Metalloid what classification criteria are used. Emsley recognised four metalloids (germanium, arsenic, antimony, and tellurium); James et al. listed twelve (Emsley's plus boron, carbon, silicon, selenium, bismuth, polonium, moscovium, and livermorium). On average, seven elements are included in such lists; individual classification arrangements tend to share common ground and vary in the ill-defined margins. A single quantitative criterion such as electronegativity is commonly used, metalloids having electronegativity values from 1.8 or 1.9 to 2.2. Further examples include packing efficiency (the fraction of volume in a crystal structure occupied by atoms) and the Goldhammer-Herzfeld criterion ratio. The commonly recognised metalloids have packing
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much