Chlorophyll a chemical energy but is not the only pigment that can be used for photosynthesis. All oxygenic photosynthetic organisms use chlorophyll "a", but differ in accessory pigments like chlorophylls "b". Chlorophyll "z" can also be found in very small quantities in the green sulfur bacteria, an anaerobic photoautotroph. These organisms use bacteriochlorophyll and some chlorophyll "a" but do not produce oxygen. Anoxygenic photosynthesis is the term applied to this process, unlike oxygenic photosynthesis where oxygen is produced during the light reactions of photosynthesis. The molecular structure of chlorophyll "a" consists of a chlorin ring, whose four nitrogen atoms surround a central
Light-dependent reactions poorly understood structure embedded within PS II called the "water-splitting complex" or the "oxygen-evolving complex". It catalyzes a reaction that splits water into electrons, protons and oxygen: 2 → 4H + 4e + The actual steps of the above reaction are running in the following way (Dolai's diagram of S-states): The electrons are transferred to special chlorophyll molecules (embedded in PS II) that are promoted to a higher-energy state by the energy of photons. The excitation P680 → P680of the reaction center pigment P680 occurs here. These special chlorophyll molecules embedded in PS II absorb the energy of photons, with