Sulfur vulcanization sulfur is not miscible in the polymer prior to vulcanization and attention is paid to prevent sulfur bloom, where it migrates to the surface of the article. Accelerators act much like catalysts allowing vulcanisation to be performed cooler yet faster and with a more efficient use of sulfur. They achieve this by reacting with and breaking the sulfur ring to form a reactive intermediate, referred to as a sulfurating agent. This in turn reacts with cure sites in the rubber to bring about vulcanization. There are two major classes of vulcanization accelerators: primary accelerators and secondary accelerators (also known as
Silicone rubber cured by a platinum-catalyzed cure system, a condensation cure system, a peroxide cure system, or an oxime cure system. For the platinum-catalyzed cure system, the curing process can be accelerated by adding heat or pressure. In a platinum-based silicone cure system, also called an "addition" system (because the key reaction-building polymer is an "Addition reaction"), two different chemical groups (a silicone hydride and a vinyl) react in the presence of platinum (which serves as the catalyst). In this reaction, an ethyl group [C(H2)- C(H2)] is formed and there are no byproducts. Two separate components must be mixed to catalyze the