Barium fluoride Barium fluoride Barium fluoride (BaF) is a chemical compound of barium and fluorine and is a salt. It is a solid which can be a transparent crystal. It occurs in nature as the mineral frankdicksonite. The solid adopts the fluorite structure and at high pressure the PbCl structure. In the vapor phase the BaF molecule is non-linear with an F-Ba-F angle of approximately 108°. This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. Another
Sterling silver Netherlands, the Baltic, Germany, and even deeper regions of central Europe." The sterling alloy originated in continental Europe and was being used for commerce as early as the 12th century in the area that is now northern Germany. In England the composition of sterling silver was subject to official assay at some date before 1158, during the reign of Henry II, but its purity was probably regulated from centuries earlier, in Saxon times. A piece of sterling silver dating from Henry II's reign was used as a standard in the Trial of the Pyx until it was deposited at the