Ethyl acetate ethanol to acetaldehyde, which leaves the wine with a sharp vinegar-like taste. In the field of entomology, ethyl acetate is an effective asphyxiant for use in insect collecting and study. In a killing jar charged with ethyl acetate, the vapors will kill the collected insect quickly without destroying it. Because it is not hygroscopic, ethyl acetate also keeps the insect soft enough to allow proper mounting suitable for a collection. Ethyl acetate can be hydrolyzed in acidic or basic conditions to regain acetic acid and ethanol. The use of an acid catalyst accelerates the hydrolysis, which is subject to the
Ethyl cyanohydroxyiminoacetate to HOAt without presenting an explosion risk such as the benzotriazoles. With water-soluble derivatives of ethyl cyanohydroxyiminoacetate (glyceroacetonide-oxyma) as additive and DIC as coupling reagent even in weakly basic aqueous solutions the linking of protected amino acids to oligopeptides is possible with a yield of 95% and a diastereomeric excess of> 99% using the model substances Z-"L"-Phg-OH and "L"-H-Pro-NH. In the coupling of amino acids, frequently occurring secondary reactions largely suppressed, which would be the formation of symmetrical acid anhydrides, racemization and epimerization and the cyclization to oxazolinones or - especially for dipeptides - to 2,5-diketopiperazines. Ethyl cyanohydroxyiminoacetate Ethyl cyanohydroxyiminoacetate