Acidity of Carboxylic Acids -

PROBLEM Calculate the $\mathrm{p} K_{\mathrm{a}}$ 's of the following acids:
20-38 (a) Lactic acid, $K_{\mathrm{a}}=8.4 \times 10^{-4}$ (b) Acrylic acid, $K_{\mathrm{a}}=5.6 \times 10^{-6}$
PROBLEM Calculate the $K_{\mathrm{a}}$ 's of the following acids:
20-39 (a) Citric acid, $\mathrm{p} K_{\mathrm{a}}=3.14$ (b) Tartaric acid, $\mathrm{p} K_{\mathrm{a}}=2.98$
PROBLEM Thioglycolic acid, $\mathrm{HSCH}_{2} \mathrm{CO}_{2} \mathrm{H}$, a substance used in depilatory agents (hair removers) has $\mathrm{p} K_{\mathrm{a}}=$
20-40 3.42. What is the percent dissociation of thioglycolic acid in a buffer solution at $\mathrm{pH}=3.0$ ?
PROBLEM In humans, the final product of purine degradation from DNA is uric acid, $\mathrm{p} K_{\mathrm{a}}=5.61$, which is 20-41 excreted in the urine. What is the percent dissociation of uric acid in urine at a typical $\mathrm{pH}=6.0$ ? Why do you think uric acid is acidic even though it does not have a $\mathrm{CO}_{2} \mathrm{H}$ group?
<img class="imgSvg" id = "m6sn3owclf28168x5ho" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3owclf28168x5ho" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 230 177.4424529586994" style="width: 230.38737291670645px; height: 177.4424529586994px; overflow: visible;"><defs><linearGradient id="line-m6sn3owclf28168x5ho-1" gradientUnits="userSpaceOnUse" x1="146.10599983839003" y1="156.7387911520632" x2="149.3986464313211" y2="125.41135144796257"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-3" gradientUnits="userSpaceOnUse" x1="140.46706069165194" y1="156.1461147653356" x2="143.75970728458302" y2="124.81867506123498"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-5" gradientUnits="userSpaceOnUse" x1="146.57917685795206" y1="125.11501325459878" x2="173.85897707716185" y2="109.36501325459878"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-7" gradientUnits="userSpaceOnUse" x1="123.17011485541413" y1="104.03739915429476" x2="146.57917685795206" y2="125.11501325459878"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-9" gradientUnits="userSpaceOnUse" x1="167.30975881640245" y1="78.55336383148389" x2="173.85897707716185" y2="109.36501325459878"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-11" gradientUnits="userSpaceOnUse" x1="119.27153253626935" y1="98.85353419648078" x2="129.52129594177953" y2="75.83218866388722"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-13" gradientUnits="userSpaceOnUse" x1="123.17011485541413" y1="104.03739915429476" x2="135.98231911230184" y2="75.26071723855281"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-15" gradientUnits="userSpaceOnUse" x1="91.84267515131353" y1="107.33004574722585" x2="123.17011485541413" y2="104.03739915429476"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-17" gradientUnits="userSpaceOnUse" x1="169.41657439663084" y1="80.45034910051126" x2="190.49418849693487" y2="57.04128709797333"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-19" gradientUnits="userSpaceOnUse" x1="165.202943236174" y1="76.65637856245654" x2="186.28055733647804" y2="53.24731655991861"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-21" gradientUnits="userSpaceOnUse" x1="135.98231911230184" y1="75.26071723855281" x2="167.30975881640245" y2="78.55336383148389"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-23" gradientUnits="userSpaceOnUse" x1="117.4670836650889" y1="49.77668191574196" x2="135.98231911230184" y2="75.26071723855281"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-25" gradientUnits="userSpaceOnUse" x1="73.32743970410061" y1="81.84601042441501" x2="91.84267515131353" y2="107.33004574722585"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-27" gradientUnits="userSpaceOnUse" x1="86.13964396098828" y1="53.06932850867308" x2="117.4670836650889" y2="49.77668191574196"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-29" gradientUnits="userSpaceOnUse" x1="120.05698503750567" y1="50.92978029886184" x2="132.86918929439332" y2="22.15309838311989"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-31" gradientUnits="userSpaceOnUse" x1="114.87718229267212" y1="48.62358353262207" x2="127.68938654955976" y2="19.84690161688011"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-33" gradientUnits="userSpaceOnUse" x1="41.7036618066362" y1="82.31918744397706" x2="73.0311015107368" y2="79.02654085104597"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-35" gradientUnits="userSpaceOnUse" x1="42.2963381933638" y1="87.95812659071517" x2="73.62377789746441" y2="84.66547999778408"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owclf28168x5ho-37" gradientUnits="userSpaceOnUse" x1="73.32743970410061" y1="81.84601042441501" x2="86.13964396098828" y2="53.06932850867308"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3owclf28168x5ho"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="143.28653026502099" cy="156.4424529586994" r="7.875" fill="black"></circle><circle cx="173.85897707716185" cy="109.36501325459878" r="7.875" fill="black"></circle><circle cx="188.38737291670645" cy="55.14430182894597" r="7.875" fill="black"></circle><circle cx="91.84267515131353" cy="107.33004574722585" r="7.875" fill="black"></circle><circle cx="42" cy="85.13865701734612" r="7.875" fill="black"></circle><circle cx="86.13964396098828" cy="53.06932850867308" r="7.875" fill="black"></circle><circle cx="130.27928792197653" cy="21" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3owclf28168x5ho {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3owclf28168x5ho {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3owclf28168x5ho)"><line