CHAPTER 1 <br> Structure and Bonding -


CHAPTER 1 <br> Structure and Bonding -

FIGURE 1.1 The enzyme HMG-CoA reductase, shown here as a so-called ribbon model, catalyzes a crucial step in the body's synthesis of cholesterol. Understanding how this enzyme functions has led to the development of drugs credited with saving millions of lives. (credit: image from the RCSB PDB (rcsb.org) of PBD ID 1HW9 (E.S. Istvan, J. Deisenhofer) (2001) Structural mechanism for statin inhibition of HMGCoA reductase Science 292: 1160-1164/RCSB PDB, CC BY 1.0)


CHAPTER CONTENTS -

1.1 Atomic Structure: The Nucleus
1.2 Atomic Structure: Orbitals
1.3 Atomic Structure: Electron Configurations
1.4 Development of Chemical Bonding Theory
1.5 Describing Chemical Bonds: Valence Bond Theory
$1.6 s p^{3}$ Hybrid Orbitals and the Structure of Methane
$1.7 s p^{3}$ Hybrid Orbitals and the Structure of Ethane
$1.8 s p^{2}$ Hybrid Orbitals and the Structure of Ethylene
1.9 sp Hybrid Orbitals and the Structure of Acetylene
1.10 Hybridization of Nitrogen, Oxygen, Phosphorus, and Sulfur
1.11 Describing Chemical Bonds: Molecular Orbital Theory
1.12 Drawing Chemical Structures


CHAPTER CONTENTS -

WHY THIS CHAPTER? We'll ease into the study of organic chemistry by first reviewing some ideas about atoms, bonds, and molecular geometry that you may recall from your general chemistry course. Much of the material in this chapter and the next is likely to be familiar to you, but it's nevertheless a good idea to make sure you understand it before moving on.


CHAPTER CONTENTS -

What is organic chemistry, and why should you study it? The answers to these questions are all around you.


