Atomic, molecular, and optical physics electron is treated quantum mechanically. In low speed collisions the approximation fails. Classical Monte-Carlo methods for the dynamics of electrons can be described as semi-classical in that the initial conditions are calculated using a fully quantum treatment, but all further treatment is classical. Atomic, Molecular and Optical physics frequently considers atoms and molecules in isolation. Atomic models will consist of a single nucleus that may be surrounded by one or more bound electrons, whilst molecular models are typically concerned with molecular hydrogen and its molecular hydrogen ion. It is concerned with processes such as ionization, above threshold ionization and excitation
Atomic orbital as a starting point for the calculation of the properties of atoms and molecules with many electrons: Although hydrogen-like orbitals are still used as pedagogical tools, the advent of computers has made STOs preferable for atoms and diatomic molecules since combinations of STOs can replace the nodes in hydrogen-like atomic orbital. Gaussians are typically used in molecules with three or more atoms. Although not as accurate by themselves as STOs, combinations of many Gaussians can attain the accuracy of hydrogen-like orbitals. The term "orbital" was coined by Robert Mulliken in 1932 as an abbreviation for "one-electron orbital wave function". However,