Barium fluoride Barium fluoride Barium fluoride (BaF) is a chemical compound of barium and fluorine and is a salt. It is a solid which can be a transparent crystal. It occurs in nature as the mineral frankdicksonite. The solid adopts the fluorite structure and at high pressure the PbCl structure. In the vapor phase the BaF molecule is non-linear with an F-Ba-F angle of approximately 108°. This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. Another
Sterling silver products. Colonial silversmiths used many of the techniques developed by those in Europe. Casting was frequently the first step in manufacturing silver pieces, as silver workers would melt down sterling silver into easily manageable ingots. Occasionally, they would create small components (e.g. teapot legs) by casting silver into iron or graphite molds, but it was rare for an entire piece to be fabricated via casting. Next, silversmiths would forge the ingots into the shapes they desired, often hammering the thinned silver against specially shaped dies to "mass produce" simple shapes like the oval end of a spoon. This process occurred