Infrared Spectroscopy -

PROBLEM Assume that you need to prepare 5-cholesten-3-one from cholesterol. How could you use IR
17-18 spectroscopy to tell whether the reaction was successful? What differences would you look for in the IR spectra of starting material and product?
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Infrared Spectroscopy -


Nuclear Magnetic Resonance Spectroscopy -

Carbon atoms bonded to electron-withdrawing - OH groups are deshielded and absorb at a lower field in the ${ }^{13} \mathrm{C}$ NMR spectrum than do typical alkane carbons. Most alcohol carbon absorptions fall in the range 50 to $80 \delta$, as shown in the following drawing for cyclohexanol:
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0588.jpg?height=280&width=347&top_left_y=2169&top_left_x=889)

Alcohols also show characteristic absorptions in the ${ }^{1} \mathrm{H}$ NMR spectrum. Hydrogens on the oxygen-bearing carbon atom are deshielded by the electron-withdrawing effect of the nearby oxygen, and their absorptions
occur in the range 3.4 to $4.5 \delta$. Spin-spin splitting, however, is not usually observed between the $\mathrm{O}-\mathrm{H}$ proton of an alcohol and the neighboring protons on carbon. Most samples contain small amounts of acidic impurities, which catalyze an exchange of the $\mathrm{O}-\mathrm{H}$ proton on a timescale so rapid that the effect of spin-spin splitting is removed. It's often possible to take advantage of this rapid proton exchange to identify the position of the $\mathrm{O}-\mathrm{H}$ absorption. If a small amount of deuterated water, $\mathrm{D}_{2} \mathrm{O}$, is added to an NMR sample tube, the $\mathrm{O}-\mathrm{H}$ proton is rapidly exchanged for deuterium and the hydroxyl absorption disappears from the spectrum.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0589.jpg?height=109&width=673&top_left_y=477&top_left_x=723)


Typical spin-spin splitting is observed between protons on the oxygen-bearing carbon and other neighbors. For example, the signal of the two $-\mathrm{CH}_{2} \mathrm{O}$ - protons in 1-propanol is split into a triplet by coupling with the neighboring $-\mathrm{CH}_{2}-$ protons (FIGURE 17.14).
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0589.jpg?height=497&width=1397&top_left_y=738&top_left_x=364)


FIGURE 17.14 ${ }^{\mathbf{1}} \mathbf{H}$ NMR spectrum of 1-propanol. The protons on the oxygen-bearing carbon are split into a triplet at $3.58 \delta$.
Phenols, like all aromatic compounds, show ${ }^{1} \mathrm{H}$ NMR absorptions near 7 to $8 \delta$, the expected position for aromatic-ring protons (Section 15.7). In addition, phenol $0-H$ protons absorb at 3 to $8 \delta$. In neither case are these absorptions uniquely diagnostic for phenols, since other kinds of protons absorb in the same range.


PROBLEM When the ${ }^{1} \mathrm{H}$ NMR spectrum of an alcohol is run in dimethyl sulfoxide (DMSO) solvent rather than
17-19 in chloroform, exchange of the $\mathrm{O}-\mathrm{H}$ proton is slow and spin-spin splitting is seen between the $\mathrm{O}-\mathrm{H}$ proton and $\mathrm{C}-\mathrm{H}$ protons on the adjacent carbon. What spin multiplicities would you expect for the hydroxyl protons in the following alcohols?
(a) 2-Methyl-2-propanol
(b) Cyclohexanol
(c) Ethanol
(d) 2-Propanol
(e) Cholesterol
(f) 1-Methylcyclohexanol


Mass Spectrometry -

As noted in Section 12.3, alcohols undergo fragmentation in the mass spectrometer by two characteristic pathways, alpha cleavage and dehydration. In the alpha-cleavage pathway, a $\mathrm{C}-\mathrm{C}$ bond nearest the hydroxyl group is broken, yielding a neutral radical plus a resonance-stabilized, oxygen-containing cation.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0589.jpg?height=159&width=1042&top_left_y=1948&top_left_x=539)


Mass Spectrometry -

In the dehydration pathway, water is eliminated, yielding an alkene radical cation.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0589.jpg?height=155&width=831&top_left_y=2167&top_left_x=647)


Mass Spectrometry -

Both fragmentation modes are apparent in the mass spectrum of 1-butanol (FIGURE 17.15). The peak at $\mathrm{m} / \mathrm{z}=$ 56 is due to loss of water from the molecular ion, and the peak at $m / z=31$ is due to an alpha cleavage.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0590.jpg?height=806&width=1362&top_left_y=191&top_left_x=376)

FIGURE 17.15 Mass spectrum of 1-butanol ( $\mathbf{M}^{+}=\mathbf{7 4}$ ). Dehydration gives a peak at $m / z=56$, and fragmentation by alpha cleavage gives a peak at $m / z=31$.