x1="146.10599983839003" y1="156.7387911520632" x2="149.3986464313211" y2="125.41135144796257" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-1')"></line><line x1="140.46706069165194" y1="156.1461147653356" x2="143.75970728458302" y2="124.81867506123498" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-3')"></line><line x1="146.57917685795206" y1="125.11501325459878" x2="173.85897707716185" y2="109.36501325459878" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-5')"></line><line x1="123.17011485541413" y1="104.03739915429476" x2="146.57917685795206" y2="125.11501325459878" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-7')"></line><line x1="167.30975881640245" y1="78.55336383148389" x2="173.85897707716185" y2="109.36501325459878" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-9')"></line><line x1="119.27153253626935" y1="98.85353419648078" x2="129.52129594177953" y2="75.83218866388722" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-11')"></line><line x1="123.17011485541413" y1="104.03739915429476" x2="135.98231911230184" y2="75.26071723855281" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-13')"></line><line x1="91.84267515131353" y1="107.33004574722585" x2="123.17011485541413" y2="104.03739915429476" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-15')"></line><line x1="169.41657439663084" y1="80.45034910051126" x2="190.49418849693487" y2="57.04128709797333" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-17')"></line><line x1="165.202943236174" y1="76.65637856245654" x2="186.28055733647804" y2="53.24731655991861" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-19')"></line><line x1="135.98231911230184" y1="75.26071723855281" x2="167.30975881640245" y2="78.55336383148389" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-21')"></line><line x1="117.4670836650889" y1="49.77668191574196" x2="135.98231911230184" y2="75.26071723855281" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-23')"></line><line x1="73.32743970410061" y1="81.84601042441501" x2="91.84267515131353" y2="107.33004574722585" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-25')"></line><line x1="86.13964396098828" y1="53.06932850867308" x2="117.4670836650889" y2="49.77668191574196" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-27')"></line><line x1="120.05698503750567" y1="50.92978029886184" x2="132.86918929439332" y2="22.15309838311989" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-29')"></line><line x1="114.87718229267212" y1="48.62358353262207" x2="127.68938654955976" y2="19.84690161688011" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-31')"></line><line x1="41.7036618066362" y1="82.31918744397706" x2="73.0311015107368" y2="79.02654085104597" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-33')"></line><line x1="42.2963381933638" y1="87.95812659071517" x2="73.62377789746441" y2="84.66547999778408" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-35')"></line><line x1="73.32743970410061" y1="81.84601042441501" x2="86.13964396098828" y2="53.06932850867308" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owclf28168x5ho-37')"></line></g><g><text x="138.03653026502099" y="161.6924529586994" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="143.28653026502099" y="156.4424529586994" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="146.57917685795206" y="125.11501325459878" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="169.92147707716185" y="114.61501325459878" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>N</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="173.85897707716185" y="109.36501325459878" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="167.30975881640245" y="78.55336383148389" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="183.13737291670645" y="60.39430182894597" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="188.38737291670645" y="55.14430182894597" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="135.98231911230184" y="75.26071723855281" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="123.17011485541413" y="104.03739915429476" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="91.84267515131353" y="99.45504574722585" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: vertical-rl;
                text-orientation: upright;
                letter-spacing: -1px;
                direction: ltr;
            "><tspan>N</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="91.84267515131353" y="107.33004574722585" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="73.32743970410061" y="81.84601042441501" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="47.25" y="90.38865701734612" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>O</tspan></text><text x="42" y="85.13865701734612" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="86.13964396098828" y="60.94432850867308" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: vertical-rl;
                text-orientation: upright;
                letter-spacing: -1px;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>N</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="86.13964396098828" y="53.06932850867308" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="117.4670836650889" y="49.77668191574196" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="125.02928792197653" y="26.25" class="element-m6sn3owclf28168x5ho" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="130.27928792197653" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>


