Derailleur gears a detent or ratchet mechanism which stops the gear lever, and hence the cable and the derailleur, after moving a specific distance with each press or pull. Indexed shifters require re-calibration when cables stretch and parts get damaged or swapped. On racing bicycles, 10-gear rear cassettes appeared in 2000, and 11-gear cassettes appeared in 2009. Most current mountain bicycles have either. Many modern, high-end mountain bikes have begun using entirely one chain ring drivetrains, with the industry constantly pushing the number of rear cogs up and up, as shown by SRAM's Eagle groupsets (1 by 12) and Rotor's recent 1
Reaction mechanism bonds are broken (and in what order), and which bonds are formed (and in what order). A complete mechanism must also explain the reason for the reactants and catalyst used, the stereochemistry observed in reactants and products, all products formed and the amount of each. The electron or arrow pushing method is often used in illustrating a reaction mechanism; for example, see the illustration of the mechanism for benzoin condensation in the following examples section. A reaction mechanism must also account for the order in which molecules react. Often what appears to be a single-step conversion is in fact a