Surfactants in paint agent". Surfactants are compounds that lower the surface tension of a liquid, the interfacial tension between two liquids, or the interfacial tension between a liquid and a solid. In solutions this behavior is known as wetting, and it occurs as a result of surfactants adsorbing to the air/water interface. Soluble surfactants are also capable of forming micelles and other aggregate structures in solution, leading to a stabilizing effect in latex paints. Surfactants in paint are used to change many end properties of a dried paint, as well as to emulsify paints in their liquid state. Surfactants affect a wide array
Surface tension area, a certain amount of energy must be added. Gibbs free energy is defined by the equation , where is enthalpy and is entropy. Based upon this and the fact that surface tension is Gibbs free energy per unit area, it is possible to obtain the following expression for entropy per unit area: Kelvin's equation for surfaces arises by rearranging the previous equations. It states that surface enthalpy or surface energy (different from surface free energy) depends both on surface tension and its derivative with temperature at constant pressure by the relationship. Fifteen years after Gibbs, J.D. van der Waals