John Adams
Adams was the first vice president under George Washington.  After Washington chose not to run again, Adams won the 1796 election.  Adams is thought to have been the first president to belong to a political party, but like George Washington, he thought himself above any particular party.  He ran for president on the Federalist ticket.  He beat Thomas Jefferson of the Democratic-Republican Party.  President candidates and vice president candidates did not run together like they do today.  Since Jefferson got the second-highest number of votes, he became vice president.