Saliva
The digestion part is by three enzymes, one each for carbohydrates, fats and proteins. The digestion started here carries on in the stomach. There are some other 'minor' enzymes as well, and we do not know the full story about them yet. Also there is a pain-killing opiorphin, and a wrap-around haptocorrin which keeps vitamin B12 safe from stomach acids. Finally, there are a set of anti-bacterial proteins which make life difficult for any bacteria which get in with the food.