Liquid metal cooled reactor Clementine was the first liquid metal cooled nuclear reactor and used mercury coolant, thought to be the obvious choice since it is liquid at room temperature. However, because of disadvantages including high toxicity, high vapor pressure even at room temperature, low boiling point, producing noxious fumes when heated, relatively low thermal conductivity, and a high neutron cross-section, it has fallen out of favor. Sodium and NaK (a eutectic sodium-potassium alloy) do not corrode steel to any significant degree and are compatible with many nuclear fuels, allowing for a wide choice of structural materials. They do, however, ignite spontaneously on contact
Liquid metal cooled reactor presents safety and maintenance issues that liquid metal designs lack. Additionally, the high temperature of the liquid metal can be used to produce vapour at higher temperature than in a water cooled reactor, leading to a higher thermodynamic efficiency. This makes them attractive for improving power output in conventional nuclear power plants. Liquid metals, being electrically highly conductive, can be moved by electromagnetic pumps. Disadvantages include difficulties associated with inspection and repair of a reactor immersed in opaque molten metal, and depending on the choice of metal, fire hazard risk (for alkali metals), corrosion and/or production of radioactive activation products