Hopetoun was born into the Scottish nobility, and succeeded his father as Earl of Hopetoun at the age of 12. He attended Eton College and the Royal Military College, Sandhurst, but opted not to pursue a full-time military career. Hopetoun sat with the Conservative Party in the House of Lords, and became a Lord-in-waiting in 1885 and Lord High Commissioner to the General Assembly of the Church of Scotland in 1887. He was appointed Governor of Victoria at the age of 29, and had a successful tenure in a time of political and economic instability.