In 1903 he published an article in "Nature" in which he discussed the possibility of using radium to date the Earth and went on to study the radioactive content of the Earth's crust to formulate a theory of thermal cycles, and examined the radioactive constituents of certain rocks as a means of calculating their age. Working in collaboration with Sir Ernest Rutherford, he used radioactive decay in minerals to estimate, in 1913, that the beginning of the Devonian period could not be less than 400 million years ago, an estimate which is in line with modern calculations.