Acidity of Carboxylic Acids -

Uric acid


Acidity of Carboxylic Acids -

PROBLEM Some $\mathrm{p} K_{\mathrm{a}}$ data for simple dibasic acids is shown. How can you account for the fact that the difference
20-42 between the first and second ionization constants decreases with increasing distance between the carboxyl groups?


Acidity of Carboxylic Acids -

| Name | Structure | $\mathbf{p K}$ | $\mathbf{p} \mathbf{K}_{\mathbf{2}}$ |
| :---: | :---: | :---: | :---: |
| Oxalic | $\mathrm{HO}_{2} \mathrm{CCO}_{2} \mathrm{H}$ | 1.2 | 4.2 |


Acidity of Carboxylic Acids -

| Succinic | $\mathrm{HO}_{2} \mathrm{CCH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}$ | 4.2 | 5.6 |
| :---: | :---: | :---: | :---: |
| Adipic | $\mathrm{HO}_{2} \mathrm{C}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{CO}_{2} \mathrm{H}$ | 4.4 | 5.4 |


Acidity of Carboxylic Acids -

Reactions of Carboxylic Acids and Nitriles
PROBLEM How could you convert butanoic acid into the following compounds? Write each step showing the 20-43 reagents needed.
(a) 1-Butanol
(b) 1-Bromobutane
(c) Pentanoic acid
(d) 1-Butene
(e) Octane

PROBLEM How could you convert each of the following compounds into butanoic acid? Write each step 20-44 showing all reagents.
(a) 1-Butanol
(b) 1-Bromobutane
(c) 1-Butene
(d) 1-Bromopropane
(e) 4-Octene

PROBLEM How could you convert butanenitrile into the following compounds? Write each step showing the 20-45 reagents needed.
(a) 1-Butanol
(b) Butylamine
(c) 2-Methyl-3-hexanone


Acidity of Carboxylic Acids -

PROBLEM How would you prepare the following compounds from benzene? More than one step is needed in 20-46 each case.
(a) $m$-Chlorobenzoic acid
(b) p-Bromobenzoic acid
(c) Phenylacetic acid, $\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}$


Acidity of Carboxylic Acids -

PROBLEM Predict the product of the reaction of $p$-methylbenzoic acid with each of the following:
20-47 (a) $\mathrm{LiAlH}_{4}$, then $\mathrm{H}_{3} \mathrm{O}^{+}$
(b) $N$-Bromosuccinimide in $\mathrm{CCl}_{4}$
(c) $\mathrm{CH}_{3} \mathrm{MgBr}$ in ether, then $\mathrm{H}_{3} \mathrm{O}^{+}$
(d) $\mathrm{KMnO}_{4}, \mathrm{H}_{3} \mathrm{O}^{+}$


Acidity of Carboxylic Acids -

PROBLEM Using ${ }^{13} \mathrm{CO}_{2}$ as your only source of labeled carbon, along with any other compounds needed, how
20-48 would you synthesize the following compounds?
(a) $\mathrm{CH}_{3} \mathrm{CH}_{2}{ }^{13} \mathrm{CO}_{2} \mathrm{H}$ (b) $\mathrm{PRODCH}_{3}{ }^{13} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}$


Acidity of Carboxylic Acids -


Acidity of Carboxylic Acids -

PROBLEM Which method-Grignard carboxylation or nitrile hydrolysis-would you use for each of the 20-50 following reactions? Explain.
(a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0725.jpg?height=158&width=641&top_left_y=1919&top_left_x=479)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0725.jpg?height=109&width=559&top_left_y=1927&top_left_x=1192)
(c)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0725.jpg?height=107&width=687&top_left_y=2093&top_left_x=486)
(d) $\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br} \longrightarrow \mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}$


Acidity of Carboxylic Acids -

PROBLEM 1,6-Hexanediamine, a starting material needed for making nylon, can be made from 1,3-butadiene.
20-51 How would you accomplish the synthesis?
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0725.jpg?height=71&width=833&top_left_y=2404&top_left_x=418)


Acidity of Carboxylic Acids -

PROBLEM 3-Methyl-2-hexenoic acid (mixture of $E$ and $Z$ isomers) has been identified as the substance 20-52 responsible for the odor of human sweat. Synthesize the compound from starting materials having five or fewer carbons.