CHAPTER CONTENTS -

Every living organism is made of organic chemicals. The proteins that make up your hair, skin, and muscles; the DNA that controls your genetic heritage; the foods that nourish you; and the medicines that heal you are all organic chemicals. Anyone with a curiosity about life and living things, and anyone who wants to be a part of the remarkable advances taking place in medicine and the biological sciences, must first understand organic chemistry. Look at the following drawings for instance, which show the chemical structures of some molecules whose names might be familiar to you. Although the drawings may appear unintelligible at this point, don't worry. They'll make perfectly good sense before long, and you'll soon be drawing similar structures for any substance you're interested in.
<img class="imgSvg" id = "m6sn3lscfoq2qq8xzw5" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3lscfoq2qq8xzw5" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 306 227.5673563305506" style="width: 305.65203155137476px; height: 227.5673563305506px; overflow: visible;"><defs><linearGradient id="line-m6sn3lscfoq2qq8xzw5-1" gradientUnits="userSpaceOnUse" x1="245.14511657143777" y1="179.57264055706784" x2="263.65203155137476" y2="154.08256213574114"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-3" gradientUnits="userSpaceOnUse" x1="213.81660362414283" y1="176.29022124942688" x2="245.14511657143777" y2="179.57264055706784"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-5" gradientUnits="userSpaceOnUse" x1="190.4599220232098" y1="200.78562443226585" x2="207.35443447015416" y2="175.7318577251555"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-7" gradientUnits="userSpaceOnUse" x1="193.39981594244512" y1="206.5673563305506" x2="213.81660362414283" y2="176.29022124942688"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-9" gradientUnits="userSpaceOnUse" x1="200.45388193120607" y1="142.47386571566082" x2="213.81660362414283" y2="176.29022124942688"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-11" gradientUnits="userSpaceOnUse" x1="156.75787946546848" y1="203.74559600204267" x2="193.39981594244512" y2="206.5673563305506"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-13" gradientUnits="userSpaceOnUse" x1="165.05400826702822" y1="146.78616509326412" x2="197.08823689295406" y2="148.01857792428711"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-15" gradientUnits="userSpaceOnUse" x1="162.12431037425222" y1="140.99926002604" x2="200.45388193120607" y2="142.47386571566082"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-17" gradientUnits="userSpaceOnUse" x1="200.45388193120607" y1="142.47386571566082" x2="221.91561053323665" y2="111.36317498335262"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-19" gradientUnits="userSpaceOnUse" x1="146.91219849526288" y1="171.84914726198392" x2="160.38604957893813" y2="198.36900027354253"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-21" gradientUnits="userSpaceOnUse" x1="140.430395269609" y1="171.6090911354154" x2="156.75787946546848" y2="203.74559600204267"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-23" gradientUnits="userSpaceOnUse" x1="140.430395269609" y1="171.6090911354154" x2="162.12431037425222" y2="140.99926002604"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-25" gradientUnits="userSpaceOnUse" x1="145.01743614763114" y1="107.1922321921734" x2="162.12431037425222" y2="140.99926002604"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-27" gradientUnits="userSpaceOnUse" x1="207.20903730826421" y1="77.09265488280354" x2="221.91561053323665" y2="111.36317498335262"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-29" gradientUnits="userSpaceOnUse" x1="106.2521541169594" y1="159.00867686498032" x2="140.430395269609" y2="171.6090911354154"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-31" gradientUnits="userSpaceOnUse" x1="145.01743614763114" y1="107.1922321921734" x2="174.13505568629563" y2="86.4330553095295"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-33" gradientUnits="userSpaceOnUse" x1="121.41149511949935" y1="84.46965117467317" x2="145.01743614763114" y2="107.1922321921734"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-35" gradientUnits="userSpaceOnUse" x1="106.78292775761527" y1="100.94325713106801" x2="145.01743614763114" y2="107.1922321921734"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-37" gradientUnits="userSpaceOnUse" x1="207.20903730826421" y1="77.09265488280354" x2="237.40119086706017" y2="68.1102351930937"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-39" gradientUnits="userSpaceOnUse" x1="198.37089361795336" y1="41.57561498125361" x2="207.20903730826421" y2="77.09265488280354"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-41" gradientUnits="userSpaceOnUse" x1="174.13505568629563" y1="86.4330553095295" x2="207.20903730826421" y2="77.09265488280354"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-43" gradientUnits="userSpaceOnUse" x1="97.4739327278456" y1="122.5340527902876" x2="106.2521541169594" y2="159.00867686498032"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-45" gradientUnits="userSpaceOnUse" x1="97.4739327278456" y1="122.5340527902876" x2="121.41149511949935" y2="84.46965117467317"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-47" gradientUnits="userSpaceOnUse" x1="111.05941668887958" y1="54.7192818968592" x2="121.41149511949935" y2="84.46965117467317"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-49" gradientUnits="userSpaceOnUse" x1="121.41149511949935" y1="84.46965117467317" x2="130.10417303556113" y2="47.711130232401274"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-51" gradientUnits="userSpaceOnUse" x1="73.12505053267786" y1="107.22322658001741" x2="106.78292775761527" y2="100.94325713106801"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-53" gradientUnits="userSpaceOnUse" x1="162.7973227942511" y1="29.1220238092163" x2="198.37089361795336" y2="41.57561498125361"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-55" gradientUnits="userSpaceOnUse" x1="200.2226989662662" y1="43.72225001123891" x2="224.07419929943626" y2="23.146635029985305"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-57" gradientUnits="userSpaceOnUse" x1="196.51908826964052" y1="39.4289799512683" x2="220.37058860281059" y2="18.853364970014695"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-59" gradientUnits="userSpaceOnUse" x1="73.12505053267786" y1="107.22322658001741" x2="97.4739327278456" y2="122.5340527902876"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-61" gradientUnits="userSpaceOnUse" x1="83.49826095936312" y1="150.76401202900493" x2="97.4739327278456" y2="122.5340527902876"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-63" gradientUnits="userSpaceOnUse" x1="130.10417303556113" y1="47.711130232401274" x2="162.7973227942511" y2="29.1220238092163"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3lscfoq2qq8xzw5-65" gradientUnits="userSpaceOnUse" x1="42" y1="102.37748315529404" x2="73.12505053267786" y2="107.22322658001741"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3lscfoq2qq8xzw5"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="245.14511657143777" cy="179.57264055706784" r="7.875" fill="black"></circle><circle cx="221.91561053323665" cy="111.36317498335262" r="7.875" fill="black"></circle><circle cx="237.40119086706017" cy="68.1102351930937" r="7.875" fill="black"></circle><circle cx="73.12505053267786" cy="107.22322658001741" r="7.875" fill="black"></circle><circle cx="83.49826095936312" cy="150.76401202900493" r="7.875" fill="black"></circle><circle cx="111.05941668887958" cy="54.7192818968592" r="7.875" fill="black"></circle><circle cx="222.22239395112342" cy="21" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3lscfoq2qq8xzw5 {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3lscfoq2qq8xzw5 {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3lscfoq2qq8xzw5)"><line x1="245.14511657143777" y1="179.57264055706784" x2="263.65203155137476" y2="154.08256213574114" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-1')"></line><line x1="213.81660362414283" y1="176.29022124942688" x2="245.14511657143777" y2="179.57264055706784" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-3')"></line><line x1="190.4599220232098" y1="200.78562443226585" x2="207.35443447015416" y2="175.7318577251555" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-5')"></line><line x1="193.39981594244512" y1="206.5673563305506" x2="213.81660362414283" y2="176.29022124942688" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-7')"></line><line x1="200.45388193120607" y1="142.47386571566082" x2="213.81660362414283" y2="176.29022124942688" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-9')"></line><line x1="156.75787946546848" y1="203.74559600204267" x2="193.39981594244512" y2="206.5673563305506" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-11')"></line><line x1="165.05400826702822" y1="146.78616509326412" x2="197.08823689295406" y2="148.01857792428711" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-13')"></line><line x1="162.12431037425222" y1="140.99926002604" x2="200.45388193120607" y2="142.47386571566082" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-15')"></line><line x1="200.45388193120607" y1="142.47386571566082" x2="221.91561053323665" y2="111.36317498335262" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-17')"></line><line