Chlorophyll a chemical energy but is not the only pigment that can be used for photosynthesis. All oxygenic photosynthetic organisms use chlorophyll "a", but differ in accessory pigments like chlorophylls "b". Chlorophyll "z" can also be found in very small quantities in the green sulfur bacteria, an anaerobic photoautotroph. These organisms use bacteriochlorophyll and some chlorophyll "a" but do not produce oxygen. Anoxygenic photosynthesis is the term applied to this process, unlike oxygenic photosynthesis where oxygen is produced during the light reactions of photosynthesis. The molecular structure of chlorophyll "a" consists of a chlorin ring, whose four nitrogen atoms surround a central
Thylakoid centers, each consisting of an antenna complex that uses chlorophylls and accessory photosynthetic pigments such as carotenoids and phycobiliproteins to harvest light at a variety of wavelengths. Each antenna complex has between 250 and 400 pigment molecules and the energy they absorb is shuttled by resonance energy transfer to a specialized chlorophyll "a" at the reaction center of each photosystem. When either of the two chlorophyll "a" molecules at the reaction center absorbs energy, an electron is excited and transferred to an electron-acceptor molecule. Photosystem I contains a pair of chlorophyll "a" molecules, designated P700, at its reaction center that