Branching (polymer chemistry) Branching (polymer chemistry) In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiply branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard
Polymer Corporation Polymer Corporation Polymer Corporation was a Canadian federal crown corporation established in 1942 to produce artificial rubber to substitute for overseas supply cut off by World War II. After the Japanese captured the Dutch East Indies in 1942, most of the world's supply of natural rubber was out of Allied hands. Due to the importance of rubber products for both modern life and modern warfare, the loss of such an important resource at this phase in the war was a crisis. A factory was established in Sarnia, Ontario, using German patents from an American licensee. Polymer produced approximately 3,300 tons