Statistical physics a probabilistic examination of the underlying microscopic systems. Historically, one of the first topics in physics where statistical methods were applied was the field of mechanics, which is concerned with the motion of particles or objects when subjected to a force. Statistical mechanics provides a framework for relating the microscopic properties of individual atoms and molecules to the macroscopic or bulk properties of materials that can be observed in everyday life, therefore explaining thermodynamics as a natural result of statistics, classical mechanics, and quantum mechanics at the microscopic level. Because of this history, the statistical physics is often considered synonymous
Metastability preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: The metastability concept originated in the physics of first-order phase transitions. It then acquired new meaning in the study of aggregated subatomic particles (in atomic nuclei or in atoms) or in molecules, macromolecules or clusters of atoms and molecules. Later, it was borrowed for the study of decision-making and information transmission systems. Many complex natural and man-made systems can demonstrate metastability. Non-equilibrium thermodynamics is a branch of physics that studies the dynamics