Sulfur vulcanization are merely the additives used for vulcanisation and that other compounds may also be added to the rubber such as fillers or polymer stabilizers. Ordinary sulfur (octasulfur) is rarely used despite its low cost. Because of the low melting point of S vs the cure temperatures, attempted vulcanization with ordinary results in sulfur bloom. Instead, various forms of polymeric sulfur are used instead. It is also possible to replace sulfur with other sulfur-donating compounds, for example accelerators bearing disulphide groups, in what is often termed 'efficient vulcanization' (EV). Disulfur dichloride may also be used for 'cold vulcanization'. Under normal circumstances,
Rubber toughening materials where crazing and yielding are comparable, a bimodal distribution of particle size may be useful for toughening. At fixed rubber concentrations, one can find that an optimal particle size is a function of the entanglement density of the polymer matrix. The neat polymer entanglement densities of PS, SAN, and PMMA are 0.056, 0.093, and 0.127 respectively. As entanglement density increases, the optimum particle size decreases linearly, ranging between 0.1 and 3 micrometers. The effect of particle size on toughening is dependent on the type of test performed. This can be explained because for different test conditions, the failure mechanism