When a potential difference is applied across a conductor, free electrons gain velocity in the direction opposite to the electric field between successive collisions (and lose velocity when traveling in the direction of the field), thus acquiring a velocity component in that direction in addition to its random thermal velocity. As a result, there is a definite small drift velocity of electrons, which is superimposed on the random motion of free electrons. Due to this drift velocity, there is a net flow of electrons opposite to the direction of the field.