BUG: DatetimeTZBlock can't assign values near dst boundary
- [x] tests added / passed
- [x] passes `git diff upstream/master | flake8 --diff`
- [x] whatsnew entry

Value assignment doesn't work if data contains DST boundary because of internal `.localize(None)`. 

```
s = pd.Series(pd.date_range('2016-11-06', freq='H', periods=3, tz='US/Eastern'))
s[1] = pd.Timestamp('2011-01-01', tz='US/Eastern')
s
#0   2016-11-06 00:00:00-04:00
#1   2016-11-06 01:00:00-04:00
#2   2016-11-06 01:00:00-05:00
# dtype: datetime64[ns, US/Eastern]
```

## [Current coverage](https://codecov.io/gh/pydata/pandas/pull/14146?src=pr) is 85.24% (diff: 100%)

> Merging [#14146](https://codecov.io/gh/pydata/pandas/pull/14146?src=pr) into [master](https://codecov.io/gh/pydata/pandas/branch/master?src=pr) will not change coverage

``` diff
@@             master     #14146   diff @@
==========================================
  Files           140        140          
  Lines         50556      50556          
  Methods           0          0          
  Messages          0          0          
  Branches          0          0          
==========================================
  Hits          43095      43095          
  Misses         7461       7461          
  Partials          0          0          
```

> Powered by [Codecov](https://codecov.io?src=pr). Last update [289cd6d...95aa6b5](https://codecov.io/gh/pydata/pandas/compare/289cd6d0df66b812921ff4c5cbade937b875406d...95aa6b5c78348b9f9d71cd58a3f1460b85edd2e6?src=pr)
 @sinhrks just that question from above.
 thanks!
