Quantum mechanics
There is some law that says what frequencies of light glowing hydrogen will produce. It has to predict spaced-out frequencies when the electrons involved are moving between orbits close to the nucleus (center) of the atom, but it also has to predict that the frequencies will get closer and closer together as we look at what the electron does in moving between orbits farther and farther out. It will also predict that the intensity differences between frequencies get closer and closer together as we go out. Where classical physics already gives the right answers by one set of equations the new physics has to give the same answers but by different equations.