A process for forming an ultrafine particle film 1, 2, 3 and 4, wherein the ultrafine particles used in the second layer among the layers formed on the substrate to constitute the ultrafine particle film are selected from {HEAD ~ the group} consisting of {TAIL ~ SiO2} and MgF2  
A process for forming an ultrafine particle film 1 , 2 , 3 and 4 , wherein the ultrafine particles used in the second layer among the layers formed on the substrate to constitute the ultrafine particle film are selected from { HEAD ~ the group } consisting of { TAIL ~ SiO2 } and MgF2
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