<p><b>六羰基鎢</b>是一種配位化合物，化學式為W(CO)<sub>6</sub>。經過它得到了第一個雙氫配合物。</p><p>它是無色固體，和同族的羰基配合物六羰基鉻與六羰基鉬一樣，是揮發性的且在空氣中穩定的物質，其中鎢原子為0價。
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<h2><span id=".E5.8C.96.E5.AD.A6.E6.80.A7.E8.B4.A8"></span><span id="化学性质">化學性質</span></h2>
<p>六羰基鎢在超酸中可以被氧化：</p>
<dl><dd>W(CO)<sub>6</sub> + 4 SbF<sub>5</sub> → [W(CO)<sub>6</sub>(FSbF<sub>5</sub>)][Sb<sub>2</sub>F<sub>11</sub>] + SbF<sub>3</sub></dd></dl><h2><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span><span id="参考文献">參考文獻</span></h2>

<h2><span id=".E6.8B.93.E5.B1.95.E9.98.85.E8.AF.BB"></span><span id="拓展阅读">拓展閱讀</span></h2>
<p><small>
</small></p><small><ul><li><cite class="citation journal">Hiroki Tanaka, Nobuaki Nakashima, Tomoyuki Yatsuhashi. Anisotropic Coulomb Explosion of CO Ligands in Group 6 Metal Hexacarbonyls: Cr(CO) 6 , Mo(CO) 6 , W(CO) 6. The Journal of Physical Chemistry A. 2016-09-08, <b>120</b> (35): 6917–6928 <span> [<span>2019-06-18</span>]</span>. <span title="國際標準連續出版物號">ISSN 1089-5639</span>. <span title="數位物件識別號">doi:10.1021/acs.jpca.6b05113</span>. （原始內容存檔於2019-10-27） <span title="連接到英語網頁">（英語）</span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%A8&amp;rft.atitle=Anisotropic+Coulomb+Explosion+of+CO+Ligands+in+Group+6+Metal+Hexacarbonyls%3A+Cr%28CO%29+6+%2C+Mo%28CO%29+6+%2C+W%28CO%29+6&amp;rft.au=Hiroki+Tanaka%2C+Nobuaki+Nakashima%2C+Tomoyuki+Yatsuhashi&amp;rft.date=2016-09-08&amp;rft.genre=article&amp;rft.issn=1089-5639&amp;rft.issue=35&amp;rft.jtitle=The+Journal+of+Physical+Chemistry+A&amp;rft.pages=6917-6928&amp;rft.volume=120&amp;rft_id=http%3A%2F%2Fpubs.acs.org%2Fdoi%2F10.1021%2Facs.jpca.6b05113&amp;rft_id=info%3Adoi%2F10.1021%2Facs.jpca.6b05113&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal"><span> </span></span></li>
<li><cite class="citation journal">Vladimir N. Smirnov, Pavel A. Vlasov. Kinetic and thermochemical characteristics of the dissociation of Mo(CO) 6 and W(CO) 6. International Journal of Chemical Kinetics. 2019-03, <b>51</b> (3): 232–245 <span> [<span>2019-06-18</span>]</span>. <span title="數位物件識別號">doi:10.1002/kin.21246</span> <span title="連接到英語網頁">（英語）</span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%A8&amp;rft.atitle=Kinetic+and+thermochemical+characteristics+of+the+dissociation+of+Mo%28CO%29+6+and+W%28CO%29+6&amp;rft.au=Vladimir+N.+Smirnov%2C+Pavel+A.+Vlasov&amp;rft.date=2019-03&amp;rft.genre=article&amp;rft.issue=3&amp;rft.jtitle=International+Journal+of+Chemical+Kinetics&amp;rft.pages=232-245&amp;rft.volume=51&amp;rft_id=http%3A%2F%2Fdoi.wiley.com%2F10.1002%2Fkin.21246&amp;rft_id=info%3Adoi%2F10.1002%2Fkin.21246&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal"><span> </span></span></li></ul></small><small></small><p><small></small>
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**六羰基鎢**是一種配位化合物，化學式為 W (CO)6。經過它得到了第一個雙氫配合物。

它是無色固體，和同族的羰基配合物六羰基鉻與六羰基鉬一樣，是揮發性的且在空氣中穩定的物質，其中鎢原子為 0 價。

## 化學性質

六羰基鎢在超酸中可以被氧化：

　
: W(CO)6 + 4 SbF5 → [W(CO)6(FSbF5)][Sb2F11] + SbF3

## 參考文獻

## 拓展閱讀

* Hiroki Tanaka, Nobuaki Nakashima, Tomoyuki Yatsuhashi. Anisotropic Coulomb Explosion of CO Ligands in Group 6 Metal Hexacarbonyls: Cr(CO) 6 , Mo(CO) 6 , W(CO) 6. The Journal of Physical Chemistry A. 2016-09-08, **120** (35): 6917–6928 [2019-06-18]. ISSN 1089-5639. doi:10.1021/acs.jpca.6b05113. （原始內容存檔於 2019-10-27） （英語）.
* Vladimir N. Smirnov, Pavel A. Vlasov. Kinetic and thermochemical characteristics of the dissociation of Mo(CO) 6 and W(CO) 6. International Journal of Chemical Kinetics. 2019-03, **51** (3): 232–245 [2019-06-18]. doi:10.1002/kin.21246 （英語）.
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