Diffie-Hellman key exchange
While very useful, Diffie-Hellman is at risk of a man-in-the-middle attack. Alice and Bob do not need to prove who they are to swap their information, which means there is a risk that Charlie can look at the information while it is being swapped, and can even pretend to be Alice or Bob to try and figure out their keys. One way this is avoided is to use authentication, where people perform extra steps to prove who they are.