Derailleur gears operates the lever while pedalling, the change in cable tension moves the chain-guide from side to side, "derailing" the chain onto different sprockets. For more information about the choice of particular gear ratios and sprocket sizes, see Bicycle gearing. "Derailleur" is a French word, spelled "dérailleur" in French, derived from the derailment of a train from its tracks. Its first recorded use was 1930. At least one notable bicycle industry author has attempted to promote the anglicized spelling of "derailer". As of 2013, however, neither Merriam-Webster nor the Oxford English Dictionary has an entry for "derailer". Various derailleur systems were
Reaction mechanism bonds are broken (and in what order), and which bonds are formed (and in what order). A complete mechanism must also explain the reason for the reactants and catalyst used, the stereochemistry observed in reactants and products, all products formed and the amount of each. The electron or arrow pushing method is often used in illustrating a reaction mechanism; for example, see the illustration of the mechanism for benzoin condensation in the following examples section. A reaction mechanism must also account for the order in which molecules react. Often what appears to be a single-step conversion is in fact a