Corrosive substance due to their capabilities of dissolving greases, proteins or mineral deposits such as limescale inside water pipes. In chemical uses, high chemical reactivity is often desirable, as the rates of chemical reactions depend on the activity (effective concentration) of the reactive species. For instance, catalytic sulfuric acid is used in the alkylation process in an oil refinery: the activity of carbocations, the reactive intermediate, is higher with stronger acidity, and thus the reaction proceeds faster. Once used, corrosives are most often recycled or neutralized. However, there have been environmental problems with untreated corrosive effluents or accidental discharges. Corrosive substance A
Gilbert N. Lewis been rationalized as a logical system, from which, given one relation, the rest could be derived. Moreover, these relations were inexact, applying only to ideal chemical systems. These were two outstanding problems of theoretical thermodynamics. In two long and ambitious theoretical papers in 1900 and 1901, Lewis tried to provide a solution. Lewis introduced the thermodynamic concept of activity and coined the term "fugacity". His new idea of fugacity, or "escaping tendency", was a function with the dimensions of pressure which expressed the tendency of a substance to pass from one chemical phase to another. Lewis believed that fugacity was