Photosynthetically active radiation the predominance of chlorophyll is autumn, when chlorophyll is degraded (because it contains N and Mg) but the accessory pigments are not (because they only contain C, H and O) and remain in the leaf producing red, yellow and orange leaves. In land plants, leaves absorb mostly red and blue light in the first layer of photosynthetic cells because of Chlorophyll absorbance. Green light, however, penetrates deeper into the leaf interior and can drive photosynthesis more efficiently than red light. Because green and yellow wavelengths can transmit through chlorophyll and the entire leaf itself, they play a crucial role in
Light-harvesting complexes of green plants pigment molecules and the energy they absorb is shuttled by resonance energy transfer to a specialized chlorophyll-protein complex known as the reaction center of each photosystem. The reaction center initiates a complex series of chemical reactions that capture energy in the form of chemical bonds. For photosystem II, when either of the two chlorophyll "a" molecules at the reaction center absorb energy, an electron is excited and transferred to an electron acceptor molecule, pheophytin, leaving the chlorophyll "a" in an oxidized state. The oxidised chlorophyll "a" replaces the electrons by photolysis that involves the oxidation of water molecules to oxygen,