History of universities in Scotland perhaps the first of their kind in the world. His students founded practical chemistry at Aberdeen soon after. William Thomson, 1st Baron Kelvin was appointed to the chair of natural philosophy at Glasgow aged only 22. His work included the mathematical analysis of electricity and formulation of the first and second laws of thermodynamics. By 1870 Kelvin and Rankine had made Glasgow the leading centre of science and engineering education and investigation in Britain. At Edinburgh, major figures included David Brewster (1781–1868), who made contributions to the science of optics and to the development of photography. Fleeming Jenkin (1833–85) was
First law of thermodynamics process at constant pressure, the heat used to produce expansion is universally interconvertible with work", but this is not a general statement of the first law. The original nineteenth century statements of the first law of thermodynamics appeared in a conceptual framework in which transfer of energy as heat was taken as a primitive notion, not defined or constructed by the theoretical development of the framework, but rather presupposed as prior to it and already accepted. The primitive notion of heat was taken as empirically established, especially through calorimetry regarded as a subject in its own right, prior to thermodynamics.