Atomic, molecular, and optical physics and chemical physics. Both subfields are primarily concerned with electronic structure and the dynamical processes by which these arrangements change. Generally this work involves using quantum mechanics. For molecular physics, this approach is known as quantum chemistry. One important aspect of molecular physics is that the essential atomic orbital theory in the field of atomic physics expands to the molecular orbital theory. Molecular physics is concerned with atomic processes in molecules, but it is additionally concerned with effects due to the molecular structure. Additionally to the electronic excitation states which are known from atoms, molecules are able to rotate and
Atomic form factor increases with the atomic number, formula_11, of the atoms in a sample. As a result X-rays are not very sensitive to light atoms, such as hydrogen and helium, and there is very little contrast between elements adjacent to each other in the periodic table. For X-ray scattering, formula_12 in the above equation is the electron charge density about the nucleus, and the form factor the Fourier transform of this quantity. The assumption of a spherical distribution is usually good enough for X-ray crystallography. In general the X-ray form factor is complex but the imaginary components only become large near an