Low-pressure area area of wind divergence aloft occurs ahead of embedded shortwave troughs, which are of smaller wavelength. Diverging winds aloft ahead of these troughs cause atmospheric lift within the troposphere below, which lowers surface pressures as upward motion partially counteracts the force of gravity. Thermal lows form due to localized heating caused by greater sunshine over deserts and other land masses. Since localized areas of warm air are less dense than their surroundings, this warmer air rises, which lowers atmospheric pressure near that portion of the Earth's surface. Large-scale thermal lows over continents help drive monsoon circulations. Low-pressure areas can also
High pressure impact. Chemical bonding is likely to change under high pressure, when the P*V term in the free energy becomes comparable to the energies of typical chemical bonds – i.e. at around 100 GPa. Among the most striking changes are metallization of oxygen at 96 GPa (rendering oxygen a superconductor), and transition of sodium from a nearly-free-electron metal to a transparent insulator at ~200 GPa. At ultimately high compression, however, all materials will metallize. High-pressure experimentation has led to the discovery of the types of minerals which are believed to exist in the deep mantle of the Earth, such as silicate