Glass-to-metal seal formation of lithium tungstate. Due to its low thermal expansion coefficient, matched to glass, tungsten is frequently used for glass-metal bonds. Tungsten forms satisfying bonds with glasses with similar thermal expansion coefficient such as high-borosilicate glass. The surface of both the metal and glass should be smooth, without scratches. Tungsten has the lowest expansion coefficient of metals and the highest melting point. 304 Stainless steel forms bonds with glass via an intermediate layer of chromium(III) oxide and iron(III) oxide. Further reactions of chromium, forming chromium silicide dendrites, are possible. The thermal expansion coefficient of steel is however fairly different from
Melting-point depression and thermal properties. This article focuses on nanoparticles because researchers have compiled a large amount of size-dependent melting data for near spherical nanoparticles. Nanoparticles are easiest to study due their ease of fabrication and simplified conditions for theoretical modeling. The melting temperature of a nanoparticle decreases sharply as the particle reaches critical diameter, usually < 50 nm for common engineering metals. Figure 1 shows the shape of a typical melting curve for a metal nanoparticle as a function of its diameter. Melting point depression is a very important issue for applications involving nanoparticles, as it decreases the functional range of