Dishwashing liquid harm household silver, fine glassware, anything with gold leaf, disposable plastics, and any objects made of brass, bronze, cast iron, pewter, tin, or wood, especially when combined with hot water and the action of a dishwasher. When dishwashing liquid is used on such objects it is intended that they be washed by hand. Hand dishwashing detergents utilize surfactants to play the primary role in cleaning. The reduced surface tension of dishwashing water, and increasing solubility of modern surfactant mixtures, allows the water to run off the dishes in a dish rack very quickly. However, most people also rinse the dishes
Surface tension area, a certain amount of energy must be added. Gibbs free energy is defined by the equation , where is enthalpy and is entropy. Based upon this and the fact that surface tension is Gibbs free energy per unit area, it is possible to obtain the following expression for entropy per unit area: Kelvin's equation for surfaces arises by rearranging the previous equations. It states that surface enthalpy or surface energy (different from surface free energy) depends both on surface tension and its derivative with temperature at constant pressure by the relationship. Fifteen years after Gibbs, J.D. van der Waals