Urszula began her 2014 season in February when she played at the Dow Classic in Midland. As the top seed, she defeated Sachia Vickery and Kateřina Siniaková in her first two rounds. Her run ended as she lost in the quarterfinals to sixth seed Sharon Fichman. At the Abierto Mexicano Telcel, Urszula was defeated in the first round by top seed and eventual champion Dominika Cibulková. After Acapulco, Urszula competed at the BNP Paribas Open. She lost in the first round to Aleksandra Wozniak. The following week, Urszula took part in the Sony Open Tennis tournament in Miami. She was defeated in the first round by Nadia Petrova. The week after Miami, Urszula played at the Monterrey Open. She lost in the first round to second seed and eventual champion Ana Ivanovic. During the Fed Cup tie versus Spain, Urszula lost both of her rubbers to María Teresa Torró Flor and Silvia Soler Espinosa. Despite her losses, Poland was still able to win the tie 3–2.