Origin and use of the term metalloid antimony and tellurium, was recorded merely on a 'sometimes' basis. Use of the term metalloid subsequently underwent a period of great flux up to 1940. Consensus as to its application to intermediate or borderline elements did not occur until the ensuing years, between 1940 and 1960. In 1947, Pauling included a reference to metalloids in his classic and influential textbook, "General chemistry: An introduction to descriptive chemistry and modern chemical theory." He described them as 'elements with intermediate properties ... occupy[ing] a diagonal region [on the periodic table], which includes boron, silicon, germanium, arsenic, antimony, tellurium, and polonium.' In 1959
Arsenic pentachloride more stable and the instability of AsCl appears anomalous. The cause is believed to be due to incomplete shielding of the nucleus in the elements following the first transition series (i.e. gallium, germanium, arsenic, selenium, bromine, and krypton) which leads to stabilisation of their 4s electrons making them less available for bonding. This effect has been termed the d-block contraction and is similar to the f-block contraction normally termed the lanthanide contraction. Arsenic pentachloride Arsenic pentachloride is a chemical compound of arsenic and chlorine. This compound was first prepared in 1976 through the UV irradiation of arsenic trichloride, AsCl, in