Cobalt a structural analog to ferrocene, with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation than ferrocene. Cobalt carbonyl (Co(CO)) is a catalyst in carbonylation and hydrosilylation reactions. Vitamin B (see below) is an organometallic compound found in nature and is the only vitamin that contains a metal atom. An example of an alkylcobalt complex in the otherwise uncommon +4 oxidation state of cobalt is the homoleptic complex (Co(1-norb)), a transition metal-alkyl complex that is notable for its stability to β-hydrogen elimination. The cobalt(III) and cobalt(V) complexes [Li(THF)][Co(1-norb)] and [Co(1-norb)][BF] are also known. Co is the only
Cobalt-59 nuclear magnetic resonance Cobalt-59 nuclear magnetic resonance Cobalt-59 nuclear magnetic resonance is a form of nuclear magnetic resonance spectroscopy that uses cobalt-59, a cobalt isotope. Co is a nucleus of spin 7/2 and 100% abundancy. The nucleus has a magnetic quadrupole moment. Among all NMR active nuclei, Co has the largest chemical shift range and the chemical shift can be correlated with the spectrochemical series. Resonances are observed over a range of 20000 ppm, the width of the signals being up to 20 kHz. A widely used standard is potassium hexacyanocobaltate (0.1M KCo(CN) in DO), which, due to its high symmetry, has a