"Catch You" was released as the album's lead single in February 2007. It is a pop rock, electronic song and talks about Ellis-Bextor chasing the guy that she wants. It received mostly positive reviews from music critics, who commended the infusion of rock guitars and electronic beats, while calling it a strident and very good song. A music video was directed by Sophie Muller and it shows Ellis-Bextor chasing someone in Venice. The song performed moderately on the charts, reaching number 8 on the UK Singles Chart, peaking inside the top twenty on the Italian and Russian Singles Chart and inside the top fifty on the charts of other countries.