Disposable chemical pads employ a one-time exothermic chemical reaction. One type, frequently used for hand warmers, is triggered by unwrapping an air-tight packet containing slightly moist iron powder and salt or catalysts which rusts over a period of hours after being exposed to oxygen in the air. Another type contains separate compartments within the pad; when the user squeezes the pad, a barrier ruptures and the compartments mix, producing heat such as the enthalpy change of solution of calcium chloride dissolving.