Brass make brass was not recognised as a metal. The King James Bible makes many references to "brass". The Shakespearean English form of the word 'brass' can mean any bronze alloy, or copper, rather than the strict modern definition of brass. The earliest brasses may have been natural alloys made by smelting zinc-rich copper ores. By the Roman period brass was being deliberately produced from metallic copper and zinc minerals using the cementation process, and variations on this method continued until the mid-19th century. It was eventually replaced by speltering, the direct alloying of copper and zinc metal which was introduced
Period 4 element can also be found in semiconductors. Germanium (Ge) is an element in period 4, between gallium and arsenic. Germanium, like silicon above it, is an important semiconductor and is commonly used in diodes and transistors, often in combination with arsenic. Germanium is fairly rare on Earth, leading to its comparatively late discovery. Germanium, in compounds, can sometimes irritate the eyes, skin, or lungs. Arsenic (As) is an element in period 4, between germanium and selenium. Arsenic, as mentioned above, is often used in semiconductors in alloys with germanium. Arsenic, in pure form and some alloys, is incredibly poisonous to all