Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Polymer Corporation Polymer Corporation Polymer Corporation was a Canadian federal crown corporation established in 1942 to produce artificial rubber to substitute for overseas supply cut off by World War II. After the Japanese captured the Dutch East Indies in 1942, most of the world's supply of natural rubber was out of Allied hands. Due to the importance of rubber products for both modern life and modern warfare, the loss of such an important resource at this phase in the war was a crisis. A factory was established in Sarnia, Ontario, using German patents from an American licensee. Polymer produced approximately 3,300 tons