Liquid metal cooled reactor Clementine was the first liquid metal cooled nuclear reactor and used mercury coolant, thought to be the obvious choice since it is liquid at room temperature. However, because of disadvantages including high toxicity, high vapor pressure even at room temperature, low boiling point, producing noxious fumes when heated, relatively low thermal conductivity, and a high neutron cross-section, it has fallen out of favor. Sodium and NaK (a eutectic sodium-potassium alloy) do not corrode steel to any significant degree and are compatible with many nuclear fuels, allowing for a wide choice of structural materials. They do, however, ignite spontaneously on contact
Liquid metal embrittlement is seen in cases where alloy additions elements have saturated the grain boundaries of the solid metal. The hardness and deformation behaviour of the solid metal affect its susceptibility to LME. Generally, harder metals are more severely embrittled. Grain size greatly influences LME. Solids with larger grains are more severely embrittled and the fracture stress varies inversely with the square root of grain diameter. Also the brittle to ductile transition temperature is increased by increasing grain size. The interfacial energy between the solid and liquid metals and the grain boundary energy of the solid metal greatly influence LME. These energies