Origin and use of the term metalloid antimony and tellurium, was recorded merely on a 'sometimes' basis. Use of the term metalloid subsequently underwent a period of great flux up to 1940. Consensus as to its application to intermediate or borderline elements did not occur until the ensuing years, between 1940 and 1960. In 1947, Pauling included a reference to metalloids in his classic and influential textbook, "General chemistry: An introduction to descriptive chemistry and modern chemical theory." He described them as 'elements with intermediate properties ... occupy[ing] a diagonal region [on the periodic table], which includes boron, silicon, germanium, arsenic, antimony, tellurium, and polonium.' In 1959
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much