BUG: Fix MutliIndexed unstack failures at tuple names
- [x] closes #19966
- [x] tests added / passed
- [x] passes `black pandas`
- [x] passes `git diff upstream/master -u -- "*.py" | flake8 --diff`
- [x] whatsnew entry

Hello @charlesdong1991! Thanks for updating this PR. We checked the lines you've touched for [PEP 8](https://www.python.org/dev/peps/pep-0008) issues, and found:









There are currently no PEP 8 issues detected in this Pull Request. Cheers! :beers: 

##### Comment last updated at 2020-01-20 20:12:00 UTC sure! @simonjayhawkins I will keep this in mind and wait for that PR to be merged together with reviews from other maintainers comment added and tests moved, and also rebased

ping @jreback  some followup reviews will be appreciated ^^ gentle ping @jreback ^^ thanks 😅  thanks @charlesdong1991 

very nice!