Ethanol: Chemical, Drug, and Poison -

The production of ethanol by fermentation of grains and sugars is one of the oldest known organic reactions, going back at least 8000 years in the Middle East and perhaps as many as 9000 years in China. Fermentation is carried out by adding yeast to an aqueous sugar solution, where enzymes break down carbohydrates into ethanol and $\mathrm{CO}_{2}$. As noted in the chapter introduction, approximately 26 billion gallons of ethanol is produced each year by fermentation of corn and sugar, with essentially the entire amount used to make bus and automobile fuel.


Ethanol: Chemical, Drug, and Poison -

$$
\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6} \xrightarrow{\text { Yeast }} 2 \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}+2 \mathrm{CO}_{2}
$$


A carbohydrate -

Ethanol is classified medically as a central nervous system (CNS) depressant. Its effects-that is, being drunk-resemble the human response to anesthetics. There is an initial excitability and increase in sociable behavior, but this results from depression of inhibition rather than from stimulation. At a blood alcohol concentration of $0.1 \%$ to $0.3 \%$, motor coordination is affected, accompanied by loss of balance, slurred speech, and amnesia. When blood alcohol concentration rises to between $0.3 \%$ and $0.4 \%$, nausea and loss of consciousness occur. Above $0.6 \%$, spontaneous respiration and cardiovascular regulation are affected, ultimately leading to death. The $\mathrm{LD}_{50}$ of ethanol is $10.6 \mathrm{~g} / \mathrm{kg}$ (Chapter 1 Chemistry Matters).


A carbohydrate -

The passage of ethanol through the body begins with its absorption in the stomach and small intestine, followed by rapid distribution to all body fluids and organs. In the pituitary gland, ethanol inhibits the production of a hormone that regulates urine flow, causing increased urine production and dehydration. In the stomach, ethanol stimulates production of acid. Throughout the body, ethanol causes blood vessels to dilate, resulting in flushing of the skin and a sensation of warmth as blood moves into capillaries beneath the surface. The result is not a warming of the body, but an increased loss of heat at the surface.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0591.jpg?height=635&width=891&top_left_y=1450&top_left_x=617)


A carbohydrate -

FIGURE 17.16 The Harger Drunkometer was the first breath analyzer, introduced in 1938 to help convict drunk drivers. (credit: "Unidentified police officer with a Harger "Drunkometer" breathalyzer" by Florida Memory, State Library and Archives of Florida/Wikimedia Commons, Public Doman)


A carbohydrate -

Ethanol metabolism occurs mainly in the liver and proceeds by oxidation in two steps, first to acetaldehyde $\left(\mathrm{CH}_{3} \mathrm{CHO}\right)$ and then to acetic acid $\left(\mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}\right)$. When continuously present in the body, ethanol and acetaldehyde are toxic, leading to the devastating physical and metabolic deterioration seen in people with chronic alcohol use disorder. The liver usually suffers the worst damage since it is the major site of alcohol metabolism.


A carbohydrate -

Approximately 17,000 people are killed each year in the United States in alcohol-related automobile accidents. Thus, all 50 states have made it illegal to drive with a blood alcohol concentration (BAC) above $0.08 \%$.


A carbohydrate -

Fortunately, simple tests have been devised for measuring blood alcohol concentration. The original breath analyzer test measured alcohol concentration in expired air by the color change occurring when the brightorange oxidizing agent potassium dichromate $\left(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\right)$ reduced to blue-green chromium(III). Current consumer devices use a conductivity sensor, and tests used by law-enforcement agencies use IR spectroscopy to measure blood-alcohol levels in expired air. Just breathe into the machine, and let the spectrum tell the tale.


Key Terms -

- alcohol
- phenoxide ion $\mathrm{ArO}^{-}$
- alkoxide ion, $\mathrm{RO}^{-}$
- protecting group
- hydroquinone
- quinone
- phenol


Key Terms -


Summary -

In previous chapters, we focused on developing general ideas of organic reactivity, looking at the chemistry of hydrocarbons and alkyl halides and seeing some of the tools used in structural studies. With that accomplished, we have now begun to study the oxygen-containing functional groups that lie at the heart of organic and biological chemistry.


Summary -

Alcohols are among the most versatile of all organic compounds. They occur widely in nature, are important industrially, and have an unusually rich chemistry. The most widely used methods of alcohol synthesis start with carbonyl compounds. Aldehydes, esters, and carboxylic acids are reduced by reaction with $\mathrm{LiAlH}_{4}$ to give primary alcohols $\left(\mathrm{RCH}_{2} \mathrm{OH}\right)$; ketones are reduced to yield secondary alcohols ( $\mathrm{R}_{2} \mathrm{CHOH}$ ).


