Kinetic isotope effect effects, while "k"/"k" ~ 1.15-1.3 are typical for β secondary kinetic isotope effect. For reactants containing several isotopically-substituted β-hydrogen atoms, the observed isotope effect is often the result of several H/D's at the β position acting in concert. In these cases, the effect of each isotopically-labeled atom is multiplicative, and cases where "k"/"k" > 2 are not uncommon. The following simple expressions relating deuterium and tritium kinetic isotope effects, which are also known as the Swain equation (or the Swain-Schaad-Stivers equations), can be derived from the general expression given above using some simplifications: i.e., In deriving these expressions, the reasonable
Beta particle long as the tritium exists (and the phosphors do not themselves chemically change); the amount of light produced will drop to half its original value in 12.32 years, the half-life of tritium. Beta-plus (or positron) decay of a radioactive tracer isotope is the source of the positrons used in positron emission tomography (PET scan). Henri Becquerel, while experimenting with fluorescence, accidentally found out that uranium exposed a photographic plate, wrapped with black paper, with some unknown radiation that could not be turned off like X-rays. Ernest Rutherford continued these experiments and discovered two different kinds of radiation: He published his