ACEVO's membership is primarily drawn from England and Wales, (third sector leaders in Scotland or Northern Ireland can join ACOSVO or CO3 respectively). Full members are CEOs (or equivalent) at charities and social enterprises. Associate membership is offered to anyone with an interest in sector leadership, including chairs and trustees (but excluding for-profit organisations), and aspiring CEOs join as senior leader members. Private organisations wishing to support and work with the sector may become part of the network as commercial partners.