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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null
NEUTRAL
rus
NOT SPAM
5
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1
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true
118
null
МАО и КОМТ. Зачем нужны? С точки зрения биохимии и физиологии нервной системы, важной задачей является не только синтезировать нейромедиаторы, но еще при этом их быстро обезвреживать и утилизировать. Почему это важно? Потому что избыток нейромедиатора в синаптической щели приведет к чрезмерному возбуждению нейрона и его повреждению. За обезвреживание и утилизацию отвечают два ключевых фермента: 1️⃣ Моноаминооксидаза (МАО) Фермент МАО отщепляет от нейромедиатора аминогруппу -NH2, в результате чего нейромедиатор превращается в другое соединение - альдегид, который уже не возбуждает синаптические рецепторы. А аминогруппа выделяется в виде аммиака NH3. ❗️ Поэтому нервная ткань сама является поставщиком продуктов азотистого обмена - аммиака! 2️⃣ Метил-трансфераза (КОМТ) Особенностью данного фермента является способность присоединять к нейромедиатору метильную группу - CH3, в результате чего метилированый нейромедиатор уже не выполняет своей функции. ❗️ Кстати донором метильной группы является активная форма метионина - S аденозин метионин (SAM). А что вы знаете про работу МАО и КОМТ? 😊
https://t.me/simplebestbiochemistry/521?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,800
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[{"ner":"МАО","lemma":"мао","label":"ORG","start_pos":0,"end_pos":3},{"ner":"КОМТ","lemma":"комт","label":"ORG","start_pos":6,"end_pos":10},{"ner":"Фермент МАО","lemma":"фермент мао","label":"PER","start_pos":426,"end_pos":437},{"ner":"МАО","lemma":"мао","label":"ORG","start_pos":1084,"end_pos":1087},{"ner":"КОМТ","lemma":"комт","label":"ORG","start_pos":1090,"end_pos":1094},{"ner":"1","lemma":"1","label":"NUM","start_pos":398,"end_pos":399},{"ner":"2","lemma":"2","label":"NUM","start_pos":481,"end_pos":482},{"ner":"3","lemma":"3","label":"NUM","start_pos":654,"end_pos":655},{"ner":"2","lemma":"2","label":"NUM","start_pos":747,"end_pos":748},{"ner":"3","lemma":"3","label":"NUM","start_pos":878,"end_pos":879}]
NEUTRAL
rus
NOT SPAM
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0.025907
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ГЛУТАТИОН. Детоксификация На прошлой неделе мы поговорили с вами про антиоксидантную функцию глутатиона и роль цистеина в его синтезе. А сегодня давайте обсудим еще одну его важную функцию - функцию обезвреживания. 👨‍⚕️ Итак, глутатион по своей структуре крупная и очень хорошо растворимая в воде молекула. Поэтому печень использует ее, как конъюгат во 2 фазе обезвреживания. Под действием фермента глутатион-S-трансферазы, молекула глутатиона в печени присоединяется к молекуле токсина через свой атом серы. Получается общая формула: глутатион-S-токсин ❗️ Таким образом, у токсина: 1️⃣ - снижаются токсичные свойства, потому что происходит маскировка токсичных группу (яркий пример в процессе обезвреживания парацетамола); 2️⃣ - у токсина, конъюгированного с глутатионом, резко возрастает способность растворяться в воде, вследствие чего токсин хорошо выводится либо с желчью, либо с мочей. Глутатион вносит важнейший вклад в процессы детоксификации, обезвреживая большой количество ксенобиотиков и токсинов! 😉
https://t.me/simplebestbiochemistry/524?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,600
0
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NEUTRAL
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​​ Чем дезинфицировать смартфоны? 📲 Главные атрибуты эпохи самоизоляции — антисептики для рук и медицинские маски — мы уже успели обсудить, но хочу обратить ваше внимание на ещё один не менее важный момент — гаджеты 💡 Мобильные телефоны уже давно стали нашими верными проводниками в решении всех бытовых задач. Можете ли вы представить вылазку до ближайшего магазина или прогулку с домашним любимцем без смартфона ? Как дела по дому, так и любой выход из него проходят с телефоном или в руке, или в кармане одежды 👣 Что мы делаем, выходя каждый раз из дома? Верно. Хватаемся за дверные ручки, нажимаем кнопки лифта, берём в руки товары в магазине, которые до нас сотни раз брали другие люди, и периодически держим в руках мобильный телефон 🤳🏻 Приходим домой. Моем руки (хорошо, что этому нас научили инструкция ВОЗ и видео в TicTok), берём в очередной раз смартфон, выложенный на полку или кровать и... Спрашивается — зачем мыли руки? 👐🏻 Думаю, вы хорошо понимаете ту цепочку, благодаря которой телефон становится главным носителем патогенных микроорганизмов . Порой страшно представить, с каких публичных мест микробы попадают на экран смартфона, из-за чего он становится в 10 раз грязнее унитаза 🚽 Некоторые специалисты заявляют, что дезинфекция носимых устройств более важна, чем ношение лицевых масок — коронавирус выживает на стеклянных поверхностях до нескольких дней 🦠 Чем очищать смартфон? Официальная рекомендация Apple и другие компании советуют делать это мягкими салфетками из микрофибры, смоченными в 70% изопропиловом спирте . Не рекомендуется использовать отбеливающие вещества (перекись водорода). Альтернатива — хлоргексидин или специальные дезинфицирующие салфетки (Clorox) 🧴 Важно — выдерживайте экспозицию! ⏰ Зараза не погибает моментально — оставьте гаджет в «визуально влажном» состоянии не менее чем на минуту. Когда нужно дезинфицировать? После каждого «выхода в свет» . Причём сначала обработали смартфон, а уже затем вымыли руки 🙌🏻 Эта рекомендация актуальна не только в период распространения вируса, но и в любое другое время . Прикладывая телефон или руки после использования гаджета к лицу, мы каждый раз переносим микробы на зоны вблизи слизистых оболочек 👀 Стоит отметить, что Bluetooth-гарнитуры эффективно сокращают эти контакты. Не исключено, что в скором времени производители будут выпускать гаджеты из специальных антибактериальных материалов и покрытий . На торговых площадках уже появляются портативные кейсы-санитайзеры со встроенными бактерицидными УФ-лампами для смартфонов. А пока мы будем учиться полезным привычкам 👩🏻‍🔬
https://t.me/ychemistry/1030?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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https://t.me/ychemistry/1031?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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[{"ner":"СИБУР ПолиЛаб","lemma":"сибур полилаб","label":"ORG","start_pos":76,"end_pos":89},{"ner":"Цифровой","lemma":"цифровой","label":"PER","start_pos":217,"end_pos":225}]
NEUTRAL
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Почему нельзя выбрасывать батарейки в мусорку? Наверняка вы слышали о том, что батарейки ни в коем случае нельзя выбрасывать в обычную мусорку и уж тем более на улицу. Говорят об этом не ради красного словца. В любой батарейке содержаться такие элементы, как свинец, никель, кадмий, литий и ртуть. Самыми опасными для жизни человека является ртуть и кадмий. Второй элемент очень токсичен. Кадмий негативно влияет на работу почечной системы, костных тканей и печени. Большинство людей считают, что ничего страшного не произойдёт, если они выбросят 1-2 батарейки. Действительно, уровень угрозы будет минимальный. Но что если кроме вас так же подумает ещё 10000 людей? Согласно Гринпис, на свалках одной Москвы было обнаружено около 15 миллионов батареек, а радиус загрязнения окружающей среды равен одному квадратному метру на каждую. Не маленькая цифра, правда? Итак, чем же грозит выброс батареек в мусорку? Батарейки или аккумуляторы в процессе коррозии начинают разрушаться и все токсичные вещества проникают прямиком в почву и грунтовые воды. Если батарейки сжечь 🔥 вместе с прочим мусором, то токсины добираются до атмосферы. Что происходит дальше — очевидно. Распространившись в почве, водоёмах и воздухе, токсичные вещества наносят серьёзный ущерб всему живому на планете. Они замедляют рост растений, попадают в организмы животных и, конечно, человека — вместе с водой, пищей животного и растительного происхождения и даже из вдыхаемого нами воздуха. Это всё может привести к раку и прочим болезням. Помни, забота о планете начинается с тебя, начни прямо сейчас 🌍 А я говорю вам спасибо за то, что дочитали, хорошей вам недели!
https://t.me/ychemistry/1033?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
2,000
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1,732,355,036
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[{"ner":"Кадмий","lemma":"кадмий","label":"LOC","start_pos":389,"end_pos":395},{"ner":"Гринпис","lemma":"гринпис","label":"PER","start_pos":675,"end_pos":682},{"ner":"Москвы","lemma":"москва","label":"LOC","start_pos":701,"end_pos":707},{"ner":"10000","lemma":"10000","label":"DATE","start_pos":653,"end_pos":658},{"ner":"1","lemma":"1","label":"NUM","start_pos":547,"end_pos":548},{"ner":"2","lemma":"2","label":"NUM","start_pos":549,"end_pos":550},{"ner":"15","lemma":"15","label":"NUM","start_pos":730,"end_pos":732}]
NEUTRAL
rus
NOT SPAM
246
0
2
1
0
0
24
31
17
7
77
17
46
true
118
null
Ферромагнитное взаимодействие. Железные гвозди временно становятся дипольными магнитами в присутствии сильного магнитного поля от большого неодимового супермагнита. Здесь неодимовый дисковый магнит установлен так, чтобы его северный полюс был направлен вверх, поэтому кончик каждого гвоздя становится южным полюсом (отталкивая друг друга), а головка каждого - северным полюсом. #интереснаяфизика
https://t.me/chemistrytg2021/9530?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,200
0
1,735,626,000
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null
NEUTRAL
rus
NOT SPAM
47
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true
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Картофель содержит сахар, воду и кислоту. Некоторые типы металлов, особенно медь и цинк, вступают в реакцию с картофелем, когда они помещаются внутрь. Металлы фактически становятся электродами, один положительным, а другой отрицательным, и электроны текут между металлами внутри картофеля, создавая небольшой электрический ток.
https://t.me/chemistrytg2021/9531?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,300
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null
NEUTRAL
rus
NOT SPAM
42
0
0
1
0
0
5
6
1
1
16
3
11
true
118
null
Помещаем медную проволоку в нитрат серебра. 2AgNO3 + Cu —> Cu(NO3)2 + Ag
https://t.me/chemistrytg2021/9532?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,400
0
1,735,658,400
1,736,456,922
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NEUTRAL
rus
NOT SPAM
13
0
0
0.75
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true
118
null
Разрушительная сила паров ацетона.
