<p><b><i>N</i>-亞磺醯基苯胺</b>是有機硫化合物，化學式C<sub>6</sub>H<sub>5</sub>NSO，這<span data-orig-title="亚磺酰胺" data-lang-code="en" data-lang-name="英語" data-foreign-title="sulfinylamine"><span>亞磺醯胺</span></span>是稻草色液體；親雙烯體；在金屬有機化合物中可作為配體。</p>
<h2><span id=".E5.88.B6.E5.A4.87.E5.8F.8A.E7.BB.93.E6.9E.84"></span><span id="制备及结构">製備及結構</span></h2>
<p><i>N</i>-亞磺醯基苯胺可由苯胺和氯化亞碸反應而成：</p>
<dl><dd>3 PhNH<sub>2</sub> + SOCl<sub>2</sub>  →  PhNSO + 2 [PhNH<sub>3</sub>]Cl</dd></dl><p>單晶衍射表明結構和二氧化硫或二亞氨基硫有相似之處，碳－氮＝硫＝氧二面角為–1.60°。</p>
<h2><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span><span id="参考文献">參考文獻</span></h2>
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**_N_- 亞磺醯基苯胺**是有機硫化合物，化學式 C6H5NSO，這亞磺醯胺是稻草色液體；親雙烯體；在金屬有機化合物中可作為配體。

## 製備及結構

_N_- 亞磺醯基苯胺可由苯胺和氯化亞碸反應而成：

　
: 3 PhNH2 + SOCl2 → PhNSO + 2 [PhNH3]Cl

單晶衍射表明結構和二氧化硫或二亞氨基硫有相似之處，碳－氮＝硫＝氧二面角為–1.60°。

## 參考文獻
1122-83-4