Calcium carbonate equilibrium pressure must exceed total atmospheric pressure of 101 kPa, which happens at 898 °C. Calcium carbonate is poorly soluble in pure water (47 mg/L at normal atmospheric CO partial pressure as shown below). The equilibrium of its solution is given by the equation (with dissolved calcium carbonate on the right): where the solubility product for [Ca] [CO] is given as anywhere from "K" = 3.7×10 to "K" = 8.7×10 at 25 °C, depending upon the data source. What the equation means is that the product of molar concentration of calcium ions (moles of dissolved Ca per liter of solution)
Calcium citrate sulfuric acid. In many individuals, bioavailability of calcium citrate is found to be equal to that of the cheaper calcium carbonate. However, alterations to the digestive tract may change how calcium is digested and absorbed. Unlike calcium carbonate, which is basic and neutralizes stomach acid, calcium citrate has no effect on stomach acid. Calcium carbonate is harder to digest than calcium citrate, and calcium carbonate carries a risk of "acid rebound" (the stomach overcompensates by producing more acid), so individuals who are sensitive to antacids or who have difficulty producing adequate stomach acid may choose calcium citrate over calcium carbonate