Compositions and methods based on the use of {HEAD ~ fluoroalkene} containing from 3 to 4 carbon atoms and at least one carbon carbon double bond, such as HFO 1214, {TAIL ~ HFO HFO} 1233, or HFO 1354, having properties highly beneficial in foaming and blowing agent applications, articles and methods 
such as
Compositions and methods based on the use of { HEAD ~ fluoroalkene } containing from 3 to 4 carbon atoms and at least one carbon carbon double bond , such as HFO 1214 , { TAIL ~ HFO HFO } 1233 , or HFO 1354 , having properties highly beneficial in foaming and blowing agent applications , articles and methods
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