Rubber toughening a lower limit for rubber-toughening particle diameter at 200 nm; it was then discovered that ultra-fine full-vulcanized powdered rubber particles with diameter of 90 nm show significant toughening of rubber epoxies. This finding underlines how this field is constantly growing and more work can be done to better model the rubber toughening effect. Acrylonitrile butadiene styrene polymer is an application of rubber toughening. The properties of this polymer come mainly from rubber toughening. The polybutadiene rubber domains in the main styrene-acrylonitrile matrix act as a stop to crack propagation. PMMA’s high optical transparency, low cost, and compressibility make it a
Rubber toughening to 30 percent showed a negative linear relationship with the brittle-tough transition temperature, after which the toughness decreased. This suggests that the toughening effect of adding rubber particles is limited to a critical concentration. This is examined further in a study on PMMA from 1998; using SAXS to analyze crazing density, it was found that crazing density increases and yield stress decreases until the critical point when the relationship flips. A material that is expected to fail by crazing is more likely to benefit from larger particles than a shear prone material, which would benefit from a smaller particle. In