Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Frasch process Frasch process The Frasch process is a method to extract sulphur from underground deposits. It is the only industrial method of recovering sulphur from elemental deposits. Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources became more commonplace (see Claus process). In the Frasch process, superheated water is pumped into the sulphur deposit; the sulfur melts and is extracted. The Frasch process is able to produce high purity sulfur. The Frasch sulfur process works best on either salt domes or bedded evaporite deposits, where sulfur is found