Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Rubber toughening of waste rubber from car tires has sparked interest in finding uses for this discarded rubber. The rubber can be turned into a fine powder, which can then be used as a toughening agent for polystyrene. However, poor miscibility between the waste rubber and polystyrene will weaken the material. This problem requires the use of a compatibilizer (see "compatibilization") in order to reduce interfacial tension and ultimately make rubber toughening of polystyrene effective. A polystyrene/styrene-butadiene copolymer acts to increase the adhesion between the dispersed and continuous phases. Rubber toughening Rubber toughening is a process in which rubber nanoparticles are interspersed