Carbon dioxide in Earth's atmosphere initial carbon dioxide in the atmosphere of the young Earth was produced by volcanic activity, modern volcanic activity releases only 130 to 230 megatonnes of carbon dioxide each year. These natural sources are nearly balanced by natural sinks, physical and biological processes which remove carbon dioxide from the atmosphere. For example, some is directly removed from the atmosphere by land plants for photosynthesis and it is soluble in water forming carbonic acid. There is a large natural flux of into and out of the biosphere and oceans. In the pre-industrial era these fluxes were largely in balance. Currently about 57%
Carbon dioxide stretching mode at 1388 cm which is only observed in the Raman spectrum. Carbon dioxide is soluble in water, in which it reversibly forms (carbonic acid), which is a weak acid since its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is formula_1 (at 25 °C). Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as molecules, not affecting the pH. The relative concentrations of , and the deprotonated forms (bicarbonate) and (carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH