Speculum metal metal mixtures usually contain two parts copper to one part tin along with a small amount of arsenic, although there are other mixtures containing silver, lead, or zinc. The knowledge of making very hard white high luster metal out of bronze-type high-tin alloys may date back more than 2000 years in China although it could also be an invention of western civilizations. Such metals were used in sculpture and to make more effective mirrors than the more common yellow easily tarnishing bronze mirrors. In that era mirrors of speculum metal, or any precious metal, were rare and only owned by
Copper alloys in aquaculture susceptible to chloride stress corrosion. Copper–silicon has a long history of use as screws, nuts, bolts, washers, pins, lag bolts, and staples in wooden sailing vessels in marine environments. The alloys are often composed of copper, silicon, and manganese. The inclusion of silicon strengthens the metal. As with the copper–nickel alloys, corrosion resistance of copper–silicon is due to protective films that form on the surface over a period of time. General corrosion rates of 0.025–0.050mm have been observed in quiet waters. This rate decreases towards the lower end of the range over long-term exposures (e.g., 400–600 days). There is generally