Clijsters made her Fed Cup debut for Belgium in 2000 at the age of 16. The top-tier World Group that year consisted of 13 teams, 12 of which were divided into three round robin groups. The winners of the round robin groups in April would compete with the defending champion United States team in a knockout format for the title in November. Belgium was placed in a group with Australia, France, and Russia. Each tie was contested over one day as a best-of-three rubbers, two in singles and the last in doubles. Clijsters only played singles, while Els Callens and Laurence Courtois played all three doubles matches. Although Clijsters narrowly lost her debut to Jelena Dokic of Australia by a score of 9–7 in the third set, her teammates were able to secure the tie. She won her other two matches against Nathalie Tauziat of France and Anna Kournikova of Russia, both of which were crucial as Belgium won each of those ties 2–1 as well to win the group. In the semifinals, Henin returned to the team as they faced the United States, the hosts for the final rounds. After Henin lost to Monica Seles, Clijsters needed to defeat Lindsay Davenport to keep Belgium in the tournament. She won the second set, but ultimately lost the match.