Branching (polymer chemistry) Branching (polymer chemistry) In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiply branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard
Polymer capacitor polymer e-caps in which a solid conductive polymer forms the electrolyte, this is much more difficult to achieve, because its conductivity comes by a chemical process of polymerization. However, the benefits of a solid polymer electrolyte, the significantly lower ESR of the capacitor and the low temperature dependence of the electrical parameters, in many cases justify the additional production steps as well as higher costs. Electrolytic capacitors with the charge transfer salt tetracyanoquinodimethane TCNQ as electrolyte, formerly produced by Sanyo with the trade name "OS-CON", in the true sense of the term "polymer" were not "polymer capacitors". TCNQ electrolytic capacitors