Two weeks prior to the domestic release of the band's self-titled debut album, "Mind's Eye" was released as Wolfmother's debut single in Australia on 16 October 2005. The Australian edition of the single was a double A-side release featuring fellow album track "Woman", with "The Earth's Rotation Around the Sun" featured as the B-side. The single debuted on the Australian Singles Chart at its peak position of number 29, remaining in the top 50 for four weeks running. It later re-entered the chart for a single week each in January and February 2006. Outside of Australia, "Mind's Eye" was issued as the band's first single on 9 January 2006, backed only with "The Earth's Rotation Around the Sun". It entered the UK Singles Chart at number 142, as well as the Scottish Singles Chart at number 88.