A larger population of "N" = 10 has 9 degrees of freedom for estimating the standard deviation. The same computations as above give us in this case a 95% CI running from 0.69 × SD to 1.83 × SD. So even with a sample population of 10, the actual SD can still be almost a factor 2 higher than the sampled SD. For a sample population N=100, this is down to 0.88 × SD to 1.16 × SD. To be more certain that the sampled SD is close to the actual SD we need to sample a large number of points.