Thermal conductivity electrons. In this case the mean velocity is the Fermi velocity which is temperature independent. The mean free path is determined by the impurities and the crystal imperfections which are temperature independent as well. So the only temperature-dependent quantity is the heat capacity "c", which, in this case, is proportional to "T". So with "k" a constant. For pure metals such as copper, silver, etc. "l" is large, so the thermal conductivity is high. At higher temperatures the mean free path is limited by the phonons, so the thermal conductivity tends to decrease with temperature. In alloys the density of
Soil thermal properties Apart from the basic soil composition, which is constant at one location, soil thermal properties are strongly influenced by the soil volumetric water content, volume fraction of solids and volume fraction of air. Air is a poor thermal conductor and reduces the effectiveness of the solid and liquid phases to conduct heat. While the solid phase has the highest conductivity it is the variability of soil moisture that largely determines thermal conductivity. As such soil moisture properties and soil thermal properties are very closely linked and are often measured and reported together. Temperature variations are most extreme at the surface