The high yield production of phosphorene has been demonstrated by many groups in solvents, but to realize the potential applications of this material, it is crucial to deposit these free-standing nanosheets in solvents systematically on substrates. H. Kaur et al. demonstrated the synthesis, interface-driven alignment and subsequent functional properties of few layer semiconducting phosphorene using Langmuir-Blodgett assembly. This is the first study which provides a straightforward and versatile solution towards the challenge of assembling nanosheets of phosphorene onto various supports and subsequently use these sheets in an electronic device. Therefore, wet assemblies techniques like Langmuir-Blodgett serves as a very valuable new entry point for the exploration of electronic as well as opto-electronic properties of phosphorene as well as other 2D layered inorganic materials.