Cobalt(II) carbonate Like most transition metal carbonates, cobalt carbonate is insoluble in water, but is readily attacked by mineral acids: Cobalt carbonate is a precursor to cobalt carbonyl and various cobalt salts. It is a component of dietary supplements since cobalt is an essential element. It is a precursor to blue pottery glazes, famously in the case of Delftware. The moderately rare spherocobaltite is the natural form of cobalt carbonate, with good specimens coming especially from the Republic of Congo. "Cobaltocalcite" is a name used for a cobaltiferous calcite variety that is quite similar in habit to spherocobaltite. The compound is harmful
Cobalt was predominantly used as a pigment. It has been used since the Middle Ages to make smalt, a blue-colored glass. Smalt is produced by melting a mixture of roasted mineral smaltite, quartz and potassium carbonate, which yields a dark blue silicate glass, which is finely ground after the production. Smalt was widely used to color glass and as pigment for paintings. In 1780, Sven Rinman discovered cobalt green, and in 1802 Louis Jacques Thénard discovered cobalt blue. Cobalt pigments such as cobalt blue (cobalt aluminate), cerulean blue (cobalt(II) stannate), various hues of cobalt green (a mixture of cobalt(II) oxide and