In 2014, Catchings missed the Fever's first 17 games of the season with a sore back and returned 6 games prior to the 2014 WNBA All-Star Game in which she was selected to play in. During the all-star game, Catchings scored a game winning basket for the Eastern Conference all-star team to put them up 125–124 with 6 seconds left in overtime. Later on in the season, the Fever finished second in the East with a 16–18 record. On August 23, 2014, Catchings became the WNBA's all-time leading playoff scorer after making a three-point field goal in Game 3 of the Eastern Conference semifinals against the Washington Mystics surpassing Lisa Leslie's 908 career playoff points. She finished the game with 22 points, 10 rebounds and 7 steals also surpassing Lisa Leslie for most WNBA career playoff rebounds (471). The Fever would then advance to the Conference Finals and were one win away from advancing to the 2014 WNBA Finals but lost 2–1 to the Chicago Sky.