https://t.me/chemistrytg2021/9533?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
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null
NEUTRAL
rus
NOT SPAM
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Экстремальный тестдрайв Запуск камеры на высоту 100 000 футов при -56°C
https://t.me/chemistrytg2021/9534?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
1,735,809,600
1,736,456,922
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Аэробная бактериальная деструкция полихлорбифенилов и их гидрокси- и метоксипроизводных Ученые из Института органического синтеза им. И. Я. Постовского УрО РАН и Института экологии и генетики микроорганизмов УрО РАН изучили процесс биодеструкции полихлорбифенилов под действием аэробных бактериальных штаммов. Показана возможность осуществления полного биоразложения полихлорбифенилов и их производных в лабораторных условиях. Представленные исследователями информация способствует развитию исследований биопревращений производных полихлораренов и их токсичности, а также разработке технологий ремедиации природных объектов, загрязненных полихлорбифенилами. Результаты работы опубликованы в журнале «Успехи химии» и могут быть использованы для совершенствования методов очистки воды, почвы и донных отложений от хлорорганических соединений. T.I.Gorbunova, D.O.Egorova, V.I.Saloutin, O.N.Chupakhin, "Aerobic bacterial degradation of polychlorinated biphenyls and their hydroxy and methoxy derivatives", Russ. Chem. Rev., 2024, 93 (11), RCR5138, https://doi.org/10.59761/RCR5138 Источник: ИОС УрО РАН #российскаянаука
https://t.me/chemrussia/5164?embed=1&mode=tme
https://t.me/
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Новые комплексы рения для создания органических светодиодов Международный коллектив ученых из Института неорганической химии имени А.В. Николаева СО РАН, Пекинского университета (Китай), Новосибирского института органической химии имени Н.Н. Ворожцова СО РАН, Венского университета (Австрия) и Силезского университета в Катовице (Польша) синтезировали прочные хиральные комплексы рения (I) с улучшенной циркулярно поляризованной фосфоресценцией (CPP) и впервые продемонстрировали циркулярно поляризованную электролюминесценцию (CPEL) от рениевых эмиттеров. Полученные соединения обладают CPP с повышенными |glum| факторами до 2,5×10(-2) и хорошей квантовой эффективностью. Первые CP-органические светодиоды (CP-OLED) на основе Re(I)-комплексов проявили желтый CPEL с |gEL|-факторами до 6,2×10(-3) и максимальной внешней квантовой эффективностью 13,2%. Исследователи также выявили подавляющее влияние магнитного поля на силу CPP эмиттеров Re (I). Результаты работы опубликованы в журнале «Angewandte Chemie International Edition» и могут быть использованы для создания органических светодиодов нового поколения. Maria P. Davydova, Ting Xu, Alexander M. Agafontsev, Lingqiang Meng, Mariusz Wolff, Maxim Yu. Petyuk, Irina Yu. Bagryanskaya, Alexey S. Berezin, Alexey V. Tkachev, Hong Meng, Alexander V. Artem'ev. Toward Rhenium-based Circularly Polarized OLEDs UsingTailored Chiral Re(CO)3 Emitters. Angew. Chem. Int. Ed. 2024. https://doi.org/10.1002/anie.202419788 Источник: НИОХ СО РАН #российскаянаука
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Ученые лаборатории химии технеция Института физической химии и электрохимии РАН изучили подверженность биообрастанию и коррозииметаллического технеция. Выяснилось, что жизнедеятельность бактерий на первом этапе провоцирует коррозионные процессы, но через некоторое время продукты метаболизма и мертвые микроорганизмы покрывают поверхность металла подобно пленке и процессы коррозии останавливаются. https://www.kommersant.ru/amp/7381192 #тожехимия
https://t.me/chemrussia/5166?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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https://telegra.ph/Ricin-11-13
https://t.me/incredible_chemistry/349?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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eng
NOT SPAM
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Анисовка - крепкий алкогольный напиток с долгой историей, начиная с XVI века. Его уникальный вкус и аромат обусловлены семенами аниса обыкновенного. В разных странах он приобрел свои особенности: во Франции - пастис, в Испании - анизетта, в Греции - узо, в Италии - самбука, в Турции - раки. Основной компонент анисовки - эфирное масло семян аниса, на 90% состоящее из анетола. Анетол бывает двух форм: безопасный транс-анетол, используемый как ароматизатор, и потенциально ядовитый цис-анетол. В эфирном масле преобладает транс-форма, но под воздействием света она может превращаться в цис-форму, делая напиток опасным. Для предотвращения этого производители разливают анисовку в бутылки из темного стекла, обычно синего или зеленого цвета, чтобы защитить напиток от света и сохранить его качество и безопасность.
https://t.me/incredible_chemistry/351?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
4,900
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[{"ner":"Франции","lemma":"франция","label":"LOC","start_pos":199,"end_pos":206},{"ner":"Испании - анизетта","lemma":"испания - анизетта","label":"LOC","start_pos":219,"end_pos":237},{"ner":"Греции - узо","lemma":"греция - узо","label":"LOC","start_pos":241,"end_pos":253},{"ner":"Италии","lemma":"италия","label":"LOC","start_pos":257,"end_pos":263},{"ner":"Турции - раки","lemma":"турция - раки","label":"LOC","start_pos":277,"end_pos":290},{"ner":"Анетол","lemma":"анетол","label":"PER","start_pos":378,"end_pos":384},{"ner":"90","lemma":"90","label":"NUM","start_pos":352,"end_pos":354}]
NEUTRAL
rus
NOT SPAM
118
0
3
0.993333
0.006667
0
16
13
3
2
45
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true
118
null
Закись азота известная как веселящий газ, была впервые синтезирована Джозефом Пристли в 1772 году. В медицине начала использоваться в 1844 году как анестетик в стоматологии. Газ вызывает эйфорию и уменьшает болевую чувствительность, но в больших дозах может быть опасен, вызывая отравление и потерю сознания. В настоящее время его применяют в медицинских процедурах, а также в пищевой и автомобильной промышленности. Однако как парниковый газ он способствует изменению климата.
https://t.me/incredible_chemistry/352?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,600
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[{"ner":"Джозефом Пристли","lemma":"джозеф пристли","label":"PER","start_pos":69,"end_pos":85},{"ner":"1772","lemma":"1772","label":"NUM","start_pos":88,"end_pos":92},{"ner":"1844","lemma":"1844","label":"NUM","start_pos":134,"end_pos":138}]
NEUTRAL
rus
NOT SPAM
67
0
2
1
0
0
11
11
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20
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9
true
118
null
Доброе утро! Вот такой торт для нашего заведующего, хирурга-аритмолога 😍
https://t.me/simplebestbiochemistry/516?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,900
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null
POSITIVE
rus
NOT SPAM
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Полезный ресурс для проверки лекарственных средств на доказанную эффективность. ⤵️ Система сразу дает ссылки на клинические исследования и метаанализы. Интересно и практично 😉 БАДы искать не стоит, потому что далеко не все зарегистрированы, как лекарственные вещества, а соответственно прошли все необходимые стадии исследований. https://mediqlab.com
https://t.me/simplebestbiochemistry/517?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,100
0
1,733,141,163
1,736,456,922
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[{"ner":"https://mediqlab.com","lemma":"https://mediqlab.com","label":"ORG","start_pos":330,"end_pos":350}]
NEUTRAL
rus
NOT SPAM
44
0
0
0.982143
0.017857
0
7
5
1
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true
118
null
ГЛУТАТИОН. Что это такое? Итак, продолжая тему ацетилцистеина, будет правильно и логично рассказать про глутатион. Наверняка те, кто работают со здоровьем с точки зрения превентивной медицины много слышали и знают про это уникальное соединение! Но давайте для начала разберемся, а что это такое? 👨‍⚕️ С точки зрения биохимии, глутатион - трипептид , потому что состоит из трех аминокислот, соединенных пептидной связью: Глутамат - Цистеин - Глицин Соединяясь друг с другом они формируют: гамма - глутамилцистеинглицин или другим термином - глутатион . 🔥 Максимально простое для понимания строение, но огромная функция для каждой клетки. ❗️ Обратите внимание, что все клетки нашего организма способны синтезировать глутатион, а особенно активно этот процесс идет в гепатоцитах - клетках печени, поскольку там роль глутатиона раскрывается во всех его функциях! А Какие именно функции он выполняет, мы разберем с вами дальше! 😉 А что вы знаете про глутатион?
https://t.me/simplebestbiochemistry/518?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,900
0
1,733,295,837
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[{"ner":"ГЛУТАТИОН","lemma":"глутатион","label":"ORG","start_pos":0,"end_pos":9},{"ner":"Глутамат - Цистеин - Глицин","lemma":"глутамат - цистеин - глицин","label":"PER","start_pos":420,"end_pos":447}]
NEUTRAL
rus
NOT SPAM
142
0
4
1
0
0
9
18
14
1
42
9
28
true
118
null
ГЛУТАТИОН. Антиоксидантная роль Как правильно многие отмечали в предыдущих уроках, глутатион - важнейший и ключевой антиоксидант нашего организма. Но важно понимать, что глутатион не самостоятельный антиоксидант, а кофермент фермента глутатионпероксидазы . ❗️ Кстати еще одним коферментом глутатионпероксидазы является селен! 🧪 Свободные радикалы, будучи чрезвычайно активными, стремятся отнять электроны у других молекул - белков, фосфолипидов мембран, ДНК и РНК, вызывая их повреждение. Глутатионпероксидаза нейтрализует 💪 эти свободные радикалы, используя глутатион, как безопасный донор электронов. 🔝 Высокая концентрация глутатиона наблюдается так или иначе во всех клетках нашего организма, что обуславливает стойкую защиту от окислительного стресса!
