In the 2000 Summer Olympics, Jing competed in both the singles and doubles events, the latter alongside Li Jiawei. In the singles event, Jing again swept her group, beating Karen Li and Sofija Tepes. She then defeated Sun Jin, Lijuan Geng, and Mihaela Steff to reach the semifinals, where she was defeated by Li Ju. In the bronze medal game, she lost to Chen Jing. In the doubles event, Jing and Li started in the round of 16, where they were defeated by Eldijana Bentsen and Tamara Boroš of Croatia. Jing again won the Sportswoman of the Year award for her Olympic performance. Following the 2000 Olympics, Jing was ranked 12th in the world by the International Table Tennis Federation.