In 2006, shortly after the World Cup, there was speculation of a move to Germany, more specifically Hannover. He ended all rumours in August 2006 by signing a one-season loan deal with PSV Eindhoven, which was followed by a contract for three and a half years which would tie him to the Philips Stadion outfit until 2010. He made his debut in the Eredivisie against Willem II, and marked his stamp in his new club by scoring two goals for a 3-1 win. The following week he became the first Ecuadorian to play in the UEFA Champions League and made his debut against Liverpool F.C.. He was voted Man of the Match in the game.