Post-transition metal defined transition elements as finishing at group 10 (nickel, palladium and platinum), therefore excluding group 11 (copper, silver and gold), and group 12 (zinc, cadmium and mercury). A survey of chemistry books in 2003 showed that the transition metals ended at either group 11 or group 12 with roughly equal frequency. Where the post-transition metals end depends on where the metalloids or nonmetals start. Boron, silicon, germanium, arsenic, antimony and tellurium are commonly recognised as metalloids; other authors treat some or all of these elements as nonmetals. The diminished metallic nature of the post-transition metals is largely attributable to the
Fullerene chemistry one or more bonds are removed chemically exposing an orifice. In this way it is possible to insert into it small molecules such as hydrogen, helium or lithium. The first such open-cage fullerene was reported in 1995. In endohedral hydrogen fullerenes the opening, hydrogen insertion and closing back up has already been demonstrated. In heterofullerenes at least one carbon atom is replaced by another element. Based on spectroscopy, substitutions have been reported with boron (borafullerenes), nitrogen (azafullerenes), oxygen, arsenic, germanium, phosphorus, silicon, iron, copper, nickel, rhodium and iridium. Reports on isolated heterofullerenes are limited to those based on nitrogen and