Potassium tree leaves, adding water, heating, and evaporating the solution. When Humphry Davy first isolated the pure element using electrolysis in 1807, he named it "potassium", which he derived from the word potash. The symbol "K" stems from "kali", itself from the root word "alkali", which in turn comes from "" "al-qalyah" "plant ashes." In 1797, the German chemist Martin Klaproth discovered "potash" in the minerals leucite and lepidolite, and realized that "potash" was not a product of plant growth but actually contained a new element, which he proposed to call "kali". In 1807, Humphry Davy produced the element via electrolysis:
Potassium and hydroponic culture in the form of chloride (KCl), sulfate (), or nitrate (). Agricultural fertilizers consume 95% of global potassium chemical production, and about 90% of this potassium is supplied as KCl. The potassium content of most plants range from 0.5% to 2% of the harvested weight of crops, conventionally expressed as amount of . Modern high-yield agriculture depends upon fertilizers to replace the potassium lost at harvest. Most agricultural fertilizers contain potassium chloride, while potassium sulfate is used for chloride-sensitive crops or crops needing higher sulfur content. The sulfate is produced mostly by decomposition of the complex minerals