Brownian motion itself can be described approximately by a Langevin equation, an equation which involves a random force field representing the effect of the thermal fluctuations of the solvent on the Brownian particle. On long timescales, the mathematical Brownian motion is well described by a Langevin equation. On small timescales, inertial effects are prevalent in the Langevin equation. However the mathematical "Brownian motion" is exempt of such inertial effects. Note that inertial effects have to be considered in the Langevin equation, otherwise the equation becomes singular. so that simply removing the inertia term from this equation would not yield an exact description,
Brownian motion left then after "N" collisions the particle's velocity will have changed by Δ"V"(2"N" − "N"). The multiplicity is then simply given by: and the total number of possible states is given by 2. Therefore, the probability of the particle being hit from the right "N" times is: As a result of its simplicity, Smoluchowski's 1D model can only qualitatively describe Brownian motion. For a realistic particle undergoing Brownian motion in a fluid many of the assumptions cannot be made. For example, the assumption that on average occurs an equal number of collisions from the right as from the left falls