 BUG guess_Datetime_format doesn't guess 27.03.2003 14:55:00.000
- [ ] closes #50317 (Replace xxxx with the GitHub issue number)
- [ ] [Tests added and passed](https://pandas.pydata.org/pandas-docs/dev/development/contributing_codebase.html#writing-tests) if fixing a bug or adding a new feature
- [ ] All [code checks passed](https://pandas.pydata.org/pandas-docs/dev/development/contributing_codebase.html#pre-commit).
- [ ] Added [type annotations](https://pandas.pydata.org/pandas-docs/dev/development/contributing_codebase.html#type-hints) to new arguments/methods/functions.
- [ ] Added an entry in the latest `doc/source/whatsnew/vX.X.X.rst` file if fixing a bug or adding a new feature.

> LGTM. Doesn't need a whatsnew right?

thanks! and no, this wouldn't (yet) make a user-facing difference

it fixes https://github.com/pandas-dev/pandas/issues/2586 by accident, but I'd say that that fits into the PDEP4-related part of the whatsnew (as in, PDEP4 should have fixed that, it just didn't quite because of an error in implementation here) merging as there's been an approval, and this is quite minor, and it unblocks another PR - if there's any other concerns / feedback I can address them in a follow-up