. Unit cells of (a) DPA-Melt and (b) DPA-Solution.
Figure 3. DPA molecule.
Figure 4. Raman spectra of the DPA crystals.
Figure 5. IR spectra of the DPA crystals.
Figure 6. Spatial conformation of the (a) DPA-Melt and the (b) DPA-Solution crystals.
Figure 7. UV-Vis absorption spectra of the DPA crystals.
Figure 8. Excitation spectra of the DPA crystals.
Figure 9. Fluorescence emission spectra of the DPA crystals.
Figure 10. TG–DSC curves of (a) DPA-Melt and (b) DPA-Solution crystals.
Table 1. Crystallographic data of DPA-Melt and DPA-Solution.
Table 2. Part of torsion angle data of DPA.
© 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ().There is been a heap of best tech proven off at IFA 2019 in Berlin – from the most recent sensible audio system and telephones, to state of the art wearables and dazzling 8K TVs.
There’s so much to soak up, however don’t fear as a result of we’ve scouted the halls, cubicles and meetings to convey you the perfect in our IFA 2019 awards.
Some difficult possible choices have been made, however our crew of crack judges were given their heads in combination to in reality thrash out which deserved our nod – so listed below are the winners of TechRadar’s IFA 2019 awards.
Best possible in display: Sonos Transfer
Our absolute best in display award for IFA 2019 is going to the Sonos Transfer. It can be expensive, however the transportable Sonos Transfer justifies each and every penny with its sensible connectivity and living-room worthy sound.
That is the primary time Sonos has created a conveyable speaker with a integrated battery, and it is a very good further to the company’s sensible speaker vary. While you get house, it could seamlessly sign up for your own home community of stressed out Sonos audio system too – making it really multi-functional.
- Palms on: Sonos Transfer overview
Best possible smartphone: Samsung Galaxy A90 5G
The Samsung Galaxy A90 5G is a characteristic packed smartphone with out the flagship price ticket. There is a large, colourful 6.7-inch Complete HD show, triple rear cameras, flagship Snapdragon 855 chipset and both 6GB or 8GB of RAM.
It is surely no slouch then, and with 5G connectivity too the Galaxy A90 5G is without doubt one of the maximum reasonably priced handsets which helps for subsequent technology community.
- Palms on: Samsung Galaxy A90 5G overview
Best possible TV: Samsung 55-inch 8K QLED
Proudly owning an 8K TV is changing into extra practical as Samsung provides its smallest high-definition panel to its line-up. The 55-inch 8K TV brings the eye-popping solution to a brand new, decrease (however nonetheless dear) worth level at a measurement which is able to with ease are compatible in maximum properties.
Samsung’s QLED panel is vibrant, colourful and detailed and it could upscale any content material to 8K.
- Palms on: Samsung 55-inch 8K QLED overview
Best possible in house theater: Nebula Soundbar Fireplace TV Version
A soundbar with Amazon smarts inbuilt – what is to not like about that? Anker’s Nebula Soundbar Fireplace TV Version supplies get admission to to Top Video, Netflix and a number of TV channel apps.
It helps 4K playback – as long as you are plugging it right into a 4K TV – and you’ll use Alexa Voice Keep an eye on by the use of the soundbar as neatly.
- First glance: Nebula Soundbar Fireplace TV Version
Best possible in sensible house: Philips Hue Edison bulbs
Philips has made its sensible bulbs fashionable with the creation of the Hue Edison vary. Carrying the preferred filament taste you can see in lots of a hipster espresso store nowadays, those are the primary Philips Hue bulbs you will not need to disguise in the back of a color.
They plug and play identical to the remainder of the Hue vary, with keep an eye on by the use of a smartphone app, or by means of the use of your voice by the use of Siri, Google Assistant or Amazon Alexa.
- Learn: Philips Hue Edison provides up funky filament bulbs
Best possible sensible speaker: Sonos Transfer
Now we have already talked concerning the Sonos Transfer, as it is bagged our absolute best in display award, so it is no marvel to search out it scooping up our absolute best sensible speaker accolade as neatly.
