Rivers started the 2016 season with 243 passing yards and a touchdown in a 33–27 loss to the Kansas City Chiefs. In Week 5, against the Oakland Raiders, he had 359 passing yards, four touchdowns, and two interceptions in the 34–31 loss. On October 13, 2016, in Week 6, Rivers passed Fouts to become the Chargers' all-time passing yards leader. In Week 7, against the Atlanta Falcons, he had a season-high 371 passing yards, one touchdown, and one interception in the 33–30 victory. Rivers struggled in 2016. Despite throwing for 33 touchdowns, Rivers threw a career-high and league-leading 21 interceptions and completed only 60.4 of his passes, the second worst of his career. Rivers posted a rating of 87.9, also the second worst of his career. These struggles resulted in the Chargers finishing 5–11 and last in the division for the second straight year. He was ranked 73rd by his fellow players on the NFL Top 100 Players of 2017.