Rubber toughening and damage competition theory. In material selection it is important to look at the interaction between the matrix and the secondary phase. For example, crosslinking within the rubber phase will promote high strength fibril formation that will toughen the rubber, preventing particle fracture. Carboxyl-terminated butadiene-acrylotnitrile (CTBN) is often used to toughen epoxies, but using CTBN alone increases the toughness at the cost of stiffness and heat resistance. Amine-terminated butadiene acrylonitrile (ATBN) is also used. Using ultra-fine full-vulcanized powdered rubber (UFPR) researchers have been able to improve all three, toughness, stiffness, and heat resistance simultaneously, resetting the stage for rubber toughening
Rubber toughening of waste rubber from car tires has sparked interest in finding uses for this discarded rubber. The rubber can be turned into a fine powder, which can then be used as a toughening agent for polystyrene. However, poor miscibility between the waste rubber and polystyrene will weaken the material. This problem requires the use of a compatibilizer (see "compatibilization") in order to reduce interfacial tension and ultimately make rubber toughening of polystyrene effective. A polystyrene/styrene-butadiene copolymer acts to increase the adhesion between the dispersed and continuous phases. Rubber toughening Rubber toughening is a process in which rubber nanoparticles are interspersed