In 2003, Tchité arrived in Liège, where he became a regular member of the first team, scoring 21 goals in 58 matches during his three years with the club. In 2005–06 season, he netted 16 times in the Belgian First Division to help his team finish as runners-up to R.S.C. Anderlecht, and that tally put him second in the goalscoring list behind only Tosin Dosunmu of K.F.C. Germinal Beerschot; at the end of the following campaign, he was named Belgium's Professional Footballer of the Year, also being the recipient of the Belgian Ebony Shoe.