Metalloid for carbon in steel casting. Of the non-metallic elements less often recognised as metalloids, selenium—in the form of ferroselenium (50–58% selenium)—is used to improve the machinability of stainless steels. All six of the elements commonly recognised as metalloids have toxic, dietary or medicinal properties. Arsenic and antimony compounds are especially toxic; boron, silicon, and possibly arsenic, are essential trace elements. Boron, silicon, arsenic, and antimony have medical applications, and germanium and tellurium are thought to have potential. Boron is used in insecticides and herbicides. It is an essential trace element. As boric acid, it has antiseptic, antifungal, and antiviral properties.
Antimony in the sulfide stibnite (SbS) which is the predominant ore mineral. Antimony compounds are often classified according to their oxidation state: Sb(III) and Sb(V). The +5 oxidation state is more stable. Antimony trioxide is formed when antimony is burnt in air. In the gas phase, the molecule of the compound is , but it polymerizes upon condensing. Antimony pentoxide () can be formed only by oxidation with concentrated nitric acid. Antimony also forms a mixed-valence oxide, antimony tetroxide (), which features both Sb(III) and Sb(V). Unlike oxides of phosphorus and arsenic, these oxides are amphoteric, do not form well-defined oxoacids,