The tetraborate anion (tetramer) includes two tetrahedral and two trigonal boron atoms symmetrically assembled in a fused bicyclic structure. The two tetrahedral boron atoms are linked together by a common oxygen atom, and each also bears a negative net charge brought by the supplementary OH− groups laterally attached to them. This intricate molecular anion also exhibits three rings: two fused distorted hexagonal (boroxole) rings and one distorted octagonal ring. Each ring is made of a succession of alternate boron and oxygen atoms. Boroxole rings are a very common structural motif in polyborate ions.