https://t.me/simplebestbiochemistry/519?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,800
0
1,733,381,721
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[{"ner":"ГЛУТАТИОН","lemma":"глутатион","label":"ORG","start_pos":0,"end_pos":9},{"ner":"🔝\nВысокая концентрация глутатиона","lemma":"🔝\nвысокий концентрация глутатиона","label":"ORG","start_pos":603,"end_pos":636}]
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Игра в конструктор. Как построить молекулу? 🧬 Со школы мы знаем, что молекулы образуются за счёт возникновения химических связей между атомами. Например, молекула воды H₂O существует благодаря ковалентным связям между атомами водорода H и кислорода O, в кристаллы поваренной соли NaCl сформированы за счет ионной связи между хлорид-ионами и натрием. Но можно ли построить молекулу без химических связей? Неожиданный ответ — отчасти да, можно . Этой идеей загорелись ученые еще в прошлом веке — и у них получилось синтезировать молекулы, разные части которых удерживаются исключительно механически . Давайте посмотрим, что это за молекулы. Первыми были получены катенаны . Представьте себе звенья цепи — кольца, соединенные друг с другом ⛓ А теперь представьте молекулу, которая имеет аналогичное строение — две циклические структуры, продетые друг в друга. Длинная органическая цепочка состоит из атомов, соединенных химической связью, но между собой кольца соединены лишь механически — как два обруча, продетых друг в друга 🔗 На картинке молекула катенана схематически изображена слева . Первые синтезы катенанов опирались на принципы вероятности. Бралась реакционная смесь из длинных молекул, которые могли при определенных условиях образовывать кольцо, и надеялись: вдруг какая-то из них во время замыкания окажется продетой в уже существующий цикл и получится два звена, соединенных между собой . Чисто статистически катенаны действительно образовывались — их удавалось зафиксировать, но содержание было чрезвычайно мало (около 0,0001%). Другой тип молекул — ротаксаны — представляет собой структуры, состоящие из гантели и надетного на нее обруча ⭕️ В данном случае соскользнуть с перекладины кольцу мешают массивные группы на концах 📍 На картинке модель молекулы ротаксана находится справа . Первые синтезы ротаксана так же были предложены на основе статистики: какая-то доля циклических молекул в смеси могла замкнуться вокруг гантелевидных молекул. Существуют катенаны с большим числом звеньев и ротаксаны с большим числом надетых колец, а так же другие типы молекул с механическим взаимодействием: узлы и молекулярные кольца . Синтез подобных веществ представляет собой интересную задачу. В настоящее время никто не надеется на авось — разработаны новые методы направленного синтеза. Также хочу сказать пару слов о применении полученных экзотических соединений. Ротаксаны стали объектом внимания и биологов, и нанотехнологов. Современные ученые рассматривают такие структуры как элементы молекулярных машин — уже построены ротаксановые молекулярные переключатели, «молекулярные мышцы» и нанороботы. Наука не стоит на месте 👩‍🔬
https://t.me/ychemistry/1026?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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[{"ner":"NaCl","lemma":"nacl","label":"ORG","start_pos":280,"end_pos":284},{"ner":"Наука","lemma":"наука","label":"PER","start_pos":2608,"end_pos":2613},{"ner":"₂","lemma":"₂","label":"NUM","start_pos":169,"end_pos":170},{"ner":"0","lemma":"0","label":"NUM","start_pos":1532,"end_pos":1533},{"ner":"0001","lemma":"0001","label":"NUM","start_pos":1534,"end_pos":1538}]
NEUTRAL
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Химия изобразительного искусства 🎨 Если, глядя на картины известных художников, вы задумываетесь не только о том, какую мысль автор хотел донести до зрителя, но и о том, из чего состоят живые мазки на полотне , то нам определенно есть о чем поговорить . Даже если вы не увлекаетесь живописью — уроки ИЗО в школьные годы не обходят никого мимо, и коробочка гуаши или медовой акварели была у каждого. Так что же входит в состав красок? 👩🏻‍🎨 Все художественные краски — масляные, акриловые, гуашевые, акварельные и др. — состоят из пигмента и связующих компонентов . Начнём со связующих веществ — они необходимы для того, чтобы скреплять частички сухого пигмента и образовывать надежный плотный слой краски . Можно сказать, что именно связующее вещество отличает один вид красок от других , потому что оно отвечает за текстуру, плотность и другие характеристики материала 🧪 Например, в художественной акварели связующим веществом является водорастворимая смола растительного происхождения — гуммиарабик 🌿 . К полученной клееобразной смеси добавляют консервант — фенол, — чтобы краски не покрывались плесенью, и пластификаторы. При растворении в воде акварель образует взвесь мельчайшего пигмента , который переносится на бумагу и создает эффект лёгкости и воздушности. В медовой акварели (что очевидно из названия) в качестве связующего вещества используют продукты переработки мёда 🍯 Это позволяет избежать использования фенола, делает краски безопасными для детского творчества , но сказывается на цветопередаче и способности красок смешиваться и наслаиваться друг на друга. Гуашь по своему составу близка к акварели и относится к водорастворимым краскам на клеевой основе — камеди или декстрине. От акварели гуашь отличается добавкой белил в основу каждого цвета. Примесь белил придаёт гуаши высокую кроющую способность и матовую бархатистость, но при высыхании её цвета выбеливаются и заметно отличаются от еще влажной краски. Совсем иначе ведут себя акриловые краски , которые при высыхании темнеют и представляют смесь пигмента, воды и полимеров акриловой кислоты. Акриловая краска не просто высыхает — в её слое проходит химическая реакция полимеризации по мере испарения воды 💧 Благодаря этому образуется прочная плёнка , которую после нанесения можно смыть только специальным растворителем. И, наконец, масляные краски , связующим веществом в которых являются специальные высыхающие масла . Обычно используют льняное масло или олифы — плёнкообразующие вещества на основе растительных масел. Под влиянием воздуха, света и тепла такие масла густеют и в тонком слое превращаются в твёрдую массу . Так масляные краски прочно закрепляются на холсте, но на это им нужно гораздо больше времени, чем тем же акриловым 🖼 Все перечисленные выше виды красок объединяет одно — пигменты . Именно они отвечают за цвет 🎨 Еще в древние времена человек научился перетирать минералы с целью получения красящих веществ. Так и по сей день — большинство пигментов в художественных красках состоят из натуральных природных соединений . Здесь можно начать совсем другой разговор, потому что между различными пигментами возникают особые взаимодействия вплоть до того, что одни красящие вещества могут разрушать другие и менять их цвет. Это почти отдельная химия 👩🏻‍🔬
https://t.me/ychemistry/1028?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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​ Йодированная соль. Нужно ли? 🤔 Йод — важный микроэлемент в нашем организме , входящий в состав гормонов щитовидной железы — тироксина (Т₄) и трийодтиронина (T₃) . При недостатке йода эти гормоны не синтезируются в необходимых количествах, что приводит к сбоям в обмене веществ и нарушению процессов роста и развития всего организма 😨 К сожалению, проблема йододефицита затрагивает около четверти населения планеты, что связано с неравномерным распространением йода 🌍 Из пищи йод в достаточных количествах получают в основном жители приморских районов. В тех местах, где содержаний йода в почве, воде и воздухе очень мало , было предложено искусственно добавлять его соединения в продукты питания. Соединения йода пробовали добавлять в хлеб, молоко, воду... Но остановились на самом универсальном и удобном варианте — поваренной соли 🧂 Как йодируют соль? По технологии добавки выделяют два способа: сухой и влажный . Здесь всё просто. В сухом методе йодирующий агент смешивают сначала с небольшим количеством поваренной соли, а потом полученный концентрат равномерно распределяют в основной массе. В данном методе важно равномерно перемешать и распределить компонент: всего 40 миллиграмм на целую тонну соли ⚖️ Во влажном способе йодирующий агент растворяют в воде и распыляют полученный раствор над массой соли. Незначительное повышение влажности поваренной соли допускается согласно ГОСТу 💦 А теперь о том, какие соединения йода используют . Йодировать соль начинали с помощью йодида калия KI , но данное соединение неустойчиво — под действием света и воздуха йодид калия окислялся до свободного йода I₂ и улетучивался. Поэтому соль с такой добавкой хранили в темных пакетах и в рамках срока годности. Сейчас соль йодируют преимущественно йодатом калия KIO₃ , который более стабилен при хранении и внешнем воздействии 🌤 С разложением соединений йода связана одна из проблем йодированной соли — она непригодна для домашнего консервирования . Выделяющийся свободный йод, как антисептик, мешает квашению капусты и засолке огурцов. Это безвредно для потребителя и сказывается лишь на эстетических качествах — овощи темнеют 🥒 Всем ли нужна йодированная соль? Нет 🤷‍♀️ Как недостаточное, так и избыточное поступление йода вызывает отрицательный эффект. Учитывая, что большинство из нас не знает об уровне йода в своём организме, не стоит надеяться, что йодированная соль станет панацеей от недугов. Безусловно, в истории есть достаточное количество благоприятных примеров : в Швейцарии, России, Казахстане и других странах центральной Азии общий уровень йододефицита удалось снизить за годы использования йодированной соли 📉 Но на мой взгляд более разумно, чтобы контроль над риском йододефицитных заболеваний проводил ваш лечащий врач . На основе анализов специалист может назначить куда более эффективные витамины и добавки, если они будут необходимы 💊 Оптимальным вариантом профилактики может стать сбалансированное и разнообразное питание : ешьте рыбу, морепродукты и морскую капусту 🐟 А соль выбирайте ту, что больше нравится 😉
https://t.me/ychemistry/1029?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
2,000
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NEUTRAL
rus
NOT SPAM
440
0
12
0.992793
0.007207
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true
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Реакция монохлорида йода и белого фосфора
https://t.me/chemistrytg2021/9525?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,400
0
1,735,539,600
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null
NEUTRAL
rus
NOT SPAM
6
0
0
1
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1
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true
118
null
Завораживающее горение стальной ваты.
https://t.me/chemistrytg2021/9526?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,200
0
1,735,550,400
1,736,456,923
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NEUTRAL
rus
NOT SPAM
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Смесевое взрывчатое вещество АСДТ, состоящее из аммиачной селитры и углеводородного горючего вещества, чаще всего, дизельного топлива.
https://t.me/chemistrytg2021/9527?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,100
0
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null
NEUTRAL
rus
NOT SPAM
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true
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Бурная реакция взаимодействие горячего парафина с холодной водой.