x1="146.91219849526288" y1="171.84914726198392" x2="160.38604957893813" y2="198.36900027354253" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-19')"></line><line x1="140.430395269609" y1="171.6090911354154" x2="156.75787946546848" y2="203.74559600204267" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-21')"></line><line x1="140.430395269609" y1="171.6090911354154" x2="162.12431037425222" y2="140.99926002604" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-23')"></line><line x1="145.01743614763114" y1="107.1922321921734" x2="162.12431037425222" y2="140.99926002604" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-25')"></line><line x1="207.20903730826421" y1="77.09265488280354" x2="221.91561053323665" y2="111.36317498335262" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-27')"></line><line x1="106.2521541169594" y1="159.00867686498032" x2="140.430395269609" y2="171.6090911354154" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-29')"></line><line x1="145.01743614763114" y1="107.1922321921734" x2="174.13505568629563" y2="86.4330553095295" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-31')"></line><line x1="121.41149511949935" y1="84.46965117467317" x2="145.01743614763114" y2="107.1922321921734" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-33')"></line><line x1="145.01743614763114" y1="107.1922321921734" x2="145.01743614763114" y2="107.1922321921734" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="140.32479831764886" y1="106.61064561746107" x2="140.38381464724955" y2="106.24955274587776" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="135.6321604876665" y1="106.02905904274874" x2="135.75019314686796" y2="105.30687329958212" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="130.93952265768417" y1="105.44747246803641" x2="131.11657164648636" y2="104.36419385328648" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="126.2468848277018" y1="104.86588589332408" x2="126.48295014610473" y2="103.42151440699084" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="121.55424699771949" y1="104.28429931861172" x2="121.84932864572313" y2="102.47883496069517" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="116.86160916773717" y1="103.70271274389938" x2="117.21570714534154" y2="101.53615551439952" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="112.1689713377548" y1="103.12112616918705" x2="112.58208564495992" y2="100.59347606810388" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><line x1="107.47633350777248" y1="102.53953959447475" x2="107.94846414457832" y2="99.65079662180824" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-35')"></line><polygon points="207.3886857020584,77.69649795397946 238.00857353179293,70.15179986230751 236.7938082023274,66.06867052387989 207.02938891447002,76.48881181162763" fill="url('#line-m6sn3lscfoq2qq8xzw5-37')"></polygon><line x1="198.37089361795336" y1="41.57561498125361" x2="207.20903730826421" y2="77.09265488280354" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-39')"></line><line x1="174.13505568629563" y1="86.4330553095295" x2="207.20903730826421" y2="77.09265488280354" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-41')"></line><line x1="97.4739327278456" y1="122.5340527902876" x2="106.2521541169594" y2="159.00867686498032" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-43')"></line><line x1="97.4739327278456" y1="122.5340527902876" x2="121.41149511949935" y2="84.46965117467317" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-45')"></line><polygon points="120.81648773394306,84.67669274328557 109.04772505199882,55.41927958121539 113.07110832576033,54.01928421250301 122.00650250505564,84.26260960606078" fill="url('#line-m6sn3lscfoq2qq8xzw5-47')"></polygon><line x1="121.41149511949935" y1="84.46965117467317" x2="130.10417303556113" y2="47.711130232401274" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-49')"></line><line x1="73.12505053267786" y1="107.22322658001741" x2="106.78292775761527" y2="100.94325713106801" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-51')"></line><line x1="162.7973227942511" y1="29.1220238092163" x2="198.37089361795336" y2="41.57561498125361" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-53')"></line><line x1="200.2226989662662" y1="43.72225001123891" x2="224.07419929943626" y2="23.146635029985305" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-55')"></line><line x1="196.51908826964052" y1="39.4289799512683" x2="220.37058860281059" y2="18.853364970014695" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-57')"></line><line x1="73.12505053267786" y1="107.22322658001741" x2="97.4739327278456" y2="122.5340527902876" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-59')"></line><line x1="97.4739327278456" y1="122.5340527902876" x2="97.4739327278456" y2="122.5340527902876" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="95.17593939658236" y1="126.66872044917747" x2="95.57922452856404" y2="126.86837290301293" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="92.87794606531916" y1="130.80338810806734" x2="93.68451632928252" y2="131.20269301573828" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="90.57995273405596" y1="134.9380557669572" x2="91.78980813000099" y2="135.5370131284636" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="88.28195940279276" y1="139.07272342584707" x2="89.89509993071947" y2="139.87133324118892" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="85.98396607152954" y1="143.20739108473694" x2="88.00039173143792" y2="144.20565335391427" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="83.68597274026634" y1="147.3420587436268" x2="86.10568353215639" y2="148.5399734666396" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-61')"></line><line x1="130.10417303556113" y1="47.711130232401274" x2="162.7973227942511" y2="29.1220238092163" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-63')"></line><line x1="42" y1="102.37748315529404" x2="73.12505053267786" y2="107.22322658001741" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3lscfoq2qq8xzw5-65')"></line></g><g><text x="263.65203155137476" y="154.08256213574114" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="245.14511657143777" y="171.69764055706784" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: vertical-rl;
                text-orientation: upright;
                letter-spacing: -1px;
                direction: ltr;
            "><tspan>O</tspan></text><text x="245.14511657143777" y="179.57264055706784" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="213.81660362414283" y="176.29022124942688" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="193.39981594244512" y="206.5673563305506" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="156.75787946546848" y="203.74559600204267" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="140.430395269609" y="171.6090911354154" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="162.12431037425222" y="140.99926002604" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="200.45388193120607" y="142.47386571566082" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="217.97811053323665" y="116.61317498335262" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="221.91561053323665" y="111.36317498335262" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="207.20903730826421" y="77.09265488280354" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">R</text><text x="233.46369086706017" y="73.3602351930937" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="237.40119086706017" y="68.1102351930937" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="174.13505568629563" y="86.4330553095295" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="145.01743614763114" y="107.1922321921734" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="106.78292775761527" y="100.94325713106801" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="78.37505053267786" y="112.47322658001741" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>N</tspan></text><text x="73.12505053267786" y="107.22322658001741" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="42" y="102.37748315529404" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="97.4739327278456" y="122.5340527902876" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">R</text><text x="78.24826095936312" y="156.01401202900493" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="83.49826095936312" y="150.76401202900493" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="106.2521541169594" y="159.00867686498032" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="121.41149511949935" y="84.46965117467317" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="105.80941668887958" y="59.9692818968592" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="111.05941668887958" y="54.7192818968592" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="130.10417303556113" y="47.711130232401274" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="162.7973227942511" y="29.1220238092163" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="198.37089361795336" y="41.57561498125361" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="218.28489395112342" y="26.25" class="element-m6sn3lscfoq2qq8xzw5" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan></text><text x="222.22239395112342" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>

