In 2006 Zane was signed by Channel 4 under an exclusive contract. He co-presented "Popworld" and the accompanying Popworld Radio podcast with Alexa Chung until the programme ended in July 2007. He has narrated an E4 television show, "Princess Nikki", and made appearances on Channel 4 entertainment programmes such as "The Law of the Playground", "8 out of 10 cats" and "Balls of Steel". He presented E4's coverage of Channel 4's hoax reality show "Space Cadets", as well as Death Wish Live, the BT Digital Music Awards in 2005 and 2006 and Carling Live 24. He has also presented television coverage of several large scale music events, including the V Festival, and the Wireless Festival in London's Hyde Park and more recently Orange Unsigned Act. He presented "Celebrity Scissorhands" first on BBC Three, then on BBC One, as part of the BBC's Children in Need charity campaign in November 2006. He has presented Channel 4's variety show based on YouTube videos, "Rude Tube", four times (February 2008, January 2009, January 2010 and October to November 2010). Zane also co-presented the Kerrang! music awards 2008 with Cristina Scabbia of Lacuna Coil. He has done promotional presenting work with BBC Blast including a piece on what creativity means.