Tritium consists of about 4.5 kilograms of plutonium-239. Since tritium undergoes radioactive decay, and is also difficult to confine physically, the much larger secondary charge of heavy hydrogen isotopes needed in a true hydrogen bomb uses solid lithium deuteride as its source of deuterium and tritium, producing the tritium "in situ" during secondary ignition. During the detonation of the primary fission bomb stage in a thermonuclear weapon (Teller-Ullam staging), the sparkplug, a cylinder of U-235/Pu-239 at the center of the fusion stage(s), begins to fission in a chain reaction, from excess neutrons channeled from the primary. The neutrons released from the
Kinetic isotope effect now relatively routine. Moreover, several qualitative and semi-quantitative models allow rough estimates of deuterium isotope effects to be made without calculations, often providing enough information to rationalize experimental data or even support or refute different mechanistic possibilities. Starting materials containing deuterium are often commercially available, making the synthesis of isotopically enriched starting materials relatively straightforward. Also, due to the large relative difference in the mass of deuterium and protium and the attendant differences in vibrational frequencies, the magnitude of the isotope effect is larger than any other pair of isotopes except protium and tritium, allowing both primary and secondary isotope