<filename>watertap/unit_models/zero_order/tests/test_chlorination_zo.py<gh_stars>0
###############################################################################
# WaterTAP Copyright (c) 2021, The Regents of the University of California,
# through Lawrence Berkeley National Laboratory, Oak Ridge National
# Laboratory, National Renewable Energy Laboratory, and National Energy
# Technology Laboratory (subject to receipt of any required approvals from
# the U.S. Dept. of Energy). All rights reserved.
#
# Please see the files COPYRIGHT.md and LICENSE.md for full copyright and license
# information, respectively. These files are also available online at the URL
# "https://github.com/watertap-org/watertap/"
#
###############################################################################
"""
Tests for zero-order Chlorination model
"""
import pytest
from io import StringIO

from pyomo.environ import (
    Block, check_optimal_termination, ConcreteModel, Constraint, value, Var)
from pyomo.util.check_units import assert_units_consistent

from idaes.core import FlowsheetBlock
from idaes.core.util import get_solver
from idaes.core.util.model_statistics import degrees_of_freedom
from idaes.core.util.testing import initialization_tester
from idaes.generic_models.costing import UnitModelCostingBlock

from watertap.unit_models.zero_order import ChlorinationZO
from watertap.core.wt_database import Database
from watertap.core.zero_order_properties import WaterParameterBlock
from watertap.core.zero_order_costing import ZeroOrderCosting

solver = get_solver()


class TestChlorinationZO_with_default_removal:
    @pytest.fixture(scope="class")
    def model(self):
        m = ConcreteModel()

        m.db = Database()

        m.fs = FlowsheetBlock(default={"dynamic": False})
        m.fs.params = WaterParameterBlock(default={
            "solute_list": ["total_coliforms_fecal_ecoli",
                            "viruses_enteric",
                            "tss"]})

        m.fs.unit = ChlorinationZO(default={"property_package": m.fs.params,
                                            "database": m.db})

        m.fs.unit.inlet.flow_mass_comp[0, "H2O"].fix(100)
        m.fs.unit.inlet.flow_mass_comp[0, "total_coliforms_fecal_ecoli"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "viruses_enteric"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "tss"].fix(1)

        return m

    @pytest.mark.unit
    def test_build(self, model):
        assert model.fs.unit.config.database == model.db
        assert model.fs.unit._tech_type == "chlorination"
        assert isinstance(model.fs.unit.initial_chlorine_demand, Var)
        assert isinstance(model.fs.unit.contact_time, Var)
        assert isinstance(model.fs.unit.concentration_time, Var)
        assert isinstance(model.fs.unit.chlorine_decay_rate, Var)
        assert isinstance(model.fs.unit.chlorine_dose, Var)
        assert isinstance(model.fs.unit.energy_electric_flow_vol_inlet, Var)
        assert isinstance(model.fs.unit.chlorine_dose_constraint, Constraint)

    @pytest.mark.component
    def test_load_parameters(self, model):
        data = model.db.get_unit_operation_parameters("chlorination")
        model.fs.unit.load_parameters_from_database(use_default_removal=True)
        assert model.fs.unit.recovery_frac_mass_H2O[0].fixed
        assert model.fs.unit.recovery_frac_mass_H2O[0].value == 1

        for (t, j), v in model.fs.unit.removal_frac_mass_solute.items():
            assert v.fixed
            if j not in data["removal_frac_mass_solute"]:
                assert v.value == data[
                    "default_removal_frac_mass_solute"]["value"]
            else:
                assert v.value == data["removal_frac_mass_solute"][j]["value"]

        assert model.fs.unit.initial_chlorine_demand[0].fixed
        assert model.fs.unit.initial_chlorine_demand[0].value == data[
            "initial_chlorine_demand"]["value"]
        assert model.fs.unit.contact_time[0].fixed
        assert model.fs.unit.contact_time[0].value == data[
            "contact_time"]["value"]
        assert model.fs.unit.concentration_time[0].fixed
        assert model.fs.unit.concentration_time[0].value == data[
            "concentration_time"]["value"]
        assert model.fs.unit.chlorine_decay_rate[0].fixed
        assert model.fs.unit.chlorine_decay_rate[0].value == data[
            "chlorine_decay_rate"]["value"]

