Nonmetal are called "metalloids" mainly in light of their physical resemblance to metals. While they each have a metallic appearance, they are brittle and only fair conductors of electricity. Boron, silicon, germanium, tellurium are semiconductors. Arsenic and antimony have the electronic band structures of semimetals although both have less stable semiconducting allotropes. Astatine has been predicted to have a metallic crystalline structure. Chemically the metalloids generally behave like (weak) nonmetals. They have moderate ionisation energies, low to high electron affinities, moderate electronegativity values, are poor to moderately strong oxidising agents, and demonstrate a tendency to form alloys with metals. The reactive
Fullerene chemistry one or more bonds are removed chemically exposing an orifice. In this way it is possible to insert into it small molecules such as hydrogen, helium or lithium. The first such open-cage fullerene was reported in 1995. In endohedral hydrogen fullerenes the opening, hydrogen insertion and closing back up has already been demonstrated. In heterofullerenes at least one carbon atom is replaced by another element. Based on spectroscopy, substitutions have been reported with boron (borafullerenes), nitrogen (azafullerenes), oxygen, arsenic, germanium, phosphorus, silicon, iron, copper, nickel, rhodium and iridium. Reports on isolated heterofullerenes are limited to those based on nitrogen and