Kinetic isotope effect approximation that reduced masses are approximately equal to the masses of the hydrogen, deuterium, or tritium was used. In addition, the vibrational motion was assumed to be approximated by a harmonic oscillator, so that formula_19 (X = H, D, or T). The subscript ""s"" refers to these "semi-classical" kinetic isotope effects, which disregard quantum tunneling. Tunneling contributions must be treated separately as a correction factor. For isotope effects involving elements other than hydrogen, many of these simplifications are not valid, and the magnitude of the isotope effect may depend strongly on some or all of the neglected factors. Thus, kinetic
Tritium tritium on the Earth's surface; but these amounts rose by 2 or 3 orders of magnitude during the post-test period. Some sources reported natural background levels were exceeded by approximately 1,000 TU in 1963 and 1964 and the isotope is used in the northern hemisphere to estimate the age of groundwater and construct hydrogeologic simulation models. Recent scientific sources have estimated atmospheric levels at the height of weapons testing to approach 1,000 TU and pre-fallout levels of rainwater to be between 5 and 10 TU. In 1963 Valentia Island Ireland recorded 2,000 TU in precipitation. While in the stratosphere (post-test