Moscardelli joined Serie B newcomer Rimini on 27 August 2005. In his first season with Rimini, he rotated with Simone Motta and Sergio Floccari for the 2 strikers place until January Floccari departed. He scored in his club debut on 10 September, that match he partnered with Motta and Moscardelli scored 1 goals; after Moscardelli was substituted by Floccari, Motta scored 2 more goals in 85 and 95 minutes and made Rimini won 4–2 against Catanzaro. He scored 6 goals in 31 games.