Accessory pigment Accessory pigment Accessory pigments are light-absorbing compounds, found in photosynthetic organisms, that work in conjunction with chlorophyll "a". They include other forms of this pigment, such as chlorophyll "b" in green algal and higher plant antennae, while other algae may contain chlorophyll "c" or "d". In addition, there are many non-chlorophyll accessory pigments, such as carotenoids or phycobiliproteins, which also absorb light and transfer that light energy to photosystem chlorophyll. Some of these accessory pigments, in particular the carotenoids, also serve to absorb and dissipate excess light energy, or work as antioxidants. The large, physically associated group of chlorophylls and
Thylakoid centers, each consisting of an antenna complex that uses chlorophylls and accessory photosynthetic pigments such as carotenoids and phycobiliproteins to harvest light at a variety of wavelengths. Each antenna complex has between 250 and 400 pigment molecules and the energy they absorb is shuttled by resonance energy transfer to a specialized chlorophyll "a" at the reaction center of each photosystem. When either of the two chlorophyll "a" molecules at the reaction center absorbs energy, an electron is excited and transferred to an electron-acceptor molecule. Photosystem I contains a pair of chlorophyll "a" molecules, designated P700, at its reaction center that