Sulfur vulcanization in the processing and compounding of rubber by Hancock and his colleagues led to a more reliable process. Around 1900, disulfiram was introduced as a vulcanizing agent, and became widely used. In 1905 George Oenslager discovered that a derivative of aniline called thiocarbanilide accelerated the reaction of sulfur with rubber, leading to shorter cure times and reducing energy consumption. This breakthrough was almost as fundamental to the rubber industry as Goodyear's sulfur cure. Accelerators made the cure process faster, improved the reliability of the process and enabled vulcanization to be applied to synthetic polymers. One year after his discovery, Oenslager
Frasch process this method, the United States produced 3.89 million tons of sulfur in 1989, and Mexico produced 1.02 million tons of sulfur in 1991. The Frasch process can be used for deposits 50–800 meters deep. 3-38 cubic meters of superheated water are required to produce every tonne of sulfur, and the associated energy cost is significant. A working demonstration model of the Frasch process suitable for the classroom has been described. Frasch process The Frasch process is a method to extract sulphur from underground deposits. It is the only industrial method of recovering sulphur from elemental deposits. Most of the world's