Spectroscopy -

PROBLEM Propose a structure for a compound $\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{2}$ that dissolves in dilute NaOH and shows the following 20-53 ${ }^{1} \mathrm{H}$ NMR spectrum: $1.08 \delta(9 \mathrm{H}$, singlet), $2.2 \delta(2 \mathrm{H}$, singlet), and $11.2 \delta(1 \mathrm{H}$, singlet $)$.


Spectroscopy -

PROBLEM What spectroscopic method could you use to distinguish among the following three isomeric acids?
20-54 Tell what characteristic features you would expect for each acid.
$\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{CO}_{2} \mathrm{H}$
$\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{2} \mathrm{CO}_{2} \mathrm{H}$


Spectroscopy -

Pentanoic acid
3-Methylbutanoic acid
2,2-Dimethylpropanoic acid
PROBLEM How would you use NMR (either ${ }^{13} \mathrm{C}$ or ${ }^{1} \mathrm{H}$ ) to distinguish between the following pairs of isomers?
20-55 (a)
<img class="imgSvg" id = "m6sn3owgpw7ldib3vyg" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3owgpw7ldib3vyg" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 248 136.50003672963368" style="width: 247.6787241777511px; height: 136.50003672963368px; overflow: visible;"><defs><linearGradient id="line-m6sn3owgpw7ldib3vyg-1" gradientUnits="userSpaceOnUse" x1="175.56391719896627" y1="21.000078493320252" x2="175.56397313031266" y2="52.50007849327061"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-3" gradientUnits="userSpaceOnUse" x1="181.2339171989573" y1="21.000068425677902" x2="181.2339731303037" y2="52.50006842562824"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-5" gradientUnits="userSpaceOnUse" x1="178.39897313030818" y1="52.500073459449425" x2="205.6787241777511" y2="68.250158627141"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-7" gradientUnits="userSpaceOnUse" x1="151.11916230812417" y1="68.25005509454509" x2="178.39897313030818" y2="52.500073459449425"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-9" gradientUnits="userSpaceOnUse" x1="145.44914322276077" y1="96.60005127746571" x2="145.4491601875294" y2="71.40005127747143"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-11" gradientUnits="userSpaceOnUse" x1="151.1191411021634" y1="99.75005509453796" x2="151.11916230812417" y2="68.25005509454509"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-13" gradientUnits="userSpaceOnUse" x1="123.83937269190088" y1="52.50003672964793" x2="151.11916230812417" y2="68.25005509454509"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-15" gradientUnits="userSpaceOnUse" x1="123.83933027997941" y1="115.50003672963366" x2="151.1191411021634" y2="99.75005509453796"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-17" gradientUnits="userSpaceOnUse" x1="102.1225396462525" y1="71.58538614922719" x2="123.9463883039997" y2="58.985400841150636"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-19" gradientUnits="userSpaceOnUse" x1="96.55956186971687" y1="68.25001836474364" x2="123.83937269190088" y2="52.50003672964793"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-21" gradientUnits="userSpaceOnUse" x1="102.12252293105993" y1="96.41465807030603" x2="123.94635462403855" y2="109.01467276222375"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-23" gradientUnits="userSpaceOnUse" x1="96.55954066375611" y1="99.7500183647365" x2="123.83933027997941" y2="115.50003672963366"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-25" gradientUnits="userSpaceOnUse" x1="96.55954066375611" y1="99.7500183647365" x2="96.55956186971687" y2="68.25001836474364"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-27" gradientUnits="userSpaceOnUse" x1="69.2797722534936" y1="52.499999999846494" x2="96.55956186971687" y2="68.25001836474364"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-29" gradientUnits="userSpaceOnUse" x1="40.58249564058522" y1="65.79486893497409" x2="67.86226789407883" y2="50.04482049703206"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-31" gradientUnits="userSpaceOnUse" x1="43.417504359414785" y1="70.70522794060295" x2="70.6972766129084" y2="54.955179502660926"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owgpw7ldib3vyg-33" gradientUnits="userSpaceOnUse" x1="69.2797722534936" y1="52.499999999846494" x2="69.27987059676153" y2="21"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3owgpw7ldib3vyg"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="178.39891719896178" cy="21.000073459499077" r="7.875" fill="black"></circle><circle cx="205.6787241777511" cy="68.250158627141" r="7.875" fill="black"></circle><circle cx="42" cy="68.25004843778852" r="7.875" fill="black"></circle><circle cx="69.27987059676153" cy="21" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3owgpw7ldib3vyg {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3owgpw7ldib3vyg {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3owgpw7ldib3vyg)"><line x1="175.56391719896627" y1="21.000078493320252" x2="175.56397313031266" y2="52.50007849327061" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-1')"></line><line x1="181.2339171989573" y1="21.000068425677902" x2="181.2339731303037" y2="52.50006842562824" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-3')"></line><line x1="178.39897313030818" y1="52.500073459449425" x2="205.6787241777511" y2="68.250158627141" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-5')"></line><line x1="151.11916230812417" y1="68.25005509454509" x2="178.39897313030818" y2="52.500073459449425" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-7')"></line><line x1="145.44914322276077" y1="96.60005127746571" x2="145.4491601875294" y2="71.40005127747143" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-9')"></line><line