In 2012, Pozzovivo won the prestigious Giro del Trentino. He was victorious in stage 3 of that race, which led the riders from Pergine to Brenzone, finishing after a steep climb, the Punta Veleno. Team cars were not allowed on that climb since it was very steep and the tarmac was inappropriate. Motorbikes were the only resource available for riders suffering a mechanical problem. The victory on that hard stage granted him the leader's jersey, which he managed to hold on to the following day on the fourth and final stage, which was disputed in snowy weather conditions. He finished that stage in third position. He also won the Mountains classification jersey.