Gas laws 1662 Robert Boyle studied the relationship between volume and pressure of a gas of fixed amount at constant temperature. He observed that volume of a given mass of a gas is inversely proportional to its pressure at a constant temperature. Boyle's law, published in 1662, states that, at constant temperature, the product of the pressure and volume of a given mass of an ideal gas in a closed system is always constant. It can be verified experimentally using a pressure gauge and a variable volume container. It can also be derived from the kinetic theory of gases: if a container,
Molar volume sample is a mixture containing "N" components, the molar volume is complex. It can be simply the sum of the individual components, and calculated using: But this is violated by many liquid-liquid mixtures. For instance mixing pure ethanol into pure water causes a "decrease" in the volume calculated by this formula. This effect is called "excess volume". For ideal gases, the molar volume is given by the ideal gas equation; this is a good approximation for many common gases at standard temperature and pressure. The ideal gas equation can be rearranged to give an expression for the molar volume of