Carbon dioxide basic water illustrates this property, in which case hydroxide is the nucleophile. Other nucleophiles react as well. For example, carbanions as provided by Grignard reagents and organolithium compounds react with to give carboxylates: In metal carbon dioxide complexes, serves as a ligand, which can facilitate the conversion of to other chemicals. The reduction of to CO is ordinarily a difficult and slow reaction: Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from absorbed from the air and water: The redox potential for this reaction near pH 7 is about −0.53 V "versus" the
Carbon dioxide clathrate Carbon dioxide clathrate Carbon dioxide hydrate is a snow-like crystalline substance composed of water ice and carbon dioxide. It normally is a Type I gas clathrate. However, there has been some experimental evidence for the development of a metastable Type II phase at A temperature near the ice melting point. The clathrate can exist below 283K (10 °C) at a range of pressures of carbon dioxide. It is quite likely to be important on Mars due to the presence of carbon dioxide and ice at low temperatures. The first evidence for the existence of CO hydrates dates back to the