Luiz Adriano scored both of his side's goals in their 2–0 win over Dynamo Kyiv in the Ukrainian derby on 16 April 2014. In Shakhtar's following Premier League match, against city-rivals Metalurh, Luiz Adriano scored the game-winning goal as Shakhtar came from a goal down to win 2–1. On 11 May, Luiz Adriano scored twice as Shakhtar clinched their fifth consecutive league title with a 3–1 win over Zorya Luhansk. In the final league match of the season on 18 May, Luiz Adriano scored both goals as Shakhtar defeated Volyn Lutsk 2–0 to finish as the leading goal-scorer with 20 strikes.