The George IV Inn, reputedly constructed in 1839, is considered to be one of the oldest hotel buildings in Australia. The cellar contains remnants of convict shackles as prisoners being transported from Sydney to Berrima prison would often be held in Picton overnight. The barn behind the hotel may date back to 1810 and is possibly the oldest building in Picton - it is used for functions such as birthday and engagement parties. The hotel is also the location of Scharer's Little Brewery, one of the first microbreweries in Australia and winner of numerous awards for its Burragorang Bock and Scharer's Lager beers.