Rotational Brownian motion the absorption tends toward a maximum and then declines with increasing frequency. The breakdown in Debye's theory in these regimes can be corrected by including inertial effects; allowing the molecules to be non-spherical; including dipole-dipole interactions between molecules; etc. These are computationally very difficult problems and rotational Brownian motion is a topic of much current research interest. Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between
Perpetual motion costs energy (requiring Maxwell's demon to perform more thermodynamic work to gauge the speed of the molecules than the amount of energy gained by the difference of temperature caused) or the unidirectionality is an illusion and occasional big violations make up for the frequent small non-violations (the Brownian ratchet will be subject to internal Brownian forces and therefore will sometimes turn the wrong way). Buoyancy is another frequently misunderstood phenomenon. Some proposed perpetual-motion machines miss the fact that to push a volume of air down in a fluid takes the same work as to raise a corresponding volume of fluid