Alessandro Volta an early electric battery, which produced a steady electric current. Volta had determined that the most effective pair of dissimilar metals to produce electricity was zinc and copper. Initially he experimented with individual cells in series, each cell being a wine goblet filled with brine into which the two dissimilar electrodes were dipped. The voltaic pile replaced the goblets with cardboard soaked in brine. In announcing his discovery of the voltaic pile, Volta paid tribute to the influences of William Nicholson, Tiberius Cavallo, and Abraham Bennet. The battery made by Volta is credited as one of the first electrochemical cells.
Alessandro Volta with brine-soaked paper, and detected the flow of electricity by other means familiar to him from his previous studies. In this way he discovered the electrochemical series, and the law that the electromotive force (emf) of a galvanic cell, consisting of a pair of metal electrodes separated by electrolyte, is the difference between their two electrode potentials (thus, two identical electrodes and a common electrolyte give zero net emf). This may be called Volta's Law of the electrochemical series. In 1800, as the result of a professional disagreement over the galvanic response advocated by Galvani, Volta invented the voltaic pile,