Hydrogen production because it is more efficient than separate hydrogen, steam and power plants. Air Products recently built an integrated steam reforming / co-generation plant in Port Arthur, Texas. Hydrogen production from natural gas or other hydrocarbons is achieved by partial oxidation. A fuel-air or fuel-oxygen mixture is partially combusted resulting in a hydrogen rich syngas. Hydrogen and carbon monoxide are obtained via the water-gas shift reaction. Carbon dioxide can be co-fed to lower the hydrogen to carbon monoxide ratio. The partial oxidation reaction occurs when a substoichiometric fuel-air mixture or fuel-oxygen is partially combusted in a reformer or partial oxidation reactor.
Carbon–hydrogen bond activation substitution at the carbon also greatly affects selectivity; the secondary methylene position is preferred over the terminal methylene position because the former has a secondary carbon while the latter has a primary one. In the oxidation of cyclohexane compound, the tertiary site on the ring is preferential over the tertiary site of the isopropyl substituent. The two methyl groups hinder the oxidation on the isopropyl group, making the less hindered cyclohexyl site more favorable. In contrast to innate selectivity, guided selectivity results from external reagents or directing groups affecting the nature of specific C-H bonds. The figure above demonstrates the