Brass make brass was not recognised as a metal. The King James Bible makes many references to "brass". The Shakespearean English form of the word 'brass' can mean any bronze alloy, or copper, rather than the strict modern definition of brass. The earliest brasses may have been natural alloys made by smelting zinc-rich copper ores. By the Roman period brass was being deliberately produced from metallic copper and zinc minerals using the cementation process, and variations on this method continued until the mid-19th century. It was eventually replaced by speltering, the direct alloying of copper and zinc metal which was introduced
Period 4 element only major application is in aluminium alloys. Titanium (Ti) is an element in period 4, between scandium and vanadium. Titanium is both one of the least dense metals and one of the strongest and most corrosion-resistant, and as such has many applications, especially in alloys with other elements, such as iron. Due to its aforementioned properties, it is commonly used in airplanes, golf clubs, and other objects that must be strong, but lightweight. Vanadium (V) is an element in period 4, between titanium and chromium. Vanadium is never found in pure form in nature, but is commonly found in compounds.