    @pytest.mark.component
    def test_degrees_of_freedom(self, model):
        assert degrees_of_freedom(model.fs.unit) == 0

    @pytest.mark.component
    def test_unit_consistency(self, model):
        assert_units_consistent(model.fs.unit)

    @pytest.mark.component
    def test_initialize(self, model):
        initialization_tester(model)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solve(self, model):
        results = solver.solve(model)

        # Check for optimal solution
        assert check_optimal_termination(results)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solution(self, model):
        assert (pytest.approx(0.101001, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].flow_vol))
        assert (pytest.approx(0.008435544, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "total_coliforms_fecal_ecoli"]))
        assert (pytest.approx(0.00332669354, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "viruses_enteric"]))
        assert (pytest.approx(9.900873, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].conc_mass_comp[
                    "tss"]))
        assert (pytest.approx(9.5, rel=1e-5) ==
                value(model.fs.unit.chlorine_dose[0]))

    @pytest.mark.component
    def test_report(self, model):
        stream = StringIO()

        model.fs.unit.report(ostream=stream)

        output = """
====================================================================================
Unit : fs.unit                                                             Time: 0.0
------------------------------------------------------------------------------------
    Unit Performance

    Variables: 

    Key                                          : Value      : Fixed : Bounds
                           CT Value ((mg*min)/L) :     450.00 :  True : (None, None)
                 Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)
                            Chlorine Dose (mg/L) :     9.5000 : False : (None, None)
                               Contact Time (hr) :     1.5000 :  True : (None, None)
                              Electricity Demand :   0.018540 : False : (0, None)
                           Electricity Intensity : 5.0000e-05 :  True : (None, None)
                  Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)
    Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)
                            Solute Removal [tss] :     0.0000 :  True : (0, None)
                Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)

------------------------------------------------------------------------------------
    Stream Table
                                                     Inlet   Treated
    Volumetric Flowrate                            0.10300   0.10100
    Mass Concentration H2O                          970.87    990.09
    Mass Concentration total_coliforms_fecal_ecoli  9.7087 0.0084355
    Mass Concentration viruses_enteric              9.7087 0.0033267
    Mass Concentration tss                          9.7087    9.9009
====================================================================================
"""

        assert output in stream.getvalue()


class TestChlorinationZO_w_o_default_removal:
    @pytest.fixture(scope="class")
    def model(self):
        m = ConcreteModel()

        m.db = Database()

        m.fs = FlowsheetBlock(default={"dynamic": False})
        m.fs.params = WaterParameterBlock(default={
            "solute_list": ["total_coliforms_fecal_ecoli", 
                            "viruses_enteric"]})

        m.fs.unit = ChlorinationZO(default={"property_package": m.fs.params,
                                            "database": m.db})

        m.fs.unit.inlet.flow_mass_comp[0, "H2O"].fix(100)
        m.fs.unit.inlet.flow_mass_comp[0, "total_coliforms_fecal_ecoli"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "viruses_enteric"].fix(1)
        return m

    @pytest.mark.unit
    def test_build(self, model):
        assert model.fs.unit.config.database == model.db
        assert model.fs.unit._tech_type == "chlorination"
        assert isinstance(model.fs.unit.initial_chlorine_demand, Var)
        assert isinstance(model.fs.unit.contact_time, Var)
        assert isinstance(model.fs.unit.concentration_time, Var)
        assert isinstance(model.fs.unit.chlorine_decay_rate, Var)
        assert isinstance(model.fs.unit.chlorine_dose, Var)
        assert isinstance(model.fs.unit.energy_electric_flow_vol_inlet, Var)
        assert isinstance(model.fs.unit.chlorine_dose_constraint, Constraint)

