On 14 May 1994, in the league's last round, at home against Valencia CF, Đukić missed a penalty kick in the game's last minute (eventual 0–0 draw), as habitual taker Donato had already been replaced and second option Bebeto refused the responsibility since he failed to score one the previous match. As a result, FC Barcelona were crowned champions instead, and the elegant defender left A Coruña at the end of 1996–97 at the age of 31 as his contract was not renewed.