In 1873 Maunder returned to the Royal Observatory, taking a position as a spectroscopic assistant. Shortly after, in 1875, he married Edith Hannah Bustin, who gave birth to six children, 3 sons, 2 daughters and a son who died in infancy. Following the death of Edith in 1888, in 1890 he met Annie Scott Dill Russell (later Annie Russell Maunder, 1868–1947), a mathematician and astronomer educated at Girton College in Cambridge, with whom he collaborated for the remainder of his life. She worked as a "lady computer" at the Observatory from 1890 to 1895.