    @pytest.mark.component
    def test_load_parameters(self, model):
        data = model.db.get_unit_operation_parameters("chlorination")
        model.fs.unit.load_parameters_from_database()
        assert model.fs.unit.recovery_frac_mass_H2O[0].fixed
        assert model.fs.unit.recovery_frac_mass_H2O[0].value == 1

        for (t, j), v in model.fs.unit.removal_frac_mass_solute.items():
            assert v.fixed
            if j not in data["removal_frac_mass_solute"]:
                assert v.value == data[
                    "default_removal_frac_mass_solute"]["value"]
            else:
                assert v.value == data["removal_frac_mass_solute"][j]["value"]

        assert model.fs.unit.initial_chlorine_demand[0].fixed
        assert model.fs.unit.initial_chlorine_demand[0].value == data[
            "initial_chlorine_demand"]["value"]
        assert model.fs.unit.contact_time[0].fixed
        assert model.fs.unit.contact_time[0].value == data[
            "contact_time"]["value"]
        assert model.fs.unit.concentration_time[0].fixed
        assert model.fs.unit.concentration_time[0].value == data[
            "concentration_time"]["value"]
        assert model.fs.unit.chlorine_decay_rate[0].fixed
        assert model.fs.unit.chlorine_decay_rate[0].value == data[
            "chlorine_decay_rate"]["value"]

    @pytest.mark.component
    def test_degrees_of_freedom(self, model):
        assert degrees_of_freedom(model.fs.unit) == 0

    @pytest.mark.component
    def test_unit_consistency(self, model):
        assert_units_consistent(model.fs.unit)

    @pytest.mark.component
    def test_initialize(self, model):
        initialization_tester(model)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solve(self, model):
        results = solver.solve(model)

        # Check for optimal solution
        assert check_optimal_termination(results)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solution(self, model):
        assert (pytest.approx(0.100001, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].flow_vol))
        assert (pytest.approx(0.0085198987836, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "total_coliforms_fecal_ecoli"]))
        assert (pytest.approx(0.003359960083, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "viruses_enteric"]))
        assert (pytest.approx(9.5, rel=1e-5) ==
                value(model.fs.unit.chlorine_dose[0]))

    @pytest.mark.component
    def test_report(self, model):
        stream = StringIO()

        model.fs.unit.report(ostream=stream)

        output = """
====================================================================================
Unit : fs.unit                                                             Time: 0.0
------------------------------------------------------------------------------------
    Unit Performance

    Variables: 

    Key                                          : Value      : Fixed : Bounds
                           CT Value ((mg*min)/L) :     450.00 :  True : (None, None)
                 Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)
                            Chlorine Dose (mg/L) :     9.5000 : False : (None, None)
                               Contact Time (hr) :     1.5000 :  True : (None, None)
                              Electricity Demand :   0.018360 : False : (0, None)
                           Electricity Intensity : 5.0000e-05 :  True : (None, None)
                  Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)
    Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)
                Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)

------------------------------------------------------------------------------------
    Stream Table
                                                     Inlet   Treated
    Volumetric Flowrate                            0.10200   0.10000
    Mass Concentration H2O                          980.39    999.99
    Mass Concentration total_coliforms_fecal_ecoli  9.8039 0.0085199
    Mass Concentration viruses_enteric              9.8039 0.0033600
====================================================================================
"""

        assert output in stream.getvalue()


def test_costing():
    m = ConcreteModel()
    m.db = Database()

    m.fs = FlowsheetBlock(default={"dynamic": False})

    m.fs.params = WaterParameterBlock(
        default={"solute_list": ["sulfur", "toc", "tss"]})

    m.fs.costing = ZeroOrderCosting()

    m.fs.unit1 = ChlorinationZO(default={
        "property_package": m.fs.params,
        "database": m.db})

    m.fs.unit1.inlet.flow_mass_comp[0, "H2O"].fix(10000)
    m.fs.unit1.inlet.flow_mass_comp[0, "sulfur"].fix(1)
    m.fs.unit1.inlet.flow_mass_comp[0, "toc"].fix(2)
    m.fs.unit1.inlet.flow_mass_comp[0, "tss"].fix(3)
    m.fs.unit1.load_parameters_from_database(use_default_removal=True)
    assert degrees_of_freedom(m.fs.unit1) == 0

    m.fs.unit1.costing = UnitModelCostingBlock(default={
        "flowsheet_costing_block": m.fs.costing})

    assert isinstance(m.fs.costing.chlorination, Block)
    assert isinstance(m.fs.costing.chlorination.capital_a_parameter, Var)
    assert isinstance(m.fs.costing.chlorination.capital_b_parameter, Var)
    assert isinstance(m.fs.costing.chlorination.capital_c_parameter, Var)

    assert isinstance(m.fs.unit1.costing.capital_cost, Var)
    assert isinstance(m.fs.unit1.costing.capital_cost_constraint,
                      Constraint)

    assert_units_consistent(m.fs)
    assert degrees_of_freedom(m.fs.unit1) == 0

    assert m.fs.unit1.electricity[0] in \
        m.fs.costing._registered_flows["electricity"]
    assert str(m.fs.costing._registered_flows["chlorine"][0]) == str(
        m.fs.unit1.chlorine_dose[0]*m.fs.unit1.properties_in[0].flow_vol)

