<p><b>氟試劑</b>（英語：Selectfluor），又名<b>1-氯甲基-4-氟-1,4-氮鎓雙環[2.2.2]辛烷雙(四氟硼酸鹽)</b>，是Air Products and Chemicals公司的商品名，在化學中用作氟供體試劑。它是雜環化合物DABCO的衍生物。它最初於1992年被報導，為無色固體。它在有機氟化學中用作親電氟化試劑。
</p>


<h2><span id=".E5.88.B6.E5.A4.87"></span><span id="制备">製備</span></h2>
<p>氟試劑可由下列方法製備：</p>
<dl><dd></dd></dl><h2><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span><span id="参考文献">參考文獻</span></h2>

<h3><span id=".E6.8B.93.E5.B1.95.E9.98.85.E8.AF.BB"></span><span id="拓展阅读">拓展閱讀</span></h3>
<ol><li>Lal, G. S., J. Org. Chem. 1993, 58, 2791.</li>
<li>Lal, G. S., Synth. Commun. 1995, 25 (5), 725.</li>
<li>Banks, R. E.; Lawrence, N. J.; Popplewell, A. L., J. Chem. Soc., Chem. Commun. 1994, 343.</li>
<li>Banks, R. E., J. Fluorine Chem. 1998, 87, 1.</li>
<li>Zupan, M.; Iskra, J.; Stavber, S., J. Fluorine Chem., 1995, 70, 7.</li>
<li>Matthews, D.P.; Miller, S. C.; Jarvi E. T.; Sabol, J. S.; McCarthy, J. R., Tettrahedron Lett. 1993, 34 (19), 3057.</li>
<li>Brunaus, M.; Dell, C. P.; Owton, W. M., J. Fluorine Chem. 1994, 201.</li>
<li>McClinton, M. A. ; Sik, V., J. Chem. Soc., Perkin Trans. I, 1992, 1891.</li>
<li>Hodson, H. F.; Madge, D. J.; Slawin, A. N. Z.; Widdawson, D. A.; Williams, D. J., Tetrahedron, 1994, 50 (6), 1899.</li>
<li>Stavber, S.; Zupan, M., J. Chem. Soc., Chem. Commun. 1994, 149.</li>
<li>Stavber, S.; Sotler, J.; Zupan, M., Tettrahedron Lett. 1994, 35 (7), 1105.</li></ol><h3><span id=".E4.B8.93.E5.88.A9.E6.96.87.E7.8C.AE"></span><span id="专利文献">專利文獻</span></h3>
<ul><li><span>US 5459267</span><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&amp;rft.number=5459267&amp;rft.cc=US&amp;rft.title="><span> </span></span> "1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts and their application as fluorinating agents"</li>
<li><span>US 55227493</span><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&amp;rft.number=55227493&amp;rft.cc=US&amp;rft.title="><span> </span></span> "Fluorinated Sulfonamide Derivatives"</li>
<li><span>US 5086178</span><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&amp;rft.number=5086178&amp;rft.cc=US&amp;rft.title="><span> </span></span> "Fluorinated Diazabicycloalkane Derivatives"</li>
<li><span>US 5473065</span><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&amp;rft.number=5473065&amp;rft.cc=US&amp;rft.title="><span> </span></span> "Fluorinated Diazabicycloalkane Derivatives"</li>
<li><span>US 5442084</span><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&amp;rft.number=5442084&amp;rft.cc=US&amp;rft.title="><span> </span></span> "Method of Selective Fluorination"</li></ul><!-- 
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**氟試劑**（英語：Selectfluor），又名 **1 - 氯甲基 - 4 - 氟 - 1,4 - 氮鎓雙環 [2.2.2] 辛烷雙 (四氟硼酸鹽)**，是 Air Products and Chemicals 公司的商品名，在化學中用作氟供體試劑。它是雜環化合物 DABCO 的衍生物。它最初於 1992 年被報導，為無色固體。它在有機氟化學中用作親電氟化試劑。

## 製備

氟試劑可由下列方法製備：

　
:

## 參考文獻

### 拓展閱讀

1. Lal, G. S., J. Org. Chem. 1993, 58, 2791.
2. Lal, G. S., Synth. Commun. 1995, 25 (5), 725.
3. Banks, R. E.; Lawrence, N. J.; Popplewell, A. L., J. Chem. Soc., Chem. Commun. 1994, 343.
4. Banks, R. E., J. Fluorine Chem. 1998, 87, 1.
5. Zupan, M.; Iskra, J.; Stavber, S., J. Fluorine Chem., 1995, 70, 7.
6. Matthews, D.P.; Miller, S. C.; Jarvi E. T.; Sabol, J. S.; McCarthy, J. R., Tettrahedron Lett. 1993, 34 (19), 3057.
7. Brunaus, M.; Dell, C. P.; Owton, W. M., J. Fluorine Chem. 1994, 201.
8. McClinton, M. A. ; Sik, V., J. Chem. Soc., Perkin Trans. I, 1992, 1891.
9. Hodson, H. F.; Madge, D. J.; Slawin, A. N. Z.; Widdawson, D. A.; Williams, D. J., Tetrahedron, 1994, 50 (6), 1899.
10. Stavber, S.; Zupan, M., J. Chem. Soc., Chem. Commun. 1994, 149.
11. Stavber, S.; Sotler, J.; Zupan, M., Tettrahedron Lett. 1994, 35 (7), 1105.

### 專利文獻

* US 5459267  "1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts and their application as fluorinating agents"
* US 55227493  "Fluorinated Sulfonamide Derivatives"
* US 5086178  "Fluorinated Diazabicycloalkane Derivatives"
* US 5473065  "Fluorinated Diazabicycloalkane Derivatives"
* US 5442084  "Method of Selective Fluorination"
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