Carbon dioxide in Earth's atmosphere initial carbon dioxide in the atmosphere of the young Earth was produced by volcanic activity, modern volcanic activity releases only 130 to 230 megatonnes of carbon dioxide each year. These natural sources are nearly balanced by natural sinks, physical and biological processes which remove carbon dioxide from the atmosphere. For example, some is directly removed from the atmosphere by land plants for photosynthesis and it is soluble in water forming carbonic acid. There is a large natural flux of into and out of the biosphere and oceans. In the pre-industrial era these fluxes were largely in balance. Currently about 57%
Carbon dioxide from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans. While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm, as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the