In 1848, she witnessed a rebellion in the Duchy of Nassau, which was suppressed by her mother and brothers. She spent the winter of 1853-54 with her mother at the court of her maternal aunt in St Petersburg in Russia. Her maternal aunt, Princess Charlotte of Württemberg, was married to Grand Duke Michael Pavlovich of Russia. The trip was not made to arrange a marriage with a Russian prince because her mother did not wish her to convert, which would have been necessary, but rather, to have her study the life in a grand court. During her stay in Russia, she was a student of the pianist Anton Rubinstein. Sophia and her mother were forced to leave Russia at the outbreak of the Crimean war. After the death of her mother in 1856, Sophia lived with her half-sister, Princess Marie Wilhemine of Wied.