Sodium amalgam sodium metal in mercury or the reverse. Sodium amalgams can be purchased from chemical supply houses. Since its introduction in the 1880s by students of Robert Bunsen, Julius Tafel and Hans Goldschmidt, sodium amalgam has also been used in organic chemistry as a powerful reducing agent, which is safer to handle than sodium itself. An example of its use is in the Emde degradation. A sodium amalgam is used in the design of the high pressure sodium lamp providing sodium to produce the proper color, and mercury to tailor the electrical characteristics of the lamp. Sodium amalgam is a by-product
Organosilver chemistry η-alkene complex. Silver is also present in other carbon-carbon bond skeletal rearrangements such as the quadricyclane to norbornadiene rearrangement, the cubane to cuneane rearrangement and the rearrangement of the cyclobutadiene dimer to cyclooctatetraene. Organosilver chemistry Organosilver chemistry in chemistry is the study of organometallic compounds containing a carbon to silver chemical bond and the study of silver as catalyst in organic reactions. In the group 11 elements silver is the element below copper. The chemistries have much in common but organosilver catalysis is much less common (mostly academic study) than organocopper chemistry due both to the relatively high price of