x1="151.1191411021634" y1="99.75005509453796" x2="151.11916230812417" y2="68.25005509454509" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-11')"></line><line x1="123.83937269190088" y1="52.50003672964793" x2="151.11916230812417" y2="68.25005509454509" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-13')"></line><line x1="123.83933027997941" y1="115.50003672963366" x2="151.1191411021634" y2="99.75005509453796" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-15')"></line><line x1="102.1225396462525" y1="71.58538614922719" x2="123.9463883039997" y2="58.985400841150636" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-17')"></line><line x1="96.55956186971687" y1="68.25001836474364" x2="123.83937269190088" y2="52.50003672964793" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-19')"></line><line x1="102.12252293105993" y1="96.41465807030603" x2="123.94635462403855" y2="109.01467276222375" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-21')"></line><line x1="96.55954066375611" y1="99.7500183647365" x2="123.83933027997941" y2="115.50003672963366" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-23')"></line><line x1="96.55954066375611" y1="99.7500183647365" x2="96.55956186971687" y2="68.25001836474364" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-25')"></line><line x1="69.2797722534936" y1="52.499999999846494" x2="96.55956186971687" y2="68.25001836474364" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-27')"></line><line x1="40.58249564058522" y1="65.79486893497409" x2="67.86226789407883" y2="50.04482049703206" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-29')"></line><line x1="43.417504359414785" y1="70.70522794060295" x2="70.6972766129084" y2="54.955179502660926" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-31')"></line><line x1="69.2797722534936" y1="52.499999999846494" x2="69.27987059676153" y2="21" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owgpw7ldib3vyg-33')"></line></g><g><text x="173.14891719896178" y="26.250073459499077" class="element-m6sn3owgpw7ldib3vyg" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="178.39891719896178" y="21.000073459499077" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="178.39897313030818" y="52.500073459449425" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="201.7412241777511" y="73.500158627141" class="element-m6sn3owgpw7ldib3vyg" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="205.6787241777511" y="68.250158627141" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="151.11916230812417" y="68.25005509454509" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="151.1191411021634" y="99.75005509453796" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="123.83933027997941" y="115.50003672963366" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="96.55954066375611" y="99.7500183647365" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="96.55956186971687" y="68.25001836474364" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="69.2797722534936" y="52.499999999846494" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="47.25" y="73.50004843778852" class="element-m6sn3owgpw7ldib3vyg" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>O</tspan></text><text x="42" y="68.25004843778852" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="64.02987059676153" y="26.25" class="element-m6sn3owgpw7ldib3vyg" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="69.27987059676153" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="123.83937269190088" y="52.50003672964793" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>
and
<img class="imgSvg" id = "m6sn3owi2c1kh97honm" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3owi2c1kh97honm" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 248 168.00012243223023" style="width: 247.67868883456708px; height: 168.00012243223023px; overflow: visible;"><defs><linearGradient id="line-m6sn3owi2c1kh97honm-1" gradientUnits="userSpaceOnUse" x1="176.98140625487918" y1="113.04494229343608" x2="204.26118557704535" y2="97.29490609875025"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-3" gradientUnits="userSpaceOnUse" x1="179.81641276992264" y1="117.955302571426" x2="207.0961920920888" y2="102.20526637674017"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-5" gradientUnits="userSpaceOnUse" x1="178.39879703182578" y1="147.00012243223023" x2="178.3989095124009" y2="115.50012243243104"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-7" gradientUnits="userSpaceOnUse" x1="151.11912696484225" y1="99.75009182427304" x2="178.3989095124009" y2="115.50012243243104"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-9" gradientUnits="userSpaceOnUse" x1="123.73229637257029" y1="109.01469705656423" x2="145.5561506852316" y2="96.41472154310647"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-11" gradientUnits="userSpaceOnUse" x1="123.83930907401563" y1="115.50006121609523" x2="151.11912696484225" y2="99.75009182427304"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-13" gradientUnits="userSpaceOnUse" x1="151.11912696484225" y1="99.75009182427304" x2="151.11916230811016" y2="68.25009182429284"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-15" gradientUnits="userSpaceOnUse" x1="96.55952652645695" y1="99.7500306079373" x2="123.83930907401563" y2="115.50006121609523"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-17" gradientUnits="userSpaceOnUse" x1="123.73235250583892" y1="58.98542513551125" x2="145.55617854388586" y2="71.58544962203761"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-19" gradientUnits="userSpaceOnUse" x1="123.83937976055148" y1="52.500061216134895" x2="151.11916230