For the 1995–96 season, Nedvěd was on the move again, this time dealt to the Pittsburgh Penguins in a blockbuster trade. In Pittsburgh, Nedvěd would have the best years of his career on an offensive team featuring superstars Mario Lemieux, Jaromir Jagr, and Ron Francis. In his first year in Pittsburgh, he recorded career highs of 45 goals and 99 points, and also put his playoff demons behind him by scoring 20 points in helping the Penguins reach the conference finals. Included in that was a monumental goal against the Washington Capitals in a quadruple-overtime thriller, which at 79:15 of OT was at the time the longest NHL game in 60 years. During the 1996–97 season, he enjoyed another solid year, finishing with 33 goals and 71 points.