Silver metal. Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm. At wavelengths shorter than 450 nm, silver's reflectivity is inferior to that of aluminium and drops to zero near 310 nm. Very high electrical and thermal conductivity is common to the elements in group 11, because their single s electron is free and does not interact with the filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The electrical conductivity of silver is the greatest of all metals, greater even than copper, but it is not widely
Thermal conductivity to 10 cm. The phonon mean free path has been associated directly with the effective relaxation length for processes without directional correlation. If V is the group velocity of a phonon wave packet, then the relaxation length formula_31 is defined as: where "t" is the characteristic relaxation time. Since longitudinal waves have a much greater phase velocity than transverse waves, "V" is much greater than "V", and the relaxation length or mean free path of longitudinal phonons will be much greater. Thus, thermal conductivity will be largely determined by the speed of longitudinal phonons. Regarding the dependence of wave velocity