811016" y2="68.25009182429284"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-21" gradientUnits="userSpaceOnUse" x1="102.22953006078018" y1="96.60003696972751" x2="102.2295583353945" y2="71.40003696974335"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-23" gradientUnits="userSpaceOnUse" x1="96.55952652645695" y1="99.7500306079373" x2="96.55956186972486" y2="68.25003060795711"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-25" gradientUnits="userSpaceOnUse" x1="96.55956186972486" y1="68.25003060795711" x2="123.83937976055148" y2="52.500061216134895"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-27" gradientUnits="userSpaceOnUse" x1="69.27977932216618" y1="52.49999999979917" x2="96.55956186972486" y2="68.25003060795711"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-29" gradientUnits="userSpaceOnUse" x1="40.58249674247827" y1="65.79485605549007" x2="67.86227606464445" y2="50.04481986080422"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-31" gradientUnits="userSpaceOnUse" x1="43.41750325752173" y1="70.70521633348" x2="70.69728257968791" y2="54.955180138794134"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3owi2c1kh97honm-33" gradientUnits="userSpaceOnUse" x1="69.27977932216618" y1="52.49999999979917" x2="69.27989180274128" y2="21"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3owi2c1kh97honm"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="205.67868883456708" cy="99.75008623774521" r="7.875" fill="black"></circle><circle cx="178.39879703182578" cy="147.00012243223023" r="7.875" fill="black"></circle><circle cx="42" cy="68.25003619448503" r="7.875" fill="black"></circle><circle cx="69.27989180274128" cy="21" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3owi2c1kh97honm {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3owi2c1kh97honm {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3owi2c1kh97honm)"><line x1="176.98140625487918" y1="113.04494229343608" x2="204.26118557704535" y2="97.29490609875025" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-1')"></line><line x1="179.81641276992264" y1="117.955302571426" x2="207.0961920920888" y2="102.20526637674017" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-3')"></line><line x1="178.39879703182578" y1="147.00012243223023" x2="178.3989095124009" y2="115.50012243243104" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-5')"></line><line x1="151.11912696484225" y1="99.75009182427304" x2="178.3989095124009" y2="115.50012243243104" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-7')"></line><line x1="123.73229637257029" y1="109.01469705656423" x2="145.5561506852316" y2="96.41472154310647" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-9')"></line><line x1="123.83930907401563" y1="115.50006121609523" x2="151.11912696484225" y2="99.75009182427304" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-11')"></line><line x1="151.11912696484225" y1="99.75009182427304" x2="151.11916230811016" y2="68.25009182429284" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-13')"></line><line x1="96.55952652645695" y1="99.7500306079373" x2="123.83930907401563" y2="115.50006121609523" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-15')"></line><line x1="123.73235250583892" y1="58.98542513551125" x2="145.55617854388586" y2="71.58544962203761" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-17')"></line><line x1="123.83937976055148" y1="52.500061216134895" x2="151.11916230811016" y2="68.25009182429284" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-19')"></line><line x1="102.22953006078018" y1="96.60003696972751" x2="102.2295583353945" y2="71.40003696974335" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-21')"></line><line x1="96.55952652645695" y1="99.7500306079373" x2="96.55956186972486" y2="68.25003060795711" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-23')"></line><line x1="96.55956186972486" y1="68.25003060795711" x2="123.83937976055148" y2="52.500061216134895" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-25')"></line><line x1="69.27977932216618" y1="52.49999999979917" x2="96.55956186972486" y2="68.25003060795711" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-27')"></line><line x1="40.58249674247827" y1="65.79485605549007" x2="67.86227606464445" y2="50.04481986080422" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-29')"></line><line x1="43.41750325752173" y1="70.70521633348" x2="70.69728257968791" y2="54.955180138794134" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-31')"></line><line x1="69.27977932216618" y1="52.49999999979917" x2="69.27989180274128" y2="21" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3owi2c1kh97honm-33')"></line></g><g><text x="201.74118883456708" y="105.00008623774521" class="element-m6sn3owi2c1kh97honm" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="205.67868883456708" y="99.75008623774521" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="178.3989095124009" y="115.50012243243104" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="173.14879703182578" y="152.25012243223023" class="element-m6sn3owi2c1kh97honm" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="178.39879703182578" y="147.00012243223023" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="151.11912696484225" y="99.75009182427304" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="123.83930907401563" y="115.50006121609523" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="96.55952652645695" y="99.7500306079373" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="96.55956186972486" y="68.25003060795711" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="69.27977932216618" y="52.49999999979917" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="47.25" y="73.50003619448503" class="element-m6sn3owi2c1kh97honm" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>O</tspan></text><text x="42" y="68.25003619448503" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="64.02989180274128" y="26.25" class="element-m6sn3owi2c1kh97honm" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="69.27989180274128" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="123.83937976055148" y="52.500061216134895" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="151.11916230811016" y="68.25009182429284" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>
