Captain America: Civil War
The cops take them to a building, where they imprison Bucky in a cage. Tony tries to convince Steve to sign the Accords but fails. Zemo comes to the building in disguise to "interview" Bucky, but starts reading commands from the red book. Bucky turns into the Winter Soldier, breaking out of his cage and fighting everyone, letting Zemo escape. The Winter Soldier almost escapes, but Steve stops him and sneaks him away with Sam. Ross tells Tony and Natasha that he wants to arrest Steve and his group and gives them 48 hours to bring them back. Natasha asks T'Challa for help, while Tony goes to Queens, New York City to recruit Peter Parker/Spider-Man.