Rotational Brownian motion Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between torques due to the imposed electric field, which tend to align the molecules, and collisions, which tend to destroy the alignment. The theory of rotational Brownian motion allows one to calculate the net result of these two competing effects, and to predict how the permittivity of a dielectric material depends on the strength and frequency of the
Brownian excursion Brownian excursion process, formula_1, is a Wiener process (or Brownian motion) conditioned to be positive and to take the value 0 at time 1. Alternatively, it is a Brownian bridge process conditioned to be positive. Another representation of a Brownian excursion formula_1 in terms of a Brownian motion process "W" (due to Paul Lévy and noted by Kiyoshi Itō and Henry P. McKean, Jr.) is in terms of the last time formula_3 that "W" hits zero before time 1 and the first time formula_4 that Brownian motion formula_5 hits zero after time 1: Let formula_7 be the time that a