Calcium carbonate equilibrium pressure must exceed total atmospheric pressure of 101 kPa, which happens at 898 °C. Calcium carbonate is poorly soluble in pure water (47 mg/L at normal atmospheric CO partial pressure as shown below). The equilibrium of its solution is given by the equation (with dissolved calcium carbonate on the right): where the solubility product for [Ca] [CO] is given as anywhere from "K" = 3.7×10 to "K" = 8.7×10 at 25 °C, depending upon the data source. What the equation means is that the product of molar concentration of calcium ions (moles of dissolved Ca per liter of solution)
Calcium sulfide lime, Ca(OH), reacts with elemental sulfur to give a "lime-sulfur", which has been used as an insecticide. The active ingredient is probably a calcium polysulfide, not CaS. Calcium sulfide decomposes upon contact with water, including moist air, giving a mixture of Ca(SH), Ca(OH), and Ca(SH)(OH). It reacts with acids such as hydrochloric acid to release toxic hydrogen sulfide gas. Oldhamite is the name for mineralogical form of CaS. It is a rare component of some meteorites and has scientific importance in solar nebula research. Burning of coal dumps can also produce the compound. Calcium sulfide Calcium sulfide is the chemical