PROBLEM Diazepam, marketed as an antianxiety medication under the name Valium, has three rings, eight
7-3 double bonds, and the formula $\mathrm{C}_{16} \mathrm{H}_{?} \mathrm{ClN}_{2} \mathrm{O}$. How many hydrogens does diazepam have? (Calculate the answer; don't count hydrogens in the structure.)
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CHAPTER CONTENTS - 7.2 Calculating the Degree of Unsaturation

Diazepam


CHAPTER CONTENTS - 7.3 Naming Alkenes

Alkenes are named using a series of rules similar to those for alkanes (Section 3.4), with the suffix -ene used instead of -ane to identify the functional group. There are three steps to this process.


STEP 1 -


STEP 1 -

STEP 2
Number the carbon atoms in the chain. Begin at the end nearer the double bond or, if the double bond is equidistant from the two ends, begin at the end nearer the first branch point. This rule ensures that the doublebond carbons receive the lowest possible numbers.


STEP 1 -

$$
\underset{6}{\mathrm{CH}_{3}} \mathrm{CH}_{5} \mathrm{C}_{4} \mathrm{CH}_{2} \underset{3}{\mathrm{C}} \mathrm{H}=\underset{2}{\mathrm{C}} \mathrm{HC}_{1} \mathrm{H}_{3}
$$


STEP 1 -

STEP 3
Write the full name. Number the substituents according to their positions in the chain, and list them alphabetically. Indicate the position of the double bond by giving the number of the first alkene carbon and placing that number directly before the parent name. If more than one double bond is present, indicate the position of each and use one of the suffixes -diene, -triene, and so on.
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2-Hexene
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2-Ethyl-1-pentene
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2-Methyl-3-hexene
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STEP 1 -

We should also note that IUPAC changed their naming recommendations in 1993 to place the locant indicating the position of the double bond immediately before the -ene suffix rather than before the parent name: but-2-ene rather than 2 -butene, for instance. This change has not been widely accepted by the chemical community in the United States, however, so we'll stay with the older but more commonly used names. Be aware, though, that you may occasionally encounter the newer system.


STEP 1 -

|  | <smiles>CCC(C)C=CC(C)C(C)C</smiles> | <smiles>C=CC(C=CC)CCC</smiles> |
| :---: | :---: | :---: |
| Newer naming system: | 2,5-Dimethylhept-3-ene | 3-Propylhexa-1,4-diene |
| (Older naming system: | 2,5-Dimethyl-3-heptene | 3-Propyl-1,4-hexadiene) |


STEP 1 -

Cycloalkenes are named similarly, but because there is no chain end to begin from, we number the cycloalkene so that the double bond is between C 1 and C 2 and the first substituent has as low a number as possible. It's not necessary to indicate the position of the double bond in the name because it's always between C1 and C2. As with open-chain alkenes, the newer but not yet widely accepted naming rules place the locant immediately before the suffix in a cyclic alkene.
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"/>

1-Methylcyclohexene
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"/>

1,4-Cyclohexadiene
<img class="imgSvg" id = "m6sn3n168xmeav22dj6" 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STEP 1 -

1,5-Dimethylcyclopentene
(New: Cyclohexa-1,4-diene)
For historical reasons, there are a few alkenes whose names are firmly entrenched in common usage but don't conform to the rules. For example, the alkene derived from ethane should be called ethene, but the name ethylene has been used for so long that it is accepted by IUPAC. TABLE 7.1 lists several other common names that are often used and are recognized by IUPAC. Note also that a $=\mathrm{CH}_{2}$ substituent is called a methylene group, a $\mathrm{H}_{2} \mathrm{C}=\mathrm{CH}$ - substituent is called a vinyl group, and a $\mathrm{H}_{2} \mathrm{C}=\mathrm{CHCH}_{2}$ - substituent is called an allyl group.


