DeVitto's modeling career started at age 15, when she began appearing in commercials, which she described to be a stepping stone to get to TV and film jobs. She was signed to Ford and Avenue One modeling agencies. Staying true to her love of music in 2002, she played violin with the Tommy Davidson Band at the Sunset Room in Hollywood. She also played violin on Raphael Saadiq's 2004 album, "Ray Ray," as well as Stevie Nicks' 2011 album "In Your Dreams".