Kinetic isotope effect approximation that reduced masses are approximately equal to the masses of the hydrogen, deuterium, or tritium was used. In addition, the vibrational motion was assumed to be approximated by a harmonic oscillator, so that formula_19 (X = H, D, or T). The subscript ""s"" refers to these "semi-classical" kinetic isotope effects, which disregard quantum tunneling. Tunneling contributions must be treated separately as a correction factor. For isotope effects involving elements other than hydrogen, many of these simplifications are not valid, and the magnitude of the isotope effect may depend strongly on some or all of the neglected factors. Thus, kinetic
Isotopes of hydrogen u) is known as "tritium" and contains one proton and two neutrons in its nucleus. It is radioactive, decaying into helium-3 through β− decay with a half-life of 12.32 years. Trace amounts of tritium occur naturally because of the interaction of cosmic rays with atmospheric gases. Tritium has also been released during nuclear weapons tests. It is used in thermonuclear fusion weapons, as a tracer in isotope geochemistry, and specialized in self-powered lighting devices. The most common method of producing tritium is by bombarding a natural isotope of lithium, lithium-6, with neutrons in a nuclear reactor. Tritium was once used