The breakdown of dioxin requires exposure of the molecular ring to a sufficiently high temperature so as to trigger thermal breakdown of the strong molecular bonds holding it together. Small pieces of fly ash may be somewhat thick, and too brief an exposure to high temperature may only degrade dioxin on the surface of the ash. For a large volume air chamber, too brief an exposure may also result in only some of the exhaust gases reaching the full breakdown temperature. For this reason there is also a time element to the temperature exposure to ensure heating completely through the thickness of the fly ash and the volume of waste gases.