Derailleur gears by 13 drive-train. Most road bicycles have two chainrings, and touring bicycles commonly have three. The rear derailleur serves double duty: moving the chain between rear sprockets and taking up chain slack caused by moving to a smaller sprocket at the rear or a smaller chainring by the front derailleur. In order to accomplish this second task, it is positioned in the path of the bottom, slack portion of chain. Sometimes the rear-derailleurs are re-purposed as chain tensioners for single-speed bicycles that cannot adjust chain tension by a different method. Although variations exist, as noted below, most rear derailleurs have
Reaction mechanism bonds are broken (and in what order), and which bonds are formed (and in what order). A complete mechanism must also explain the reason for the reactants and catalyst used, the stereochemistry observed in reactants and products, all products formed and the amount of each. The electron or arrow pushing method is often used in illustrating a reaction mechanism; for example, see the illustration of the mechanism for benzoin condensation in the following examples section. A reaction mechanism must also account for the order in which molecules react. Often what appears to be a single-step conversion is in fact a