https://t.me/chemistrytg2021/9528?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,000
0
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null
NEUTRAL
rus
NOT SPAM
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Светодиод в жидком азоте
https://t.me/chemistrytg2021/9529?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,100
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Пятая научно-практическая конференция для школьников «Неорганическая химия и материаловедение: поколение NEXT» в ИОНХ РАН В Институте общей и неорганической химии имени Н.С. Курнакова РАН состоялась Пятая научно-практическая конференция для школьников «Неорганическая химия и материаловедение: поколение NEXT», в которой приняли участие более 30 учащихся старших классов из 10 московских школ. Конференция проводилась при поддержке Института развития профильного обучения ГАОУ ВО «Московский городской педагогический университет» в рамках городского образовательного проекта Департамента образования и науки города Москвы «Академический класс в московской школе». Участники мероприятия выступили с докладами, посвященными собственным исследованиям, выполненным под руководством учителей школ, преподавателей вузов и научных сотрудников институтов. Тематики работ охватывали такие современные направления неорганической химии и материаловедения, как синтез и исследование функциональных материалов, изучение строения и медико-биологических свойств координационных соединений, получение наночастиц металлов, новых термобарьерных покрытий и ценных химических продуктов из бионефти. В завершение мероприятия состоялась церемония награждения победителей и призёров. Информация о мероприятии, список победителей и призеров размещены на сайте проекта «Академический класс в московской школе» #конференция #ионх
https://t.me/chemrussia/5153?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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В Институте органической химии имени Н.Д. Зелинского РАН состоялось заседание Общего собрания Отделения химии и наук о материалах РАН. Его центральным событием стала научная сессия «Взаимодействие ОХНМ РАН с органами государственной власти и организациями реального сектора экономики в решении проблем научно-технологического развития Российской Федерации». На заседании состоялось вручение почетных грамот от министра промышленности и торговли РФ за активную деятельность в рамках взаимодействия с Минпромторгом, благодарностей за участие в экспертной оценке работ участников Конкурса для молодых ученых, приуроченного к 300-летию Российской академии наук, а также почетных грамот в честь юбилея членов ОХНМ. 🔗 Ссылка на фото. Мероприятие началось с приветственных слов заместителя министра науки и высшего образования РФ Дениса Сергеевича Секиринского , заместителя директора Департамента химической промышленности Министерства промышленности и торговли РФ Шамиля Рустямовича Юлгушева и президента Российского Союза химиков Виктора Петровича Иванова . В рамках научной программы были представлены доклады, охватывающие ключевые направления развития химии и материаловедения: 🔹 «Лазерные стратегии в решении проблем инновационного материаловедения: от авиации, теплоэнергетики и строительства до медицины и электроэнергетики» —академик РАН Людмила Борисовна Бойнович. 🔹 «Сотрудничество ИНХС РАН с предприятиями реального сектора экономики в области технологий газо- и нефтехимии» — член-корреспондент РАН Антон Львович Максимов. 🔹 «Обратный инжиниринг полировальных паст на основе оксида церия» — член-корреспондент РАН Владимир Константинович Иванов. 🔹 «Сотрудничество ИОХ РАН с предприятиями реального сектора экономики и ФОИВами в области гликотехнологий» — член-корреспондент РАН Николай Эдуардович Нифантьев. 🔹 «Физикохимия поверхности в ракетно-космической отрасли» — член-корреспондент РАН Алексей Константинович Буряк. 🔹 «Металл-ионные аккумуляторы: проблемы и перспективы» — член-корреспондент РАН Евгений Викторович Антипов. 🔹 «Химическая технология материалов ядерной энергетики: новые разработки и внедрения» — член-корреспондент РАН Иван Гундарович Тананаев. 🔹 «Химия в сельском хозяйстве» — член-корреспондент РАН Александр Олегович Терентьев. 🔹 «Ресурсосберегающий метод извлечения лития из рудных материалов и жидких сред» — член-корреспондент РАН Руслан Хажсетович Хамизов и генеральный директор АО «НПП «Радий» Магомет Абубекирович Конов. 🔹 «Участие ФИЦ ПХФ и МХ РАН в разработке материалов для микроэлектроники» — д.х.н. Эльмира Рашатовна Бадамшина и к.х.н. Георгий Васильевич Малков. 🔹 «Разработки порошковой металлургии для реального сектора экономики» — член-корреспондент РАН Михаил Иванович Алымов. Заседание подчеркнуло важность сотрудничества науки с государственными структурами и бизнесом для решения приоритетных задач страны. Доклады продемонстрировали потенциал научных разработок для внедрения в различных отраслях — от ракетостроения и медицины до сельского хозяйства и энергетики.
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Фильм «Препараты для жизни Андрея Жданова» Старший научный сотрудник Института общей и неорганической химии им. Н.С. Курнакова РАН, к.х.н. Андрей Жданов стал главным героем фильма из цикла «Российский код. Суверенное будущее», посвященного молодым талантливым учёным и изобретателям, создающим в России реальные технологии будущего. Он рассказал о создании препаратов для бор-нейтронозахватной терапии (БНЗТ). Развитие метода БНЗТ требует от химиков-синтетиков создания эффективных лекарственных средств, содержащих изотоп бора-10. С лечением методами БНЗТ связаны надежды очень и очень многих людей в нашей стране и во всем мире. #российскиеученые #ионх
https://t.me/chemrussia/5161?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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Цикл семинаров «Новые функциональные материалы: синтез, свойства и области применения» в ИОНХ РАН Цикл семинаров организован Советом молодых ученых ИОНХ РАН при поддержке Научного совета РАН по неорганической химии в рамках Десятилетия науки и технологий. На rutube-канале ИОНХ РАН опубликована видеозапись лекции: к.т.н. Севостьянова Михаила Анатольевича «Титановые сплавы для медицинского применения» . С подробной информацией о мероприятии можно ознакомиться на сайте ИОНХ РАН #ионх #российскаянаука
https://t.me/chemrussia/5162?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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NEUTRAL
rus
NOT SPAM
65
0
10
0.988506
0.011494
0
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true
118
null
https://telegra.ph/Pochemu-vcherashnyaya-eda-nevkusnaya-10-22
https://t.me/incredible_chemistry/345?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,100
0
1,698,037,200
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https://t.me/incredible_chemistry/346?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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NEUTRAL
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https://telegra.ph/Kak-svyokla-prevrashchaetsya-v-sahar-10-25
https://t.me/incredible_chemistry/347?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,800
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https://telegra.ph/Krovyanye-soli-10-27
https://t.me/incredible_chemistry/348?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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[{"ner":"10-27","lemma":"10-27","label":"DATE","start_pos":34,"end_pos":39},{"ner":"27","lemma":"27","label":"NUM","start_pos":37,"end_pos":39}]
NEUTRAL
eng
NOT SPAM
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НИЗКИЙ ГОМОЦИСТЕИН. Что значит? Мы много знаем про повышенный гомоцистеин, про его способность повреждать эндотелий и лежать в основе патогенеза многих заболеваний еще на самом раннем этапе. ❓ Но о чем нам может сказать пониженный уровень гомоцистеина в плазме крови? Имеет ли это диагностический смысл? Низким уровне мы можем называть значения гомоцистеина менее 5 ммол/л. 🧑🏼‍⚕️ Стоит сказать, что такие значения носят значительно более благоприятный характер с точки зрения профилактики сердечно-сосудистых заболеваний, но тем не менее тоже имеют определенные метаболические причины! С точки зрения биохимии я могу выделить три самостоятельных причины, каждые из которых мы рассмотрим в отдельных уроках. 1️⃣ Гиперметилирование Для превращения гомоцистеина в метионин требуются витамины Б9 и Б12. При слишком агрессивной поддержке данными витаминами метилирование гомоцистеина до метионина происходит слишком быстро, а потому уровень гомоцистеина находится на низком уровне. ❓ Может возникнуть вопрос, а что плохого? Проблема заключается в том, что гомоцистеин кроме восстановления в метионин еще и является источником аминокислоты цистеина , который необходим для синтеза белка, глутатиона, желчных кислот, КоэнзимаА и прочих продуктов. Однако если гомоцистеин очень низкий, то и синтез цистеина из гомоцистеина идет медленно. Что делать? 😳 ❗️ Сделать перерыв в приеме в первую очередь витамина Б9 и Б12 до тех пор, пока гомоцистеин не вернется в референс. Но есть и другие причины низкого гомоцистеина, которые мы обсудим с вами в дальнейшем! А вы знали об этом?
https://t.me/simplebestbiochemistry/509?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,100
0
1,732,516,662
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[{"ner":"НИЗКИЙ","lemma":"низкий","label":"ORG","start_pos":0,"end_pos":6},{"ner":"ГОМОЦИСТЕИН","lemma":"гомоцистеин","label":"ORG","start_pos":7,"end_pos":18},{"ner":"метионина","lemma":"метионин","label":"PER","start_pos":883,"end_pos":892},{"ner":"5","lemma":"5","label":"NUM","start_pos":364,"end_pos":365},{"ner":"1","lemma":"1","label":"NUM","start_pos":707,"end_pos":708},{"ner":"9","lemma":"9","label":"NUM","start_pos":791,"end_pos":792},{"ner":"12","lemma":"12","label":"NUM","start_pos":796,"end_pos":798},{"ner":"9","lemma":"9","label":"NUM","start_pos":1400,"end_pos":1401},{"ner":"12","lemma":"12","label":"NUM","start_pos":1405,"end_pos":1407}]
NEUTRAL
rus
NOT SPAM
224
0
8
1
0
0
26
31
19
3
68
15
36
true
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null
Не только в роли слушателя, но и докладчика на XXX Съезде сердечно-сосудистых хирургов! 😉 Рассказываю про успешный случай устранения атипичной тахикардии!
