<p><b>乙醯丙酮鉑(II)</b>是一種配位化合物，化學式為Pt(O<sub>2</sub>C<sub>5</sub>H<sub>7</sub>)<sub>2</sub>。
</p>


<h2><span id=".E5.88.B6.E5.A4.87"></span><span id="制备">製備</span></h2>
<p>在1 N高氯酸介質中，將高氯酸汞加入至四氯合鉑(II)酸鉀溶液中攪拌，再加入高氯酸銀，過濾後得到含有橙黃色的[Pt(H<sub>2</sub>O)<sub>4</sub>]<sup>2+</sup>離子，在鹼性條件下將乙醯丙酮的鹼性溶液加至上述Pt(II)溶液中，產生暗灰色沉澱，攪動下變為黃色，即乙醯丙酮鉑(II)。</p>
<dl><dd>[Pt(H<sub>2</sub>O)<sub>4</sub>]<sup>2+</sup> + 2 H(acac) + 2 OH<sup>−</sup> → Pt(acac)<sub>2</sub> + 6 H<sub>2</sub>O</dd></dl><p>它也可由六氟合鉑(IV)酸在含有乙醇的高氯酸中與乙醯丙酮反應得到。</p>
<h2><span id=".E6.80.A7.E8.B4.A8"></span><span id="性质">性質</span></h2>
<p>乙醯丙酮鉑(II)可以和其它配位能力更強的配體反應，得到新的配合物。它和乙醯丙酮銀混合，可以增加乙醯丙酮銀的熱穩定性。</p>
<h2><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span><span id="参考文献">參考文獻</span></h2>

<h2><span id=".E6.8B.93.E5.B1.95.E9.98.85.E8.AF.BB"></span><span id="拓展阅读">拓展閱讀</span></h2>
<ul><li>Kumar, Vikesh; Kumar, Manish; Gupta, Divya; Tripathi, M. R. Spectroscopic studies on the molecular association of Pt(NO<sub>2</sub>-acac)<sub>​2</sub> with heterocyclic N-bases（頁面存檔備份，存於網際網路檔案館）. <i>Pharma Chemica</i>, 2009. 1 (2): 170-176. ISSN: 0975-413X.</li>
<li><cite class="citation journal">Okeya, Seichi; Ooi, Shun』ichiro; Matsumoto, Keiji; Nakamura, Yukio; Kawaguchi, Shinichi. Bis(β-diketonato)-palladram(II) and -platinum(II) Complexes. Bulletin of the Chemical Society of Japan. 1981, <b>54</b> (4): 1085–1095. <span title="國際標準連續出版物號">ISSN 0009-2673</span>. <span title="數位物件識別號">doi:10.1246/bcsj.54.1085</span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E4%B9%99%E9%85%B0%E4%B8%99%E9%85%AE%E9%93%82%28II%29&amp;rft.atitle=Bis%28%CE%B2-diketonato%29-palladram%28II%29+and+-platinum%28II%29+Complexes&amp;rft.au=Kawaguchi%2C+Shinichi&amp;rft.au=Matsumoto%2C+Keiji&amp;rft.au=Nakamura%2C+Yukio&amp;rft.au=Ooi%2C+Shun%E2%80%99ichiro&amp;rft.aufirst=Seichi&amp;rft.aulast=Okeya&amp;rft.date=1981&amp;rft.genre=article&amp;rft.issn=0009-2673&amp;rft.issue=4&amp;rft.jtitle=Bulletin+of+the+Chemical+Society+of+Japan&amp;rft.pages=1085-1095&amp;rft.volume=54&amp;rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fsim_bulletin-of-the-chemical-society-of-japan_1981-04_54_4%2Fpage%2F1085&amp;rft_id=info%3Adoi%2F10.1246%2Fbcsj.54.1085&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal"><span> </span></span></li>
<li><cite class="citation journal">Mojović, Zorica; Mentus, S.; Tešić, Ž. Introduction of Pt and Pd Nanoclusters in Zeolite Cavities by Thermal Degradation of Acetylacetonates. Materials Science Forum. 2004,. 453-454: 257–262. <span title="國際標準連續出版物號">ISSN 1662-9752</span>. <span title="數位物件識別號">doi:10.4028/www.scientific.net/MSF.453-454.257</span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E4%B9%99%E9%85%B0%E4%B8%99%E9%85%AE%E9%93%82%28II%29&amp;rft.atitle=Introduction+of+Pt+and+Pd+Nanoclusters+in+Zeolite+Cavities+by+Thermal+Degradation+of+Acetylacetonates&amp;rft.au=Mentus%2C+S.&amp;rft.au=Te%C5%A1i%C4%87%2C+%C5%BD.&amp;rft.aufirst=Zorica&amp;rft.aulast=Mojovi%C4%87&amp;rft.date=2004&amp;rft.genre=article&amp;rft.issn=1662-9752&amp;rft.jtitle=Materials+Science+Forum&amp;rft.pages=257-262&amp;rft.volume=453-454&amp;rft_id=info%3Adoi%2F10.4028%2Fwww.scientific.net%2FMSF.453-454.257&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal"><span> </span></span></li></ul>
**乙醯丙酮鉑 (II)** 是一種配位化合物，化學式為 Pt (O2C5H7)2。

## 製備

在 1 N 高氯酸介質中，將高氯酸汞加入至四氯合鉑 (II) 酸鉀溶液中攪拌，再加入高氯酸銀，過濾後得到含有橙黃色的 [Pt (H2O)4]2+ 離子，在鹼性條件下將乙醯丙酮的鹼性溶液加至上述 Pt (II) 溶液中，產生暗灰色沉澱，攪動下變為黃色，即乙醯丙酮鉑 (II)。

　
: [Pt(H2O)4]2+ + 2 H(acac) + 2 OH− → Pt(acac)2 + 6 H2O

它也可由六氟合鉑 (IV) 酸在含有乙醇的高氯酸中與乙醯丙酮反應得到。

## 性質

乙醯丙酮鉑 (II) 可以和其它配位能力更強的配體反應，得到新的配合物。它和乙醯丙酮銀混合，可以增加乙醯丙酮銀的熱穩定性。

## 參考文獻

## 拓展閱讀

* Kumar, Vikesh; Kumar, Manish; Gupta, Divya; Tripathi, M. R. Spectroscopic studies on the molecular association of Pt(NO2-acac)​2 with heterocyclic N-bases（頁面存檔備份，存於網際網路檔案館）. _Pharma Chemica_, 2009. 1 (2): 170-176. ISSN: 0975-413X.
* Okeya, Seichi; Ooi, Shun』ichiro; Matsumoto, Keiji; Nakamura, Yukio; Kawaguchi, Shinichi. Bis(β-diketonato)-palladram(II) and -platinum(II) Complexes. Bulletin of the Chemical Society of Japan. 1981, **54** (4): 1085–1095. ISSN 0009-2673. doi:10.1246/bcsj.54.1085.
* Mojović, Zorica; Mentus, S.; Tešić, Ž. Introduction of Pt and Pd Nanoclusters in Zeolite Cavities by Thermal Degradation of Acetylacetonates. Materials Science Forum. 2004,. 453-454: 257–262. ISSN 1662-9752. doi:10.4028/www.scientific.net/MSF.453-454.257.
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