Branching (polymer chemistry) Branching (polymer chemistry) In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiply branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard
Sulfur 14th century the Latin ' was restored, for '; and by the 15th century the full Latin spelling was restored, for "sulfur, sulphur". The parallel "f~ph" spellings continued in Britain until the 19th century, when the word was standardized as "sulphur". "Sulfur" was the form chosen in the United States, whereas Canada uses both. The IUPAC adopted the spelling "sulfur" in 1990, as did the Nomenclature Committee of the Royal Society of Chemistry in 1992, restoring the spelling "sulfur" to Britain. Oxford Dictionaries note that "in chemistry and other technical uses ... the "-f-" spelling is now the standard form