In 1965, Smith matriculated at Mount Holyoke College, where she was one of the few Black students. She quickly became involved with the Civil Actions Group, which, among other issues, was involved in organizing against the Vietnam War. Although Mount Holyoke did not have a Students for Democratic Society (SDS) chapter on campus, Smith and other Mount Holyoke students admired and imitated the group's efforts. During her year at the New School for Social Research, Smith traveled to Chicago and participated in the protests accompanying the Democratic National Convention.