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What are quantum numbers and what do they mean?
How are the quantum numbers related to each other?
The values of n, l, and ml determine each other, while ms is independent. Specifically, n can take on any positive integer value, l can take on any integer value between 0 and n-1, ml can take on any integer value between -l and +l, and ms can either be +1/2 or -1/2.