Amalgam (chemistry) with copper. A nitric acid solution of salts under investigation is applied to a piece of copper foil, and any mercury ions present will leave spots of silvery-coloured amalgam. Silver ions leave similar spots but are easily washed away, making this a means of distinguishing silver from mercury. The redox reaction involved where mercury oxidizes the copper is: Dental amalgam has been studied and is generally considered to be safe for humans, though the validity of some studies and their conclusions have been questioned. Amalgam (chemistry) An amalgam is an alloy of mercury with another metal, which may be a
Physical organic chemistry Physical organic chemistry Physical organic chemistry, a term coined by Louis Hammett in 1940, refers to a discipline of organic chemistry that focuses on the relationship between chemical structures and reactivity, in particular, applying experimental tools of physical chemistry to the study of organic molecules. Specific focal points of study include the rates of organic reactions, the relative chemical stabilities of the starting materials, reactive intermediates, transition states, and products of chemical reactions, and non-covalent aspects of solvation and molecular interactions that influence chemical reactivity. Such studies provide theoretical and practical frameworks to understand how changes in structure in solution