Nonmetal are called "metalloids" mainly in light of their physical resemblance to metals. While they each have a metallic appearance, they are brittle and only fair conductors of electricity. Boron, silicon, germanium, tellurium are semiconductors. Arsenic and antimony have the electronic band structures of semimetals although both have less stable semiconducting allotropes. Astatine has been predicted to have a metallic crystalline structure. Chemically the metalloids generally behave like (weak) nonmetals. They have moderate ionisation energies, low to high electron affinities, moderate electronegativity values, are poor to moderately strong oxidising agents, and demonstrate a tendency to form alloys with metals. The reactive
Arsenic pentachloride more stable and the instability of AsCl appears anomalous. The cause is believed to be due to incomplete shielding of the nucleus in the elements following the first transition series (i.e. gallium, germanium, arsenic, selenium, bromine, and krypton) which leads to stabilisation of their 4s electrons making them less available for bonding. This effect has been termed the d-block contraction and is similar to the f-block contraction normally termed the lanthanide contraction. Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in