Horseshoe to the modern hoof boot. Historians differ on the origin of the horseshoe. Because iron was a valuable commodity, and any worn out items were generally reforged and reused, it is difficult to locate clear archaeological evidence. Although some credit the Druids, there is no hard evidence to support this claim. In 1897 four bronze horseshoes with what are apparently nail holes were found in an Etruscan tomb dated around 400 B.C. The assertion by some historians that the Romans invented the "mule shoes" sometime after 100 BC is supported by a reference by Catullus who died in 54 BC.
Sausage casing laminated or co-extruded with a polymer with an affinity for meat protein causing the meat to stick to the film, resulting in some loss when the casing is peeled, but higher overall yield due to better moisture control. Plastic casings are generally made from polymers such as polyamide, polypropylene, or polyethylene. Polyamide (Nylon) plastic casings are the most commonly used in production of cooked sausages and hams such as luncheon meat and bologna. Polyamide casings come in two main varieties: Oriented and non-oriented. The oriented polyamide are shrinkable casings and will shrink during the cooking process thereby reducing the water