In 2006, Ng released her solo debut album ""With A Boy like You"". Her song 「愛你變成恨你」won her her first Commercial Radio Hong Kong Top Ten Gold Songs award. At the time, Ng had made a record of being the youngest female singer who had ever been awarded with a Top Ten Gold Song award from CRHK at the age of 20; she had kept this record until 2012, when Kimberley Chen, a Taiwanese singer, won a Top Ten Gold Song award from CRHK at the age of 18.