Tritium ordinary hydrogen, but they do fuse the small minority of deuterium nuclei. Like the other isotopes of hydrogen, tritium is difficult to confine. Rubber, plastic, and some kinds of steel are all somewhat permeable. This has raised concerns that if tritium were used in large quantities, in particular for fusion reactors, it may contribute to radioactive contamination, although its short half-life should prevent significant long-term accumulation in the atmosphere. The high levels of atmospheric nuclear weapons testing that took place prior to the enactment of the Partial Test Ban Treaty proved to be unexpectedly useful to oceanographers. The high levels
Kinetic isotope effect now relatively routine. Moreover, several qualitative and semi-quantitative models allow rough estimates of deuterium isotope effects to be made without calculations, often providing enough information to rationalize experimental data or even support or refute different mechanistic possibilities. Starting materials containing deuterium are often commercially available, making the synthesis of isotopically enriched starting materials relatively straightforward. Also, due to the large relative difference in the mass of deuterium and protium and the attendant differences in vibrational frequencies, the magnitude of the isotope effect is larger than any other pair of isotopes except protium and tritium, allowing both primary and secondary isotope