Volatility (chemistry) Volatility (chemistry) In chemistry and physics, volatility is quantified by the tendency of a substance to vaporize. Volatility is directly related to a substance's vapor pressure. At a given temperature, a substance with higher vapor pressure vaporizes more readily than a substance with a lower vapor pressure. The term is primarily written to be applied to liquids; however, it may be used to describe the process of sublimation which is associated with solid substances, such as dry ice (solid carbon dioxide) and osmium tetroxide (OsO), which can change directly from the solid state to a vapor, without becoming liquid. The
Degrees of freedom (physics and chemistry) In quantum mechanics, the motion degrees of freedom are superseded with the concept of wave function, and operators which correspond to other degrees of freedom have discrete spectra. For example, intrinsic angular momentum operator (which corresponds to the rotational freedom) for an electron or photon has only two eigenvalues. This discreteness becomes apparent when action has an order of magnitude of the Planck constant, and individual degrees of freedom can be distinguished. Degrees of freedom (physics and chemistry) In physics, a degree of freedom is an independent physical parameter in the formal description of the state of a physical system.