The thermal diffusion process was based on Sydney Chapman and David Enskog's theory, which explained that when a mixed gas passes through a temperature gradient, the heavier one tends to concentrate at the cold end and the lighter one at the warm end. Since hot gases tend to rise and cool ones tend to fall, this can be used as a means of isotope separation. This process was first demonstrated by Klaus Clusius and Gerhard Dickel in Germany in 1938. It was developed by US Navy scientists, but was not one of the enrichment technologies initially selected for use in the Manhattan Project. This was primarily due to doubts about its technical feasibility, but the inter-service rivalry between the Army and Navy also played a part.