Isotope geochemistry this reason, enrichments are typically reported in "per mil" (‰, parts per thousand). These enrichments (δ) represent the ratio of heavy isotope to light isotope in the sample over the ratio of a standard. That is, Hydrogen isotope biogeochemistry Carbon has two stable isotopes, C and C, and one radioactive isotope, C. The stable carbon isotope ratio, "δ"C, is measured against Vienna Pee Dee Belemnite (VPDB). The stable carbon isotopes are fractionated primarily by photosynthesis (Faure, 2004). The C/C ratio is also an indicator of paleoclimate: a change in the ratio in the remains of plants indicates a change in
Kinetic isotope effect now relatively routine. Moreover, several qualitative and semi-quantitative models allow rough estimates of deuterium isotope effects to be made without calculations, often providing enough information to rationalize experimental data or even support or refute different mechanistic possibilities. Starting materials containing deuterium are often commercially available, making the synthesis of isotopically enriched starting materials relatively straightforward. Also, due to the large relative difference in the mass of deuterium and protium and the attendant differences in vibrational frequencies, the magnitude of the isotope effect is larger than any other pair of isotopes except protium and tritium, allowing both primary and secondary isotope