Rotational Brownian motion the absorption tends toward a maximum and then declines with increasing frequency. The breakdown in Debye's theory in these regimes can be corrected by including inertial effects; allowing the molecules to be non-spherical; including dipole-dipole interactions between molecules; etc. These are computationally very difficult problems and rotational Brownian motion is a topic of much current research interest. Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between
Brownian bridge Brownian bridge A Brownian bridge is a continuous-time stochastic process "B"("t") whose probability distribution is the conditional probability distribution of a Wiener process "W"("t") (a mathematical model of Brownian motion) subject to the condition (when standardized) that "W"(T) = 0, so that the process is pinned at the origin at both "t=0" and "t=T". More precisely: The expected value of the bridge is zero, with variance formula_2, implying that the most uncertainty is in the middle of the bridge, with zero uncertainty at the nodes. The covariance of "B"("s") and "B"("t") is "s"(T − "t")/T if "s" < "t". The