Brownian motion diverges as the window shrinks, thus rendering the calculation a singular perturbation problem. Brownian motion Brownian motion or pedesis (from "leaping") is the random motion of particles suspended in a fluid (a liquid or a gas) resulting from their collision with the fast-moving molecules in the fluid. This pattern of motion typically alternates random fluctuations in a particle's position inside a fluid sub-domain with a relocation to another sub-domain. Each relocation is followed by more fluctuations within the new closed volume. This pattern describes a fluid at thermal equilibrium, defined by a given temperature. Within such fluid there exists no
Brownian motion left then after "N" collisions the particle's velocity will have changed by Δ"V"(2"N" − "N"). The multiplicity is then simply given by: and the total number of possible states is given by 2. Therefore, the probability of the particle being hit from the right "N" times is: As a result of its simplicity, Smoluchowski's 1D model can only qualitatively describe Brownian motion. For a realistic particle undergoing Brownian motion in a fluid many of the assumptions cannot be made. For example, the assumption that on average occurs an equal number of collisions from the right as from the left falls