Thermal conductivity heat flow may not be exactly the same as the direction of the thermal gradient. In metals, thermal conductivity approximately tracks electrical conductivity according to the Wiedemann–Franz law, as freely moving valence electrons transfer not only electric current but also heat energy. However, the general correlation between electrical and thermal conductance does not hold for other materials, due to the increased importance of phonon carriers for heat in non-metals. Highly electrically conductive silver is less thermally conductive than diamond, which is an electrical insulator, but due to its orderly array of atoms it is conductive of heat via phonons. The
Thermal conductivity and it is measured in watts per square metre of surface area for a temperature gradient of 1 K per unit thickness of 1 m". Therefore, specific thermal conductivity is calculated as: where: formula_14 = temperature difference (K, or °C) = 1 K during measurement Absolute thermal conductivity, on the other hand, has units of formula_15 or formula_16, and can be expressed as where formula_18 = absolute thermal conductivity (W/K, or W/°C). Substituting formula_18 for formula_20 into the first equation yields the equation which converts from absolute thermal conductivity to specific thermal conductivity: Solving for formula_18, we get the equation