1889: Film NegativesCellulose nitrate film was developed by Eastman Kodak in 1889 and refined in 1903. It is made of silver gelatin on a cellulose nitrate base. The negatives are flammable and therefore can be dangerous. Nitrate sheet film was used widely though the 1930s, while nitrate roll film was used through the 1950s. The nitrate base was replaced with cellulose acetate in 1923. By 1937, Cellulose diacetate was used as the base, and beginning in 1947 Cellulose triacetate was used. Polyester film was introduced around 1960.