On July 7, he was selected to his seventh consecutive All-Star Game, played at Great American Ball Park in Cincinnati. In the Reds' clubhouse for the All-Star Game, Molina shared a locker with Reds' second baseman Brandon Phillips. Since the brawl between the Cardinals and Reds in 2010, the two mended their schism, and Molina has a photograph of their families together. When informed whose locker he was using, Molina replied, "This is Phillips' locker? How about that? I'll have to write something to him." While the pregame roster introductions were made, Reds fans booed all six Cardinals players who were selected, and even former Cardinal Albert Pujols. When Molina was introduced, he smiled and turned and pointed his thumbs toward the back of his jersey. Pujols provided levity when he then joined in the booing. After the game, Molina remarked to reporters, "when you spend 12 years coming to Cincinnati and you beat them so many times, they’re going to boo you." In his career to that point, he hit .319 with a .352 on-base percentage and .500 slugging percentage in 270 career at-bats at Great American Ball Park.