Summary -

Alcohols are also prepared by reaction of carbonyl compounds with Grignard reagents, RMgX. Addition of a Grignard reagent to formaldehyde yields a primary alcohol, addition to an aldehyde yields a secondary alcohol, and addition to a ketone or an ester yields a tertiary alcohol. The Grignard reaction is limited by the fact that Grignard reagents can't be prepared from alkyl halides that contain reactive functional groups in the same molecule. This problem can sometimes be avoided by protecting the interfering functional group. Alcohols are often protected by formation of trialkylsilyl ethers.


Summary -

Alcohols undergo many reactions and can be converted into many other functional groups. They can be dehydrated to give alkenes by treatment with $\mathrm{POCl}_{3}$ and can be transformed into alkyl halides by treatment with $\mathrm{PBr}_{3}$ or $\mathrm{SOCl}_{2}$. Furthermore, alcohols are weakly acidic ( $\mathrm{p} K_{\mathrm{a}} \approx 16-18$ ) and react with strong bases and with alkali metals to form alkoxide anions, which are used frequently in organic synthesis. Perhaps the most important reaction of alcohols is their oxidation to carbonyl compounds. Primary alcohols yield either aldehydes or carboxylic acids, secondary alcohols yield ketones, but tertiary alcohols are not normally oxidized.


Summary -

Phenols are aromatic counterparts of alcohols but are more acidic ( $\mathrm{p} K_{\mathrm{a}} \approx 10$ ) because their corresponding phenoxide anions are resonance stabilized by delocalization of the negative charge into the aromatic ring. Substitution of the aromatic ring by an electron-withdrawing group increases phenol acidity, and substitution by an electron-donating group decreases acidity. Phenols can be oxidized to quinones, and quinones can be reduced back to hydroquinones.


Summary of Reactions -

1. Synthesis of alcohols
a. Reduction of carbonyl compounds (Section 17.4)
(1) Aldehydes
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0592.jpg?height=112&width=576&top_left_y=2226&top_left_x=807)


Summary of Reactions -

Primary alcohol
(2) Ketones
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=128&width=597&top_left_y=191&top_left_x=786)


Secondary alcohol -

(3) Esters
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=129&width=665&top_left_y=456&top_left_x=779)


Secondary alcohol -

Primary alcohol
(4) Carboxylic acids
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=129&width=497&top_left_y=727&top_left_x=847)


Secondary alcohol -

Primary alcohol
b. Grignard addition to carbonyl compounds (Section 17.5)
(1) Formaldehyde
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=125&width=567&top_left_y=1038&top_left_x=817)


Secondary alcohol -

Primary alcohol
(2) Aldehydes
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=126&width=557&top_left_y=1303&top_left_x=806)

Secondary alcohol
(3) Ketones
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=131&width=562&top_left_y=1566&top_left_x=819)

Tertiary alcohol
(4) Esters
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=128&width=752&top_left_y=1839&top_left_x=735)


Secondary alcohol -

Tertiary alcohol
2. Reactions of alcohols
a. Dehydration (Section 17.6)
(1) Tertiary alcohols
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0593.jpg?height=150&width=451&top_left_y=2213&top_left_x=891)
(2) Secondary and tertiary alcohols
b. Oxidation (Section 17.7)
(1) Primary alcohols
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0594.jpg?height=137&width=494&top_left_y=189&top_left_x=864)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0594.jpg?height=199&width=554&top_left_y=432&top_left_x=818)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0594.jpg?height=123&width=554&top_left_y=622&top_left_x=821)


Secondary alcohol -

Carboxylic acid
(2) Secondary alcohols
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0594.jpg?height=139&width=510&top_left_y=874&top_left_x=859)


Secondary alcohol -

Ketone
3. Oxidation of phenols to quinones (Section 17.10)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0594.jpg?height=259&width=450&top_left_y=1128&top_left_x=870)


Additional Problems -


Visualizing Chemistry -

PROBLEM Give IUPAC names for the following compounds:


17-20 (a) -


17-20 (a) -

PROBLEM Draw the structure of the carbonyl compound(s) from which each of the following alcohols might
17-21 have been prepared, and show the products you would obtain by treatment of each alcohol with (1) Na metal, (2) $\mathrm{SOCl}_{2}$, and (3) Dess-Martin periodinane.
(a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=312&width=494&top_left_y=210&top_left_x=488)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=294&width=502&top_left_y=216&top_left_x=1061)


17-20 (a) -

PROBLEM Predict the product from reaction of the following substance (reddish brown $=\mathrm{Br}$ ) with:


