Barium fluoride Barium fluoride Barium fluoride (BaF) is a chemical compound of barium and fluorine and is a salt. It is a solid which can be a transparent crystal. It occurs in nature as the mineral frankdicksonite. The solid adopts the fluorite structure and at high pressure the PbCl structure. In the vapor phase the BaF molecule is non-linear with an F-Ba-F angle of approximately 108°. This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. Another
Pewter known as "trifling metal" or "trifle", was used for holloware and is made up of fine metal with approximately 4% lead. The last type of pewter, known as "lay" or "ley" metal, was used for items that were not in contact with food or drink. It consisted of tin with 15% lead. These three alloys were used with little variation until the 20th century. Older pewters with higher lead content are heavier, tarnish faster, and oxidation gives them a darker silver-gray color. Pewters containing lead are no longer used in items that will come in contact with the human body