Calcium carbonate equilibrium pressure must exceed total atmospheric pressure of 101 kPa, which happens at 898 °C. Calcium carbonate is poorly soluble in pure water (47 mg/L at normal atmospheric CO partial pressure as shown below). The equilibrium of its solution is given by the equation (with dissolved calcium carbonate on the right): where the solubility product for [Ca] [CO] is given as anywhere from "K" = 3.7×10 to "K" = 8.7×10 at 25 °C, depending upon the data source. What the equation means is that the product of molar concentration of calcium ions (moles of dissolved Ca per liter of solution)
Calcium chlorate complicated by calcium hydroxide depositing on the cathode, preventing the flow of current. When concentrated solutions of calcium chlorate and potassium chloride are combined, potassium chlorate precipitates: This is the second step of the Liebig process for the manufacture of potassium chlorate. Solutions of calcium chlorate react with solutions of alkali carbonates to give a precipitate of calcium carbonate and the alkali chlorate in solution: On strong heating, calcium chlorate decomposes to give oxygen and calcium chloride: Cold, dilute solutions of calcium chlorate and sulfuric acid react to give a precipitate of calcium sulfate and chloric acid in solution: Contact