3200 Phaethon
Phaethon approaches the Sun closer than any other numbered asteroid. Its perihelion (closest approach to the Sun) is only 0.140 AU – less than half Mercury's perihelion distance. It is a Mercury-, Venus-, Earth- and Mars-crosser. The surface temperature at perihelion could reach ~1025 K, or 1400 F. For this reason, it was named after the Greek myth of Phaëton, son of the sun god Helios.