Pauli proposed in 1924 a new quantum degree of freedom (or quantum number) with two possible values, to resolve inconsistencies between observed molecular spectra and the developing theory of quantum mechanics. He formulated the Pauli exclusion principle, perhaps his most important work, which stated that no two electrons could exist in the same quantum state, identified by four quantum numbers including his new two-valued degree of freedom. The idea of spin originated with Ralph Kronig. A year later, George Uhlenbeck and Samuel Goudsmit identified Pauli's new degree of freedom as electron spin, in which Pauli for a very long time wrongly refused to believe.