<filename>watertap/unit_models/zero_order/tests/test_chlorination_zo.py<gh_stars>0
###############################################################################
# WaterTAP Copyright (c) 2021, The Regents of the University of California,
# through Lawrence Berkeley National Laboratory, Oak Ridge National
# Laboratory, National Renewable Energy Laboratory, and National Energy
# Technology Laboratory (subject to receipt of any required approvals from
# the U.S. Dept. of Energy). All rights reserved.
#
# Please see the files COPYRIGHT.md and LICENSE.md for full copyright and license
# information, respectively. These files are also available online at the URL
# "https://github.com/watertap-org/watertap/"
#
###############################################################################
"""
Tests for zero-order Chlorination model
"""
import pytest
from io import StringIO

from pyomo.environ import (
    Block, check_optimal_termination, ConcreteModel, Constraint, value, Var)
from pyomo.util.check_units import assert_units_consistent

from idaes.core import FlowsheetBlock
from idaes.core.util import get_solver
from idaes.core.util.model_statistics import degrees_of_freedom
from idaes.core.util.testing import initialization_tester
from idaes.generic_models.costing import UnitModelCostingBlock

from watertap.unit_models.zero_order import ChlorinationZO
from watertap.core.wt_database import Database
from watertap.core.zero_order_properties import WaterParameterBlock
from watertap.core.zero_order_costing import ZeroOrderCosting

solver = get_solver()


class TestChlorinationZO_with_default_removal:
    @pytest.fixture(scope="class")
    def model(self):
        m = ConcreteModel()

        m.db = Database()

        m.fs = FlowsheetBlock(default={"dynamic": False})
        m.fs.params = WaterParameterBlock(default={
            "solute_list": ["total_coliforms_fecal_ecoli",
                            "viruses_enteric",
                            "tss"]})

        m.fs.unit = ChlorinationZO(default={"property_package": m.fs.params,
                                            "database": m.db})

        m.fs.unit.inlet.flow_mass_comp[0, "H2O"].fix(100)
        m.fs.unit.inlet.flow_mass_comp[0, "total_coliforms_fecal_ecoli"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "viruses_enteric"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "tss"].fix(1)

        return m

    @pytest.mark.unit
    def test_build(self, model):
        assert model.fs.unit.config.database == model.db
        assert model.fs.unit._tech_type == "chlorination"
        assert isinstance(model.fs.unit.initial_chlorine_demand, Var)
        assert isinstance(model.fs.unit.contact_time, Var)
        assert isinstance(model.fs.unit.concentration_time, Var)
        assert isinstance(model.fs.unit.chlorine_decay_rate, Var)
        assert isinstance(model.fs.unit.chlorine_dose, Var)
        assert isinstance(model.fs.unit.energy_electric_flow_vol_inlet, Var)
        assert isinstance(model.fs.unit.chlorine_dose_constraint, Constraint)

    @pytest.mark.component
    def test_load_parameters(self, model):
        data = model.db.get_unit_operation_parameters("chlorination")
        model.fs.unit.load_parameters_from_database(use_default_removal=True)
        assert model.fs.unit.recovery_frac_mass_H2O[0].fixed
        assert model.fs.unit.recovery_frac_mass_H2O[0].value == 1

        for (t, j), v in model.fs.unit.removal_frac_mass_solute.items():
            assert v.fixed
            if j not in data["removal_frac_mass_solute"]:
                assert v.value == data[
                    "default_removal_frac_mass_solute"]["value"]
            else:
                assert v.value == data["removal_frac_mass_solute"][j]["value"]

        assert model.fs.unit.initial_chlorine_demand[0].fixed
        assert model.fs.unit.initial_chlorine_demand[0].value == data[
            "initial_chlorine_demand"]["value"]
        assert model.fs.unit.contact_time[0].fixed
        assert model.fs.unit.contact_time[0].value == data[
            "contact_time"]["value"]
        assert model.fs.unit.concentration_time[0].fixed
        assert model.fs.unit.concentration_time[0].value == data[
            "concentration_time"]["value"]
        assert model.fs.unit.chlorine_decay_rate[0].fixed
        assert model.fs.unit.chlorine_decay_rate[0].value == data[
            "chlorine_decay_rate"]["value"]

