Sulfur vulcanization sulfur is not miscible in the polymer prior to vulcanization and attention is paid to prevent sulfur bloom, where it migrates to the surface of the article. Accelerators act much like catalysts allowing vulcanisation to be performed cooler yet faster and with a more efficient use of sulfur. They achieve this by reacting with and breaking the sulfur ring to form a reactive intermediate, referred to as a sulfurating agent. This in turn reacts with cure sites in the rubber to bring about vulcanization. There are two major classes of vulcanization accelerators: primary accelerators and secondary accelerators (also known as
Union Sulphur Company original patents thus expired in 1908. Competitors such as the Freeport Sulphur Company quickly emerged and began to use the Frasch Process to extract sulfur from other nearby salt dome sites. The Union Sulphur Company tried to stop the Freeport Sulphur Company by suing on the basis of later patents that improved upon the original patents. The Delaware District Court largely sided with the Union Sulphur Co. The Third Circuit Court of Appeals, however, reversed the district court, concluding that the new patents were not really new inventions, but merely extensions of the original expired patents. Union Sulphur appealed to