Polymer such as rubber, suberin, melanin and lignin. Naturally occurring polymers such as cotton, starch and rubber were familiar materials for years before synthetic polymers such as polyethene and perspex appeared on the market. Many commercially important polymers are synthesized by chemical modification of naturally occurring polymers. Prominent examples include the reaction of nitric acid and cellulose to form nitrocellulose and the formation of vulcanized rubber by heating natural rubber in the presence of sulfur. Ways in which polymers can be modified include oxidation, cross-linking and endcapping. Especially in the production of polymers the gas separation by membranes has acquired increasing
Rubber band approximation) that elastic polymers do not store any potential energy in stretched chemical bonds. No elastic work is done to "stretch" molecules when work is done upon these bulk polymers. Instead, all work done to the rubber is "released" (not stored) and appears immediately in the polymer as thermal energy. Conversely, when the polymer does work on the surroundings (such as contracting to lift an object) it converts thermal energy to work in the process and cools in the same manner as an ideal gas, expanding while doing work. In the UK during 2004, following complaints from the public about