https://t.me/simplebestbiochemistry/513?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,800
0
1,732,685,652
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rus
NOT SPAM
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НИЗКИЙ ГОМОЦИСТЕИН. Дефицит серосодержащих аминокислот Предыдущий пост на эту тему вызвал бурную реакцию и много вопросов, поэтому мы продолжаем. 🧑🏼‍⚕️ Напоминаю, что гомоцистеин имеет два пути: восстановиться до метионина или пойти по пути синтез цистеина (важнейший транссульфатный путь). Поэтому при недостатке метионина и цистеина (две серосодержащие аминокислоты), гомоцистеин будет идти активно на их синтез при наличии соответствующих кофакторов: Б6, Б9, Б12, а потому иметь тенденцию к снижению в крови. ❓ Отсюда вопрос, когда возникает этот недостаток? 1️⃣ Истинный дефицит серосодержащих аминокислот При низкобелковом питании, диетах, вегетарианстве, беременности, активном росте, восстановлении после болезни и прочее. 2️⃣ Высокая потребность в серосодержащих аминокислотах А вот эта причина более интересна. Особую роль мы выделяем в цистеине - ключевой аминокислоте для синтеза глутатиона. При хронической интоксикации (препараты, экология, питание), усиленном окислительном стрессе, воспалении - синтез глутатиона будет ускорен в связи с его высокими потребностями, а потому цистеин будет активно расходоваться на этот метаболический путь. ❗️ Активный расход цистеина будет затрачивать пул гомоцистеина для его пополнения. А потому концентрация гомоцистеина в плазме крови начнет снижаться. А что вы думаете по этому поводу? 😉
https://t.me/simplebestbiochemistry/514?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,000
0
1,732,776,898
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[{"ner":"НИЗКИЙ","lemma":"низкий","label":"ORG","start_pos":0,"end_pos":6},{"ner":"ГОМОЦИСТЕИН","lemma":"гомоцистеин","label":"ORG","start_pos":7,"end_pos":18},{"ner":"метионина","lemma":"метионин","label":"PER","start_pos":213,"end_pos":222},{"ner":"синтез цистеина","lemma":"синтез цистеин","label":"PER","start_pos":241,"end_pos":256},{"ner":"цистеина","lemma":"цистеина","label":"PER","start_pos":326,"end_pos":334},{"ner":"6","lemma":"6","label":"NUM","start_pos":455,"end_pos":456},{"ner":"9","lemma":"9","label":"NUM","start_pos":459,"end_pos":460},{"ner":"12","lemma":"12","label":"NUM","start_pos":463,"end_pos":465},{"ner":"1","lemma":"1","label":"NUM","start_pos":562,"end_pos":563},{"ner":"2","lemma":"2","label":"NUM","start_pos":730,"end_pos":731}]
NEUTRAL
rus
NOT SPAM
177
0
8
1
0
0
20
22
5
3
64
10
40
true
118
null
АЦЕТИЛЦИСТЕИН. Биохимическая роль Продолжая нашу тему про цистеин, нельзя не упомянуть про ацетилцистеин или АЦЦ! Для большинства он ассоциируется в первую очередь, как препарат, улучшающий отхождение вязкой мокроты. Поэтому в клинических рекомендациях он фигурирует как средство для санации трахеобронхиального дерева 🫁 . ❗️ Но его вклад значительно больше! Ацетилцистеин - фактически представляет собой стабильный цистеин, который пополняет фонд цистеина в организме. 1️⃣ Во-первых, цистеин - важнейший субстрат для синтеза глутатиона, поэтому АЦЦ оказывает антиоксидантную роль и улучшает детоксификационную функцию печени. За все спасибо глутатиону! 🙏 2️⃣ Во-вторых, АЦЦ сам по себе может выступать, как антиоксидант за счет наличия свободной сульфогруппы -SH, связывая и нейтрализуя свободные радикалы, оказывая тем самым противовоспалительную роль и уменьшая окислительный стресс. Вот такой вот уникальный АЦЦ! А вы используете его? 😉
https://t.me/simplebestbiochemistry/515?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,300
0
1,732,959,446
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Как исследуют реальные объекты? 🔬 Вполне очевидно, как проводятся эксперименты с лабораторными реактивами — просто берём раствор в баночке с полки и смешиваем его в колбе с другим реактивом 🧪 Но проблема возникает, когда речь заходит о реальных объектах . Вы вряд ли что-то сможете определить, засунув кусок торта , ломтик колбасы или горсть земли в пробирку 🍰 Чтобы провести анализ, необходимо перевести объект в подходящую форму , и обычно такой формой является раствор . Причем необходимо учитывать, желаем мы определить конкретный элемент (содержание серы S в нефтепродуктах), соединение (примесь метанола CH₃OH в этиловом спирте) или целую группу веществ (общая кислотность вина), потому что часть из них может улетучиваться в виде газов, реагировать между собой с образованием побочных продуктов или распадаться вовсе ⚗️ Проще говоря, способ разложения выбирается индивидуально для решения конкретной химической задачи. Главное — перевести в раствор все определяемые компоненты и не допустить их потерь 👩🏻‍🔬 Издавна способы разложения пробы делятся на «сухие» 🔥 и «мокрые» 💧 Под «мокрыми» методами разложения понимается растворение пробы в растворителях, преимущественно в кислотах и их смесях при нагревании. Идеальным вариантом является чистая вода, но зачастую вещество не будет растворяться в ней 💦 Например, многие сульфидные руды растворяют при нагревании в соляной кислоте HCl с добавлением азотной HNO₃ . Зачастую добавляют окисляющие реагенты (перекись водорода, бром и др.), которые ускоряют процесс растворения и переводят вещество в удобную для анализа форму. Избежать потерь серы в виде газа сероводорода H₂S при анализе серосодержащих руд можно с помощью концентрированной азотной кислоты и брома, которые сразу окисляют сульфиды до сульфатов 💥 Мокрый способ разложения используется при определении содержания белков в пищевых продуктах методом Кьельдаля . Например, овсяную или гречневую крупу растворяют в концентрированной серной кислоте с добавлением катализатора и при нагревании. И только после разложения пробы проводят анализ 🍪 Для растворения полимерных материалов используют органические растворители: спирты, эфиры, жидкие углеводороды и хлорорганику 🧽 «Сухие» способы разложения используются реже — в тех случаях, когда проба не растворяется или содержит сложные органические примеси. В таких ситуациях пробу прокаливают над пламенем горелки, в муфельной печи или токе кислорода. Зачастую для вскрытия пробы используются различные твёрдые плавни (например, карбонат и пиросульфат натрия) и добавляются окислители (нитраты и хлораты) 🌡 Внимательно нужно относиться к выбору посуды для сухого разложения. Сплавление необходимо проводить в тугоплавких керамических, графитовых или платиновых тиглях. При щелочном разложении нельзя использовать стеклянную или керамическую посуду, потому что входящие в её состав оксиды кремния SiO₂ будут постепенно растворяться в щелочи 😱 Современное оборудование позволяет проводить разложение пробы в герметичных сосудах — автоклавах . Использование автоклавов позволяет избежать улетучивания и разбрызгивания компонентов, а также ускорить сам процесс минерализации, потому что разложение протекает при высоком давлении (10-20 атмосфер) 🧭 Всё шире и шире используется современное оборудование для минерализации реальных объектов — специальные микроволновые печи . Принцип работы у них такой же, как у бытовых микроволновок, только размер и мощность побольше. По сравнению с традиционными лабораторными методами разложения, использование микроволновых минерализаторов ускоряет процесс почти в 20 раз ⏳
https://t.me/ychemistry/1023?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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​​ Веселящий газ. Как работает наркоз? 😷 В настоящее время почти невозможно представить даже незначительное хирургическое вмешательство без применения анестезии . Она необходима не только для того, чтобы пациент не чувствовал боли , но и чтобы убрать напряжение мышц и других тканей , мешающее работе хирурга. Только мало кто знает, что применение современных анестезирующих препаратов начиналось с открытия самых простых химических веществ 👩🏻‍🔬 Каким образом анестезия блокирует боль? Если совсем просто, то сами по себе болевые ощущения формируются в головном или спинном мозге в ответ на болевые импульсы , идущие от специальных рецепторов по всему телу 🧠 Анестезия блокирует нервные окончания , нарушая цепочку специальных биохимических реакций, — из-за этого болевой импульс не доходит до центральной нервной системы. Местная анестезия нарушает передачу импульса в определенном участке, а общая (именно её называют наркозом ) полностью угнетает ЦНС, убирая болевую чувствительность по всему телу. Одним из самых популярных веществ для ингаляционного наркоза является оксид азота (I) N₂O (закись азота) . Вскоре после его открытия на рубеже 17-18 веков было обнаружено, что вдыхание небольших количеств закиси азота сопровождается эффектом опьянения, эйфории и появлением приступов смеха . За эту особенность закиси азота дали еще одно название — веселящий газ . Смекалистые умельцы уже на том этапе исторического развития нашли открытому газу альтернативное применение, вдыхая его на светских вечеринках. Впрочем, мало что изменилось. Воздушные шары с веселящим газом по-прежнему продают в клубах и на вечеринках. Но я настаиваю на том, чтобы вы не злоупотребляли закисью азота без медицинской необходимости 🤔 В высоких концентрациях оксид азота применяется в медицине для обеспечения хирургического наркоза во время мелких и крупных операций. Другим популярным летучим веществом для ингаляционной анестезии является диэтиловый эфир . Вещество с простой химической формулой получило широкое распространение в анестезиологии благодаря сильному эффекту и безопасности применения . Выдающийся отечественный хирург Н.И.Пирогов первым в истории медицины начал оперировать в полевых условиях раненых с использованием диэтилового эфира в качестве обезболивающего. В современной медицине используются различные комбинации анестезирующих веществ для достижения эффективного и безопасного наркоза. Помимо веществ ингаляционного типа , то есть тех, что вводятся через дыхательные пути (+ к упомянутым выше: хлороформ, фторотан, изофлуран ), распространены инъекционные вещества — кетамин, производные барбитуровой кислоты и др. 🧪 Выбор типа анестезии и препаратов осуществляется анестезиологом на основе предварительных исследований. Именно он контролирует как состояние организма во время операции, так и режим подачи анестезирующих веществ. Поэтому ни одно оперативное вмешательство не может обойтись без врача-анестезиолога 😉
https://t.me/ychemistry/1024?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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​​ Биотопливо 🌱 В эпоху, когда мировое сообщество обеспокоено проблемой глобального потепления , исследуется множество способов уменьшить выбросы парниковых газов в атмосферу. Далеко не новым, но, возможно, эффективным решением является использование биотоплива 🔋 Само слово биотопливо у многих на слуху, но мало кто действительно интересовался, из чего его производят. Биотопливо — топливо из растительного или животного сырья, из продуктов жизнедеятельности организмов или органических промышленных отходов. Различают несколько видов биотоплива: • Твёрдое биотопливо 🧱 Обычные дрова известны людям с древнейших времён и активно используются по сей день. Для их производства выращивают специальные энергетические леса , состоящие из быстрорастущих пород (тополь, эвкалипт, ива), и используют ту древесину, которая непригодна для строительства и декоративных целей. С развитием технологий появились топливные брикеты и гранулы (пеллеты), состоящие из спрессованных отходов деревообработки — опилок и шелухи. При их сгорании выделяется в полтора раза больше энергии, чем при сгорании обычных дров, но почти в два раза меньше, чем при сгорании каменного угля. В качестве источников дешевой энергии используют так же высушенный навоз, солому и торф . Твердое биотопливо составляет почти 60% от всего производимого биотоплива — около 38% населения использует его в бытовых целях 🔥 • Жидкое биотопливо 💧 Биоэтанол (этиловые спирт) служит альтернативой бензину , либо дополнением к нему для уменьшения количества выхлопных газов. В некоторых странах на законодательном уровне утверждено использование этанола в качестве добавки к бензину для сокращения потребления нефти. Ярким примером является Бразилия — лидер в производстве и использовании биоэтанола из сахарного тростника в качестве топлива 🇧🇷 В США биоэтанол вырабатывают преимущественно из кукурузы . К категории жидкого биотоплива так же относятся метанол и бутанол, диметиловый эфир и биодизель — моторное топливо на основе жиров животного и растительного происхождения 🌿 • Газообразное биотопливо 💨 При брожении биологической массы выделяется большое количество биогаза — смеси метана и оксида углерода , — который так же используется в качестве топлива для бытовых и промышленных нужд. Так же распространён метод получения биоводорода при действии бактерий на биомассу 🦠 Казалось бы, решение многих экологических проблем связано с отказом от минерального сырья и переходом на биотопливо... Но не всё так очевидно . Несомненно, при сгорании биотоплива не выделяется токсичных выхлопных газов, а выбросы CO₂ ощутимо меньше , чем при использовании угля или нефти. Существует даже представление об «углеродной нейтральности» , согласно которому получение энергии из растений не приводит к увеличению общего количества СО₂ в экосистеме. Но все эти доводы подвергаются разумной критике. 🤔 Если говорить об использовании дров, то представление об углеродной нейтральности рушится в краткосрочной перспективе. CO₂ моментально образуется в процессе сжигания древесины, а извлечение его из атмосферы происходит при росте новых деревьев в течение десятков и сотен лет . Эту временную задержку обычно называют «углеродным долгом» , а для европейских лесов он может достигать двухсот лет 🌳 В той же Бразилии для производства жидкого биотоплива в колоссальных количествах вырубаются естественные леса в пользу плантаций сахарного тростника и сокращаются территории , занятые пищевыми и кормовыми культурами, что в совокупности наносит большой вред экологии и увеличивает цены на продовольственные товары 🌎 К тому же, переход на использование биотоплива требует технических модификаций ⚙️ На биоэтаноле могут работать только так называемые «Flex-Fuel» автомобили с модифицированным двигателем внутреннего сгорания и гибким выбором топлива 🚘 Может быть, за биотопливом стоит будущее... Но пока мы выяснили, что полный переход на топливо из растительного и животного сырья связан с множеством трудностей 👩🏻‍🔬
https://t.me/ychemistry/1025?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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NEUTRAL
rus
NOT SPAM
547
0
12
0.994278
0.005722
0
75
54
14
11
192
20
84
true
118
null
Запускаем ракету под лёд.
