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Microsoft Publisher 2010 helps you create professional-looking publications quickly and easily. With Publisher, you can create, design, and publish professional marketing and communication materials for print, and for mail or e-mail merges.
A PDF is the file used to design your book for print; an eBook's main purpose, on the other hand, is to be read on an eReader. eBooks have a very different internal structure, and are meant to be manipulated. In fact, that's one of the biggest draws for people who use eReaders.