Sulfur vulcanization sulfur is not miscible in the polymer prior to vulcanization and attention is paid to prevent sulfur bloom, where it migrates to the surface of the article. Accelerators act much like catalysts allowing vulcanisation to be performed cooler yet faster and with a more efficient use of sulfur. They achieve this by reacting with and breaking the sulfur ring to form a reactive intermediate, referred to as a sulfurating agent. This in turn reacts with cure sites in the rubber to bring about vulcanization. There are two major classes of vulcanization accelerators: primary accelerators and secondary accelerators (also known as
Thiokol Thiokol Thiokol (variously Thiokol Chemical Corporation, Morton-Thiokol Inc., Cordant Technologies Inc., Thiokol Propulsion, AIC Group, ATK Thiokol, ATK Launch Systems Group; finally Orbital ATK before becoming part of Northrop Grumman) was an American corporation concerned initially with rubber and related chemicals, and later with rocket and missile propulsion systems. Its name is a portmanteau of the Greek words for sulfur (θειον ""theion"") and glue (κολλα ""kolla""), an allusion to the company's initial product, Thiokol polymer. The Thiokol Chemical Company was founded in 1929. Its initial business was a range of synthetic rubber and polymer sealants. Thiokol was a major supplier