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Chaotropic agent. A chaotropic agent is a molecule in water solution that can disrupt the hydrogen bonding network between water molecules (i.e. exerts chaotropic activity). This has an effect on the stability of the native state of other molecules in the solution, mainly macromolecules (proteins, nucleic acids) by weakening the hydrophobic effect.
Prototropy is the most common form of tautomerism and refers to the relocation of a proton. Prototropic tautomerism may be considered as a subset of acid-base behavior. Prototropic tautomers are sets of isomeric protonation states with the same empirical formula and total charge.Tautomerizations are catalyzed by:here are two specific further subcategories of tautomerizations. Annular tautomerism is a type of prototropic tautomerism wherein a proton can occupy two or more positions of a heterocyclic system, for example, 1 H-and 3 H-imidazole; 1 H -, 2 H-and 4 H - 1,2,4-triazole; 1 H-and 2 H-isoindole.