Kinetic isotope effect effects, while "k"/"k" ~ 1.15-1.3 are typical for β secondary kinetic isotope effect. For reactants containing several isotopically-substituted β-hydrogen atoms, the observed isotope effect is often the result of several H/D's at the β position acting in concert. In these cases, the effect of each isotopically-labeled atom is multiplicative, and cases where "k"/"k" > 2 are not uncommon. The following simple expressions relating deuterium and tritium kinetic isotope effects, which are also known as the Swain equation (or the Swain-Schaad-Stivers equations), can be derived from the general expression given above using some simplifications: i.e., In deriving these expressions, the reasonable
On-Line Isotope Mass Separator or to the REX accelerator for acceleration to higher energies. The facility is operated by the ISOLDE Collaboration comprising CERN and 9 European countries. One of the major experiments in ISOLDE is the Miniball-setup. An upgrade of the post-acceleration system is currently on-going, ready to produce energetic Radioactive-Ion Beams (RIBs) of up to 10 MeV per nucleon in 2018. On-Line Isotope Mass Separator The On-Line Isotope Mass Separator, also known as the ISOLDE Radioactive Ion Beam Facility, is a facility located at CERN on the PS Booster. It started operating in 1967 and was rebuilt twice with major upgrades in