It is nice to peer Sonos breaking into new spaces (find it irresistible has with its Ikea partnership), and the addition of a conveyable, Bluetooth speaker with nice sound high quality to the variety is a welcome one.
- Palms on: Sonos Transfer overview
Best possible headphones: Sony WI-1000XM2
Sony’s new noise-canceling neckband earphones glance to be any other spectacular addition to this line of big-hitting buds.
Those new headphones construct at the class-leading design in their predecessors, packing in an up to date noise -cancellation processor – the similar one that is utilized in our all-time favourite true wi-fi earbuds, the Sony WF-1000XM3s.
- Palms on: Sony WI-1000XM2 overview
Best possible wearable: Garmin Venu
The Garmin Venu is filled with all of the options you’d be expecting from a Garmin smartwatch comparable to GPS and a middle charge track, at the side of a colourful AMOLED show – the primary time this display kind has featured on considered one of its watches.
The place the Venu in reality excels is with health monitoring, with the broadest vary of 24/7 well being tracking options to be had together with sleep and breathing monitoring, peculiar middle charge indicators, rigidity monitoring, menstrual cycle monitoring, rest reminders, hydration monitoring, and extra.
- Palms on: Garmin Venu overview
Best possible in Computing: Asus ProArt StudioBook
The ProArt StudioBook One is the “maximum graphically-powerful pc” on the planet – plus it has a touchscreen show as an alternative of a touchpad, which is beautiful cool.
With an Nvidia Quadro RTX 6000 graphics card and an Intel Core i9 processor, in addition to a 15-inch 4K Pantone validated show with 120Hz refresh charge, it’s surely set to be a shockingly {powerful} cell workstation that’s geared toward virtual creatives and pros.
- Learn: Asus ProArt StudioBook is probably the most graphically-powerful pc on the planet
- IFA 2019 is Europe’s largest tech display, and the TechRadar crew is in Berlin to convey you all of the breaking information and hands-on first impressions of latest TVs, telephones, laptops, wearables and different units as they are introduced.Shares of Canadian dairy giant Saputo (SAP.TO) fell on Tuesday after an activist short-seller took aim at the company in a lengthy report questioning its financial transparency and commitment to environmental, social, and governance matters.
Saputo, a Montreal-based company, is a major producer of cheese, fluid milk, and cream, with divisions in the U.S. and Europe, as well as Australia and Argentina. In August, Saputo announced a global plan to modernize its operations and cut costs beginning in fiscal 2024, with the aim of saving about $9 million annually before taxes by fiscal 2025.
In a 147-page report released Tuesday, New York-based Spruce Point Capital Management cites “numerous concerns” about Saputo's ability to meet the pillars of the plan, including plummeting liquid milk consumption.
“Spruce Point believes Saputo has an untenable cost structure in a thin margin, low to no growth industry,” the report’s authors wrote.
In an email to Yahoo Finance Canada, a Saputo spokesperson called Spruce Point's research "without merit," adding that the report contains "mischaracterizations and incorrect information, which are misleading and solely intended to benefit the author." The spokesperson added that Saputo has not engaged with Spruce Point, and remains committed to its strategic plan.
Spruce Point states that increased financial stress at the dairy giant has led to reduced transparency and disclosures for investors, noting the company has stopped outlining its market share in Canada, revenue contribution from acquisitions, and excess manufacturing by region.
The activist firm also says the company lacks transparency on ESG progress as environmental compliance costs have soared.
Toronto-listed shares of Saputo fell 4.46 per cent to $32.76 as at 3:15 p.m. ET. Year-to-date, the stock has climbed more than 20 per cent.
Earlier this month, analysts at CIBC Capital Markets and RBC Capital markets issued Saputo shares “outperform” ratings in separate research notes.
“While the strategic plan benefits are back-end loaded, Saputo appears to be finding its whey [sic] back to better and more consistent earnings/growth,” RBC’s Irene Nattel