The first publications of Schrödinger about atomic theory and the theory of spectra began to emerge only from the beginning of the 1920s, after his personal acquaintance with Sommerfeld and Wolfgang Pauli and his move to Germany. In January 1921, Schrödinger finished his first article on this subject, about the framework of the Bohr-Sommerfeld effect of the interaction of electrons on some features of the spectra of the alkali metals. Of particular interest to him was the introduction of relativistic considerations in quantum theory. In autumn 1922 he analyzed the electron orbits in an atom from a geometric point of view, using methods developed by the mathematician Hermann Weyl (1885–1955). This work, in which it was shown that quantum orbits are associated with certain geometric properties, was an important step in predicting some of the features of wave mechanics. Earlier in the same year he created the Schrödinger equation of the relativistic Doppler effect for spectral lines, based on the hypothesis of light quanta and considerations of energy and momentum. He liked the idea of his teacher Exner on the statistical nature of the conservation laws, so he enthusiastically embraced the articles of Bohr, Kramers, and Slater, which suggested the possibility of violation of these laws in individual atomic processes (for example, in the process of emission of radiation). Although the experiments of Hans Geiger and Walther Bothe soon cast doubt on this, the idea of energy as a statistical concept was a lifelong attraction for Schrödinger and he discussed it in some reports and publications.