With Molina as the starting catcher in 2013, Puerto Rico earned the silver medal. Edwin Rodríguez, who had scouted Molina in Puerto Rico before the Cardinals signed him, became the manager for the 2013 squad. Shortly after learning he would be the 2013 manager, Rodríguez contacted Molina for input on constructing the roster. Molina prepared for the Classic by playing 14 games for the winter league team in Puerto Rico Rodríguez managed. Molina was voted on the All-World Baseball Classic team for the first time.