Graphene Graphene Graphene is an allotrope (form) of carbon consisting of a single layer of carbon atoms arranged in a hexagonal lattice. It is a semimetal with small overlap between the valence and the conduction bands (zero bandgap material).<ref name="10.1002/adma.201502544 p.6519-6525"></ref> It is the basic structural element of many other allotropes of carbon, such as graphite, diamond, charcoal, carbon nanotubes and fullerenes. Graphene has many uncommon properties. It is the strongest material ever tested, conducts heat and electricity efficiently, and is nearly transparent. Graphene shows a large and nonlinear diamagnetism, greater than that of graphite, and can be levitated by neodymium
Atom transfer radical polymerization new catalysis system involving photoredox reaction of 10-phenothiazine. The metal-free ATRP has been demonstrated to be capable of controlled polymerization of methacrylates. This technique was later expanded to polymerization of acrylonitrile by Matyjaszewski et al. Atom transfer radical polymerization Atom transfer radical polymerization (ATRP) is an example of a reversible-deactivation radical polymerization. Like its counterpart, ATRA, or atom transfer radical addition, ATRP is a means of forming a carbon-carbon bond with a transition metal catalyst. The polymerization from this method is called atom transfer radical addition polymerization (ATRAP). As the name implies, the atom transfer step is crucial in the