The concentration of Sm and Nd in silicate minerals increase with the order in which they crystallise from a magma according to Bowen's reaction series. Samarium is accommodated more easily into mafic minerals, so a mafic rock which crystallises mafic minerals will concentrate neodymium in the melt phase relative to samarium. Thus, as a melt undergoes fractional crystallization from a mafic to a more felsic composition, the abundance of Sm and Nd changes, as does the ratio between Sm and Nd.