DOC: add warning section in indexing docs. 
Add warning section in indexing docs. Close #12947.

yeah this needs a bit more documentation of _why_ this doesn't work and then what you should do instead.
 ## [Current coverage](https://codecov.io/gh/pydata/pandas/pull/13060?src=pr) is **84.14%**

> Merging [#13060](https://codecov.io/gh/pydata/pandas/pull/13060?src=pr) into [master](https://codecov.io/gh/pydata/pandas/branch/master?src=pr) will not change coverage

``` diff
@@             master     #13060   diff @@
==========================================
  Files           137        137          
  Lines         50227      50227          
  Methods           0          0          
  Messages          0          0          
  Branches          0          0          
==========================================
  Hits          42261      42261          
  Misses         7966       7966          
  Partials          0          0          
```

> Powered by [Codecov](https://codecov.io?src=pr). Last updated by [c6110e2...55ffdb1](https://codecov.io/gh/pydata/pandas/compare/c6110e25b3eceb2f25022c2aa9ccea03c0b8b359...55ffdb1e63d9d785dd3859531dc4fe24bbfe1396)
 Add why the DataFrame assignment may not work and then the correct to do it. Anything else I can do?
