Branching (polymer chemistry) Branching (polymer chemistry) In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiply branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard
Frasch process Frasch process The Frasch process is a method to extract sulphur from underground deposits. It is the only industrial method of recovering sulphur from elemental deposits. Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources became more commonplace (see Claus process). In the Frasch process, superheated water is pumped into the sulphur deposit; the sulfur melts and is extracted. The Frasch process is able to produce high purity sulfur. The Frasch sulfur process works best on either salt domes or bedded evaporite deposits, where sulfur is found