Thermal conductivity heat flow may not be exactly the same as the direction of the thermal gradient. In metals, thermal conductivity approximately tracks electrical conductivity according to the Wiedemann–Franz law, as freely moving valence electrons transfer not only electric current but also heat energy. However, the general correlation between electrical and thermal conductance does not hold for other materials, due to the increased importance of phonon carriers for heat in non-metals. Highly electrically conductive silver is less thermally conductive than diamond, which is an electrical insulator, but due to its orderly array of atoms it is conductive of heat via phonons. The
Thermal bridge the temperature difference experienced on either side of the thermal bridge. When a temperature difference is present, heat flow will follow the path of least resistance through the material with the highest thermal conductivity and lowest thermal resistance; this path is a thermal bridge. Thermal bridging describes a situation in a building where there is a direct connection between the outside and inside through one or more elements that possess a higher thermal conductivity than the rest of the envelope of the building. Surveying buildings for thermal bridges is performed using passive infrared thermography (IRT) according to the International Organization