In this equation, formula_4 is the number of free charges per unit volume. These charges are the ones that have made the volume non-neutral, and they are sometimes referred to as the space charge. This equation says, in effect, that the flux lines of D must begin and end on the free charges. In contrast formula_5 is the density of all those charges that are part of a dipole, each of which is neutral. In the example of an insulating dielectric between metal capacitor plates, the only free charges are on the metal plates and dielectric contains only dipoles. If the dielectric is replaced by a doped semiconductor or an ionised gas, etc, then electrons move relative to the ions, and if the system is finite they both contribute to formula_4 at the edges.