Rubber toughening a lower limit for rubber-toughening particle diameter at 200 nm; it was then discovered that ultra-fine full-vulcanized powdered rubber particles with diameter of 90 nm show significant toughening of rubber epoxies. This finding underlines how this field is constantly growing and more work can be done to better model the rubber toughening effect. Acrylonitrile butadiene styrene polymer is an application of rubber toughening. The properties of this polymer come mainly from rubber toughening. The polybutadiene rubber domains in the main styrene-acrylonitrile matrix act as a stop to crack propagation. PMMA’s high optical transparency, low cost, and compressibility make it a
Rubber toughening materials where crazing and yielding are comparable, a bimodal distribution of particle size may be useful for toughening. At fixed rubber concentrations, one can find that an optimal particle size is a function of the entanglement density of the polymer matrix. The neat polymer entanglement densities of PS, SAN, and PMMA are 0.056, 0.093, and 0.127 respectively. As entanglement density increases, the optimum particle size decreases linearly, ranging between 0.1 and 3 micrometers. The effect of particle size on toughening is dependent on the type of test performed. This can be explained because for different test conditions, the failure mechanism