Guar gum needs to be thin enough to make it easier to pump. Then as it flows down the pipe, the fluid needs to gel up to support the proppant and flush it deep into the fractures. After that process, the gel has to break down so we can flow back and recover the fracking fluid, but leave the proppant behind. This requires a chemical process which produces then breaks the gel cross-linking at a predictable rate. Guar+boron+proprietary chemicals can accomplish both of these goals at once. Guar gum retards ice crystal growth nonspecifically by slowing mass transfer across the solid/liquid interface.
Guar gum gum shows a clear low shear plateau on the flow curve and is strongly shear thinning. The rheology of guar gum is typical for a random coil polymer. It does not show the very high low shear plateau viscosities seen with more rigid polymer chains such as xanthan gum. It is very thixotropic above 1% concentration, but below 0.3%, the thixotropy is slight. Guar gum shows viscosity synergy with xanthan gum. Guar gum and micellar casein mixtures can be slightly thixotropic if a biphase system forms. One use of guar gum is as a thickening agent in foods and medicines