Antimony discontinued. Antimony is resistant to attack by acids. Four allotropes of antimony are known: a stable metallic form and three metastable forms (explosive, black and yellow). Elemental antimony is a brittle, silver-white shiny metalloid. When slowly cooled, molten antimony crystallizes in a trigonal cell, isomorphic with the gray allotrope of arsenic. A rare explosive form of antimony can be formed from the electrolysis of antimony trichloride. When scratched with a sharp implement, an exothermic reaction occurs and white fumes are given off as metallic antimony forms; when rubbed with a pestle in a mortar, a strong detonation occurs. Black antimony
Germanium becomes the allotrope "β-germanium" with the same structure as β-tin. Like silicon, gallium, bismuth, antimony, and water, germanium is one of the few substances that expands as it solidifies (i.e. freezes) from the molten state. Germanium is a semiconductor. Zone refining techniques have led to the production of crystalline germanium for semiconductors that has an impurity of only one part in 10, making it one of the purest materials ever obtained. The first metallic material discovered (in 2005) to become a superconductor in the presence of an extremely strong electromagnetic field was an alloy of germanium, uranium, and rhodium. Pure