Scorpia then joins the new Sinister Six (though there were seven members total). The team's main purpose was to stop Kaine from killing any more of Spider-Man's enemies. When Kaine disguised himself as Spider-Man and attacked Hobgoblin, Scorpia immediately joined the others in the battle. However, they were not accustomed to working together, much to Scorpia's disdain. Spider-Man eventually entered the battle and was able to defeat Scorpia herself. She also participated in another battle against Spider-Man with some of her former allies, and new ones such as Boomerang and Jack O' Lantern. She was defeated when Spider-Man threw Jack O'Lantern at her.