Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Union Sulphur Company land. He assumed that the sulfur deposits extended laterally underneath his property, and he planned to extract the sulfur with a new method. He would insert three pipes down into the sulfur. Super-heated water would be pumped down one pipe to melt the sulfur, and compressed air would be pumped down another pipe. The increased pressure from the compressed air would then force the molten sulfur up through the empty third pipe. Upon drilling on his property, however, Frasch discovered that the sulfur was only located beneath the American Sulphur Company property. The American Sulfur Company was not a fly-by-night