Brownian motion apart once the particle is in motion. Also, there would be a distribution of different possible Δ"V"s instead of always just one in a realistic situation. The diffusion equation yields an approximation of the time evolution of the probability density function associated to the position of the particle going under a Brownian movement under the physical definition. The approximation is valid on short timescales. The time evolution of the position of the Brownian particle itself is best described using Langevin equation, an equation which involves a random force field representing the effect of the thermal fluctuations of the solvent on
Rotational Brownian motion imposed electric field. Rotational Brownian motion was first discussed by Peter Debye, who applied Einstein's theory of translational Brownian motion to the rotation of molecules having permanent electric dipoles. Debye ignored inertial effects and assumed that the molecules were spherical, with an intrinsic, fixed dipole moment. He derived expressions for the dielectric relaxation time and for the permittivity. These formulae have been successfully applied to many materials. However, Debye's expression for the permittivity predicts that the absorption tends toward a constant value when the frequency of the applied electric field becomes very large—the "Debye plateau". This is not observed; instead,