Ocean storage of carbon dioxide ocean waters in order to increase carbon dioxide (CO2) uptake from the atmosphere, possibly resulting in mitigating its global warming effects. Iron is a trace element in ocean and its presence is vital for photosynthesis in plants, and in particular phytoplanktons, as It has been shown that iron deficiency can limit ocean productivity and phytoplankton growth. For this reason, “iron hypothesis” was put forward by Martin in late 1980s where he suggested that changes in iron supply in iron-deficient ocean-waters can bloom plankton growth and have a significant effect on the concentrations of atmospheric carbon dioxide by altering rates of
Carbon dioxide stretching mode at 1388 cm which is only observed in the Raman spectrum. Carbon dioxide is soluble in water, in which it reversibly forms (carbonic acid), which is a weak acid since its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is formula_1 (at 25 °C). Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as molecules, not affecting the pH. The relative concentrations of , and the deprotonated forms (bicarbonate) and (carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH