Kinetic isotope effect effects, while "k"/"k" ~ 1.15-1.3 are typical for β secondary kinetic isotope effect. For reactants containing several isotopically-substituted β-hydrogen atoms, the observed isotope effect is often the result of several H/D's at the β position acting in concert. In these cases, the effect of each isotopically-labeled atom is multiplicative, and cases where "k"/"k" > 2 are not uncommon. The following simple expressions relating deuterium and tritium kinetic isotope effects, which are also known as the Swain equation (or the Swain-Schaad-Stivers equations), can be derived from the general expression given above using some simplifications: i.e., In deriving these expressions, the reasonable
Tritium radioluminescence for night use and small lights (which need to be more reliable than battery powered lights yet not interfere with night vision or be bright enough to easily give away one's location) used mostly by military personnel fall under the latter application. Tritium lighting is made using glass tubes with a phosphor layer in them and tritium gas inside the tube. Such a tube is known as a "gaseous tritium light source" (GTLS), or "beta light" (since the tritium undergoes beta decay). The tritium in a gaseous tritium light source undergoes beta decay, releasing electrons that cause the phosphor layer