Polymer architecture via abstraction of a hydrogen, can create a mid-chain growth site. Branching can be quantified by the branching index. An effect related to branching is chemical crosslinking - the formation of covalent bonds between chains. Crosslinking tends to increase T and increase strength and toughness. Among other applications, this process is used to strengthen rubbers in a process known as vulcanization, which is based on crosslinking by sulfur. Car tires, for example, are highly crosslinked in order to reduce the leaking of air out of the tire and to toughen their durability. Eraser rubber, on the other hand, is not
Union Sulphur Company original patents thus expired in 1908. Competitors such as the Freeport Sulphur Company quickly emerged and began to use the Frasch Process to extract sulfur from other nearby salt dome sites. The Union Sulphur Company tried to stop the Freeport Sulphur Company by suing on the basis of later patents that improved upon the original patents. The Delaware District Court largely sided with the Union Sulphur Co. The Third Circuit Court of Appeals, however, reversed the district court, concluding that the new patents were not really new inventions, but merely extensions of the original expired patents. Union Sulphur appealed to