Hydrogen isotope biogeochemistry assumed that helium-3 was the radioactive component. The work of Luis Walter Alvarez and Robert Cornog first isolated tritium and reversed Rutherford's incorrect notion. Alvarez reasoned that tritium was radioactive, but did not measure the half-life, although calculations at the time suggested over ten years. At the end of World War II, the physical chemist Willard Libby detected the residual radioactivity of a tritium sample with a Geiger counter, providing a more accurate understanding of the half-life, now accepted at 12.3 years. The discovery of hydrogen isotopes also impacted the field of physics in the 1940s, as Nuclear Magnetic Resonance
Tritium emitted by nuclear fission. This potentially offsets or reverses the intended effect of the tritium, which was to generate many free neutrons, if too much helium-3 has accumulated from the decay of tritium. Therefore, it is necessary to replenish tritium in boosted bombs periodically. The estimated quantity needed is 4 grams per warhead. To maintain constant levels of tritium, about 0.20 grams per warhead per year must be supplied to the bomb. One mole of deuterium-tritium gas would contain about 3.0 grams of tritium and 2.0 grams of deuterium. In comparison, the 20 moles of plutonium in a nuclear bomb