Silver perchlorate Silver perchlorate Silver perchlorate is the chemical compound with the formula AgClO. This white solid forms a monohydrate and is mildly deliquescent. It is a useful source of the Ag ion, although the presence of perchlorate presents risks. It is used as a catalyst in organic chemistry. Silver perchlorate is created by heating a mixture of perchloric acid with silver nitrate. Alternatively, it can be prepared by the reaction between barium perchlorate and silver sulfate, or from the reaction of perchloric acid with silver oxide. Silver perchlorate is noteworthy for its solubility in aromatic solvents such as benzene (52.8 g/L)
Sterling silver items in the “New World” ranging from simple buckles to ornate Rococo coffee pots. Although silversmiths of this era were typically familiar with all precious metals, they primarily worked in sterling silver. The colonies lacked an assay office during this time (the first would be established in 1814), so American silversmiths adhered to the standard set by the London Goldsmiths Company: sterling silver consisted of 91.5 - 92.5% by weight silver and 8.5–7.5 wt% copper. Stamping each of their pieces with their personal maker's mark, colonial silversmiths relied upon their own status to guarantee the quality and composition of their