(c) $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CO}_{2} \mathrm{H}$ and
$\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}$
(d)
$\left(\mathrm{CH}_{3}\right)_{2} \mathrm{C}=\mathrm{CHCH}_{2} \mathrm{CO}_{2} \mathrm{H}$
and
<img class="imgSvg" id = "m6sn3ox33j6rnif8rhl" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3ox33j6rnif8rhl" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 188 127.12661664071133" style="width: 188.4138650195203px; height: 127.12661664071133px; overflow: visible;"><defs><linearGradient id="line-m6sn3ox33j6rnif8rhl-1" gradientUnits="userSpaceOnUse" x1="116.29905804073547" y1="21.000005033821175" x2="116.29911397208187" y2="52.500005033771515"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-3" gradientUnits="userSpaceOnUse" x1="121.96905804072654" y1="20.999994966178825" x2="121.96911397207293" y2="52.499994966129165"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-5" gradientUnits="userSpaceOnUse" x1="119.13411397207739" y1="52.49999999995034" x2="146.4138650195203" y2="68.25008516764191"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-7" gradientUnits="userSpaceOnUse" x1="91.85430314989338" y1="68.24998163504603" x2="119.13411397207739" y2="52.49999999995034"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-9" gradientUnits="userSpaceOnUse" x1="88.56163546717076" y1="99.57741912251304" x2="91.85430314989338" y2="68.24998163504603"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-11" gradientUnits="userSpaceOnUse" x1="63.07762985939926" y1="55.43775800555209" x2="91.85430314989338" y2="68.24998163504603"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-13" gradientUnits="userSpaceOnUse" x1="57.74998163509571" y1="106.12661664071133" x2="88.56163546717076" y2="99.57741912251304"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-15" gradientUnits="userSpaceOnUse" x1="42" y1="78.84680581852733" x2="63.07762985939926" y2="55.43775800555209"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ox33j6rnif8rhl-17" gradientUnits="userSpaceOnUse" x1="42" y1="78.84680581852733" x2="57.74998163509571" y2="106.12661664071133"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3ox33j6rnif8rhl"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="119.13405804073099" cy="21" r="7.875" fill="black"></circle><circle cx="146.4138650195203" cy="68.25008516764191" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3ox33j6rnif8rhl {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3ox33j6rnif8rhl {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3ox33j6rnif8rhl)"><line x1="116.29905804073547" y1="21.000005033821175" x2="116.29911397208187" y2="52.500005033771515" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-1')"></line><line x1="121.96905804072654" y1="20.999994966178825" x2="121.96911397207293" y2="52.499994966129165" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-3')"></line><line x1="119.13411397207739" y1="52.49999999995034" x2="146.4138650195203" y2="68.25008516764191" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-5')"></line><line x1="91.85430314989338" y1="68.24998163504603" x2="119.13411397207739" y2="52.49999999995034" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-7')"></line><line x1="88.56163546717076" y1="99.57741912251304" x2="91.85430314989338" y2="68.24998163504603" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-9')"></line><line x1="63.07762985939926" y1="55.43775800555209" x2="91.85430314989338" y2="68.24998163504603" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-11')"></line><line x1="57.74998163509571" y1="106.12661664071133" x2="88.56163546717076" y2="99.57741912251304" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-13')"></line><line x1="42" y1="78.84680581852733" x2="63.07762985939926" y2="55.43775800555209" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-15')"></line><line x1="42" y1="78.84680581852733" x2="57.74998163509571" y2="106.12661664071133" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ox33j6rnif8rhl-17')"></line></g><g><text x="113.88405804073099" y="26.25" class="element-m6sn3ox33j6rnif8rhl" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="119.13405804073099" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="119.13411397207739" y="52.49999999995034" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="142.4763650195203" y="73.50008516764191" class="element-m6sn3ox33j6rnif8rhl" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="146.4138650195203" y="68.25008516764191" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="91.85430314989338" y="68.24998163504603" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="88.56163546717076" y="99.57741912251304" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="57.74998163509571" y="106.12661664071133" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="42" y="78.84680581852733" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="63.07762985939926" y="55.43775800555209" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>


