Sulfur vulcanization sulfur is not miscible in the polymer prior to vulcanization and attention is paid to prevent sulfur bloom, where it migrates to the surface of the article. Accelerators act much like catalysts allowing vulcanisation to be performed cooler yet faster and with a more efficient use of sulfur. They achieve this by reacting with and breaking the sulfur ring to form a reactive intermediate, referred to as a sulfurating agent. This in turn reacts with cure sites in the rubber to bring about vulcanization. There are two major classes of vulcanization accelerators: primary accelerators and secondary accelerators (also known as
Texas Gulf Sulfur Company by the Frasch Process to that date. The company entered the Mexican market in 1949, with its subsidiary Cia. Exploradora del Istmo, S.A. Headquarters were established in Coatzacoalcos in 1950, and production from their Nopalapa plant commenced in 1957. By 1958, Texas Gulf had produced 69,490,00 tons of sulfur, which was 53.7 percent of the total Frasch sulphur production from 1895 through 1957. In April 1972, the company became TexasGulf. In 1981 the company was acquired by Elf Aquitaine. Texas Gulf Sulfur Company The Texas Gulf Sulphur Company was one of the largest sulfur mining companies in the world from