On 17 February 2012, Cavani scored two goals against Fiorentina, helping Napoli go in fifth place ahead of Internazionale. On 21 February, Cavani scored the second goal against Chelsea in the Champions League round of 16 first leg in Naples. He also provided the assists for both of Ezequiel Lavezzi's goals that game. Napoli subsequently went on to win this game 3–1. Following Napoli's exit from the Champions League at the hands of Chelsea, Cavani scored two goals against Udinese in the last ten minutes to earn a much-needed draw to keep Napoli in the hunt for the last Champions League qualifying spot. A few days later, he converted a fantastic counter-attack against Siena to book Napoli a place in the Coppa Italia final. On 21 April, he celebrated his 200th career league appearance by scoring in a 2–0 win against Novara. Cavani finished the league season with 23 goals, tied for third on the goal scoring charts with Udinese striker Antonio Di Natale. On 20 May, Cavani scored a penalty against Juventus in the 2012 Coppa Italia final at the Stadio Olimpico, Rome, which Napoli won 2–0. Cavani finished the tournament as the top goalscorer, with five goals.