Glass-to-metal seal formation of lithium tungstate. Due to its low thermal expansion coefficient, matched to glass, tungsten is frequently used for glass-metal bonds. Tungsten forms satisfying bonds with glasses with similar thermal expansion coefficient such as high-borosilicate glass. The surface of both the metal and glass should be smooth, without scratches. Tungsten has the lowest expansion coefficient of metals and the highest melting point. 304 Stainless steel forms bonds with glass via an intermediate layer of chromium(III) oxide and iron(III) oxide. Further reactions of chromium, forming chromium silicide dendrites, are possible. The thermal expansion coefficient of steel is however fairly different from
Melting-point depression the interfacial energies between the solid and liquid phases, volumes and surface areas of each phase, and size of the nanoparticle. The model calculations show that the liquid phase forms at lower temperatures for smaller nanoparticles. Once the liquid phase forms, the free energy conditions quickly change and favor melting. Equation 6 gives the melting conditions for a spherical nanoparticle according to the LNG model. formula_6 The bond-order-length-strength (BOLS) model employs an atomistic approach to explain melting point depression. The model focuses on the cohesive energy of individual atoms rather than a classical thermodynamic approach. The BOLS model calculates the