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Statistical approach to calculate thermodynamic properties for propane
Jurij Avsec, K. A... Watanabe, 2005, izvirni znanstveni članek

Opis: The paper describes a mathematical model to compute equilibrium thermodynamic properties in the fluid phase of pure hydrocarbons with the aid of classical thermodynamics and statistical associating chain theories. In the present paper thermodynamic properties for propane, as an example of hydrocarbon substances, are calculated. To calculate the thermodynamic properties of real fluids, models based on the Lennard-Jones intermolecular potential were applied. To calculate the thermodynamic properties of real fluids with the aid of classical thermodynamics, Miyamoto-Watanabe (MW) equations, developed in terms of the Helmholtz energy were used. Analytical results obtained by statistical thermodynamics are compared with the MW model and show relatively good agreement.
Ključne besede: statistical thermodynamics, propane, thermodynamic properties, SAFT model, chain theory
Objavljeno: 01.06.2012; Ogledov: 851; Prenosov: 37
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An approach to calculate thermodynamic properties of mixtures including Propane, n-Butane, and Isobutane
Jurij Avsec, Koichi Watanabe, 2005, izvirni znanstveni članek

Opis: This paper discusses a mathematical model for computing the thermodynamic properties of propane, n-butane, isobutane, and their mixtures, in the fluid phase using a method based upon statistical chain theory. The constants necessary for computations such as the characteristic temperatures of rotation, electronic state, etc. and the moments of inertia are obtained analytically applying a knowledge of the atomic structure of the molecule. The paper presents a procedure for calculating thermodynamic properties such aspressure, speed of sound, the Joule-Thomson coefficient, compressibility, enthalpy, and thermal expansion coefficient. This paper will discuss, for the first time, the application of statistical chain theory for accurate properties of binary and ternary mixtures including propane, n-butane, and isobutane, in their entire fluid phases. To calculate the thermodynamic properties of Lennard-Jones chains, the Liu-Li-Lu model has been used. The thermodynamic properties of the hydrocarbon mixtures are obtained using the one-fluid theory.
Ključne besede: statistical thermodynamics, chain theory, mixtures, transport properties, hydrocarbons, isobutane, n-butane, propane, refrigerants
Objavljeno: 01.06.2012; Ogledov: 1052; Prenosov: 41
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Encyclopedia of complexity and systems science
slovar, enciklopedija, leksikon, priročnik, atlas, zemljevid

Objavljeno: 01.06.2012; Ogledov: 1452; Prenosov: 58
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On semigroups of normal matrices
Bojana Zalar, 2003, izvirni znanstveni članek

Opis: Semigroups of normal complex square matrices having a finite spectrum are studied. It is shown that every mamber ▫$A$▫ of such a semigroup satisfies the condition ▫$A^ast = A^n$▫, where ▫$n$▫ does not depend on the matrix ▫$A$▫. Further, it is shown that such a semigroup is completely reducible, and each irreducible contraction consists of a group of unitary matrices and, aventually, the zero matrix.
Ključne besede: mathematics, matrix theory, normal matrices, spectrum, semigroups, reducability
Objavljeno: 01.06.2012; Ogledov: 877; Prenosov: 46
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