Ali started working on her debut solo album soon after leaving iiO, a process which took her four years. Her first solo release was the 2006 single, "Who is Watching?", a collaboration with Dutch DJ Armin van Buuren, which appeared on his album "Shivers". This was followed by "Something to Lose" in 2006, a duet with singer Rosko, produced by John Creamer & Stephane K and released by Ultra Records. The track was licensed to Roger Sanchez's "Release Yourself, Vol. 5", as well as Sharam Tayebi of Deep Dish for his Global Underground debut "Dubai".