Accessory pigment Accessory pigment Accessory pigments are light-absorbing compounds, found in photosynthetic organisms, that work in conjunction with chlorophyll "a". They include other forms of this pigment, such as chlorophyll "b" in green algal and higher plant antennae, while other algae may contain chlorophyll "c" or "d". In addition, there are many non-chlorophyll accessory pigments, such as carotenoids or phycobiliproteins, which also absorb light and transfer that light energy to photosystem chlorophyll. Some of these accessory pigments, in particular the carotenoids, also serve to absorb and dissipate excess light energy, or work as antioxidants. The large, physically associated group of chlorophylls and
Chlorophyll directly absorbing light and performing charge separation events without the assistance of other chlorophyll pigments, but the probability of that happening under a given light intensity is small. Thus, the other chlorophylls in the photosystem and antenna pigment proteins all cooperatively absorb and funnel light energy to the reaction center. Besides chlorophyll "a", there are other pigments, called accessory pigments, which occur in these pigment–protein antenna complexes. Chlorophylls are numerous in types, but all are defined by the presence of a fifth ring beyond the four pyrrole-like rings. Most chlorophylls are classified as chlorins, which are reduced relatives to porphyrins