Williams played a small role in the 2004 sports film "Friday Night Lights" (his older brother, Lloyd Hill was on the team the movie was based on). Williams played the role of an assistant coach for Midland Lee High School, which is one of Permian's biggest rivals. His one spoken line in the film was, "He ain’t going to play." Williams is also the co-founder, with college teammate BJ Johnson, of MVP Vodka, an All-American Wheat vodka made in Dallas, TX.