Alessandro Volta an early electric battery, which produced a steady electric current. Volta had determined that the most effective pair of dissimilar metals to produce electricity was zinc and copper. Initially he experimented with individual cells in series, each cell being a wine goblet filled with brine into which the two dissimilar electrodes were dipped. The voltaic pile replaced the goblets with cardboard soaked in brine. In announcing his discovery of the voltaic pile, Volta paid tribute to the influences of William Nicholson, Tiberius Cavallo, and Abraham Bennet. The battery made by Volta is credited as one of the first electrochemical cells.
Volta potential by its work function, and so dissimilar metals can show an electric potential difference even at equilibrium. The Volta potential is "not" an intrinsic property of the two bulk metals under consideration, but rather is determined by work function differences between the metals' surfaces. Just like the work function, the Volta potential depends sensitively on surface state, contamination, and so on. The potential is given by the formula: formula_1, where V is the potential, The Volta potential can be significant (of order 1 volt) but it cannot be measured directly by an ordinary voltmeter. A voltmeter does not measure vacuum