Following his departure from the NFL, Williams worked on television in 1990 as a college football analyst for the Black Entertainment Television (BET). Despite enjoying the change of pace, Williams longed to return to football and when a high school head coaching position opened up in 1991 at the new Pointe Coupee Central High School in the unincorporated Labarre area of Pointe Coupee Parish, Louisiana, Williams applied for the job and was hired for the position. Williams led the 35-player team to a 5–5 record in the season, including an upset of the second-ranked school in the state.