Kinetic isotope effect approximation that reduced masses are approximately equal to the masses of the hydrogen, deuterium, or tritium was used. In addition, the vibrational motion was assumed to be approximated by a harmonic oscillator, so that formula_19 (X = H, D, or T). The subscript ""s"" refers to these "semi-classical" kinetic isotope effects, which disregard quantum tunneling. Tunneling contributions must be treated separately as a correction factor. For isotope effects involving elements other than hydrogen, many of these simplifications are not valid, and the magnitude of the isotope effect may depend strongly on some or all of the neglected factors. Thus, kinetic
Tritium section for thermal neutrons is about 0.52 millibarns, whereas that of oxygen-16 () is about 0.19 millibarns and that of oxygen-17 () is about 240 millibarns. Tritium is an uncommon product of the nuclear fission of uranium-235, plutonium-239, and uranium-233, with a production of about one atom per each 10,000 fissions. The release or recovery of tritium needs to be considered in the operation of nuclear reactors, especially in the reprocessing of nuclear fuels and in the storage of spent nuclear fuel. The production of tritium is not a goal, but rather a side-effect. It is discharged to the atmosphere