What are Lithium, Sodium, Potassium, Rubidium and Caesium?
Alkali metal oxides (containing the O ion), peroxides (containing the ion, where there is a single bond between the two oxygen atoms), superoxides (containing the ion), and many others. Lithium burns in air to form lithium oxide, but sodium reacts with oxygen to form a mixture of sodium oxide and sodium peroxide. Potassium forms a mixture of potassium peroxide and potassium superoxide, while rubidium and caesium form the superoxide exclusively. Their reactivity increases going down the group: while lithium, sodium and potassium merely burn in air, rubidium and caesium are pyrophoric (spontaneously catch fire in air). The smaller alkali metals tend to
Rubidium metal reacts violently with water. As with potassium (which is slightly less reactive) and caesium (which is slightly more reactive), this reaction is usually vigorous enough to ignite the hydrogen gas it produces. Rubidium has also been reported to ignite spontaneously in air. It forms amalgams with mercury and alloys with gold, iron, caesium, sodium, and potassium, but not lithium (even though rubidium and lithium are in the same group). Rubidium has a very low ionization energy of only 406 kJ/mol. Rubidium and potassium show a very similar purple color in the flame test, and distinguishing the two elements requires