STEP 1 -

$$
\mathrm{H}_{2} \mathrm{C} \geqslant \quad \mathrm{H}_{2} \mathrm{C}=\mathrm{CH}<\quad \mathrm{H}_{2} \mathrm{C}=\mathrm{CH}-\mathrm{CH}_{2} \geqslant
$$


STEP 1 -

A methylene group A vinyl group An allyl group


STEP 1 -

| Compound | Systematic name | Common name |
| :---: | :---: | :---: |
| $\mathrm{H}_{2} \mathrm{C}=\mathrm{CH}_{2}$ | Ethene | Ethylene |
| $\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CH}_{2}$ | Propene | Propylene |
| <smiles>C=C(C)C</smiles> | 2-Methylpropene | Isobutylene |
| <smiles>C=CC(=C)C</smiles> | 2-Methyl-1,3-butadiene | Isoprene |


STEP 1 -

PROBLEM Give IUPAC names for the following compounds:


STEP 1 -

PROBLEM Draw structures corresponding to the following IUPAC names:
7-5 (a) 2-Methyl-1,5-hexadiene (b) 3-Ethyl-2,2-dimethyl-3-heptene
(c) 2,3,3-Trimethyl-1,4,6-octatriene (d) 3,4-Diisopropyl-2,5-dimethyl-3-hexene


STEP 1 -

PROBLEM Change the following old names to new, post-1993 names, and draw the structure of each 7-7 compound:
(a) 2,5,5-Trimethyl-2-hexene
(b) 2,3-Dimethyl-1,3-cyclohexadiene


STEP 1 - 7.4 Cis-Trans Isomerism in Alkenes

We saw in the chapter on Structure and Bonding that the carbon-carbon double bond can be described in two ways. In valence bond language (Section 1.8), the carbons are $s p^{2}$-hybridized and have three equivalent hybrid orbitals that lie in a plane at angles of $120^{\circ}$ to one another. The carbons form a $\sigma$ bond by a head-on overlap of $s p^{2}$ orbitals and form a $\pi$ bond by sideways overlap of unhybridized $p$ orbitals oriented perpendicular to the $s p^{2}$ plane, as shown in FIGURE 1.15.


In molecular orbital language (Section 1.11), interaction between the p orbitals leads to one bonding and one antibonding $\pi$ molecular orbital. The $\pi$ bonding MO has no node between nuclei and results from a combination of $p$ orbital lobes with the same algebraic sign. The $\pi$ antibonding MO has a node between nuclei and results from a combination of lobes with different algebraic signs, as shown in FIGURE 1.19.


Although essentially free rotation around single bonds is possible (Section 3.6), the same is not true of double bonds. For rotation to occur around a double bond, the $\pi$ bond must break and re-form (FIGURE 7.3). Thus, the barrier to double-bond rotation must be at least as great as the strength of the $\pi$ bond itself, an estimated 350 $\mathrm{kJ} / \mathrm{mol}(84 \mathrm{kcal} / \mathrm{mol})$. Recall that the barrier to bond rotation in ethane is only $12 \mathrm{~kJ} / \mathrm{mol}$.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0205.jpg?height=592&width=1028&top_left_y=1303&top_left_x=543)

FIGURE 7.3 The $\boldsymbol{\pi}$ bond must break for rotation to take place around a carbon-carbon double bond.
The lack of rotation around carbon-carbon double bonds is of more than just theoretical interest; it also has chemical consequences. Imagine the situation for a disubstituted alkene such as 2-butene. (Disubstituted means that two substituents other than hydrogen are bonded to the double-bond carbons.) The two methyl groups in 2-butene can either be on the same side of the double bond or on opposite sides, a situation similar to that in disubstituted cycloalkanes (Section 4.2).


Since bond rotation can't occur, the two 2-butenes can't spontaneously interconvert; they are different, isolable compounds. As with disubstituted cycloalkanes, we call such compounds cis-trans stereoisomers. The compound with substituents on the same side of the double bond is called cis-2-butene, and the isomer with substituents on opposite sides is trans-2-butene (FIGURE 7.4).
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0206.jpg?height=191&width=606&top_left_y=235&top_left_x=369)
cis-2-Butene
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trans-2-Butene


FIGURE 7.4 Cis and trans isomers of 2-butene. The cis isomer has the two methyl groups on the same side of the double bond, and the trans isomer has methyl groups on opposite sides.