Oxycodone (OxyContin)
<img class="imgSvg" id = "m6sn3ltthswhn66v8zq" src="data:image/svg+xml;base64,<svg id="smiles-m6sn3ltthswhn66v8zq" xmlns="http://www.w3.org/2000/svg" viewBox="0 0 452 185.06185453059953" style="width: 451.7568281761079px; height: 185.06185453059953px; overflow: visible;"><defs><linearGradient id="line-m6sn3ltthswhn66v8zq-1" gradientUnits="userSpaceOnUse" x1="384.2728423484101" y1="121.32819595870967" x2="409.7568281761079" y2="102.81289238750966"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-3" gradientUnits="userSpaceOnUse" x1="384.2728423484101" y1="121.32819595870967" x2="387.56541925652283" y2="152.65564298690146"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-5" gradientUnits="userSpaceOnUse" x1="355.4961575575884" y1="108.51599815935869" x2="384.2728423484101" y2="121.32819595870967"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-7" gradientUnits="userSpaceOnUse" x1="330.01217172989055" y1="127.03130173055871" x2="355.4961575575884" y2="108.51599815935869"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-9" gradientUnits="userSpaceOnUse" x1="301.2354869390689" y1="114.21910393120774" x2="330.01217172989055" y2="127.03130173055871"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-11" gradientUnits="userSpaceOnUse" x1="275.751501111371" y1="132.73440750240775" x2="301.2354869390689" y2="114.21910393120774"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-13" gradientUnits="userSpaceOnUse" x1="275.751501111371" y1="132.73440750240775" x2="279.04407801948383" y2="164.06185453059953"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-15" gradientUnits="userSpaceOnUse" x1="246.9748163205494" y1="119.92220970305678" x2="275.751501111371" y2="132.73440750240775"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-17" gradientUnits="userSpaceOnUse" x1="237.24078772042787" y1="149.88049215068747" x2="246.9748163205494" y2="119.92220970305678"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-19" gradientUnits="userSpaceOnUse" x1="216.16316542777952" y1="113.37299835648406" x2="246.9748163205494" y2="119.92220970305678"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-21" gradientUnits="userSpaceOnUse" x1="246.9748163205494" y1="119.92220970305678" x2="262.7248101989154" y2="92.64240594952084"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-23" gradientUnits="userSpaceOnUse" x1="190.6791342598197" y1="131.8882395223574" x2="216.16316542777952" y2="113.37299835648406"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-25" gradientUnits="userSpaceOnUse" x1="212.87051180491778" y1="82.04555939125973" x2="216.16316542777952" y2="113.37299835648406"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-27" gradientUnits="userSpaceOnUse" x1="216.16316542777952" y1="113.37299835648406" x2="219.45581905064137" y2="144.70043732170842"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-29" gradientUnits="userSpaceOnUse" x1="241.64719084557856" y1="69.23334867683597" x2="262.7248101989154" y2="92.64240594952084"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-31" gradientUnits="userSpaceOnUse" x1="161.90244946899804" y1="119.0760417230064" x2="190.6791342598197" y2="131.8882395223574"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-33" gradientUnits="userSpaceOnUse" x1="212.87051180491778" y1="82.04555939125973" x2="241.64719084557856" y2="69.23334867683597"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-35" gradientUnits="userSpaceOnUse" x1="212.87051180491778" y1="82.04555939125973" x2="220.49104465762275" y2="51.48124230350453"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-37" gradientUnits="userSpaceOnUse" x1="184.09382701409612" y1="69.23336159190873" x2="212.87051180491778" y2="82.04555939125973"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-39" gradientUnits="userSpaceOnUse" x1="158.60979584613625" y1="87.74860275778208" x2="161.90244946899804" y2="119.0760417230064"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-41" gradientUnits="userSpaceOnUse" x1="184.09382701409612" y1="69.23336159190873" x2="201.70839761324476" y2="43.118674103684626"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-43" gradientUnits="userSpaceOnUse" x1="158.60979584613625" y1="87.74860275778208" x2="184.09382701409612" y2="69.23336159190873"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-45" gradientUnits="userSpaceOnUse" x1="180.80117339123427" y1="37.90592262668439" x2="184.09382701409612" y2="69.23336159190873"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-47" gradientUnits="userSpaceOnUse" x1="129.83311105531465" y1="74.93640495843113" x2="158.60979584613625" y2="87.74860275778208"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-49" gradientUnits="userSpaceOnUse" x1="140.99522524698762" y1="113.86329024600619" x2="158.60979584613625" y2="87.74860275778208"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-51" gradientUnits="userSpaceOnUse" x1="152.0244886004126" y1="25.093724827333432" x2="180.80117339123427" y2="37.90592262668439"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-53" gradientUnits="userSpaceOnUse" x1="104.34907988735478" y1="93.45164612430449" x2="129.83311105531465" y2="74.93640495843113"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-55" gradientUnits="userSpaceOnUse" x1="126.5404574324528" y1="43.60896599320682" x2="129.83311105531465" y2="74.93640495843113"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-57" gradientUnits="userSpaceOnUse" x1="122.2125782026097" y1="105.50072204618631" x2="129.83311105531465" y2="74.93640495843113"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-59" gradientUnits="userSpaceOnUse" x1="132.421603959106" y1="46.34456748685224" x2="152.80882889347384" y2="31.532374554153535"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-61" gradientUnits="userSpaceOnUse" x1="126.5404574324528" y1="43.60896599320682" x2="152.0244886004126" y2="25.093724827333432"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-63" gradientUnits="userSpaceOnUse" x1="75.57239509653311" y1="80.63944832495355" x2="104.34907988735478" y2="93.45164612430449"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-65" gradientUnits="userSpaceOnUse" x1="97.76377264163112" y1="30.796768193855854" x2="126.5404574324528" y2="43.60896599320682"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-67" gradientUnits="userSpaceOnUse" x1="72.2797414736713" y1="49.31200935972922" x2="75.57239509653311" y2="80.63944832495355"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-69" gradientUnits="userSpaceOnUse" x1="72.2797414736713" y1="49.31200935972922" x2="97.76377264163112" y2="30.796768193855854"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-71" gradientUnits="userSpaceOnUse" x1="42.000000000000014" y1="57.994592862790455" x2="72.2797414736713" y2="49.31200935972922"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient><linearGradient id="line-m6sn3ltthswhn66v8zq-73" gradientUnits="userSpaceOnUse" x1="58.47104399655191" y1="21" x2="72.2797414736713" y2="49.31200935972922"><stop stop-color="currentColor" offset="20%"></stop><stop stop-color="currentColor" offset="100%"></stop></linearGradient></defs><mask id="text-mask-m6sn3ltthswhn66v8zq"><rect x="0" y="0" width="100%" height="100%" fill="white"></rect><circle cx="237.24078772042787" cy="149.88049215068747" r="7.875" fill="black"></circle><circle cx="220.49104465762275" cy="51.48124230350453" r="7.875" fill="black"></circle><circle cx="201.70839761324476" cy="43.118674103684626" r="7.875" fill="black"></circle><circle cx="42.000000000000014" cy="57.994592862790455" r="7.875" fill="black"></circle><circle cx="58.47104399655191" cy="21" r="7.875" fill="black"></circle><circle cx="140.99522524698762" cy="113.86329024600619" r="7.875" fill="black"></circle></mask><style>
                .element-m6sn3ltthswhn66v8zq {
                    font: 14px Helvetica, Arial, sans-serif;
                    alignment-baseline: 'middle';
                }
                .sub-m6sn3ltthswhn66v8zq {
                    font: 8.4px Helvetica, Arial, sans-serif;
                }
            </style><g mask="url(#text-mask-m6sn3ltthswhn66v8zq)"><line x1="384.2728423484101" y1="121.32819595870967" x2="409.7568281761079" y2="102.81289238750966" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-1')"></line><line x1="384.2728423484101" y1="121.32819595870967" x2="387.56541925652283" y2="152.65564298690146" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-3')"></line><line x1="355.4961575575884" y1="108.51599815935869" x2="384.2728423484101" y2="121.32819595870967" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-5')"></line><line x1="330.01217172989055" y1="127.03130173055871" x2="355.4961575575884" y2="108.51599815935869" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-7')"></line><line x1="301.2354869390689" y1="114.21910393120774" x2="330.01217172989055" y2="127.03130173055871" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-9')"></line><line x1="275.751501111371" y1="132.73440750240775" x2="301.2354869390689" y2="114.21910393120774" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-11')"></line><line x1="275.751501111371" y1="132.73440750240775" x2="279.04407801948383" y2="164.06185453059953" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-13')"></line><polygon points="246.71857236456236,120.49774339887321 274.885152498272,134.68025952159664 276.61784972447,130.78855548321886 247.23106027653643,119.34667600724035" fill="url('#line-m6sn3ltthswhn66v8zq-15')"></polygon><line x1="237.24078772042787" y1="149.88049215068747" x2="246.9748163205494" y2="119.92220970305678" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-17')"></line><line x1="216.16316542777952" y1="113.37299835648406" x2="246.9748163205494" y2="119.92220970305678" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-19')"></line><line x1="246.9748163205494" y1="119.92220970305678" x2="262.7248101989154" y2="92.64240594952084" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-21')"></line><line x1="190.6791342598197" y1="131.8882395223574" x2="216.16316542777952" y2="113.37299835648406" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-23')"></line><line x1="212.87051180491778" y1="82.04555939125973" x2="216.16316542777952" y2="113.37299835648406" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-25')"></line><line x1="216.16316542777952" y1="113.37299835648406" x2="216.16316542777952" y2="113.37299835648406" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="216.43329605002862" y1="118.09563315571674" x2="216.88083089238899" y2="118.0485952468187" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="216.70342667227771" y1="122.81826795494939" x2="217.59849635699842" y2="122.72419213715334" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="216.97355729452684" y1="127.54090275418206" x2="218.31616182160786" y2="127.39978902748797" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="217.2436879167759" y1="132.26353755341472" x2="219.03382728621733" y2="132.07538591782262" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="217.513818539025" y1="136.98617235264737" x2="219.75149275082674" y2="136.75098280815723" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="217.7839491612741" y1="141.70880715188005" x2="220.4691582154362" y2="141.42657969849188" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-27')"></line><line