Silver metal. Protected silver has greater optical reflectivity than aluminium at all wavelengths longer than ~450 nm. At wavelengths shorter than 450 nm, silver's reflectivity is inferior to that of aluminium and drops to zero near 310 nm. Very high electrical and thermal conductivity is common to the elements in group 11, because their single s electron is free and does not interact with the filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The electrical conductivity of silver is the greatest of all metals, greater even than copper, but it is not widely
Thermal conductivity Time variation due to phonon decay is described with a relaxation time ("τ") approximation which states that the more the phonon number deviates from its equilibrium value, the more its time variation increases. At steady state conditions and local thermal equilibrium are assumed we get the following equation Using the relaxation time approximation for the Boltzmann equation and assuming steady-state conditions, the phonon thermal conductivity "λ" can be determined. The temperature dependence for "λ" originates from the variety of processes, whose significance for "λ" depends on the temperature range of interest. Mean free path is one factor that determines the