Liquid metal cooled reactor Clementine was the first liquid metal cooled nuclear reactor and used mercury coolant, thought to be the obvious choice since it is liquid at room temperature. However, because of disadvantages including high toxicity, high vapor pressure even at room temperature, low boiling point, producing noxious fumes when heated, relatively low thermal conductivity, and a high neutron cross-section, it has fallen out of favor. Sodium and NaK (a eutectic sodium-potassium alloy) do not corrode steel to any significant degree and are compatible with many nuclear fuels, allowing for a wide choice of structural materials. They do, however, ignite spontaneously on contact
Metal halides it a liquid at room temperature. They are usually insoluble in water, but soluble in organic solvent. Polymeric metal halides generally have melting and boiling points that are higher than monomeric metal halides, but lower than ionic metal halides. They are soluble only in the presence of a ligand which liberates discrete units. For example, palladium chloride is quite insoluble in water, but it dissolves well in concentrated sodium chloride solution: Palladium chloride is insoluble in most organic solvents, but it forms soluble monomeric units with acetonitrile and benzonitrile: The tetrahedral tetrahalides of the first-row transition metals are prepared by