Potassium ethyl xanthate Potassium ethyl xanthate Potassium ethyl xanthate (KEX) is an organosulfur compound with the chemical formula CHCHOCSK. It is a pale yellow powder that is used in the mining industry for the separation of ores. Unlike the related sodium ethyl xanthate, the potassium salt exists as an anhydrous salt. Xanthate salts are prepared by the action of alkoxides on carbon disulfide. The alkoxide is often generated in situ from potassium hydroxide: Potassium ethyl xanthate is a pale yellow powder that is stable at high pH but rapidly hydrolyses at pH <9 at 25 °C. Unlike the sodium derivative, potassium xanthate crystallizes
Ethyl carbamate Another important mechanism for ethyl carbamate formation in alcoholic beverages is the reaction from cyanide as precursor, which causes comparably high levels in spirits derived from cyanogenic plants (i.e. predominantly stone-fruit spirits and cachaça). Ethyl carbamate is not acutely toxic to humans, as reflected by its use as a medicine. Acute toxicity studies show that the lowest fatal dose in rats, mice, and rabbits equals 1.2 grams/kg or more. When ethyl carbamate was used medicinally, about 50 percent of the patients exhibited nausea and vomiting, and long time use led to gastroenteric hemorrhages. The compound has almost no odor and