The Lithuanian squad featured returning Olympic medalists: discus thrower Virgilijus Alekna, trap shooter Daina Gudzinevičiūtė, and the men's basketball team, being led by team captain Saulius Štombergas, who later became the nation's flag bearer in the opening ceremony. Along with Alekna, Stombergas, and Gudzineviciute, road cyclists and twin sisters Jolanta and Rasa Polikevičiūtė and javelin thrower Rita Ramanauskaitė made their third Olympic appearances as the most experienced members of the team. Other notable Lithuanian athletes included Stombergas' teammate and NBA basketball star Darius Songaila, track cyclist Simona Krupeckaitė, and two-time world champion Andrejus Zadneprovskis in men's modern pentathlon.