Brass than in brass produced by cementation. These may be "natural alloys" manufactured by smelting zinc rich copper ores in redox conditions. Many have similar tin contents to contemporary bronze artefacts and it is possible that some copper-zinc alloys were accidental and perhaps not even distinguished from copper. However the large number of copper-zinc alloys now known suggests that at least some were deliberately manufactured and many have zinc contents of more than 12% wt which would have resulted in a distinctive golden color. By the 8th–7th century BC Assyrian cuneiform tablets mention the exploitation of the "copper of the mountains"
Period 4 element only major application is in aluminium alloys. Titanium (Ti) is an element in period 4, between scandium and vanadium. Titanium is both one of the least dense metals and one of the strongest and most corrosion-resistant, and as such has many applications, especially in alloys with other elements, such as iron. Due to its aforementioned properties, it is commonly used in airplanes, golf clubs, and other objects that must be strong, but lightweight. Vanadium (V) is an element in period 4, between titanium and chromium. Vanadium is never found in pure form in nature, but is commonly found in compounds.