Cobalt(II) fluoride Cobalt(II) fluoride Cobalt(II) fluoride is a chemical compound with the formula (CoF). It is a pink crystalline solid compound which is antiferromagnetic at low temperatures (T=37.7 K) The formula is given for both the red tetragonal crystal, (CoF), and the tetrahydrate red orthogonal crystal, (CoF·4HO). CoF is used in oxygen-sensitive fields, namely metal production. In low concentrations, it has public health uses. CoF is sparingly soluble in water. The compound can be dissolved in warm mineral acid, and will decompose in boiling water. Yet the hydrate is water-soluble, especially the di-hydrate CoF·2H O and tri-hydrate CoF·3HO forms of the compound.
Cobalt with water and oxygen to brown cobalt(III) hydroxide (Co(OH)). At temperatures of 600–700 °C, CoO oxidizes to the blue cobalt(II,III) oxide (CoO), which has a spinel structure. Black cobalt(III) oxide (CoO) is also known. Cobalt oxides are antiferromagnetic at low temperature: CoO (Néel temperature 291 K) and CoO (Néel temperature: 40 K), which is analogous to magnetite (FeO), with a mixture of +2 and +3 oxidation states. The principal chalcogenides of cobalt include the black cobalt(II) sulfides, CoS, which adopts a pyrite-like structure, and cobalt(III) sulfide (CoS). Four dihalides of cobalt(II) are known: cobalt(II) fluoride (CoF, pink), cobalt(II) chloride (CoCl,