Gas laws 1662 Robert Boyle studied the relationship between volume and pressure of a gas of fixed amount at constant temperature. He observed that volume of a given mass of a gas is inversely proportional to its pressure at a constant temperature. Boyle's law, published in 1662, states that, at constant temperature, the product of the pressure and volume of a given mass of an ideal gas in a closed system is always constant. It can be verified experimentally using a pressure gauge and a variable volume container. It can also be derived from the kinetic theory of gases: if a container,
Internal energy the translational energy of the individual atoms. Monatomic particles do not rotate or vibrate, and are not electronically excited to higher energies except at very high temperatures. Therefore, internal energy changes in an ideal gas may be described solely by changes in its kinetic energy. Kinetic energy is simply the internal energy of the perfect gas and depends entirely on its pressure, volume and thermodynamic temperature. The internal energy of an ideal gas is proportional to its mass (number of moles) "n" and to its temperature "T" where "c" is the heat capacity (at constant volume) of the gas. The