Glass-to-metal seal formation of lithium tungstate. Due to its low thermal expansion coefficient, matched to glass, tungsten is frequently used for glass-metal bonds. Tungsten forms satisfying bonds with glasses with similar thermal expansion coefficient such as high-borosilicate glass. The surface of both the metal and glass should be smooth, without scratches. Tungsten has the lowest expansion coefficient of metals and the highest melting point. 304 Stainless steel forms bonds with glass via an intermediate layer of chromium(III) oxide and iron(III) oxide. Further reactions of chromium, forming chromium silicide dendrites, are possible. The thermal expansion coefficient of steel is however fairly different from
Filler metal point than the base metal, so that the joint may be made by bringing the whole assembly up to temperature without everything melting as one. Complex joints, typically for jewellery or live steam boilermaking may be made in stages, with filler metals of progressively lower melting points used in turn. Early joints are thus not destroyed by heating to the later temperatures. Welding processes work around the melting point of the base metal and require the base metal itself to begin melting. They usually require more precise distribution of heat from a small torch, as melting the entire workpiece is