https://t.me/chemistrytg2021/9520?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
1,735,453,200
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null
NEUTRAL
rus
NOT SPAM
4
0
0
1
0
0
0
1
0
0
1
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1
true
118
null
Пенополистирол загорается после контакта с гептоксидом марганца. В небольшую кучку перманганата калия добавляется немного серной кислоты. При этом немедленно образуется маслянистый гептоксид маганезия, который быстро окисляет полимер стирола в бурной реакции.
https://t.me/chemistrytg2021/9521?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,100
0
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null
NEUTRAL
rus
NOT SPAM
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true
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Тротуарный паркет или асфальтовые покрытия с водопроницаемостью, которые позволяют воде попадать в почву. Это отличный способ избежать наводнения, особенно в городах.
https://t.me/chemistrytg2021/9522?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,200
0
1,735,474,800
1,736,456,924
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null
NEUTRAL
rus
NOT SPAM
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Перекись водорода + жидкое мыло + йодид калия.
https://t.me/chemistrytg2021/9523?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,000
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NEUTRAL
rus
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Эксперимент «Фиолетовое облако» Этот эксперимент красив тем, что при взаимодействии двух простых веществ образуется яркий искрящийся дымовой вулкан.
https://t.me/chemistrytg2021/9524?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,400
0
1,735,496,400
1,736,456,924
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18-19 февраля 2025 г. в Москве пройдёт очный семинар «СОВРЕМЕННОЕ АНАЛИТИЧЕСКОЕ ОБОРУДОВАНИЕ ДЛЯ ПРОМЫШЛЕННОСТИ И НАУЧНЫХ ИССЛЕДОВАНИЙ». В программе семинара: • Доклады ведущих специалистов компании «Группа Ай-Эм-Си» о новинках аналитического оборудования на российском рынке: принцип работы, технические характеристики, опыт применения.  Программа семинара включает: • Посещение демо-лаборатории IMC, где представлено оборудование: ВЭЖХ-Хроматограф Wellsep 2000, Анализатор масел и технических жидкостей Oilspec 1000, Анализатор размеров частиц ProSizer 500Н, Анализатор серы и углерода SDHFCS 1000, Термогравиметрический анализатор TGA 1300, Дифференциальный сканирующий калориметр DSC 500JL, Анализатор удельной поверхности и пористости ProSurf 1220. • Экскурсия в демо-центр Focused Photonics (FPI), знакомство с приборами EXPEC 6500, SUPEC 7000, EXPEC 5210, EXPEC 5231, MWD790S СВЧ. Участие в семинаре бесплатное. Требуется предварительная регистрация. https://imc-systems.ru/about/news/meropriyatiya/priglashaem-na-seminar-v-moskve-18-19-fevralya-2025-g/ #семинар
https://t.me/chemrussia/5146?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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Новые протон-проводящие мембраны топливных элементов Ученые из Института химии растворов им. Г.А. Крестова РАН разработали подход к созданию новых протон-проводящих мембран топливных элементов. Предложенный способ основан на использовании промышленного полимера полибензимидазола, протонных алкиламмониевых ионных жидкостей и неорганического наполнителя. Исследования показали, что полученные мембраны обладают высокой проводимостью и достаточной электрохимической стабильностью. Результаты работы опубликованы в журнале «Solid State Ionics» и могут найти применение для создания стационарных электростанций, автономных источников тепло- и электроснабжения зданий, двигателей транспортных средств. Yuliya A. Fadeeva, Liudmila E. Shmukler, Liubov P. Safonova. Ionic liquid/polybenzimidazole/SiO2 composite membranes for medium temperature operating. Solid State Ionics, Vol. 417, 2024, 116720. https://doi.org/10.1016/j.ssi.2024.116720 Источник: ИХР РАН / ISC RAS #российскаянаука
https://t.me/chemrussia/5147?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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Оксид фтора или фторид кислорода? Термин "оксид фтора" неверен, так как в оксиде кислород связан с более электроотрицательным элементом. Поскольку кислород занимает второе место после фтора по электроотрицательности, соединения кислорода с фтором называются фторидами, как дифторид кислорода (OF2). Дифторид кислорода — реакционноспособное соединение, применяется как окислитель ракетного топлива и в газодинамических химических лазерах. Получают его реакцией фтора с водой или кислородом при высоких температурах.
https://t.me/incredible_chemistry/340?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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[{"ner":"2","lemma":"2","label":"NUM","start_pos":295,"end_pos":296}]
NEUTRAL
rus
NOT SPAM
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Мечтал узнать почему Марс красный? Из чего состоит марсианский грунт? Есть ли на Марсе вода? Наконец "Невероятная химия" подготовила тебе все ответы!
https://t.me/incredible_chemistry/342?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,600
0
1,697,691,600
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https://t.me/incredible_chemistry/343?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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null
NEUTRAL
rus
NOT SPAM
4
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true
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Сколько в металла человеке? Организм человека содержит в себе ряд металлов, хотя их общий процент в массе тела составляет всего около 4%. Среди них наиболее распространены кальций, натрий и магний. Кальций в основном сконцентрирован в костях, играя ключевую роль в формировании и поддержании костной ткани. Натрий же присутствует в межклеточной жидкости и цитоплазме клеток, действуя как электролит и поддерживая баланс жидкости в организме. Магний, распределенный в мышцах и нервной системе, критичен для работы нервной системы и сердца. Эти металлы, наряду с другими, такими как железо в крови, медь в печени, играют важную роль в поддержании здоровья и функционирования организма на оптимальном уровне.
