Tritium consists of about 4.5 kilograms of plutonium-239. Since tritium undergoes radioactive decay, and is also difficult to confine physically, the much larger secondary charge of heavy hydrogen isotopes needed in a true hydrogen bomb uses solid lithium deuteride as its source of deuterium and tritium, producing the tritium "in situ" during secondary ignition. During the detonation of the primary fission bomb stage in a thermonuclear weapon (Teller-Ullam staging), the sparkplug, a cylinder of U-235/Pu-239 at the center of the fusion stage(s), begins to fission in a chain reaction, from excess neutrons channeled from the primary. The neutrons released from the
Tritium emitted by nuclear fission. This potentially offsets or reverses the intended effect of the tritium, which was to generate many free neutrons, if too much helium-3 has accumulated from the decay of tritium. Therefore, it is necessary to replenish tritium in boosted bombs periodically. The estimated quantity needed is 4 grams per warhead. To maintain constant levels of tritium, about 0.20 grams per warhead per year must be supplied to the bomb. One mole of deuterium-tritium gas would contain about 3.0 grams of tritium and 2.0 grams of deuterium. In comparison, the 20 moles of plutonium in a nuclear bomb