SS316 ステンレス鋼のトリチウムの除染(4) : エッチング表面における水素捕獲と放出のモデリングjpnhttp://hdl.handle.net/10110/985info:doi/10.15099/00006491Departmental Bulletin Paper赤石, 憲也村田, 大樹鳥養, 祐二渡辺, 国昭松山, 政夫Penzhorn, R.-D.Removal of tritium from 316 stainless steel (4) : Modeling of hydrogen trapping and release in chemically etched surface of tritium occluded stainless steel sampleWhen a stainless-steel sample occluded with tritium was dissolved the thickness a few 10 μm chemically, it was observed by a coauthor, Murata that tritium concentration at the newly formed top surface increased with time, while tritium release occurred from the surface to the gas phase. In this paper, a model to explain tritium accumulation and release at the etched surface is described. For the modeling, it was assumed that some of the segregated tritium atoms from the bulk to the surface are trapped on adsorption sites and become immobile, and that some of them are released from the top surface to the gas phase. By solving a one-dimensional diffusion equation, the rates of accumulation and release of tritium were estimated, and compared with experimental results. The comparison showed good agreement between experimental result and theoretical calculation.富山大学水素同位体科学研究センター研究報告 = Annual Report of Hydrogen Isotope Research Center, Toyama University25516220050916-8486AA11841872application/pdfpublisherhttps://toyama.repo.nii.ac.jp/?action=repository_action_common_download&item_id=6497&item_no=1&attribute_id=18&file_no=1富山大学水素同位体科学研究センターArticle2016-02-17