Volta potential by its work function, and so dissimilar metals can show an electric potential difference even at equilibrium. The Volta potential is "not" an intrinsic property of the two bulk metals under consideration, but rather is determined by work function differences between the metals' surfaces. Just like the work function, the Volta potential depends sensitively on surface state, contamination, and so on. The potential is given by the formula: formula_1, where V is the potential, The Volta potential can be significant (of order 1 volt) but it cannot be measured directly by an ordinary voltmeter. A voltmeter does not measure vacuum
Output impedance order of 1 ohm. When there is a current through a cell, the measured e.m.f. is lower than when there is no current delivered by the cell. The reason for this is that part of the available energy of the cell is used up to drive charges through the cell. This energy wasted by the so-called "internal resistance" of that cell. This wasted energy shows up as lost voltage. Internal resistance is r = (E − V)/I . Output impedance The output impedance of an electrical network is the measure of the opposition to current flow (impedance), both static (resistance)