In one aspect, a method for rapid analysis of charged metabolites or metabolites that contain, or may be induced to contain, a charge through the generation of suites of {HEAD ~ analyte matrix interactions} that enable {TAIL ~ the performance} of high throughput metabolomics without the use of chromatography is provided 
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In one aspect , a method for rapid analysis of charged metabolites or metabolites that contain , or may be induced to contain , a charge through the generation of suites of { HEAD ~ analyte matrix interactions } that enable { TAIL ~ the performance } of high throughput metabolomics without the use of chromatography is provided
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