Coal-burning MHDs have intensely corrosive environments with slag. The slag both protects and corrodes MHD materials. In particular, migration of oxygen through the slag accelerates corrosion of metallic anodes. Nonetheless, very good results have been reported with stainless steel electrodes at 900K. Another, perhaps superior option is a spinel ceramic, FeAl2O4 - Fe3O4. The spinel was reported to have electronic conductivity, absence of a resistive reaction layer but with some diffusion of iron into the alumina. The diffusion of iron could be controlled with a thin layer of very dense alumina, and water cooling in both the electrodes and alumina insulators.