In cooling systems of nuclear reactors, the formation of free oxygen would promote corrosion and is counteracted by addition of hydrogen to the cooling water. The hydrogen is not consumed as for each molecule reacting with oxygen one molecule is liberated by radiolysis of water; the excess hydrogen just serves to shift the reaction equilibriums by providing the initial hydrogen radicals. The reducing environment in pressurized water reactors is less prone to buildup of oxidative species. The chemistry of boiling water reactor coolant is more complex, as the environment can be oxidizing. Most of the radiolytic activity occurs in the core of the reactor where the neutron flux is highest; the bulk of energy is deposited in water from fast neutrons and gamma radiation, the contribution of thermal neutrons is much lower. In air-free water, the concentration of hydrogen, oxygen, and hydrogen peroxide reaches steady state at about 200 Gy of radiation. In presence of dissolved oxygen, the reactions continue until the oxygen is consumed and the equilibrium is shifted. Neutron activation of water leads to buildup of low concentrations of nitrogen species; due to the oxidizing effects of the reactive oxygen species, these tend to be present in the form of nitrate anions. In reducing environments, ammonia may be formed. Ammonia ions may be however also subsequently oxidized to nitrates. Other species present in the coolant water are the oxidized corrosion products (e.g. chromates) and fission products (e.g. pertechnetate and periodate anions, uranyl and neptunyl cations). Absorption of neutrons in hydrogen nuclei leads to buildup of deuterium and tritium in the water.