Law of multiple proportions example of the law can be seen by comparing ethane (CH) with propane (CH). The weight of hydrogen which combines with 1 g carbon is 0.252 g in ethane and 0.224 g in propane. The ratio of those weights is 1.125, which can be expressed as the ratio of two small numbers 9:8. The law of multiple proportions is best demonstrated using simple compounds. For example, if one tried to demonstrate it using the hydrocarbons decane (chemical formula CH) and undecane (CH), one would find that 100 grams of carbon could react with 18.46 grams of hydrogen to produce decane
Law of multiple proportions or with 18.31 grams of hydrogen to produce undecane, for a ratio of hydrogen masses of 121:120, which is hardly a ratio of "small" whole numbers. The law fails with non-stoichiometric compounds and also doesn't work well with polymers and oligomers. Law of multiple proportions In chemistry, the law of multiple proportions is one of the basic laws of stoichiometry used to establish the atomic theory, alongside the law of conservation of mass (matter) and the law of definite proportions. It is sometimes called Dalton's Law after its discoverer, the British chemist John Dalton, who published it in the first