Photosynthetically active radiation the predominance of chlorophyll is autumn, when chlorophyll is degraded (because it contains N and Mg) but the accessory pigments are not (because they only contain C, H and O) and remain in the leaf producing red, yellow and orange leaves. In land plants, leaves absorb mostly red and blue light in the first layer of photosynthetic cells because of Chlorophyll absorbance. Green light, however, penetrates deeper into the leaf interior and can drive photosynthesis more efficiently than red light. Because green and yellow wavelengths can transmit through chlorophyll and the entire leaf itself, they play a crucial role in
Chlorophyll directly absorbing light and performing charge separation events without the assistance of other chlorophyll pigments, but the probability of that happening under a given light intensity is small. Thus, the other chlorophylls in the photosystem and antenna pigment proteins all cooperatively absorb and funnel light energy to the reaction center. Besides chlorophyll "a", there are other pigments, called accessory pigments, which occur in these pigment–protein antenna complexes. Chlorophylls are numerous in types, but all are defined by the presence of a fifth ring beyond the four pyrrole-like rings. Most chlorophylls are classified as chlorins, which are reduced relatives to porphyrins