In the case of Magic Angle Spinning DNP (MAS-DNP), the mechanism is different but to understand it, a two spins system can still be used. The polarization process of the nucleus still occurs when the microwave irradiation excites the Double Quantum or Zero Quantum transition, but due to the fact that the sample is spinning, this condition is only met for a short time at each rotor cycle (which makes it periodical). The DNP process in that case happens step by step and not continuously as in the static case.