Speculum metal metal mixtures usually contain two parts copper to one part tin along with a small amount of arsenic, although there are other mixtures containing silver, lead, or zinc. The knowledge of making very hard white high luster metal out of bronze-type high-tin alloys may date back more than 2000 years in China although it could also be an invention of western civilizations. Such metals were used in sculpture and to make more effective mirrors than the more common yellow easily tarnishing bronze mirrors. In that era mirrors of speculum metal, or any precious metal, were rare and only owned by
Group 6 element 1924. For about a century after its isolation, molybdenum had no industrial use, owing to its relative scarcity, difficulty extracting the pure metal, and the immaturity of the metallurgical subfield. Early molybdenum steel alloys showed great promise in their increased hardness, but efforts were hampered by inconsistent results and a tendency toward brittleness and recrystallization. In 1906, William D. Coolidge filed a patent for rendering molybdenum ductile, leading to its use as a heating element for high-temperature furnaces and as a support for tungsten-filament light bulbs; oxide formation and degradation require that moly be physically sealed or held in an