Polymer architecture via abstraction of a hydrogen, can create a mid-chain growth site. Branching can be quantified by the branching index. An effect related to branching is chemical crosslinking - the formation of covalent bonds between chains. Crosslinking tends to increase T and increase strength and toughness. Among other applications, this process is used to strengthen rubbers in a process known as vulcanization, which is based on crosslinking by sulfur. Car tires, for example, are highly crosslinked in order to reduce the leaking of air out of the tire and to toughen their durability. Eraser rubber, on the other hand, is not
Rubber band approximation) that elastic polymers do not store any potential energy in stretched chemical bonds. No elastic work is done to "stretch" molecules when work is done upon these bulk polymers. Instead, all work done to the rubber is "released" (not stored) and appears immediately in the polymer as thermal energy. Conversely, when the polymer does work on the surroundings (such as contracting to lift an object) it converts thermal energy to work in the process and cools in the same manner as an ideal gas, expanding while doing work. In the UK during 2004, following complaints from the public about