x1="241.64719084557856" y1="69.23334867683597" x2="262.7248101989154" y2="92.64240594952084" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-29')"></line><line x1="161.90244946899804" y1="119.0760417230064" x2="190.6791342598197" y2="131.8882395223574" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-31')"></line><line x1="212.87051180491778" y1="82.04555939125973" x2="241.64719084557856" y2="69.23334867683597" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-33')"></line><polygon points="213.48179814667287,82.19797004831383 222.55777467022335,51.9965354773541 218.42431464502215,50.96594912965496 212.2592254631627,81.89314873420562" fill="url('#line-m6sn3ltthswhn66v8zq-35')"></polygon><line x1="184.09382701409612" y1="69.23336159190873" x2="212.87051180491778" y2="82.04555939125973" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-37')"></line><line x1="158.60979584613625" y1="87.74860275778208" x2="161.90244946899804" y2="119.0760417230064" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-39')"></line><line x1="184.09382701409612" y1="69.23336159190873" x2="184.09382701409612" y2="69.23336159190873" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="186.54947912190966" y1="65.19034010725262" x2="186.92254608602715" y2="65.4419768300976" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="189.00513122972322" y1="61.14731862259653" x2="189.7512651579582" y2="61.650592068286485" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="191.46078333753678" y1="57.10429713794042" x2="192.57998422988922" y2="57.85920730647537" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="193.91643544535032" y1="53.061275653284326" x2="195.40870330182025" y2="54.06782254466425" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="196.37208755316388" y1="49.01825416862822" x2="198.23742237375131" y2="50.27643778285312" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="198.82773966097744" y1="44.97523268397211" x2="201.06614144568235" y2="46.48505302104199" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-41')"></line><line x1="158.60979584613625" y1="87.74860275778208" x2="184.09382701409612" y2="69.23336159190873" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-43')"></line><line x1="180.80117339123427" y1="37.90592262668439" x2="184.09382701409612" y2="69.23336159190873" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-45')"></line><line x1="129.83311105531465" y1="74.93640495843113" x2="158.60979584613625" y2="87.74860275778208" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-47')"></line><polygon points="159.13208959590074,88.10089416976506 142.7610755438104,115.0543707341391 139.22937495016484,112.67220975787328 158.08750209637176,87.3963113457991" fill="url('#line-m6sn3ltthswhn66v8zq-49')"></polygon><line x1="152.0244886004126" y1="25.093724827333432" x2="180.80117339123427" y2="37.90592262668439" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-51')"></line><line x1="104.34907988735478" y1="93.45164612430449" x2="129.83311105531465" y2="74.93640495843113" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-53')"></line><line x1="126.5404574324528" y1="43.60896599320682" x2="129.83311105531465" y2="74.93640495843113" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-55')"></line><line x1="129.83311105531465" y1="74.93640495843113" x2="129.83311105531465" y2="74.93640495843113" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="128.47171457678206" y1="79.4666201440751" x2="128.9083476780357" y2="79.57548489911373" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="127.11031809824951" y1="83.99683532971905" x2="127.9835843007568" y2="84.21456483979634" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="125.74892161971695" y1="88.52705051536302" x2="127.05882092347788" y2="88.85364478047894" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="124.38752514118438" y1="93.05726570100695" x2="126.13405754619896" y2="93.49272472116152" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="123.02612866265181" y1="97.58748088665092" x2="125.20929416892005" y2="98.13180466184413" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="121.66473218411926" y1="102.11769607229488" x2="124.28453079164113" y2="102.77088460252673" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-57')"></line><line x1="132.421603959106" y1="46.34456748685224" x2="152.80882889347384" y2="31.532374554153535" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-59')"></line><line x1="126.5404574324528" y1="43.60896599320682" x2="152.0244886004126" y2="25.093724827333432" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-61')"></line><line x1="75.57239509653311" y1="80.63944832495355" x2="104.34907988735478" y2="93.45164612430449" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-63')"></line><line x1="97.76377264163112" y1="30.796768193855854" x2="126.5404574324528" y2="43.60896599320682" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-65')"></line><line x1="72.2797414736713" y1="49.31200935972922" x2="75.57239509653311" y2="80.63944832495355" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-67')"></line><line x1="72.2797414736713" y1="49.31200935972922" x2="97.76377264163112" y2="30.796768193855854" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-69')"></line><line x1="42.000000000000014" y1="57.994592862790455" x2="72.2797414736713" y2="49.31200935972922" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-71')"></line><line x1="72.2797414736713" y1="49.31200935972922" x2="72.2797414736713" y2="49.31200935972922" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="70.00620821381962" y1="45.16384150917783" x2="70.41066549038717" y2="44.96657440236184" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="67.7326749539679" y1="41.01567365862644" x2="68.54158950710303" y2="40.621139444994455" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="65.45914169411623" y1="36.86750580807504" x2="66.6725135238189" y2="36.27570448762707" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="63.18560843426454" y1="32.71933795752366" x2="64.80343754053479" y2="31.930269530259693" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="60.912075174412834" y1="28.57117010697226" x2="62.93436155725064" y2="27.584834572892305" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line><line x1="58.63854191456116" y1="24.423002256420858" x2="61.06528557396652" y2="23.239399615524917" style="stroke-linecap:round;stroke-dasharray:none;stroke-width:1.26" stroke="url('#line-m6sn3ltthswhn66v8zq-73')"></line></g><g><text x="409.7568281761079" y="102.81289238750966" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="384.2728423484101" y="121.32819595870967" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="387.56541925652283" y="152.65564298690146" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="355.4961575575884" y="108.51599815935869" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="330.01217172989055" y="127.03130173055871" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="301.2354869390689" y="114.21910393120774" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="275.751501111371" y="132.73440750240775" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="279.04407801948383" y="164.06185453059953" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="246.9748163205494" y="119.92220970305678" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">R</text><text x="231.99078772042787" y="155.13049215068747" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="237.24078772042787" y="149.88049215068747" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="262.7248101989154" y="92.64240594952084" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="241.64719084557856" y="69.23334867683597" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="212.87051180491778" y="82.04555939125973" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="215.24104465762275" y="56.73124230350453" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="220.49104465762275" y="51.48124230350453" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="184.09382701409612" y="69.23336159190873" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="196.45839761324476" y="48.368674103684626" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="201.70839761324476" y="43.118674103684626" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="180.80117339123427" y="37.90592262668439" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="152.0244886004126" y="25.093724827333432" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="126.5404574324528" y="43.60896599320682" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="97.76377264163112" y="30.796768193855854" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="72.2797414736713" y="49.31200935972922" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="47.250000000000014" y="63.244592862790455" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: rtl; unicode-bidi: bidi-override;
            "><tspan>H</tspan></text><text x="42.000000000000014" y="57.994592862790455" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="53.22104399655191" y="26.25" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>O</tspan><tspan style="unicode-bidi: plaintext;">H</tspan></text><text x="58.47104399655191" y="21" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="75.57239509653311" y="80.63944832495355" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="104.34907988735478" y="93.45164612430449" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="129.83311105531465" y="74.93640495843113" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">R</text><text x="122.2125782026097" y="105.50072204618631" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="158.60979584613625" y="87.74860275778208" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">S</text><text x="135.74522524698762" y="119.11329024600619" class="element-m6sn3ltthswhn66v8zq" fill="currentColor" style="
                text-anchor: start;
                writing-mode: horizontal-tb;
                text-orientation: mixed;
                letter-spacing: normal;
                direction: ltr;
            "><tspan>H</tspan></text><text x="140.99522524698762" y="113.86329024600619" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="161.90244946899804" y="119.0760417230064" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="190.6791342598197" y="131.8882395223574" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text><text x="216.16316542777952" y="113.37299835648406" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            ">R</text><text x="219.45581905064137" y="144.70043732170842" class="debug" fill="#ff0000" style="
                font: 5px Droid Sans, sans-serif;
            "></text></g></svg>"/>


