Atoms in molecules Atoms in molecules The quantum theory of atoms in molecules (QTAIM) is a model of molecular and condensed matter electronic systems (such as crystals) in which the principal objects of molecular structure - atoms and bonds - are natural expressions of a system's observable electron density distribution function. An electron density distribution of a molecule is a probability distribution that describes the average manner in which the electronic charge is distributed throughout real space in the attractive field exerted by the nuclei. According to QTAIM, molecular structure is revealed by the stationary points of the electron density together with the
Electron affinity Electron affinity In chemistry and atomic physics, the electron affinity ("E") of an atom or molecule is defined as the amount of energy "released" or "spent" when an electron is added to a neutral atom or molecule in the gaseous state to form a negative ion. In solid state physics, the electron affinity for a surface is defined somewhat differently (see below). This property is measured for atoms and molecules in the gaseous state only, since in a solid or liquid state their energy levels would be changed by contact with other atoms or molecules. A list of the electron