During the 2005–06 season, Huet eventually won the starting job in goal for the Canadiens at the expense of José Théodore, who was subsequently traded to Colorado in exchange for goaltender David Aebischer. He also won the Molson Cup in February 2006. He won the Best Defensive Player award from the NHL during the first week of March, ousting goaltenders such as the Ottawa Senators' Ray Emery and the New Jersey Devils' Martin Brodeur, with a 3–0–0 record and a 1.67 GAA. For the second time of the year, he was named NHL Best Defensive Player on April 3 with a 3–0–0 record, a 0.65 GAA and 0.979 SV%, ousting goaltenders Martin Brodeur, Flames goalie Miikka Kiprusoff and Detroit's Manny Legace.