BUG: fix .iat assignment creates a new column
- in response to gh-23236
- changes the fallback of .iat to .iloc on type error

using .iat to assign incompatible value after this change:
```python
>>> import pandas as pd
>>> df = pd.DataFrame({"a":[0]})
>>> df
   a
0  0
>>> df.iat[0,0] = None
>>> df
    a
0 NaN
```

- [x] closes #23236
- [x] tests added / passed
- [x] passes `git diff upstream/master -u -- "*.py" | flake8 --diff`
- [x] whatsnew entry

# [Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=h1) Report
> Merging [#24495](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=desc) into [master](https://codecov.io/gh/pandas-dev/pandas/commit/1ebfd8a9fda12cd68c3e068b777c7a0a2470dfaf?src=pr&el=desc) will **decrease** coverage by `<.01%`.
> The diff coverage is `66.66%`.

[![Impacted file tree graph](https://codecov.io/gh/pandas-dev/pandas/pull/24495/graphs/tree.svg?width=650&token=eZ4WkYLtcO&height=150&src=pr)](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=tree)

```diff
@@            Coverage Diff             @@
##           master   #24495      +/-   ##
==========================================
- Coverage   92.31%    92.3%   -0.01%     
==========================================
  Files         166      166              
  Lines       52412    52414       +2     
==========================================
+ Hits        48382    48383       +1     
- Misses       4030     4031       +1
```

| Flag | Coverage Δ | |
|---|---|---|
| #multiple | `90.73% <66.66%> (-0.01%)` | :arrow_down: |
| #single | `43.05% <0%> (-0.01%)` | :arrow_down: |

| [Impacted Files](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=tree) | Coverage Δ | |
|---|---|---|
| [pandas/core/frame.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvZnJhbWUucHk=) | `96.85% <66.66%> (-0.06%)` | :arrow_down: |

------

[Continue to review full report at Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=continue).
> **Legend** - [Click here to learn more](https://docs.codecov.io/docs/codecov-delta)
> `Δ = absolute <relative> (impact)`, `ø = not affected`, `? = missing data`
> Powered by [Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=footer). Last update [1ebfd8a...9515bb7](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=lastupdated). Read the [comment docs](https://docs.codecov.io/docs/pull-request-comments).
 # [Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=h1) Report
> Merging [#24495](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=desc) into [master](https://codecov.io/gh/pandas-dev/pandas/commit/1ebfd8a9fda12cd68c3e068b777c7a0a2470dfaf?src=pr&el=desc) will **increase** coverage by `<.01%`.
> The diff coverage is `100%`.

[![Impacted file tree graph](https://codecov.io/gh/pandas-dev/pandas/pull/24495/graphs/tree.svg?width=650&token=eZ4WkYLtcO&height=150&src=pr)](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=tree)

```diff
@@            Coverage Diff             @@
##           master   #24495      +/-   ##
==========================================
+ Coverage   92.31%   92.31%   +<.01%     
==========================================
  Files         166      166              
  Lines       52412    52402      -10     
==========================================
- Hits        48382    48373       -9     
+ Misses       4030     4029       -1
```

| Flag | Coverage Δ | |
|---|---|---|
| #multiple | `90.73% <100%> (ø)` | :arrow_up: |
| #single | `42.83% <0%> (-0.23%)` | :arrow_down: |

| [Impacted Files](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=tree) | Coverage Δ | |
|---|---|---|
| [pandas/core/frame.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvZnJhbWUucHk=) | `96.91% <100%> (ø)` | :arrow_up: |
| [pandas/compat/\_\_init\_\_.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvbXBhdC9fX2luaXRfXy5weQ==) | `57.91% <0%> (-0.39%)` | :arrow_down: |
| [pandas/core/arrays/timedeltas.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvYXJyYXlzL3RpbWVkZWx0YXMucHk=) | `87.42% <0%> (-0.26%)` | :arrow_down: |
| [pandas/util/testing.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL3V0aWwvdGVzdGluZy5weQ==) | `87.68% <0%> (-0.08%)` | :arrow_down: |
| [pandas/core/arrays/period.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvYXJyYXlzL3BlcmlvZC5weQ==) | `98.35% <0%> (-0.05%)` | :arrow_down: |
| [pandas/core/indexes/datetimes.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvaW5kZXhlcy9kYXRldGltZXMucHk=) | `96.31% <0%> (-0.02%)` | :arrow_down: |
| [pandas/core/indexes/datetimelike.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvaW5kZXhlcy9kYXRldGltZWxpa2UucHk=) | `96.22% <0%> (-0.02%)` | :arrow_down: |
| [pandas/core/computation/ops.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvY29tcHV0YXRpb24vb3BzLnB5) | `95.63% <0%> (+0.03%)` | :arrow_up: |
| [pandas/core/indexes/base.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvaW5kZXhlcy9iYXNlLnB5) | `96.37% <0%> (+0.09%)` | :arrow_up: |
| [pandas/core/arrays/datetimes.py](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree#diff-cGFuZGFzL2NvcmUvYXJyYXlzL2RhdGV0aW1lcy5weQ==) | `97.91% <0%> (+0.17%)` | :arrow_up: |
| ... and [2 more](https://codecov.io/gh/pandas-dev/pandas/pull/24495/diff?src=pr&el=tree-more) | |

------

[Continue to review full report at Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=continue).
> **Legend** - [Click here to learn more](https://docs.codecov.io/docs/codecov-delta)
> `Δ = absolute <relative> (impact)`, `ø = not affected`, `? = missing data`
> Powered by [Codecov](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=footer). Last update [1ebfd8a...486c25d](https://codecov.io/gh/pandas-dev/pandas/pull/24495?src=pr&el=lastupdated). Read the [comment docs](https://docs.codecov.io/docs/pull-request-comments).
 lgtm. ping on green. thanks @RoeiRaz 