Molina's two older brothers, Bengie and José Molina, played a combined 28 seasons in the major leagues. Each of the three brothers has won at least one World Series ring, making them the only trio of brothers with such a distinction (Bengie and José both won their first while with the Anaheim Angels in 2002). They are also the only trio of brothers to play as catchers in the major leagues. Of a total of nineteen trios of brothers who have played in the Major Leagues – including the DiMaggios and the Cruzes – only one other trio of brothers has all appeared in a World Series: Matty, Félipe and Jesús Alou.