Barium permanganate heptoxide. Barium permanganate Barium permanganate is a chemical compound, with the formula Ba(MnO). Barium permanganate may be produced by disproportionation of barium manganate in a mildly acidic solution, or by oxidation of barium manganate with strong oxidants. Preparations relying on aqueous reactions of barium manganate are extremely slow process due to the low solubility of the manganate. Permanganic acid can be prepared by the reaction of dilute sulfuric acid with a solution barium permanganate, the insoluble barium sulfate byproduct being removed by filtering: The sulfuric acid used must be dilute; reactions of permanganates with concentrated sulfuric acid yield the anhydride,
Calamine brass Calamine brass Calamine brass is brass produced by a particular alloying technique using the zinc ore calamine directly, rather than first refining it to metallic zinc. Direct zinc smelting appears to have been unknown in Europe until the mid-18th century, even though the alloyed calamine brass was in use for centuries, and metallic zinc was produced directly via reducing-atmosphere smelting in India and China from the 12th century CE onwards. Brass is an alloy of copper and zinc and, when it was first developed, methods for producing metallic zinc were unknown. Metallurgists wishing to produce brass thus used calamine (actually