Glass-to-metal seal formation of lithium tungstate. Due to its low thermal expansion coefficient, matched to glass, tungsten is frequently used for glass-metal bonds. Tungsten forms satisfying bonds with glasses with similar thermal expansion coefficient such as high-borosilicate glass. The surface of both the metal and glass should be smooth, without scratches. Tungsten has the lowest expansion coefficient of metals and the highest melting point. 304 Stainless steel forms bonds with glass via an intermediate layer of chromium(III) oxide and iron(III) oxide. Further reactions of chromium, forming chromium silicide dendrites, are possible. The thermal expansion coefficient of steel is however fairly different from
Melting-point depression to its cohesive energy, a (T=Ca). Since atoms near the surface have fewer bonds and reduced cohesive energy, they require less energy to free from the solid phase. Melting point depression of high surface to volume ratio materials results from this effect. For the same reason, surfaces of bulk materials can melt at lower temperatures than the bulk material. The theoretical size-dependent melting point of a material can be calculated through classical thermodynamic analysis. The result is the Gibbs–Thomson equation shown in Equation 2. formula_2 Where: T = Bulk Melting temperature A normalized Gibbs–Thomson Equation for gold nanoparticles is plotted