Nonmetal inconsistently classified by different authors. Elements sometimes also classified as nonmetals are the metalloids boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), and astatine (At). The nonmetal selenium (Se) is sometimes instead classified as a metalloid, particularly in environmental chemistry. Nonmetals show more variability in their properties than do metals. These properties are largely determined by the interatomic bonding strengths and molecular structures of the nonmetals involved, both of which are subject to variation as the number of valence electrons in each nonmetal varies. Metals, in contrast, have more homogenous structures and their properties are more
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much