General Problems -

PROBLEM As a general rule, equatorial alcohols are esterified more readily than axial alcohols. What product
27-37 would you expect to obtain from reaction of the following two compounds with 1 equivalent of acetic anhydride?
(a)
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(b)
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PROBLEM Propose a mechanistic pathway for the biosynthesis of isoborneol. A carbocation rearrangement is
27-38 needed at one point in the scheme.
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Isoborneol -

PROBLEM Digitoxigenin is a heart stimulant obtained from the purple foxglove Digitalis purpurea and used
27-39 in the treatment of heart disease. Draw the three-dimensional conformation of digitoxigenin, and identify the two -OH groups as axial or equatorial.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-1011.jpg?height=375&width=725&top_left_y=954&top_left_x=418)


Isoborneol -

PROBLEM What product would you obtain by reduction of digitoxigenin (Problem 27-39) with $\mathrm{LiAlH}_{4}$ ? By
27-40 oxidation with the Dess-Martin periodinane?
PROBLEM Vaccenic acid, $\mathrm{C}_{18} \mathrm{H}_{34} \mathrm{O}_{2}$, is a rare fatty acid that gives heptanal and 11-oxoundecanoic acid
27-41 $\left[\mathrm{OHC}\left(\mathrm{CH}_{2}\right)_{9} \mathrm{CO}_{2} \mathrm{H}\right]$ on ozonolysis followed by zinc treatment. When allowed to react with $\mathrm{CH}_{2} \mathrm{I}_{2} / \mathrm{Zn}(\mathrm{Cu})$, vaccenic acid is converted into lactobacillic acid. What are the structures of vaccenic and lactobacillic acids?


Isoborneol -

PROBLEM Eleostearic acid, $\mathrm{C}_{18} \mathrm{H}_{30} \mathrm{O}_{2}$, is a rare fatty acid found in the tung oil used for finishing furniture. On
27-42 ozonolysis followed by treatment with zinc, eleostearic acid furnishes one part pentanal, two parts glyoxal ( $\mathrm{OHC}-\mathrm{CHO}$ ), and one part 9 -oxononanoic acid $\left[\mathrm{OHC}\left(\mathrm{CH}_{2}\right)_{7} \mathrm{CO}_{2} \mathrm{H}\right]$. What is the structure of eleostearic acid?


Isoborneol -

PROBLEM Diterpenoids are derived biosynthetically from geranylgeranyl diphosphate (GGPP), which is itself
27-43 biosynthesized by reaction of farnesyl diphosphate with isopentenyl diphosphate. Show the structure of GGPP, and propose a mechanism for its biosynthesis from FPP and IPP.


Isoborneol -

PROBLEM Diethylstilbestrol (DES) has estrogenic activity even though it is structurally unrelated to steroids.
27-44 Once used as an additive in animal feed, DES has been implicated as a causative agent in several types of cancer. Show how DES can be drawn so that it is sterically similar to estradiol.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-1011.jpg?height=353&width=1085&top_left_y=2160&top_left_x=414)


Isoborneol -

PROBLEM Cembrene, $\mathrm{C}_{20} \mathrm{H}_{32}$, a diterpenoid hydrocarbon isolated from pine resin, has a UV absorption at 245 27-45 nm, but dihydrocembrene $\left(\mathrm{C}_{20} \mathrm{H}_{34}\right)$, the product of hydrogenation with 1 equivalent of $\mathrm{H}_{2}$, has no UV absorption. On exhaustive hydrogenation, 4 equivalents of $\mathrm{H}_{2}$ react, and octahydrocembrene, $\mathrm{C}_{20} \mathrm{H}_{40}$, is produced. On ozonolysis of cembrene, followed by treatment of the ozonide with zinc, four carbonyl-containing products are obtained:
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-1012.jpg?height=153&width=1074&top_left_y=430&top_left_x=420)


Isoborneol -

Propose a structure for cembrene that is consistent with its formation from geranylgeranyl diphosphate.


Isoborneol -


Isoborneol -

PROBLEM Fatty acids are synthesized by a multistep route that starts with acetate. The first step is a reaction
27-47 between protein-bound acetyl and malonyl units to give a protein-bound 3 -ketobutyryl unit. Show the mechanism, and tell what kind of reaction is occurring.
![](https://cdn.mathpix.com/cropped/2025_02_06_5556f7656cbdcaa0f9a7g-1012.jpg?height=516&width=1357&top_left_y=1195&top_left_x=411)