Nanoporous membranes are fundamentally different than polymer-based membranes in that their chemistry is different and that they do not follow the Robeson limit for a variety of reasons. The simplified figure of a nanoporous membrane shows a small portion of an example membrane structure with cavities and windows. The white portion represents the area where the molecule can move and the blue shaded areas represent the walls of the structure. In the engineering of these membranes, the size of the cavity (Lcy x Lcz) and window region (Lwy x Lwz) can be modified so that the desired permeation is achieved. It has been shown that the permeability of a membrane is the production of adsorption and diffusion. In low loading conditions, the adsorption can be computed by the Henry coefficient.