Acyl Phosphates, $\mathrm{RCO}_{2} \mathrm{PO}_{3}{ }^{2-}$ and $\mathrm{RCO}_{2} \mathrm{PO}_{3} \mathrm{R}^{r}$ -

Acyl phosphates are named by citing the acyl group and adding the word phosphate. If an alkyl group is attached to one of the phosphate oxygens, it is identified after the name of the acyl group. In biological chemistry, acyl
adenosyl phosphates are particularly common.
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Benzoyl phosphate
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Acetyl adenosyl phosphate


A summary of nomenclature rules for carboxylic acid derivatives is given in TABLE 21.1.
TABLE 21.1 Nomenclature of Carboxylic Acid Derivatives


| Functional group | Structure | Name ending |
| :---: | :---: | :---: |
| Carboxylic acid | <smiles>[R]C(=O)O</smiles> | -ic acid
 (-carboxylic acid) |
| Acid halide | <smiles>[R]C([X])=O</smiles> | -oyl halide
 (-carbonyl halide) |
| Acid anhydride | <smiles>[R]C(=O)OC([R])[R]</smiles> | anhydride |
| Amide | <smiles>R16N</smiles> | -amide
 (-carboxamide) |
| Ester | <smiles>[R]OC([R])=O</smiles> | -oate
 (-carboxylate) |
| Thioester | <smiles>[R]C(=O)[Sn]</smiles> | -thioate
 (-carbothioate) |
| Acyl phosphate | <smiles></smiles> | -oyl phosphate |


PROBLEM Give IUPAC names for the following substances:


PROBLEM Draw structures corresponding to the following names:
21-2 (a) Phenyl benzoate (b) $N$-Ethyl- $N$-methylbutanamide (c) 2,4-Dimethylpentanoyl chloride
(d) Methyl 1-methylcyclohexanecarboxylate (e) Ethyl 3-oxopentanoate
(f) Methyl $p$-bromobenzenethioate (g) Formic propanoic anhydride
(h) cis-2-Methylcyclopentanecarbonyl bromide


Acyl Phosphates, $\mathrm{RCO}_{2} \mathrm{PO}_{3}{ }^{2-}$ and $\mathrm{RCO}_{2} \mathrm{PO}_{3} \mathrm{R}^{r}$ - 21.2 Nucleophilic Acyl Substitution Reactions

The addition of a nucleophile to a polar $\mathrm{C}=\mathrm{O}$ bond is the key step in three of the four major carbonyl-group reactions. We saw in the chapter on Aldehydes and Ketones: Nucleophilic Addition Reactions that when a nucleophile adds to an aldehyde or ketone, the initially formed tetrahedral intermediate can be protonated to yield an alcohol. When a nucleophile adds to a carboxylic acid derivative, however, a different reaction path is taken. The initially formed tetrahedral intermediate eliminates one of the two substituents originally bonded to the carbonyl carbon, leading to a net nucleophilic acyl substitution reaction (FIGURE 21.2).
(a) Aldehyde or ketone: nucleophilic addition
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0735.jpg?height=283&width=795&top_left_y=1290&top_left_x=622)
(b) Carboxylic acid derivative: nucleophilic acyl substitution
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0735.jpg?height=291&width=914&top_left_y=1681&top_left_x=619)

FIGURE 21.2 The general mechanisms of nucleophilic addition and nucleophilic acyl substitution reactions. Both reactions begin with addition of a nucleophile to a polar $\mathrm{C}=\mathrm{O}$ bond to give a tetrahedral, alkoxide ion intermediate. (a) The intermediate formed from an aldehyde or ketone is protonated to give an alcohol, but (b) the intermediate formed from a carboxylic acid derivative expels a leaving group to give a new carbonyl compound.


The difference in behavior between aldehydes/ketones and carboxylic acid derivatives is a consequence of structure. Carboxylic acid derivatives have an acyl carbon bonded to a group -Y that can act as a leaving group, often as a stable anion. As soon as the tetrahedral intermediate is formed, the leaving group is expelled to generate a new carbonyl compound. Aldehydes and ketones, however, have no such leaving group, however, and therefore don't undergo substitution.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0736.jpg?height=191&width=369&top_left_y=200&top_left_x=607)


A carboxylic acid derivative
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0736.jpg?height=199&width=514&top_left_y=193&top_left_x=1044)


An aldehyde


A ketone


The net effect of the addition/elimination sequence is a substitution of the nucleophile for the -Y group that was originally bonded to the acyl carbon. Thus, the overall reaction is superficially similar to the kind of nucleophilic substitution that occurs during an $\mathrm{S}_{\mathrm{N}} 2$ reaction (Section 11.3), but the mechanisms of the two reactions are completely different. An $\mathrm{S}_{\mathrm{N}} 2$ reaction occurs in a single step by backside displacement of the leaving group, while a nucleophilic acyl substitution takes place in two steps and involves a tetrahedral intermediate.


PROBLEM Show the mechanism of the following nucleophilic acyl substitution reaction, using curved arrows
21-3 to indicate the electron flow in each step:
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0736.jpg?height=196&width=725&top_left_y=845&top_left_x=413)


Relative Reactivity of Carboxylic Acid Derivatives -

Both the initial addition step and the subsequent elimination step can affect the overall rate of a nucleophilic acyl substitution reaction, but the addition is usually the rate-limiting step. Thus, any factor that makes the carbonyl group more reactive toward nucleophiles favors the substitution process.


Steric and electronic factors are both important in determining reactivity. Sterically, we find within a series of similar acid derivatives that unhindered, accessible carbonyl groups react with nucleophiles more readily than do sterically hindered carbonyl groups. The reactivity order is
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0736.jpg?height=180&width=915&top_left_y=1431&top_left_x=602)