Glass-to-metal seal formation of lithium tungstate. Due to its low thermal expansion coefficient, matched to glass, tungsten is frequently used for glass-metal bonds. Tungsten forms satisfying bonds with glasses with similar thermal expansion coefficient such as high-borosilicate glass. The surface of both the metal and glass should be smooth, without scratches. Tungsten has the lowest expansion coefficient of metals and the highest melting point. 304 Stainless steel forms bonds with glass via an intermediate layer of chromium(III) oxide and iron(III) oxide. Further reactions of chromium, forming chromium silicide dendrites, are possible. The thermal expansion coefficient of steel is however fairly different from
Melting-point depression during experiment. Melting point depression was predicted in 1909 by Pawlow. Takagi first observed melting point depression of several types of metal nanoparticles in 1954. A variable intensity electron beam from a transmission electron microscope melted metal nanoparticles in early experiments. Diffraction patterns changed from characteristic crystalline patterns to liquid patterns as the small particles melted, allowing Takagi to estimate the melting temperature from the electron beam energy. Nanoparticles have a much greater surface to volume ratio than bulk materials. The increased surface to volume ratio means surface atoms have a much greater effect on chemical and physical properties of