Guar gum improved electrolyte compatibility. These changes in properties result in increased use in different fields, like textile printing, explosives, and oil-water fracturing applications. Guar molecules have a tendency to aggregate during the hydraulic fracturing process, mainly due to intermolecular hydrogen bonding. These aggregates are detrimental to oil recovery because they clog the fractures, restricting the flow of oil. Cross-linking guar polymer chains prevents aggregation by forming metal – hydroxyl complexes. The first crosslinked guar gels were developed in the late ‘60’s. Several metal additives have been used for crosslinking, among them are chromium, aluminum, antimony, zirconium, and the more commonly used,
Sol–gel process Sol–gel process In materials science, the sol–gel process is a method for producing solid materials from small molecules. The method is used for the fabrication of metal oxides, especially the oxides of silicon (Si) and titanium (Ti). The process involves conversion of monomers into a colloidal solution ("sol") that acts as the precursor for an integrated network (or "gel") of either discrete particles or network polymers. Typical precursors are metal alkoxides. In this chemical procedure, a "sol" (a colloidal solution) is formed that then gradually evolves towards the formation of a gel-like diphasic system containing both a liquid phase and