Brownian ratchet a heat bath in that they undergo random Brownian motion with a mean kinetic energy that is determined by the temperature. The device is imagined as being small enough that the impulse from a single molecular collision can turn the paddle. Although such collisions would tend to turn the rod in either direction with equal probability, the pawl allows the ratchet to rotate in one direction only. The net effect of many such random collisions would seem to be that the ratchet rotates continuously in that direction. The ratchet's motion then can be used to do work on other systems,
Brownian motion in 1908 and Perrin in 1909. The confirmation of Einstein's theory constituted empirical progress for the kinetic theory of heat. In essence, Einstein showed that the motion can be predicted directly from the kinetic model of thermal equilibrium. The importance of the theory lay in the fact that it confirmed the kinetic theory's account of the second law of thermodynamics as being an essentially statistical law. Smoluchowski's theory of Brownian motion starts from the same premise as that of Einstein and derives the same probability distribution "ρ"("x", "t") for the displacement of a Brownian particle along the "x" in time