Brownian motion apart once the particle is in motion. Also, there would be a distribution of different possible Δ"V"s instead of always just one in a realistic situation. The diffusion equation yields an approximation of the time evolution of the probability density function associated to the position of the particle going under a Brownian movement under the physical definition. The approximation is valid on short timescales. The time evolution of the position of the Brownian particle itself is best described using Langevin equation, an equation which involves a random force field representing the effect of the thermal fluctuations of the solvent on
Brownian motion consideration the velocity of the Brownian particle, "U", which depends on the collisions that tend to accelerate and decelerate it. The larger "U" is, the greater will be the collisions that will retard it so that the velocity of a Brownian particle can never increase without limit. Could such a process occur, it would be tantamount to a perpetual motion of the second type. And since equipartition of energy applies, the kinetic energy of the Brownian particle, formula_30, will be equal, on the average, to the kinetic energy of the surrounding fluid particle, formula_31. In 1906 Smoluchowski published a one-dimensional