    @pytest.mark.component
    def test_degrees_of_freedom(self, model):
        assert degrees_of_freedom(model.fs.unit) == 0

    @pytest.mark.component
    def test_unit_consistency(self, model):
        assert_units_consistent(model.fs.unit)

    @pytest.mark.component
    def test_initialize(self, model):
        initialization_tester(model)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solve(self, model):
        results = solver.solve(model)

        # Check for optimal solution
        assert check_optimal_termination(results)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solution(self, model):
        assert (pytest.approx(0.101001, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].flow_vol))
        assert (pytest.approx(0.008435544, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "total_coliforms_fecal_ecoli"]))
        assert (pytest.approx(0.00332669354, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "viruses_enteric"]))
        assert (pytest.approx(9.900873, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].conc_mass_comp[
                    "tss"]))
        assert (pytest.approx(9.5, rel=1e-5) ==
                value(model.fs.unit.chlorine_dose[0]))

    @pytest.mark.component
    def test_report(self, model):
        stream = StringIO()

        model.fs.unit.report(ostream=stream)

        output = """
====================================================================================
Unit : fs.unit                                                             Time: 0.0
------------------------------------------------------------------------------------
    Unit Performance

    Variables: 

    Key                                          : Value      : Fixed : Bounds
                           CT Value ((mg*min)/L) :     450.00 :  True : (None, None)
                 Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)
                            Chlorine Dose (mg/L) :     9.5000 : False : (None, None)
                               Contact Time (hr) :     1.5000 :  True : (None, None)
                              Electricity Demand :   0.018540 : False : (0, None)
                           Electricity Intensity : 5.0000e-05 :  True : (None, None)
                  Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)
    Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)
                            Solute Removal [tss] :     0.0000 :  True : (0, None)
                Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)

------------------------------------------------------------------------------------
    Stream Table
                                                     Inlet   Treated
    Volumetric Flowrate                            0.10300   0.10100
    Mass Concentration H2O                          970.87    990.09
    Mass Concentration total_coliforms_fecal_ecoli  9.7087 0.0084355
    Mass Concentration viruses_enteric              9.7087 0.0033267
    Mass Concentration tss                          9.7087    9.9009
====================================================================================
"""

        assert output in stream.getvalue()


class TestChlorinationZO_w_o_default_removal:
    @pytest.fixture(scope="class")
    def model(self):
        m = ConcreteModel()

        m.db = Database()

        m.fs = FlowsheetBlock(default={"dynamic": False})
        m.fs.params = WaterParameterBlock(default={
            "solute_list": ["total_coliforms_fecal_ecoli", 
                            "viruses_enteric"]})

        m.fs.unit = ChlorinationZO(default={"property_package": m.fs.params,
                                            "database": m.db})

        m.fs.unit.inlet.flow_mass_comp[0, "H2O"].fix(100)
        m.fs.unit.inlet.flow_mass_comp[0, "total_coliforms_fecal_ecoli"].fix(1)
        m.fs.unit.inlet.flow_mass_comp[0, "viruses_enteric"].fix(1)
        return m

    @pytest.mark.unit
    def test_build(self, model):
        assert model.fs.unit.config.database == model.db
        assert model.fs.unit._tech_type == "chlorination"
        assert isinstance(model.fs.unit.initial_chlorine_demand, Var)
        assert isinstance(model.fs.unit.contact_time, Var)
        assert isinstance(model.fs.unit.concentration_time, Var)
        assert isinstance(model.fs.unit.chlorine_decay_rate, Var)
        assert isinstance(model.fs.unit.chlorine_dose, Var)
        assert isinstance(model.fs.unit.energy_electric_flow_vol_inlet, Var)
        assert isinstance(model.fs.unit.chlorine_dose_constraint, Constraint)

