Apatite
Fluorapatite (or fluoroapatite) is more resistant to acid attack than is hydroxyapatite. In the mid-20th century it was discovered that communities whose water supply naturally contained fluorine had lower rates of dental caries.  Fluoridated water allows exchange in the teeth of fluoride ions for hydroxyl groups in apatite. Similarly, toothpaste often includes a source of fluoride anions (e.g. sodium fluoride, sodium monofluorophosphate).