Rotational Brownian motion the absorption tends toward a maximum and then declines with increasing frequency. The breakdown in Debye's theory in these regimes can be corrected by including inertial effects; allowing the molecules to be non-spherical; including dipole-dipole interactions between molecules; etc. These are computationally very difficult problems and rotational Brownian motion is a topic of much current research interest. Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between
Brownian motion moment of probability of displacement formula_2, is interpreted as mass diffusivity "D": Then the density of Brownian particles "ρ" at point "x" at time "t" satisfies the diffusion equation: Assuming that "N" particles start from the origin at the initial time "t"=0, the diffusion equation has the solution This expression (which is a normal distribution with the mean formula_12 and variance formula_13 usually called Brownian motion formula_14) allowed Einstein to calculate the moments directly. The first moment is seen to vanish, meaning that the Brownian particle is equally likely to move to the left as it is to move to