Arsenic Arsenic Arsenic is a chemical element with symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but only the gray form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for example, in car batteries and ammunition). Arsenic is a common n-type dopant in semiconductor electronic devices, and the optoelectronic compound gallium arsenide is the second most commonly used semiconductor after doped silicon. Arsenic and its
Arsenic pentachloride Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in liquid chlorine at −105 °C. AsCl decomposes at around −50 °C. The structure of the solid was finally determined in 2001. AsCl is similar to phosphorus pentachloride, PCl in having a trigonal bipyramidal structure where the equatorial bonds are shorter than the axial bonds (As-Cl = 210.6 pm, 211.9 pm; As-Cl= 220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimony pentachloride are much