Accessory pigment Accessory pigment Accessory pigments are light-absorbing compounds, found in photosynthetic organisms, that work in conjunction with chlorophyll "a". They include other forms of this pigment, such as chlorophyll "b" in green algal and higher plant antennae, while other algae may contain chlorophyll "c" or "d". In addition, there are many non-chlorophyll accessory pigments, such as carotenoids or phycobiliproteins, which also absorb light and transfer that light energy to photosystem chlorophyll. Some of these accessory pigments, in particular the carotenoids, also serve to absorb and dissipate excess light energy, or work as antioxidants. The large, physically associated group of chlorophylls and
Light-harvesting complex optimize these rates. Chlorophylls and carotenoids are important in light-harvesting complexes present in plants. Chlorophyll b is almost identical to chlorophyll a except it has a formyl group in place of a methyl group. This small difference makes chlorophyll b absorb light with wavelengths between 400 and 500 nm more efficiently. Carotenoids are long linear organic molecules that have alternating single and double bonds along their length. Such molecules are called polyenes. Two examples of carotenoids are lycopene and β-carotene. These molecules also absorb light most efficiently in the 400 – 500 nm range. Due to their absorption region, carotenoids