Glass plate negatives and ambrotypes are prone to breakage. Deterioration of film negatives, regardless of type, is humidity and temperature dependent. Nitrate film will first fade, then become brittle and sticky. It will then soften, adhere to paper enclosures, and produce an odor. Finally, it will disintegrate into a brown, acrid powder. Because of its flammability, it must be handled with particular care. Cellulose aetate, diacetate, and triacetate film produce acetic acid, which smells like vinegar. The deterioration process is therefore known as "vinegar syndrome." The negatives become very brittle and, in diacetate and triacetate film, the base shrinks, causing grooves (“channeling”).