Nonmetal as nonmetals. Among the reactive nonmetals, carbon, phosphorus, selenium, and iodine—which border the metalloids—show some metallic character, as does hydrogen. Among the noble gases, radon is the most metallic and begins to show some cationic behaviour, which is unusual for a nonmetal. The seven metalloids are boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), and astatine (At). On a standard periodic table, they occupy a diagonal area in the p-block extending from boron at the upper left to astatine at lower right, along the dividing line between metals and nonmetals shown on some periodic tables. They
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much