Brass than in brass produced by cementation. These may be "natural alloys" manufactured by smelting zinc rich copper ores in redox conditions. Many have similar tin contents to contemporary bronze artefacts and it is possible that some copper-zinc alloys were accidental and perhaps not even distinguished from copper. However the large number of copper-zinc alloys now known suggests that at least some were deliberately manufactured and many have zinc contents of more than 12% wt which would have resulted in a distinctive golden color. By the 8th–7th century BC Assyrian cuneiform tablets mention the exploitation of the "copper of the mountains"
Period 5 element other metal is not easily oxidized in air and is used to coat other metals to prevent corrosion. The firstalloy, used in large scale since 3000 BC, was bronze, an alloy of tin and copper. After 600 BC pure metallic tin was produced. Pewter, which is an alloy of 85–90% tin with the remainder commonly consisting of copper, antimony and lead, was used for tableware from the Bronze Age until the 20th century. In modern times tin is used in many alloys, most notably tin/lead soft solders, typically containing 60% or more of tin. Another large application for tin is