She won a gold medal in the Two-woman competition at the 2010 Winter Olympics with Kaillie Humphries. The silver medal was won by fellow Canadians Shelley-Ann Brown and Helen Upperton. It marked the first time at the 2010 Olympics that Canadians had won two medals in one event. For winning the Gold Medal, Moyse was on the cover of Hello! Canada in March 2010. Moyse joins former University of Toronto student-athlete Jayna Hefford as the only University of Toronto graduates to claim a gold medal at the 2010 Vancouver Winter Games.