Brownian motion apart once the particle is in motion. Also, there would be a distribution of different possible Δ"V"s instead of always just one in a realistic situation. The diffusion equation yields an approximation of the time evolution of the probability density function associated to the position of the particle going under a Brownian movement under the physical definition. The approximation is valid on short timescales. The time evolution of the position of the Brownian particle itself is best described using Langevin equation, an equation which involves a random force field representing the effect of the thermal fluctuations of the solvent on
Brownian motion in 1908 and Perrin in 1909. The confirmation of Einstein's theory constituted empirical progress for the kinetic theory of heat. In essence, Einstein showed that the motion can be predicted directly from the kinetic model of thermal equilibrium. The importance of the theory lay in the fact that it confirmed the kinetic theory's account of the second law of thermodynamics as being an essentially statistical law. Smoluchowski's theory of Brownian motion starts from the same premise as that of Einstein and derives the same probability distribution "ρ"("x", "t") for the displacement of a Brownian particle along the "x" in time