Guar gum improved electrolyte compatibility. These changes in properties result in increased use in different fields, like textile printing, explosives, and oil-water fracturing applications. Guar molecules have a tendency to aggregate during the hydraulic fracturing process, mainly due to intermolecular hydrogen bonding. These aggregates are detrimental to oil recovery because they clog the fractures, restricting the flow of oil. Cross-linking guar polymer chains prevents aggregation by forming metal – hydroxyl complexes. The first crosslinked guar gels were developed in the late ‘60’s. Several metal additives have been used for crosslinking, among them are chromium, aluminum, antimony, zirconium, and the more commonly used,
Hydraulic fracturing formation. There are two methods of transporting proppant in the fluidhigh-rate and high-viscosity. High-viscosity fracturing tends to cause large dominant fractures, while high-rate (slickwater) fracturing causes small spread-out micro-fractures. Water-soluble gelling agents (such as guar gum) increase viscosity and efficiently deliver proppant into the formation. Fluid is typically a slurry of water, proppant, and chemical additives. Additionally, gels, foams, and compressed gases, including nitrogen, carbon dioxide and air can be injected. Typically, 90% of the fluid is water and 9.5% is sand with chemical additives accounting to about 0.5%. However, fracturing fluids have been developed using liquefied petroleum gas (LPG)