During Dionne's time with the Los Angeles Kings, he played eleven and a half seasons and formed the famed "Triple Crown Line", centring Charlie Simmer and Dave Taylor. Despite Dionne's production during the regular season, he was frustrated with the Kings' lack of playoff success; they made the postseason from 1976–82 but only advanced to the second round three times for a total of 43 playoff games. During the 1986–87 season, Dionne mentored the rookies of the Kings as Mickey Redmond had mentored him during his rookie years in Detroit. He took eventual Calder Trophy winner Luc Robitaille, Jimmy Carson and Steve Duchesne under his wing.