Hydrogen isotope biogeochemistry assumed that helium-3 was the radioactive component. The work of Luis Walter Alvarez and Robert Cornog first isolated tritium and reversed Rutherford's incorrect notion. Alvarez reasoned that tritium was radioactive, but did not measure the half-life, although calculations at the time suggested over ten years. At the end of World War II, the physical chemist Willard Libby detected the residual radioactivity of a tritium sample with a Geiger counter, providing a more accurate understanding of the half-life, now accepted at 12.3 years. The discovery of hydrogen isotopes also impacted the field of physics in the 1940s, as Nuclear Magnetic Resonance
Tritium boron, cadmium, or hafnium), at the reactors of the commercial Watts Bar Nuclear Generating Station from 2003–2005 followed by extraction of tritium from the rods at the new Tritium Extraction Facility at the Savannah River Site beginning in November 2006. Tritium leakage from the rods during reactor operations limits the number that can be used in any reactor without exceeding the maximum allowed tritium levels in the coolant. Tritium has an atomic mass of 3.0160492 u. Diatomic tritium ( or ) is a gas at standard temperature and pressure. Combined with oxygen, it forms a liquid called tritiated water ().