Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Rubber toughening makes epoxies a candidate of interest for rubber toughening research to fine-tune the toughening processes. Some of the factors affecting the toughness of epoxy nanocomposites include the chemical identity of the epoxy curing agent, entanglement density, and interfacial adhesion. Curing epoxy 618 with piperidine, for example, produces tougher epoxies than when boron trifluoride-ethylamine is used. Low entanglement density increases the toughness. Bisphenol A can be added to lower the crosslinking density of epoxy 618, thereby increasing the fracture toughness. Bisphenol A and a rubber filler increase toughness synergistically. In textbooks and literature before 2002 it was assumed that there is