<p><b>螺[5.5]十一烷</b>是一種螺環化合物，化學式為C<sub>11</sub>H<sub>20</sub>。它可作為源於雙(環己基羰基)過氧化物和4-戊烯酸叔丁酯反應產生的環己基自由基副產物產生。</p>


<h2><span id=".E5.88.B6.E5.A4.87"></span><span id="制备">製備</span></h2>
<p>四氫糖醇在吡啶中和三溴化磷反應，得到四氫呋喃甲基溴；4-戊烯-1-醇的格氏試劑在吡啶中和三溴化磷反應，得到5-溴-1-戊烯。回流混合物，在磷酸中於135-140°C加熱，用石油醚和水處理，得到中間體螺[5.5]十一烯。190°C下在鉑碳催化劑下加氫，洗滌後在金屬鈉存在下蒸餾，得到產物螺[5.5]十一烷。</p>
<h2><span id=".E5.8F.82.E8.A7.81"></span><span id="参见">參見</span></h2>
<ul><li><span data-orig-title="2,4,8,10-四氧杂螺［5.5］十一烷" data-lang-code="de" data-lang-name="德语" data-foreign-title="2,4,8,10-Tetraoxaspiro(5.5)undecan"><span>2,4,8,10-四氧雜螺[5.5]十一烷</span></span></li></ul><h2><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span><span id="参考文献">參考文獻</span></h2>

<h2><span id=".E6.8B.93.E5.B1.95.E9.98.85.E8.AF.BB"></span><span id="拓展阅读">拓展閱讀</span></h2>
<p><small>
</small></p><small><ol><li>Novikova, N. B.; Sokolova, I. M.; Soboleva, L. I.; Golovkina, L. S.; Petrov, A. A. Mass-spectrometric study of monomethyl-substituted spiro[4.4]nonanes, spiro[4.5]decanes, and spiro[5.5]undecanes<span title="俄語">（俄文）</span>（單甲基取代的螺[4.4]壬烷、螺[4.5]癸烷和螺[5.5]十一烷的質譜研究）. <i>Neftekhimiya</i>, 1986. 26 (4): 499-503.</li>
<li>B·羅洛夫, F·泰爾, K·林茨,等. 螺(5.5)十一烷衍生物: CN, CN 102083790 A[P]. 2011.</li></ol></small><small></small><p><small></small>
</p>
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**螺 [5.5] 十一烷**是一種螺環化合物，化學式為 C11H20。它可作為源於雙 (環己基羰基) 過氧化物和 4 - 戊烯酸叔丁酯反應產生的環己基自由基副產物產生。

## 製備

四氫糖醇在吡啶中和三溴化磷反應，得到四氫呋喃甲基溴；4 - 戊烯 - 1 - 醇的格氏試劑在吡啶中和三溴化磷反應，得到 5 - 溴 - 1 - 戊烯。回流混合物，在磷酸中於 135-140°C 加熱，用石油醚和水處理，得到中間體螺 [5.5] 十一烯。190°C 下在鉑碳催化劑下加氫，洗滌後在金屬鈉存在下蒸餾，得到產物螺 [5.5] 十一烷。

## 參見

* 2,4,8,10 - 四氧雜螺 [5.5] 十一烷

## 參考文獻

## 拓展閱讀

1. Novikova, N. B.; Sokolova, I. M.; Soboleva, L. I.; Golovkina, L. S.; Petrov, A. A. Mass-spectrometric study of monomethyl-substituted spiro[4.4]nonanes, spiro[4.5]decanes, and spiro[5.5]undecanes（俄文）（單甲基取代的螺 [4.4] 壬烷、螺 [4.5] 癸烷和螺 [5.5] 十一烷的質譜研究）. _Neftekhimiya_, 1986. 26 (4): 499-503.
2. B・羅洛夫，F・泰爾，K・林茨，等。螺 (5.5) 十一烷衍生物: CN, CN 102083790 A [P]. 2011.
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