Brass make brass was not recognised as a metal. The King James Bible makes many references to "brass". The Shakespearean English form of the word 'brass' can mean any bronze alloy, or copper, rather than the strict modern definition of brass. The earliest brasses may have been natural alloys made by smelting zinc-rich copper ores. By the Roman period brass was being deliberately produced from metallic copper and zinc minerals using the cementation process, and variations on this method continued until the mid-19th century. It was eventually replaced by speltering, the direct alloying of copper and zinc metal which was introduced
Native metal more reactive than gold. Natural alloys of the platinum group metals include: native osmium (Os,Ir,Ru), rutheniridosmine (Ir,Os,Ru), ruthenium (Ru,Ir), palladium (Pd,Pt), platinum Pt, and rhodium (Rh,Pt). In addition gold, copper, iron, mercury, tin and lead may occur in alloys of this group. As with gold, salts and other compounds of the platinum group metals are rare; native platinum and related metals and alloys are the predominant minerals bearing these metals. These metals occur associated with ultramafic intrusions and placer deposits derived from those intrusions. Native copper has been historically mined as an early source of the metal. The term Old