Kinetic isotope effect approximation that reduced masses are approximately equal to the masses of the hydrogen, deuterium, or tritium was used. In addition, the vibrational motion was assumed to be approximated by a harmonic oscillator, so that formula_19 (X = H, D, or T). The subscript ""s"" refers to these "semi-classical" kinetic isotope effects, which disregard quantum tunneling. Tunneling contributions must be treated separately as a correction factor. For isotope effects involving elements other than hydrogen, many of these simplifications are not valid, and the magnitude of the isotope effect may depend strongly on some or all of the neglected factors. Thus, kinetic
Beta particle long as the tritium exists (and the phosphors do not themselves chemically change); the amount of light produced will drop to half its original value in 12.32 years, the half-life of tritium. Beta-plus (or positron) decay of a radioactive tracer isotope is the source of the positrons used in positron emission tomography (PET scan). Henri Becquerel, while experimenting with fluorescence, accidentally found out that uranium exposed a photographic plate, wrapped with black paper, with some unknown radiation that could not be turned off like X-rays. Ernest Rutherford continued these experiments and discovered two different kinds of radiation: He published his