Rotational Brownian motion Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between torques due to the imposed electric field, which tend to align the molecules, and collisions, which tend to destroy the alignment. The theory of rotational Brownian motion allows one to calculate the net result of these two competing effects, and to predict how the permittivity of a dielectric material depends on the strength and frequency of the
Brownian motion left then after "N" collisions the particle's velocity will have changed by Δ"V"(2"N" − "N"). The multiplicity is then simply given by: and the total number of possible states is given by 2. Therefore, the probability of the particle being hit from the right "N" times is: As a result of its simplicity, Smoluchowski's 1D model can only qualitatively describe Brownian motion. For a realistic particle undergoing Brownian motion in a fluid many of the assumptions cannot be made. For example, the assumption that on average occurs an equal number of collisions from the right as from the left falls