Hydrogen isotope biogeochemistry assumed that helium-3 was the radioactive component. The work of Luis Walter Alvarez and Robert Cornog first isolated tritium and reversed Rutherford's incorrect notion. Alvarez reasoned that tritium was radioactive, but did not measure the half-life, although calculations at the time suggested over ten years. At the end of World War II, the physical chemist Willard Libby detected the residual radioactivity of a tritium sample with a Geiger counter, providing a more accurate understanding of the half-life, now accepted at 12.3 years. The discovery of hydrogen isotopes also impacted the field of physics in the 1940s, as Nuclear Magnetic Resonance
Tritium Therefore, the basin tritium concentration becomes a function of the residence times within the basin, sinks (radioactive decay) or sources of tritium, and the input function. For the Ohio River, the tritium data indicated that about 40% of the flow was composed of precipitation with residence times of less than 1 year (in the Ohio basin) and older waters consisted of residence times of about 10 years. Thus, the short residence times (less than 1 year) corresponded to the "prompt-flow" component of the two-member mixing model. As for the Missouri River, results indicated that residence times were approximately 4 years