Carbon–hydrogen bond activation a C-H activation. Carbon–hydrogen bond activation Carbon–hydrogen bond functionalization (C–H functionalization) is a type of reaction in which a carbon–hydrogen bond is cleaved and replaced with a carbon-X bond (where X is usually carbon, oxygen, or nitrogen). The term usually implies that a transition metal is involved in the C-H cleavage process. Reactions classified by the term typically involve the hydrocarbon first to react with a metal catalyst to create an organometallic complex in which the hydrocarbon is coordinated to the inner-sphere of a metal, either via an intermediate "alkane or arene complex" or as a transition state leading to
Carbon diselenide Carbon diselenide Carbon diselenide is an inorganic compound with the chemical formula CSe. It is a yellow-orange oily liquid with pungent odor. It is an analogue of carbon disulfide (CS). This light-sensitive compound is insoluble in water and soluble in organic solvents. Carbon diselenide is a linear molecule with D symmetry. It is produced by reacting selenium powder with dichloromethane vapor near 550 °C. It was first reported by Grimm and Metzger, who prepared it by treating hydrogen selenide with carbon tetrachloride in a hot tube. Like carbon disulfide, carbon diselenide polymerizes under high pressure. The structure of the polymer