Sulfur vulcanization a reaction with low levels of unsaturated organic linkers (e.g. 1,3‐diisopropenylbenzene). This process is called inverse vulcanisation and produces polymers where sulfur is the main component. It is not currently of commercial importance but had been investigated as a means of producing polymers for lithium–sulfur batterys and for creating water filters with a high affinity for mercury. The curing of rubber has been carried out since prehistoric times. The name of the first major civilization in Guatemala and Mexico, the Olmec, means 'rubber people' in the Aztec language. Ancient Mesoamericans, spanning from ancient Olmecs to Aztecs, extracted latex from "Castilla
Toughening Toughening Toughening refers to improving the fracture resistance of a given material. Crack propagation has an associated irreversible work, which is related to a material's toughness. Designing against this crack propagation leads to toughening the material. For the case of a ductile material such as a metal, this toughness is typically proportional to the fracture stress and strain as well as the gauge length of the crack. The plane strain toughness in a metal is given by: where The toughness of a brittle material is typically twice the surface energy associated with the formation of the fracture surfaces. There are