https://t.me/incredible_chemistry/344?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
3,300
0
1,697,778,001
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[{"ner":"4","lemma":"4","label":"NUM","start_pos":135,"end_pos":136}]
NEUTRAL
rus
NOT SPAM
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Всем доброго утра и продуктивного рабочего дня ❤️ 💪🏻
https://t.me/simplebestbiochemistry/505?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
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ВИТАМИН С И ОКСАЛАТЫ Мы продолжаем с вами разговор о щавелевой кислоте, и сегодня мы скажем с вами об одном неотъемлемом источнике оксалата в нашем организме - аскорбиновой кислоте. 👨‍⚕️ На самом деле логика проста - витамин С - природный донор электронов, поэтому когда аскорбиновая кислота в процессе работы отдает 2 электрона и 2 протона водорода, она превращается в дегидроаскорбиновую кислоту . Простым языком - это «разряженный» 🪫 или окисленный витамин С, который надо восстановить до активной формы. На помощь приходит глутатион. А вот если глутатиона дефицит или аскорбиновая кислота в избытке ❗️ , то она окисляется до своих конечных продуктов, одним из которых будет щавелевая кислота! Таким образом, витамин С вносит свой вклад в пополнение фонда оксалата в нашем организме, а сверх высокие дозировки аскорбиновой кислоты могут быть ассоциированны с оксалатурией! А вы знали об этом? 😊
https://t.me/simplebestbiochemistry/506?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,100
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[{"ner":"ВИТАМИН","lemma":"витамин","label":"ORG","start_pos":0,"end_pos":7},{"ner":"2","lemma":"2","label":"NUM","start_pos":317,"end_pos":318},{"ner":"2","lemma":"2","label":"NUM","start_pos":331,"end_pos":332}]
NEUTRAL
rus
NOT SPAM
138
0
9
1
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0
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true
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null
Обмен метионина и гомоцистеина - одна из моих любимых тем в биохимии ❤️ Всегда с удовольствием и интересом рассказываю этот удивительно логичный и, на самом деле, вовсе не сложный процесс. Сегодня вновь повторяли его с учеником на занятии. 🧑🏼‍⚕️ Напомню, что метионин - донор метильной группы (-CH3), которая используется для синтеза и созревания многих активных веществ. А отдав метильную группу, метионин превращается в гомоцистеин, который далее либо снова восстанавливается до метионина ♻️ (путь 1) или идет на синтез цистеина (путь 2). А что вы знаете про этот обмен? 😉
https://t.me/simplebestbiochemistry/507?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,700
0
1,732,354,332
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[{"ner":"метионина","lemma":"метионин","label":"PER","start_pos":6,"end_pos":15},{"ner":"3","lemma":"3","label":"NUM","start_pos":297,"end_pos":298},{"ner":"1","lemma":"1","label":"NUM","start_pos":500,"end_pos":501},{"ner":"2","lemma":"2","label":"NUM","start_pos":537,"end_pos":538}]
NEUTRAL
rus
NOT SPAM
89
0
3
0.99187
0.00813
0
6
10
5
4
27
7
24
true
118
null
#о_рабочем Имплантация электрокардиостимулятора! ⚙️ Сегодня жизнь пациента с ЭКС ничем не отличается от обычного человека. Семья, спорт, путешествия, активное долголетие. Чрезвычайно умные и продуманные девайсы с большим перечнем настроек и функций. Всегда объясняю пациентам, что эти устройства не инвалидизируют, а, наоборот, оздоравливают и возвращают в привычный темп жизни! 💪🏻
https://t.me/simplebestbiochemistry/508?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
1,700
0
1,732,443,631
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​​ Разрушители озонового слоя 🌎 Раз уж мы обсудили принципы, на основе которых работают холодильники , нельзя пройти мимо связанной с использованием хладагентов проблемы разрушения озонового слоя . О том, как формируется озоновой слой, из-за чего появляются озоновые дыры и какую роль в этом процессе играют фреоны , предлагаю узнать прямо сейчас 👁 Озоновый слой — это слой атмосферы Земли с наибольшим содержанием озона. Молекула озона O₃ образуется в результате действия ультрафиолетового излучения Солнца на привычный для нас молекулярный кислород 🌤 O₂ + УФ-излучение → 2O: (образуется высокоактивный атомарный кислород ) O₂ + O: → O₃ (который затем реагирует с другой молекулой кислорода, образуя озон) В равновесии с реакцией получения озона находится процесс его разрушения под действием того же солнечного излучения: O₃ + УФ-излучение → O₂ + O: O₃ + O: → 2O₂ (озон разрушается, превращаясь в две молекулы кислорода) В ходе реакций образования и распада озона поглощаются самые опасные типы УФ-излучения , благодаря чему возможно существование живых организмов на поверхности нашей планеты 🐸 Существует несколько механизмов разрушения озонового слоя, один из которых упомянут выше. В природе процессы образования-разрушения сбалансированы — сколько озона погибает в ходе одной реакции, столько образуется в ходе другой. Но деятельность человека внесла свои коррективы, сместив баланс, как чашу весов, в сторону разрушения ⚖️ И одну из ключевых ролей в этом процессе сыграли фреоны . Фреоны — производные метана CH₄ (реже этана С₂Н₆), в которых атомы водорода заменены на фтор F, хлор Cl или бром Br . Они были получены американским химиком То́масом Ми́джли с целью сделать холодильники безопасными, поскольку ранее в них использовались ядовитые и горючие вещества 👨🏻‍🔬 Помимо уникальных термических свойств, фреоны инертны, невзрывоопасны и нетоксичны , что способствовало их распространению не только в холодильных установках, но и в качестве основы аэрозолей, газовых баллончиков и огнетушителей 🧯 К сожалению, некоторые фреоны ( не все! ), попадая в атмосферу и достигая озонового слоя, вступают в реакцию с озоном, ускоряя его разрушение , что и приводит к образованию озоновых дыр . Массовое использование фреонов во второй половине прошлого века сильно отразилось на толщине озонового слоя в отдельных регионах. Это наглядно можно проследить на ежегодном мониторинге 🌍 Мировое сообщество не оставило эту проблему без внимания, ограничив использование тех фреонов, которые оказывают озоноразрушающее влияние, но в отдельных странах до сих пор производится часть из них ( R-12 и R-22 ). И пока организации стараются перейти на безопасные для озонового слоя фреоны, над Антарктидой еще долго будет зиять огромнейшая озоновая дыра , в образовании которой важную роль сыграло их накопление ☁️ Конечно, в одном ряду с фреонами истончают озоновый слой и другие результаты деятельности человека. Но вы только задумайтесь, какой огромный вклад в этот процесс внесло небольшое открытие, сделанное одним человеком 🤔
https://t.me/ychemistry/1020?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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Телеграм-канал «Химия в России и за рубежом» https://t.me/chemrussia - это новости российской и зарубежной химической науки, объявления о химических конференциях и самая свежая информация о наиболее интересных химических исследованиях. Канал ведут химики из самого известного химического института Российской академии наук - ИОНХ РАН!
https://t.me/ychemistry/1021?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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​​ Диффузия. Как распространяются запахи? 👃 А еще почему смешиваются краски двух разных цветов? Благодаря чему мы дышим и получаем питательные вещества из пищи? Как промышленные отходы попадают в атмосферу и водоёмы ? Всё это происходит благодаря диффузии — процессу проникновения молекул одного вещества между молекулами другого 💢 Основной причиной диффузии является постоянное движение молекул и стремление к равновесию . Когда в одной области появляется избыточная концентрация частиц, молекулы стремятся перейти в области с меньшей концентрацией. Концентрация выравнивается за счёт взаимного проникновения частиц. Диффузия может протекать в разных агрегатных состояниях: газ, жидкость, твёрдое тело . И в каждой среде скорость смешивания частиц увеличивается при нагревании — чем выше температура, тем быстрее движутся частицы 🌡 Также скорость диффузии можно увеличить за счёт внешнего воздействия — чтобы сахар быстрее растворился в чае, мы размешиваем его ложкой ☕ Диффузия в газах происходит быстрее всего 💨 Частицы газа далеко удалены друг от друга. Между ними существуют огромные промежутки , сквозь которые легко и быстро перемещаются молекулы другого вещества. Поэтому запах освежителя воздуха за считанные секунды распространяется по комнате, а новые парфюм коллеги ощущается по всему офису уже с порога. Диффузия в жидкостях протекает ощутимо дольше 💦 В зависимости от температуры и плотности вещества, на смешивание может понадобиться от пары минут до нескольких часов. Это связано с тем, что промежутки между соседними молекулами жидкости меньше размеров самих молекул — частицы не бегают свободно от столкновения до столкновения, как в газе, а колеблются около одного положения или перескоками меняются местами с соседними молекулами. Поэтому мы можем наблюдать, как медленно растекается капля краски в стакане с водой, оставляя потрясающие объемные узоры 🌀 Из-за большой плотности твердых тел диффузия в них протекает очень медленно — без внешнего воздействия на появление первых признаков смешивания уйдёт несколько лет. Промежутки между частицами в кристаллической структуре очень маленькие , поэтому другим веществам трудно проникнуть между ними. В одном из экспериментов друг на друга были положены две пластины — свинцовая и золотая . Спустя пять лет было обнаружено, что золото незначительно проникло в свинцовую пластину, а атомы свинца — в золотую. Но не более, чем на один миллиметр 🔬 Поэтому диффузию в твердых телах ускоряют в условиях высокой температуры и механического воздействия . Мы довольно-таки быстро можем смешать два куска разноцветного пластилина, переминая их в руках 👐 Но если просто прижать их друг к другу и оставит, то на смешивание уйдут годы 🤔 Диффузия играет главную роль во многих биологических процессах . Благодаря ей осуществляется газообмен в лёгких, всасывание веществ в кишечнике, навигация животных по запаху и поиск пищи плотоядными рыбами в воде 🐟 И так же быстро благодаря диффузии выхлопные газы попадают в атмосферу, а реки, озера и моря загрязняются токсичными отходами производства 🏭
https://t.me/ychemistry/1022?embed=1&mode=tme
https://t.me/
https://t.me/s/ychemistry
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null
NEUTRAL
rus
NOT SPAM
442
0
5
1
0
0
47
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13
148
30
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true
118
null
Соединяем кипяток и жидкий азот. Таким "взрывом" происходит конденсация паров воды при быстром охлаждении.
