Barium fluoride Barium fluoride Barium fluoride (BaF) is a chemical compound of barium and fluorine and is a salt. It is a solid which can be a transparent crystal. It occurs in nature as the mineral frankdicksonite. The solid adopts the fluorite structure and at high pressure the PbCl structure. In the vapor phase the BaF molecule is non-linear with an F-Ba-F angle of approximately 108°. This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. Another
Sterling silver Royal Mint in 1843. It bears the royal stamp "ENRI. REX" ("King Henry") but this was added later, in the reign of Henry III. The first legal definition of sterling silver appeared in 1275, when a statute of Edward I specified that 12 Troy ounces of silver for coinage should contain 11 ounces pennyweights of silver and pennyweights of alloy, with 20 pennyweights to the Troy ounce. This is (not precisely) equivalent to a millesimal fineness of 926. In Colonial America, sterling silver was used for currency and general goods as well. Between 1634 and 1776, some 500 silversmiths created