Volatility (chemistry) Volatility (chemistry) In chemistry and physics, volatility is quantified by the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure. At a given temperature, a substance with higher vapor pressure vaporizes more readily than a substance with a lower vapor pressure. The term is primarily written to be applied to liquids; however, it may be used to describe the process of sublimation which is associated with solid substances, such as dry ice (solid carbon dioxide) and osmium tetroxide (OsO), which can change directly from the solid state to a vapor, without becoming liquid. The
Physical chemistry Physical chemistry Physical chemistry is the study of macroscopic, atomic, subatomic, and particulate phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibrium. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a macroscopic or supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular/atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to resolve include the effects