    @pytest.mark.component
    def test_load_parameters(self, model):
        data = model.db.get_unit_operation_parameters("chlorination")
        model.fs.unit.load_parameters_from_database()
        assert model.fs.unit.recovery_frac_mass_H2O[0].fixed
        assert model.fs.unit.recovery_frac_mass_H2O[0].value == 1

        for (t, j), v in model.fs.unit.removal_frac_mass_solute.items():
            assert v.fixed
            if j not in data["removal_frac_mass_solute"]:
                assert v.value == data[
                    "default_removal_frac_mass_solute"]["value"]
            else:
                assert v.value == data["removal_frac_mass_solute"][j]["value"]

        assert model.fs.unit.initial_chlorine_demand[0].fixed
        assert model.fs.unit.initial_chlorine_demand[0].value == data[
            "initial_chlorine_demand"]["value"]
        assert model.fs.unit.contact_time[0].fixed
        assert model.fs.unit.contact_time[0].value == data[
            "contact_time"]["value"]
        assert model.fs.unit.concentration_time[0].fixed
        assert model.fs.unit.concentration_time[0].value == data[
            "concentration_time"]["value"]
        assert model.fs.unit.chlorine_decay_rate[0].fixed
        assert model.fs.unit.chlorine_decay_rate[0].value == data[
            "chlorine_decay_rate"]["value"]

    @pytest.mark.component
    def test_degrees_of_freedom(self, model):
        assert degrees_of_freedom(model.fs.unit) == 0

    @pytest.mark.component
    def test_unit_consistency(self, model):
        assert_units_consistent(model.fs.unit)

    @pytest.mark.component
    def test_initialize(self, model):
        initialization_tester(model)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solve(self, model):
        results = solver.solve(model)

        # Check for optimal solution
        assert check_optimal_termination(results)

    @pytest.mark.solver
    @pytest.mark.skipif(solver is None, reason="Solver not available")
    @pytest.mark.component
    def test_solution(self, model):
        assert (pytest.approx(0.100001, rel=1e-5) ==
                value(model.fs.unit.properties_treated[0].flow_vol))
        assert (pytest.approx(0.0085198987836, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "total_coliforms_fecal_ecoli"]))
        assert (pytest.approx(0.003359960083, rel=1e-5) == value(
            model.fs.unit.properties_treated[0].conc_mass_comp[
                "viruses_enteric"]))
        assert (pytest.approx(9.5, rel=1e-5) ==
                value(model.fs.unit.chlorine_dose[0]))

    @pytest.mark.component
    def test_report(self, model):
        stream = StringIO()

        model.fs.unit.report(ostream=stream)

        output = """
====================================================================================
Unit : fs.unit                                                             Time: 0.0
------------------------------------------------------------------------------------
    Unit Performance

    Variables: 

    Key                                          : Value      : Fixed : Bounds
                           CT Value ((mg*min)/L) :     450.00 :  True : (None, None)
                 Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)
                            Chlorine Dose (mg/L) :     9.5000 : False : (None, None)
                               Contact Time (hr) :     1.5000 :  True : (None, None)
                              Electricity Demand :   0.018360 : False : (0, None)
                           Electricity Intensity : 5.0000e-05 :  True : (None, None)
                  Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)
    Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)
                Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)

------------------------------------------------------------------------------------
    Stream Table
                                                     Inlet   Treated
    Volumetric Flowrate                            0.10200   0.10000
    Mass Concentration H2O                          980.39    999.99
    Mass Concentration total_coliforms_fecal_ecoli  9.8039 0.0085199
    Mass Concentration viruses_enteric              9.8039 0.0033600
====================================================================================
"""

        assert output in stream.getvalue()


def test_costing():
    m = ConcreteModel()
    m.db = Database()

    m.fs = FlowsheetBlock(default={"dynamic": False})

    m.fs.params = WaterParameterBlock(
        default={"solute_list": ["sulfur", "toc", "tss"]})

    m.fs.costing = ZeroOrderCosting()

    m.fs.unit1 = ChlorinationZO(default={
        "property_package": m.fs.params,
        "database": m.db})

