Carbon dioxide basic water illustrates this property, in which case hydroxide is the nucleophile. Other nucleophiles react as well. For example, carbanions as provided by Grignard reagents and organolithium compounds react with to give carboxylates: In metal carbon dioxide complexes, serves as a ligand, which can facilitate the conversion of to other chemicals. The reduction of to CO is ordinarily a difficult and slow reaction: Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from absorbed from the air and water: The redox potential for this reaction near pH 7 is about −0.53 V "versus" the
Carbon dioxide removal need atmospheric reduction of 50 ppm plus an additional 2 ppm per year of current emissions. Carbon dioxide removal is different from reducing emissions, as the former produces an outlet of carbon dioxide from Earth's atmosphere, whereas the latter decreases the inlet of carbon dioxide to the atmosphere. Both have the same net effect, but for achieving carbon dioxide concentration levels below present levels, carbon dioxide removal is critical. Also for meeting higher concentration levels, carbon dioxide removal is increasingly considered to be crucial as it provides the only possibility to fill the gap between needed reductions to meet mitigation