17-22 -

![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=329&width=554&top_left_y=622&top_left_x=428)
(a) $\mathrm{PBr}_{3}$
(b) Aqueous $\mathrm{H}_{2} \mathrm{SO}_{4}$
(c) $\mathrm{SOCl}_{2}$
(d) Dess-Martin periodinane (e) $\mathrm{Br}_{2}, \mathrm{FeBr}_{3}$


17-22 -

PROBLEM Predict the product from reaction of the following substance with:
17-23
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=340&width=572&top_left_y=1112&top_left_x=443)
(a) $\mathrm{NaBH}_{4}$; then $\mathrm{H}_{3} \mathrm{O}^{+}$(b) $\mathrm{LiAlH}_{4}$; then $\mathrm{H}_{3} \mathrm{O}^{+}$(c) $2 \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{MgBr}$; then $\mathrm{H}_{3} \mathrm{O}^{+}$


17-22 -

PROBLEM Name and assign $R$ or $S$ stereochemistry to the product(s) you would obtain by reaction of the
17-24 following substance with ethylmagnesium bromide. Is the product chiral? Is it optically active? Explain.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=307&width=456&top_left_y=1733&top_left_x=493)


Mechanism Problems -

PROBLEM Evidence for the intermediate carbocations in the acid-catalyzed dehydration of alcohols comes
17-25 from the observation that rearrangements sometimes occur. Propose a mechanism to account for the formation of 2,3-dimethyl-2-butene from 3,3-dimethyl-2-butanol.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0595.jpg?height=185&width=776&top_left_y=2328&top_left_x=414)


Mechanism Problems -


Isopropylidenecyclopentane -

PROBLEM Epoxides react with Grignard reagents to yield alcohols. Propose a mechanism.
17-27
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=218&width=600&top_left_y=533&top_left_x=410)


Isopropylidenecyclopentane -

PROBLEM Treatment of the following epoxide with aqueous acid produces a carbocation intermediate that
$\mathbf{1 7 - 2 8}$ reacts with water to give a diol product. Show the structure of the carbocation, and propose a mechanism for the second step.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=251&width=1242&top_left_y=918&top_left_x=409)


Isopropylidenecyclopentane -

PROBLEM Reduction of 2-butanone with $\mathrm{NaBH}_{4}$ yields 2-butanol. Is the product chiral? Is it optically active?
17-29 Explain.
PROBLEM The conversion of $3^{\circ}$ alcohols into $3^{\circ}$ alkyl halides under acidic conditions involves two cationic
17-30 intermediates. For each reaction, draw the complete mechanism using curved arrows.
(a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=199&width=467&top_left_y=1405&top_left_x=479)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=115&width=551&top_left_y=1409&top_left_x=1009)
(c)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=175&width=649&top_left_y=1620&top_left_x=478)


Isopropylidenecyclopentane -

PROBLEM Identify the type of substitution mechanism $\left(\mathrm{S}_{\mathrm{N}} 1, \mathrm{~S}_{\mathrm{N}} 2\right)$ involved in the conversion of the following
17-31 alcohols into the corresponding alkyl halide.
(a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=112&width=220&top_left_y=1917&top_left_x=481)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=84&width=165&top_left_y=1923&top_left_x=698)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=118&width=191&top_left_y=1914&top_left_x=883)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=112&width=543&top_left_y=1917&top_left_x=1130)
(c)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=104&width=646&top_left_y=2049&top_left_x=482)


Isopropylidenecyclopentane -

PROBLEM The conversion of $3^{\circ}$ alcohols into alkenes under acidic conditions involves two cationic 17-32 intermediates. For each reaction, draw the complete mechanism using curved arrows.
(a)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=196&width=454&top_left_y=2279&top_left_x=478)
(b)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0596.jpg?height=107&width=364&top_left_y=2283&top_left_x=997)
<img class="imgSvg" id = "m6sn3oevj4vd95xvk6" 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CAgICAgIGZvbnQ6IDVweCBEcm9pZCBTYW5zLCBzYW5zLXNlcmlmOwogICAgICAgICAgICAiPjwvdGV4dD48dGV4dCB4PSI2OS4yNzk3Njg0MTAyNjI0OCIgeT0iNjguMjUwMDE4MzY0ODkwMDIiIGNsYXNzPSJkZWJ1ZyIgZmlsbD0iI2ZmMDAwMCIgc3R5bGU9IgogICAgICAgICAgICAgICAgZm9udDogNXB4IERyb2lkIFNhbnMsIHNhbnMtc2VyaWY7CiAgICAgICAgICAgICI+PC90ZXh0PjwvZz48L3N2Zz4="/>
(c)
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0597.jpg?height=194&width=668&top_left_y=212&top_left_x=482)