Fractionation of carbon isotopes in oxygenic photosynthesis characterization of food chains. Oxygenic photosynthesis is a metabolic pathway facilitated by autotrophs, including plants, algae, and cyanobacteria. This pathway converts inorganic carbon dioxide from the atmosphere or aquatic environment into carbohydrates, using water and energy from light, then releases molecular oxygen as a product. Organic carbon contains less of the stable isotope Carbon-13, or C, relative to the initial inorganic carbon from the atmosphere or water because photosynthetic carbon fixation involves several fractionating reactions with kinetic isotope effects. These reactions undergo a kinetic isotope effect because they are limited by overcoming an activation energy barrier. The lighter isotope has
Electrochemical reduction of carbon dioxide carbon monoxide (CO). In carbon fixation, plants convert carbon dioxide into sugars, from which many biosynthetic pathways originate. The catalyst responsible for this conversion, RuBisCo, is the most common protein on earth. Some anaerobic organisms employ enzymes to convert CO to carbon monoxide, from which fatty acids can be made. In industry, a few products are made from CO, including urea, salicylic acid, methanol, and certain inorganic and organic carbonates. In the laboratory, carbon dioxide is sometimes used to prepare carboxylic acids. No electrochemical process involving CO has been commercialized. The electrochemical reduction of carbon dioxide to CO is usually