Steam digester Torricelli and further developed by German scientist Otto von Guericke with his Magdeburg hemispheres. Guerike's demonstration was documented by Gaspar Schott, in a book that was read by Robert Boyle. Boyle and his assistant Robert Hooke improved Guericke's air pump design and built their own. From this, through various experiments, they formulated what is called Boyle's law, which states that the volume of a body of an ideal gas is inversely proportional to its pressure. Soon the ideal gas law was formulated. Based on these concepts in 1679 a Boyle's associate, named Denis Papin, built a "bone digester", which is
Molar volume sample is a mixture containing "N" components, the molar volume is complex. It can be simply the sum of the individual components, and calculated using: But this is violated by many liquid-liquid mixtures. For instance mixing pure ethanol into pure water causes a "decrease" in the volume calculated by this formula. This effect is called "excess volume". For ideal gases, the molar volume is given by the ideal gas equation; this is a good approximation for many common gases at standard temperature and pressure. The ideal gas equation can be rearranged to give an expression for the molar volume of