Spectroscopy -

PROBLEM Compound $\mathbf{A}, \mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{3}$, has infrared absorptions at 1710 and 2500 to $3100 \mathrm{~cm}^{-1}$ and has the ${ }^{1} \mathrm{H}$ 20-56 NMR spectrum shown. Propose a structure for A.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0726.jpg?height=500&width=1402&top_left_y=1425&top_left_x=416)


General Problems -

PROBLEM A chemist in need of 2,2-dimethylpentanoic acid decided to synthesize some by reaction of 20-57 2-chloro-2-methylpentane with NaCN , followed by hydrolysis of the product. After the reaction sequence was carried out, however, none of the desired product could be found. What do you suppose went wrong?


General Problems -

PROBLEM Show how you might prepare the anti-inflammatory agent ibuprofen starting from 20-58 isobutylbenzene. More than one step is needed.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0727.jpg?height=278&width=834&top_left_y=178&top_left_x=410)


General Problems -

PROBLEM The following synthetic schemes all have at least one flaw in them. What is wrong with each?
20-59 (a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0727.jpg?height=160&width=722&top_left_y=519&top_left_x=479)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0727.jpg?height=158&width=733&top_left_y=688&top_left_x=479)
(c)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0727.jpg?height=166&width=646&top_left_y=855&top_left_x=485)


General Problems -

PROBLEM p-Aminobenzoic acid (PABA) was once widely used as a sunscreen agent. Propose a synthesis of
20-60 PABA starting from toluene.
PROBLEM Propose a synthesis of the anti-inflammatory drug fenclorac from phenylcyclohexane.


20-61 -


20-61 -

PROBLEM The $\mathrm{p} K_{\mathrm{a}}$ 's of five $p$-substituted benzoic acids $\left(\mathrm{YC}_{6} \mathrm{H}_{4} \mathrm{CO}_{2} \mathrm{H}\right)$ are listed below. Rank the corresponding
20-62 substituted benzenes $\left(\mathrm{YC}_{6} \mathrm{H}_{5}\right)$ in order of their increasing reactivity toward electrophilic aromatic substitution. If benzoic acid has $\mathrm{p} K_{\mathrm{a}}=4.19$, which of the substituents are activators and which are deactivators?


20-61 -

| Substituent $\mathbf{Y}$ |  |
| :---: | :---: |
| $-\mathrm{Si}\left(\mathrm{CH}_{3}\right)_{3}$ | 4.27 |
| $-\mathrm{CH}=\mathrm{CHC} \equiv \mathrm{N}$ | 4.03 |
| $-\mathrm{HgCH}_{3}$ | 4.10 |
| $-\mathrm{OSO}_{2} \mathrm{CH}_{3}$ | 3.84 |
| $-\mathrm{PCl}_{2}$ | 3.59 |


20-61 -

PROBLEM How would you carry out the following transformations? More than one step is needed in each case.