Freije played for the Vanderbilt University Commodores men's basketball team from 2000 to 2004. He chose to come to Vanderbilt due to his relationship with head basketball coach Kevin Stallings. In 2004, he was named First Team All-SEC and led the Commodores to the Sweet 16 of the NCAA Tournament for the first time since 1993. He left Vanderbilt as the leading scorer in school history, having surpassed Phil Cox in 2004. His record was broken in 2008 by Shan Foster.