Willis Resilience Expedition of the deposition rate of Tritium, a radioactive isotope of hydrogen, across Antarctica. The relatively short half-life of Tritium means it can be used to date snow and ice up to around 150 years old. The data can then be used to better understand the global water cycle, which is intrinsically linked to changes in climate. This will be the first large-scale study of Tritium in Antarctica since Tritium returned to normal levels following the spike caused by thermonuclear tests in the 1960s. The samples will be sent to GNS Science, a New Zealand Crown Research Institute, for analysis. Once
Hydrogen isotope biogeochemistry constants would allow extrapolation to original isotopic compositions. While this solution holds promise, there is too much disagreement in the literature for robust calibrations. Vapor isotope effects occur for protium, deuterium, and tritium, because each isotope has different thermodynamic properties in the liquid and gaseous phases. For water molecules, the condensed phase is more enriched while the vapor is more depleted. For example, rain condensing from a cloud will be heavier than the vapor starting point. Generally, the large variations in deuterium concentrations of water are from the fractionations between liquid, vapor, and solid reservoirs. In contrast to the fractionation