Ethyl sulfate process in which ethylene is reacted with sulfuric acid to produce ethyl sulfate followed by hydrolysis, but this method has been mostly replaced by direct hydration of ethylene. Ethyl sulfate can be produced in a laboratory setting by reacting ethanol with sulfuric acid under a gentle boil, while keeping the reaction below 140 °C. The sulfuric acid must be added dropwise or the reaction must be actively cooled because the reaction itself is highly exothermic. If the temperature exceeds 140 °C, the ethyl sulfate product tends to react with residual ethanol starting material, producing diethyl ether. If the temperature exceeds
Ethyl group to polystyrene. Approximately 24.7 million tons of ethylbenzene were produced in 1999. Many ethyl-containing compounds are generated by electrophilic ethylation, i.e. treatment of nucleophiles with sources of Et. Triethyloxonium tetrafluoroborate [EtO]BF is such a reagent. For good nucleophiles, less electrophilic reagents are employed, such as ethyl halides. In unsymmetrical ethylated compounds, the methylene protons in the ethyl substituent are diastereotopic. Chiral reagents are known to stereoselectively modify such substituents. The name of the group is derived from the Aether, the first-born Greek elemental god of air (and at that time a general term for any highly volatile compound) and "hyle",