https://t.me/chemistrytg2021/9517?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
2,900
0
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1,736,456,925
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null
NEUTRAL
rus
NOT SPAM
14
0
0
1
0
0
2
2
0
0
7
0
4
true
118
null
Создаем фейковую кровь Тиоцианат калия KSCN + Хлорид железа(III) FeCl3
https://t.me/chemistrytg2021/9518?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,000
0
1,735,399,200
1,736,456,925
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[{"ner":"KSCN\n+ Хлорид железа(III","lemma":"kscn\n+ хлорид железа(iii","label":"ORG","start_pos":39,"end_pos":63},{"ner":"3","lemma":"3","label":"NUM","start_pos":69,"end_pos":70}]
NEUTRAL
rus
NOT SPAM
10
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Бросание пера и металлического куба в вакууме При отсутствии сопротивления воздуха все тела испытывают одинаковое ускорение под действием силы тяжести. #интереснаяфизика
https://t.me/chemistrytg2021/9519?embed=1&mode=tme
https://t.me/
https://t.me/s/chemistrytg2021
3,000
0
1,735,410,001
1,736,456,925
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В Шуваловском корпусе МГУ 13 декабря в 17:00 прошло торжественное мероприятие, посвященное 95-летию химического факультета. В рамках юбилея состоялась научно-популярная выставка инновационных проектов, где молодые ученые представили свои исследования и разработки. В холле второго этажа гости могли ознакомиться с достижениями ведущих научных групп факультета: от разработок костных имплантов и люминофоров нового поколения до материалов для авиационной промышленности и технологий экологической очистки территорий. На первом этаже была представлена масштабная экспозиция, посвященная Д.И. Менделееву. Химический факультет МГУ входит в ТОП-100 международных рейтингов. Более половины академиков отделения химии и наук о материалах РАН — выпускники факультета. Среди партнеров химфака — крупнейшие предприятия добывающей и перерабатывающей промышленности, отраслевые министерства, а также ведущие компании и университеты мира. Фото: Елена Либрик / Научная Россия Подробнее на портале Научная Россия #химфак_мгу
https://t.me/chemrussia/5142?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
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[{"ner":"Шуваловском корпусе","lemma":"шуваловском корпус","label":"ORG","start_pos":2,"end_pos":21},{"ner":"МГУ","lemma":"мгу","label":"ORG","start_pos":22,"end_pos":25},{"ner":"Д.И. Менделееву","lemma":"д.и. менделеев","label":"PER","start_pos":585,"end_pos":600},{"ner":"МГУ","lemma":"мгу","label":"ORG","start_pos":623,"end_pos":626},{"ner":"РАН","lemma":"ран","label":"ORG","start_pos":731,"end_pos":734},{"ner":"Елена Либрик","lemma":"елена либрик","label":"PER","start_pos":932,"end_pos":944},{"ner":"Научная Россия\nПодробнее","lemma":"научный россия\nподробнее","label":"LOC","start_pos":947,"end_pos":971},{"ner":"Научная Россия","lemma":"научный россия","label":"ORG","start_pos":983,"end_pos":997},{"ner":"17:00","lemma":"17:00","label":"DATE","start_pos":39,"end_pos":44},{"ner":"13 декабря","lemma":"13 декабря","label":"DATE","start_pos":26,"end_pos":36},{"ner":"00","lemma":"00","label":"NUM","start_pos":42,"end_pos":44},{"ner":"95","lemma":"95","label":"NUM","start_pos":91,"end_pos":93},{"ner":"100","lemma":"100","label":"NUM","start_pos":640,"end_pos":643}]
NEUTRAL
rus
NOT SPAM
124
0
8
1
0
0
25
11
0
1
49
4
18
true
118
null
50 оттенков оксида кобальта Современные керамисты добавляют в краску оксид кобальта для создания насыщенного синего цвета. Наложение слоев краски в различных вариациях дает богатую палитру оттенков. Эта техника появилась давно, еще в древние времена и с тех пор не потеряла своей актуальности. Кобальт был идентифицирован в синей стеклянной лампе из Месопотамии, возраст которой датируется 2000 лет до нашей эры, в синем стекле из Древнего Египта, Сирии и Помпеи. Персидские ремесленники в VIII-XIII веках использовали добавки кобальтовой руды при создания низкотемпературных глазурей. По всей видимости, руда содержала кобальтин CoAsS, серебристо-белый минерал с красноватым оттенком, но чаще черный из-за присутствия железа, или эритрин Co3(AsO4)2•8H2O – минерал малинового цвета. Позже в Китае во время правления династии Юань (1271 – 1368 гг) мастера из Цзиндэчжэня изобрели новый метод работы с керамикой – теперь фарфор, с нанесенным «кобальтовыми» красками рисунком, обжигали при высокой, более 1200 С, температуре. Китайский синий фарфор стал более доступным и популярным во всем мире в XVII-XVIII веках. Роспись оксидом кобальта использовали голландские мастера при создании Дельфтского фаянса, а в России «синий кобальт» стал визитной карточкой Гжели. Фото: Керамистка Фелисити Айлиф использует оксид кобальта для росписи своих гигантских ваз.
https://t.me/chemrussia/5143?embed=1&mode=tme
https://t.me/
https://t.me/s/chemrussia
1,300
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Дизайн высокоэффективных TADF эмиттеров на основе фосфин-карбеновых комплексов Cu(I), Ag(I) и Au(I) Ученые из Института неорганической химии имени А.В. Николаева СО РАН, Института химической кинетики и горения им. В.В. Воеводского СО РАН, Новосибирского государственного университета, Института элементоорганических соединений им. А.Н. Несмеянова РАН синтезировали двухъядерные комплексы меди(I), серебра(I) и золота(I), которые проявляют при комнатной температуре короткоживущую TADF в желто-голубой области, а их квантовая эффективность достигает 89%. Для получения комплексов была использована стратегия дизайна центро-симметричных структур, основанная на модели А.С. Давыдова для молекулярных кристаллов. Практический потенциал созданных эмиттеров продемонстрирован на примере их использования в качестве инновационных термо- и вапохромных люминесцентных красителей для криптографии. Результаты работы, выполненной при поддержке РНФ (грант №19-73-20196П) и Минобрнауки России, опубликованы в журнале «Inorganic Chemistry Frontiers». Alexander V. Artem’ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan. Toward highly efficient TADF-active Cu(I), Ag(I) and Au(I) carbene complexes using symmetry-based design strategy. Inorg. Chem. Front., 2024, 11, 8778-8788. DOI: 10.1039/D4QI01996B. https://doi.org/10.1039/D4QI01996B Источник: ИНХ СО РАН #российскаянаука
https://t.me/chemrussia/5145?embed=1&mode=tme
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https://telegra.ph/Otkrytie-Aleka-Dzheffrisa-Geneticheskaya-daktiloskopiya-10-12
https://t.me/incredible_chemistry/337?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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[{"ner":"10-12","lemma":"10-12","label":"DATE","start_pos":75,"end_pos":80},{"ner":"12","lemma":"12","label":"NUM","start_pos":78,"end_pos":80}]
NEUTRAL
eng
NOT SPAM
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В 1845 году работая с соединениями платины итальянский химик Микеле Пейроне получил вещество которое пригодилось только через 100 лет.
https://t.me/incredible_chemistry/338?embed=1&mode=tme
https://t.me/
https://t.me/s/incredible_chemistry
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[{"ner":"Микеле Пейроне","lemma":"микеле пейроне","label":"PER","start_pos":61,"end_pos":75},{"ner":"1845","lemma":"1845","label":"NUM","start_pos":2,"end_pos":6},{"ner":"100","lemma":"100","label":"NUM","start_pos":126,"end_pos":129}]
NEUTRAL
rus
NOT SPAM
19
0
1
1
0
0
2
3
1
1
6
0
1
true
118
null
ОКСАЛАТЫ. Что это такое? Часто в повседневной практике мы встречаемся с понятием оксалаты, оксалатурия, но нет окончательного и четкого понимания, что вообще такое оксалаты и откуда они берутся? Оксалат или щавелевая кислота - побочный метаболит, который оказывается в нашем организме двумя путями - попадает с пищей или синтезируется эндогенно. ❗️ Важно! Не путать оксалат и оксалоацетат! Оксалат не выполняет фактически никакой функции и является конечным продуктом, который направлен исключительно на выведение. Ключевым органом экскреции являются почки, которые выводят оксалат с мочей. Сама по себе щавелевая кислота хорошо растворяется в воде, но при реакции с кальцием образуется оксалатная соль, которая уже плохо растворяется в воде и выпадает в осадок в виде острых кристаллов. И чем больше этой оксалатной соли образуется, тем они интенсивнее выпадают в осадок и формируют сперва песок, а потом полноценные камни. А вы знаете откуда именно берутся оксалаты? 😉
https://t.me/simplebestbiochemistry/501?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,200
0
1,731,479,887
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[{"ner":"ОКСАЛАТЫ","lemma":"оксалаты","label":"ORG","start_pos":0,"end_pos":8}]
NEUTRAL
rus
NOT SPAM
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ОКСАЛАТЫ И ПИТАНИЕ Как мы сказали с вами в предыдущем посте, существует экзогенный путь попадания щавелевой кислоты - поступление через ЖКТ с пищей. 🌱 Щавелевая кислота - метаболит растительных организмов, поэтому все растительные продукты содержат оксалат и при их употреблении они оказываются в ЖКТ. ❗️ Но! Сама по себе щавелевая кислота (она же оксалат) очень плохо всасывается из ЖКТ. Происходит это потому, что оксалат активно взаимодействует с ионами кальция 🧪 и образуется оксалат кальция (тот же, что и в почках), который плохо растворяется в воде, выпадает в виде осадка и проходит транзитом по ЖКТ. Также важная роль отводится бактерии Oxalobacter formigenes . Эта анаэробная бактерия, представитель здоровой микробиоты, использует щавелевую кислоту, как энергетический источник с помощью фермента «оксалил-КоА карбоксилазы». Этот фермент есть только у данной бактерии и в его состав входит витамин Б6. Это пример того, что витамины нужны не только нашему организму, но и тем организмам, которые заселяют наш ЖКТ. Всасывается не более 4-5% от общего количества щавелевой кислоты, но тем не менее ограничение продуктов с избытком оксалатов рационально при оксалатурии 👨‍⚕️
https://t.me/simplebestbiochemistry/502?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
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[{"ner":"ОКСАЛАТЫ И","lemma":"оксалаты и","label":"ORG","start_pos":0,"end_pos":10},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":136,"end_pos":139},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":297,"end_pos":300},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":384,"end_pos":387},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":604,"end_pos":607},{"ner":"КоА","lemma":"коа","label":"ORG","start_pos":817,"end_pos":820},{"ner":"ЖКТ","lemma":"жкт","label":"ORG","start_pos":1019,"end_pos":1022},{"ner":"6","lemma":"6","label":"NUM","start_pos":910,"end_pos":911},{"ner":"4","lemma":"4","label":"NUM","start_pos":1045,"end_pos":1046},{"ner":"5","lemma":"5","label":"NUM","start_pos":1047,"end_pos":1048}]
NEUTRAL
rus
NOT SPAM
173
0
9
0.991031
0.008969
0
17
19
13
3
54
11
31
true
118
null
МАГНИЙ И ОКСАЛАТЫ КАЛЬЦИЯ В предыдущих постах мы уже сказали с вами, что щавелевая кислота, которая активно выводится почками, может соединяться в почечных протоках с ионами Ca2+ и превращаться в нерастворимый осадок - фактически кристалл - кальция оксалат. Тот самый, который оказывает поврежадющее действие на слизистую, эпителиальные клетки, может закупоривать и нарушать нормальный пассаж мочи по мочевым путям. ❓ Однако, что происходит в присутствии магния? Если в моче растет концентрация магния, то было установлено экспериментально, что он начинает конкурировать с кальцием за связь с оксалатом, тем самым замедляя скорость образования кальция оксалата и его количество. По данным литературы, скорость образования кальция оксалата в присутствии Mg2+ замедляется в 100-1000 раз (исследования в пробирке). Магния оксалат - хорошо растворимая соль, которая не создает проблемы, поскольку быстро растворяется в моче. ⤴️ На фото выше вы можете заметить микрокопию мазка мочи. Квадратные острые кристаллы 💎 , это те самые кальциевые оксалаты. Кстати обратите внимания, что в поле зрения попал дрожжевой гриб, вероятнее всего Candida.
https://t.me/simplebestbiochemistry/504?embed=1&mode=tme
https://t.me/
https://t.me/s/simplebestbiochemistry
2,000
0
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NEUTRAL
rus
NOT SPAM
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true