Kinetic isotope effect approximation that reduced masses are approximately equal to the masses of the hydrogen, deuterium, or tritium was used. In addition, the vibrational motion was assumed to be approximated by a harmonic oscillator, so that formula_19 (X = H, D, or T). The subscript ""s"" refers to these "semi-classical" kinetic isotope effects, which disregard quantum tunneling. Tunneling contributions must be treated separately as a correction factor. For isotope effects involving elements other than hydrogen, many of these simplifications are not valid, and the magnitude of the isotope effect may depend strongly on some or all of the neglected factors. Thus, kinetic
Radioactive contamination from the Rocky Flats Plant caused by normal operations rather than accidental releases. From September 1947 to April 1969 there were 5 or more accidental surface water releases of tritium. Tritium, a radioactive element which was found in scrap material from Rocky Flats, was therefore directed in to the Great Western Reservoir. This was uncovered in 1973 and following this, urine samples were taken from people living or working near Broomfield who could have drunk water from the reservoir. The findings of the samples showed that those who were exposed to contaminated water had tritium concentrations near seven times higher than normal (4,300 picocuries per