Silicon Silicon Silicon is a chemical element with symbol Si and atomic number 14. It is a hard and brittle crystalline solid with a blue-grey metallic lustre; and it is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, and lead are below it. It is relatively unreactive. Because of its large chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its melting and boiling points of 1414 °C and 3265
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much