Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Foam rubber Foam rubber Foam rubber (also known as cellular, sponge, or expanded rubber) refers to rubber that has been manufactured with a foaming agent to create an air-filled matrix structure. Commercial foam rubbers are generally made of either polyurethane or natural latex. Latex foam rubber, used in mattresses, is well known for its endurance. Polyurethane is a thermosetting polymer that comes from combination of Methyl di-isocyanate and polyethylene and some other chemical additives. Foam rubber was first produced in 1929 by Dunlop Rubber researcher chemists E. A. Murphy and Eric Owen using whipped latex. In 1937 isocyanate based materials were first