CHAPTER CONTENTS -

Cholesterol


CHAPTER CONTENTS -

Benzylpenicillin


CHAPTER CONTENTS -

Historically, the term organic chemistry dates to the mid-1700s, when it was used to mean the chemistry of substances found in living organisms. Little was known about chemistry at that time, and the behavior of the "organic" substances isolated from plants and animals seemed different from that of the "inorganic" substances found in minerals. Organic compounds were generally low-melting solids and were usually more difficult to isolate, purify, and work with than high-melting inorganic compounds.


CHAPTER CONTENTS -

By the mid-1800s, however, it was clear that there was no fundamental difference between organic and inorganic compounds. The only distinguishing characteristic of organic compounds is that all contain the element carbon.


CHAPTER CONTENTS -

Organic chemistry, then, is the study of carbon compounds. But why is carbon special? Why, of the more than 197 million presently known chemical compounds, do almost all of them contain carbon? The answers to these questions come from carbon's electronic structure and its consequent position in the periodic table (FIGURE 1.2). As a group 4A element, carbon can share four valence electrons and form four strong covalent bonds. Furthermore, carbon atoms can bond to one another, forming long chains and rings. Carbon, alone of all elements, is able to form an immense diversity of compounds, from the simple methane, with one carbon atom, to the staggeringly complex DNA, which can have more than 100 million carbons.


CHAPTER CONTENTS -

| Grou 1A |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  | 8A |
| :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: | :---: |
| H | 2A |  |  |  |  |  |  |  |  |  |  | 3A | 4A | 5A | 6A | 7A | He |
| Li | Be |  |  |  |  |  |  |  |  |  |  | B | C | N | 0 | F | Ne |
| Na | Mg |  |  |  |  |  |  |  |  |  |  | Al | Si | P | S | Cl | Ar |
| K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr |
| Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe |
| Cs | Ba | La | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | TI | Pb | Bi | Po | At | Rn |
| Fr | Ra | Ac |  |  |  |  |  |  |  |  |  |  |  |  |  |  |  |


CHAPTER CONTENTS -

FIGURE 1.2 Carbon, hydrogen, and other elements commonly found in organic compounds are shown in the colors typically used to represent them.


