Brownian motion on the discontinuous structure of matter". The direction of the force of atomic bombardment is constantly changing, and at different times the particle is hit more on one side than another, leading to the seemingly random nature of the motion. The many-body interactions that yield the Brownian pattern cannot be solved by a model accounting for every involved molecule. In consequence only probabilistic models applied to molecular populations can be employed to describe it. Two such models of the statistical mechanics, due to Einstein and Smoluchowski are presented below. Another, pure probabilistic class of models is the class of the
Perpetual motion costs energy (requiring Maxwell's demon to perform more thermodynamic work to gauge the speed of the molecules than the amount of energy gained by the difference of temperature caused) or the unidirectionality is an illusion and occasional big violations make up for the frequent small non-violations (the Brownian ratchet will be subject to internal Brownian forces and therefore will sometimes turn the wrong way). Buoyancy is another frequently misunderstood phenomenon. Some proposed perpetual-motion machines miss the fact that to push a volume of air down in a fluid takes the same work as to raise a corresponding volume of fluid