Rotational Brownian motion Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between torques due to the imposed electric field, which tend to align the molecules, and collisions, which tend to destroy the alignment. The theory of rotational Brownian motion allows one to calculate the net result of these two competing effects, and to predict how the permittivity of a dielectric material depends on the strength and frequency of the
Brownian bridge Brownian bridge A Brownian bridge is a continuous-time stochastic process "B"("t") whose probability distribution is the conditional probability distribution of a Wiener process "W"("t") (a mathematical model of Brownian motion) subject to the condition (when standardized) that "W"(T) = 0, so that the process is pinned at the origin at both "t=0" and "t=T". More precisely: The expected value of the bridge is zero, with variance formula_2, implying that the most uncertainty is in the middle of the bridge, with zero uncertainty at the nodes. The covariance of "B"("s") and "B"("t") is "s"(T − "t")/T if "s" < "t". The