CHAPTER CONTENTS -

Not all carbon compounds are derived from living organisms, however. Modern chemists have developed a remarkably sophisticated ability to design and synthesize new organic compounds in the laboratory-medicines, dyes, polymers, and a host of other substances. Organic chemistry touches the lives of
everyone. Its study can be a fascinating undertaking.


CHAPTER CONTENTS - 1.1 Atomic Structure: The Nucleus

As you might remember from your general chemistry course, an atom consists of a dense, positively charged nucleus surrounded at a relatively large distance by negatively charged electrons (FIGURE 1.3). The nucleus consists of subatomic particles called neutrons, which are electrically neutral, and protons, which are positively charged. Because an atom is neutral overall, the number of positive protons in the nucleus and the number of negative electrons surrounding the nucleus are the same.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0003.jpg?height=253&width=963&top_left_y=573&top_left_x=580)

FIGURE 1.3 A schematic view of an atom. The dense, positively charged nucleus contains most of the atom's mass and is surrounded by negatively charged electrons. The three-dimensional view on the right shows calculated electron-density surfaces. Electron density increases steadily toward the nucleus and is 40 times greater at the blue solid surface than at the gray mesh surface.


Although extremely small-about $10^{-14}$ to $10^{-15}$ meter ( m ) in diameter-the nucleus nevertheless contains essentially all the mass of the atom. Electrons have negligible mass and circulate around the nucleus at a distance of approximately $10^{-10} \mathrm{~m}$. Thus, the diameter of a typical atom is about $2 \times 10^{-10} \mathrm{~m}$, or 200 picometers (pm), where $1 \mathrm{pm}=10^{-12} \mathrm{~m}$. To give you an idea of how small this is, a thin pencil line is about 3 million carbon atoms wide. Although most chemists throughout the world use the International System (SI) of units and describe small distances in picometers, many organic chemists and biochemists in the United States still use the unit angstrom ( $\AA$ ) to express atomic distances, where $1 \AA=100 \mathrm{pm}=10^{-10} \mathrm{~m}$. As you probably did in your general chemistry course, however, we'll stay with SI units in this book.


A specific atom is described by its atomic number ( $Z$ ), which gives the number of protons (or electrons) it contains, and its mass number ( $\boldsymbol{A}$, which gives the total number of protons and neutrons in its nucleus. All the atoms of a given element have the same atomic number: 1 for hydrogen, 6 for carbon, 15 for phosphorus, and so on; but they can have different mass numbers depending on how many neutrons they contain. Atoms with the same atomic number but different mass numbers are called isotopes. The element carbon, for instance, has three isotopes that occur naturally, with mass numbers of 12,13 , and 14. Carbon- 12 has a natural abundance of $98.89 \%$, carbon-13 has a natural abundance of $1.11 \%$, and carbon-14 has only a negligible natural abundance.


The weighted-average of an element's naturally occurring isotopes is called atomic weight and is given in unified atomic mass units (u) or daltons (Da) where 1 u or 1 Da is defined as one twelfth the mass of one atom of carbon-12. Thus, the atomic weight is 1.008 u for hydrogen, 12.011 u for carbon, 30.974 u for phosphorus, and so on. Atomic weights of all elements are given in the periodic table in Appendix $D$.


CHAPTER CONTENTS - 1.2 Atomic Structure: Orbitals

How are the electrons distributed in an atom? You might recall from your general chemistry course that, according to the quantum mechanical model, the behavior of a specific electron in an atom can be described by a mathematical expression called a wave equation-the same type of expression used to describe the motion of waves in a fluid. The solution to a wave equation is called a wave function, or orbital, and is denoted by the lowercase Greek letter psi ( $\psi$ ).
When the square of the wave function, $\psi^{2}$, is plotted in three-dimensional space, an orbital describes the volume of space around a nucleus that an electron is most likely to occupy. You might therefore think of an orbital as looking like a photograph of the electron taken at a slow shutter speed. In such a photo, the orbital would appear as a blurry cloud, indicating the region of space where the electron has been. This electron cloud doesn't have a sharp boundary, but for practical purposes we can set the limits by saying that an orbital represents the space where an electron spends $90 \%$ to $95 \%$ of its time.


What do orbitals look like? There are four different kinds of orbitals, denoted $s, p, d$, and $f$, each with a different shape. Of the four, we'll be concerned primarily with $s$ and $p$ orbitals because these are the most common in
organic and biological chemistry. An $s$ orbital has a spherical shape, with the nucleus at its center; a $p$ orbital has a dumbbell shape with two parts, or lobes; and four of the five $d$ orbitals have a cloverleaf shape with four lobes, as shown in FIGURE 1.4. The fifth $d$ orbital is shaped like an elongated dumbbell with a doughnut around its middle.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0004.jpg?height=234&width=226&top_left_y=460&top_left_x=513)


An $s$ orbital
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0004.jpg?height=324&width=223&top_left_y=410&top_left_x=929)

A p orbital
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0004.jpg?height=321&width=310&top_left_y=411&top_left_x=1317)


Ad orbital


FIGURE 1.4 Representations of $\boldsymbol{s}, \boldsymbol{p}$, and $\boldsymbol{d}$ orbitals. An $s$ orbital is spherical, a $p$ orbital is dumbbell-shaped, and four of the five $d$ orbitals are cloverleaf-shaped. Different lobes of $p$ orbitals are often drawn for convenience as teardrops, but their actual shape is more like that of a doorknob, as indicated.


