Vulcanization Vulcanization Vulcanization (British: vulcanisation) is a chemical process used to harden rubber. Vulcanization traditionally referred to the treatment of natural rubber with sulfur and this remains the most common example, however the term has also grown to include the hardening of other (synthetic) rubbers via various means. Examples include silicone rubber via room temperature vulcanizing and chloroprene rubber (neoprene) using metal oxides. Vulcanisation can therefore be defined as the curing of elastomers; with the terms 'vulcanization' and 'curing' sometimes used interchangeably in this context. It works by forming cross-links between sections of polymer chain which results in increased rigidity and
Rubber band approximation) that elastic polymers do not store any potential energy in stretched chemical bonds. No elastic work is done to "stretch" molecules when work is done upon these bulk polymers. Instead, all work done to the rubber is "released" (not stored) and appears immediately in the polymer as thermal energy. Conversely, when the polymer does work on the surroundings (such as contracting to lift an object) it converts thermal energy to work in the process and cools in the same manner as an ideal gas, expanding while doing work. In the UK during 2004, following complaints from the public about