Thermal conductivity heat flow may not be exactly the same as the direction of the thermal gradient. In metals, thermal conductivity approximately tracks electrical conductivity according to the Wiedemann–Franz law, as freely moving valence electrons transfer not only electric current but also heat energy. However, the general correlation between electrical and thermal conductance does not hold for other materials, due to the increased importance of phonon carriers for heat in non-metals. Highly electrically conductive silver is less thermally conductive than diamond, which is an electrical insulator, but due to its orderly array of atoms it is conductive of heat via phonons. The
Lumped element model of sections, or lumps, so that the Biot number is acceptably small. Some characteristic lengths of thermal systems are: For arbitrary shapes, it may be useful to consider the characteristic length to be volume / surface area. A useful concept used in heat transfer applications once the condition of steady state heat conduction has been reached, is the representation of thermal transfer by what is known as thermal circuits. A thermal circuit is the representation of the resistance to heat flow in each element of a circuit, as though it were an electrical resistor. The heat transferred is analogous to