The orbitals in an atom are organized into different layers around the nucleus called electron shells, which are centered around the nucleus and have successively larger size and energy. Different shells contain different numbers and kinds of orbitals, and each orbital within a shell can be occupied by two electrons. The first shell contains only a single $s$ orbital, denoted $1 s$, and thus holds only 2 electrons. The second shell contains one $2 s$ orbital and three $2 p$ orbitals and thus holds a total of 8 electrons. The third shell contains a $3 s$ orbital, three $3 p$ orbitals, and five $3 d$ orbitals, for a total capacity of 18 electrons. These orbital groupings and their energy levels are shown in FIGURE 1.5.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0004.jpg?height=429&width=1009&top_left_y=1257&top_left_x=561)

FIGURE 1.5 Energy levels of electrons in an atom. The first shell holds a maximum of 2 electrons in one $1 s$ orbital; the second shell holds a maximum of 8 electrons in one $2 s$ and three $2 p$ orbitals; the third shell holds a maximum of 18 electrons in one $3 s$, three $3 p$, and $3 d$ orbitals; and so on. The two electrons in each orbital are represented by five up and down arrows, $\uparrow \downarrow$. Although not shown, the energy level of the $4 s$ orbital falls between $3 p$ and $3 d$.


The three different $p$ orbitals within a given shell are oriented in space along mutually perpendicular directions, denoted $p_{\mathrm{x}}, p_{\mathrm{y}}$, and $p_{\mathrm{z}}$. As shown in FIGURE 1.6, the two lobes of each $p$ orbital are separated by a region of zero electron density called a node. Furthermore, the two orbital regions separated by the node have different algebraic signs, + and -, in the wave function, as represented by the different colors in FIGURE 1.4 and FIGURE 1.6. As we'll see in Section 1.11, these algebraic signs for different orbital lobes have important consequences with respect to chemical bonding and chemical reactivity.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0005.jpg?height=373&width=350&top_left_y=193&top_left_x=519)


A $2 p_{\mathrm{x}}$ orbital
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0005.jpg?height=367&width=331&top_left_y=196&top_left_x=905)

A $2 p_{\mathrm{y}}$ orbital
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0005.jpg?height=372&width=365&top_left_y=191&top_left_x=1254)

A $\mathbf{2} p_{z}$ orbital


FIGURE 1.6 Shapes of the $2 p$ orbitals. Each of the three mutually perpendicular, dumbbell-shaped orbitals has two lobes separated by a node. The two lobes have different algebraic signs in the corresponding wave function, as indicated by the different colors.


CHAPTER CONTENTS - 1.3 Atomic Structure: Electron Configurations

The lowest-energy arrangement, or ground-state electron configuration, of an atom is a list of the orbitals occupied by its electrons. We can predict this arrangement by following three rules.


RULE 1 -

The lowest-energy orbitals fill up first, $1 s \rightarrow 2 s \rightarrow 2 p \rightarrow 3 s \rightarrow 3 p \rightarrow 4 s \rightarrow 3 d$, according to the following graphic, a statement called the Aufbau principle. Note that the $4 s$ orbital lies between the $3 p$ and $3 d$ orbitals in energy.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0005.jpg?height=693&width=655&top_left_y=1090&top_left_x=735)


RULE 1 -

RULE 2
Electrons act in some ways as if they were spinning around an axis, somewhat as the earth spins. This spin can have two orientations, denoted as up ( $\uparrow$ ) and down ( $\downarrow$ ). Only two electrons can occupy an orbital, and they must have opposite spins, a statement called the Pauli exclusion principle.


RULE 1 -

RULE 3
If two or more empty orbitals of equal energy are available, one electron occupies each with spins parallel until all orbitals are half-full, a statement called Hund's rule.


RULE 1 -

Some examples of how these rules apply are shown in TABLE 1.1. Hydrogen, for instance, has only one electron, which must occupy the lowest-energy orbital. Thus, hydrogen has a $1 s$ ground-state configuration. Carbon has six electrons and the ground-state configuration $1 s^{2} 2 s^{2} 2 p_{x}{ }^{1} 2 p_{y}{ }^{1}$, and so forth. Note that a superscript is used to represent the number of electrons in a particular orbital.


RULE 1 -

| TABLE 1.1 <br> Elements | Ground-State Electron Configurations of Some |  |  |  |
| :--- | :--- | :--- | :--- | :--- |
| Element | Atomic number | Configuration |  |  |
| Hydrogen | 1 | $1 s$ | $\uparrow$ |  |
| Carbon | 6 | $2 p$ | $\uparrow \uparrow$ | $\uparrow$ |


RULE 1 -

PROBLEM What is the ground-state electron configuration of each of the following elements:
1-1 (a) Oxygen (b) Nitrogen (c) Sulfur


RULE 1 -

PROBLEM How many electrons does each of the following biological trace elements have in its outermost $\mathbf{1 - 2}$ electron shell?
(a) Magnesium
(b) Cobalt
(c) Selenium


RULE 1 - 1.4 Development of Chemical Bonding Theory

By the mid-1800s, the new science of chemistry was developing rapidly, especially in Europe, and chemists had begun to probe the forces holding compounds together. In 1858, the German chemist August Kekulé and the Scottish chemist Archibald Couper independently proposed that, in all organic compounds, carbon is tetravalent-it always forms four bonds when it joins other elements to form stable compounds. Furthermore, said Kekulé, carbon atoms can bond to one another to form extended chains of linked atoms. In 1865, Kekulé provided another major advance when he suggested that carbon chains can double back on themselves to form rings of atoms.

Although Kekule and Couper were correct in describing the tetravalent nature of carbon, chemistry was still viewed in a two-dimensional way until 1874. In that year, the Dutch chemist Jacobus van't Hoff and French chemist Joseph Le Bel added a third dimension to our ideas about organic compounds when they proposed that the four bonds of carbon are not oriented randomly but have specific spatial directions. Van't Hoff went even further and suggested that the four atoms to which carbon is bonded sit at the corners of a regular tetrahedron, with carbon in the center.


A representation of a tetrahedral carbon atom is shown in FIGURE 1.7. Note the conventions used to show threedimensionality: solid lines represent bonds in the plane of the page, the heavy wedged line represents a bond coming out of the page toward the viewer, and the dashed line represents a bond receding back behind the page, away from the viewer. Get used to them; these representations will be used throughout the text.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-0007.jpg?height=508&width=1163&top_left_y=174&top_left_x=481)

FIGURE 1.7 A representation of van't Hoff's tetrahedral carbon atom. The solid lines represent bonds in the plane of the paper, the heavy wedged line represents a bond coming out of the plane of the page toward the viewer, and the dashed line represents a bond going back behind the plane of the page away from the viewer.