During the 2013–14 campaign, in the week of October 21 and 27, Kessel scored in all three of Toronto's games. In the Maple Leafs' first game, he scored his fourth career hat-trick, including the game-winner, in a 4–2 victory of the Anaheim Ducks. He then scored in Toronto's next game, a 5–2 loss to the Columbus Blue Jackets, and concluded the week by recording a goal and an assist in a 4–1 victory over the Pittsburgh Penguins. For his efforts, Kessel was named Second Star of the Week after leading the NHL with five goals scored in that timeframe. Kessel continued his successful week with a two-goal, two-assist effort against Edmonton in a 4–0 Maple Leafs victory.