On 11 July 2010, Nenê joined Paris Saint-Germain F.C. in a deal believed to be around €5.5 million. "I'm very happy to have signed for Paris," the player told PSG's official website, adding: "Like PSG, I'm hoping to have a big league season and to pull something off in the Europa League". He scored in his first official appearance, a 3–1 home win against AS Saint-Étienne, adding two on 11 September against newly promoted AC Arles-Avignon (4–0, home). Halfway through the season he had already registered 13 goals, making him the third-highest scorer only behind Moussa Sow and Kevin Gameiro; his displays, free-kick ability and attacking flair earned him comparisons with Ronaldinho, a compatriot who played at the Parc des Princes earlier in the decade, but he only scored one more goal until the end of the campaign, with PSG finally finishing fourth.