Water megamasers were the first type of megamaser discovered. The first water megamaser was found in 1979 in NGC 4945, a galaxy in the nearby Centaurus A/M83 Group. The first hydroxyl megamaser was found in 1982 in Arp 220, which is the nearest ultraluminous infrared galaxy to the Milky Way. All subsequent OH megamasers that have been discovered are also in luminous infrared galaxies, and there are a small number of OH kilomasers hosted in galaxies with lower infrared luminosities. Most luminous infrared galaxies have recently merged or interacted with another galaxy, and are undergoing a burst of star formation. Many of the characteristics of the emission in hydroxyl megamasers are distinct from that of hydroxyl masers within the Milky Way, including the amplification of background radiation and the ratio of hydroxyl lines at different frequencies. The population inversion in hydroxyl molecules is produced by far infrared radiation that results from absorption and re-emission of light from forming stars by surrounding interstellar dust. Zeeman splitting of hydroxyl megamaser lines may be used to measure magnetic fields in the masing regions, and this application represents the first detection of Zeeman splitting in a galaxy other than the Milky Way.