Polymer degradation into the bore of the pipe, and fuel leakage and fire may follow. The problem of ozone cracking can be prevented by adding anti-ozonants to the rubber before vulcanization. Ozone cracks were commonly seen in automobile tire sidewalls, but are now seen rarely thanks to these additives. On the other hand, the problem does recur in unprotected products such as rubber tubing and seals. The polymers are susceptible to attack by atmospheric oxygen, especially at elevated temperatures encountered during processing to shape. Many process methods such as extrusion and injection moulding involve pumping molten polymer into tools, and the high
Rubber toughening and CTBN toughened epoxies. Engineers use an energy-balance approach to model how particle size and rubber modulus factors influence material toughness. Both particle size and modulus show positive correlation with brittle-tough transition temperatures. They are both shown to affect the cavitation process occurring at the crack tip process zone early in deformation, preceding large-scale crazing and shear yielding. In order to show increased toughness under strain, the volumetric strain must overcome the energy of void formation as modeled by the equation: formula_1 "where formula_2 and formula_3 are the shear modulus and bulk modulus of the rubber, formula_4 is the volume