Cobalt for "goblin ore") for some of the blue-pigment producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the "kobold". Today, some cobalt is produced specifically from one of a number of metallic-lustered ores, such as for example cobaltite (CoAsS). The element is however more usually produced as a by-product of copper and nickel mining. The copper belt in the Democratic Republic of the Congo
Cobalt with water and oxygen to brown cobalt(III) hydroxide (Co(OH)). At temperatures of 600–700 °C, CoO oxidizes to the blue cobalt(II,III) oxide (CoO), which has a spinel structure. Black cobalt(III) oxide (CoO) is also known. Cobalt oxides are antiferromagnetic at low temperature: CoO (Néel temperature 291 K) and CoO (Néel temperature: 40 K), which is analogous to magnetite (FeO), with a mixture of +2 and +3 oxidation states. The principal chalcogenides of cobalt include the black cobalt(II) sulfides, CoS, which adopts a pyrite-like structure, and cobalt(III) sulfide (CoS). Four dihalides of cobalt(II) are known: cobalt(II) fluoride (CoF, pink), cobalt(II) chloride (CoCl,