A process for forming an ultrafine particle film 1, 2, 3 and 4, wherein the ultrafine particles used in the second layer among {HEAD ~ the layers} formed on {TAIL ~ the substrate} to constitute the ultrafine particle film are selected from the group consisting of SiO2 and MgF2  
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A process for forming an ultrafine particle film 1 , 2 , 3 and 4 , wherein the ultrafine particles used in the second layer among { HEAD ~ the layers } formed on { TAIL ~ the substrate } to constitute the ultrafine particle film are selected from the group consisting of SiO2 and MgF2
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