Water of crystallization degree of hydration can be critical to the resulting chemical properties. For example, anhydrous RhCl is not soluble in water and is relatively useless in organometallic chemistry whereas RhCl•3HO is versatile. Similarly, hydrated AlCl is a poor Lewis acid and thus inactive as a catalyst for Friedel-Crafts reactions. Samples of AlCl must therefore be protected from atmospheric moisture to preclude the formation of hydrates. Crystals of hydrated copper(II) sulfate consist of [Cu(HO)] centers linked to SO ions. Copper is surrounded by six oxygen atoms, provided by two different sulfate groups and four molecules of water. A fifth water resides elsewhere
Chemical compound covalent bonds, salts held together by ionic bonds, intermetallic compounds held together by metallic bonds, or the subset of chemical complexes that are held together by coordinate covalent bonds. Pure chemical elements are generally not considered chemical compounds, failing the two or more atom requirement, though they often consist of molecules composed of multiple atoms (such as in the diatomic molecule H, or the polyatomic molecule S, etc.). Many chemical compounds have a unique numerical identifier assigned by the Chemical Abstracts Service (CAS): its CAS number. There is varying and sometimes inconsistent nomenclature differentiating substances, which include truly non-stoichiometric examples,