Sulfur vulcanization in the processing and compounding of rubber by Hancock and his colleagues led to a more reliable process. Around 1900, disulfiram was introduced as a vulcanizing agent, and became widely used. In 1905 George Oenslager discovered that a derivative of aniline called thiocarbanilide accelerated the reaction of sulfur with rubber, leading to shorter cure times and reducing energy consumption. This breakthrough was almost as fundamental to the rubber industry as Goodyear's sulfur cure. Accelerators made the cure process faster, improved the reliability of the process and enabled vulcanization to be applied to synthetic polymers. One year after his discovery, Oenslager
Frasch process Frasch process The Frasch process is a method to extract sulphur from underground deposits. It is the only industrial method of recovering sulphur from elemental deposits. Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources became more commonplace (see Claus process). In the Frasch process, superheated water is pumped into the sulphur deposit; the sulfur melts and is extracted. The Frasch process is able to produce high purity sulfur. The Frasch sulfur process works best on either salt domes or bedded evaporite deposits, where sulfur is found