    m.fs.unit1.inlet.flow_mass_comp[0, "H2O"].fix(10000)
    m.fs.unit1.inlet.flow_mass_comp[0, "sulfur"].fix(1)
    m.fs.unit1.inlet.flow_mass_comp[0, "toc"].fix(2)
    m.fs.unit1.inlet.flow_mass_comp[0, "tss"].fix(3)
    m.fs.unit1.load_parameters_from_database(use_default_removal=True)
    assert degrees_of_freedom(m.fs.unit1) == 0

    m.fs.unit1.costing = UnitModelCostingBlock(default={
        "flowsheet_costing_block": m.fs.costing})

    assert isinstance(m.fs.costing.chlorination, Block)
    assert isinstance(m.fs.costing.chlorination.capital_a_parameter, Var)
    assert isinstance(m.fs.costing.chlorination.capital_b_parameter, Var)
    assert isinstance(m.fs.costing.chlorination.capital_c_parameter, Var)

    assert isinstance(m.fs.unit1.costing.capital_cost, Var)
    assert isinstance(m.fs.unit1.costing.capital_cost_constraint,
                      Constraint)

    assert_units_consistent(m.fs)
    assert degrees_of_freedom(m.fs.unit1) == 0

    assert m.fs.unit1.electricity[0] in \
        m.fs.costing._registered_flows["electricity"]
    assert str(m.fs.costing._registered_flows["chlorine"][0]) == str(
        m.fs.unit1.chlorine_dose[0]*m.fs.unit1.properties_in[0].flow_vol)

############################################################################### # WaterTAP Copyright (c) 2021, The Regents of the University of California, # through Lawrence Berkeley National Laboratory, Oak Ridge National # Laboratory, National Renewable Energy Laboratory, and National Energy # Technology Laboratory (subject to receipt of any required approvals from # the U.S. Dept. of Energy). All rights reserved. # # Please see the files COPYRIGHT.md and LICENSE.md for full copyright and license # information, respectively. These files are also available online at the URL # "https://github.com/watertap-org/watertap/" # ############################################################################### Tests for zero-order Chlorination model # Check for optimal solution ==================================================================================== Unit : fs.unit                                                             Time: 0.0 ------------------------------------------------------------------------------------     Unit Performance      Variables:       Key                                          : Value      : Fixed : Bounds                            CT Value ((mg*min)/L) :     450.00 :  True : (None, None)                  Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)                             Chlorine Dose (mg/L) :     9.5000 : False : (None, None)                                Contact Time (hr) :     1.5000 :  True : (None, None)                               Electricity Demand :   0.018540 : False : (0, None)                            Electricity Intensity : 5.0000e-05 :  True : (None, None)                   Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)     Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)                             Solute Removal [tss] :     0.0000 :  True : (0, None)                 Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)  ------------------------------------------------------------------------------------     Stream Table                                                      Inlet   Treated     Volumetric Flowrate                            0.10300   0.10100     Mass Concentration H2O                          970.87    990.09     Mass Concentration total_coliforms_fecal_ecoli  9.7087 0.0084355     Mass Concentration viruses_enteric              9.7087 0.0033267     Mass Concentration tss                          9.7087    9.9009 ==================================================================================== # Check for optimal solution ==================================================================================== Unit : fs.unit                                                             Time: 0.0 ------------------------------------------------------------------------------------     Unit Performance      Variables:       Key                                          : Value      : Fixed : Bounds                            CT Value ((mg*min)/L) :     450.00 :  True : (None, None)                  Chlorine Decay Rate (mg/(L*hr)) :     3.0000 :  True : (None, None)                             Chlorine Dose (mg/L) :     9.5000 : False : (None, None)                                Contact Time (hr) :     1.5000 :  True : (None, None)                               Electricity Demand :   0.018360 : False : (0, None)                            Electricity Intensity : 5.0000e-05 :  True : (None, None)                   Initial Chlorine Demand (mg/L) :     0.0000 :  True : (None, None)     Solute Removal [total_coliforms_fecal_ecoli] :    0.99915 :  True : (0, None)                 Solute Removal [viruses_enteric] :    0.99966 :  True : (0, None)  ------------------------------------------------------------------------------------     Stream Table                                                      Inlet   Treated     Volumetric Flowrate                            0.10200   0.10000     Mass Concentration H2O                          980.39    999.99     Mass Concentration total_coliforms_fecal_ecoli  9.8039 0.0085199     Mass Concentration viruses_enteric              9.8039 0.0033600 ====================================================================================