Isotope geochemistry this reason, enrichments are typically reported in "per mil" (‰, parts per thousand). These enrichments (δ) represent the ratio of heavy isotope to light isotope in the sample over the ratio of a standard. That is, Hydrogen isotope biogeochemistry Carbon has two stable isotopes, C and C, and one radioactive isotope, C. The stable carbon isotope ratio, "δ"C, is measured against Vienna Pee Dee Belemnite (VPDB). The stable carbon isotopes are fractionated primarily by photosynthesis (Faure, 2004). The C/C ratio is also an indicator of paleoclimate: a change in the ratio in the remains of plants indicates a change in
Hydrogen isotope biogeochemistry constants would allow extrapolation to original isotopic compositions. While this solution holds promise, there is too much disagreement in the literature for robust calibrations. Vapor isotope effects occur for protium, deuterium, and tritium, because each isotope has different thermodynamic properties in the liquid and gaseous phases. For water molecules, the condensed phase is more enriched while the vapor is more depleted. For example, rain condensing from a cloud will be heavier than the vapor starting point. Generally, the large variations in deuterium concentrations of water are from the fractionations between liquid, vapor, and solid reservoirs. In contrast to the fractionation