Branching (polymer chemistry) Branching (polymer chemistry) In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type. Branched polymers have more compact and symmetrical molecular conformations, and exhibit intra-heterogeneous dynamical behavior with respect to the unbranched polymers. In crosslinking rubber by vulcanization, short sulfur branches link polyisoprene chains (or a synthetic variant) into a multiply branched thermosetting elastomer. Rubber can also be so completely vulcanized that it becomes a rigid solid, so hard
Rubber band approximation) that elastic polymers do not store any potential energy in stretched chemical bonds. No elastic work is done to "stretch" molecules when work is done upon these bulk polymers. Instead, all work done to the rubber is "released" (not stored) and appears immediately in the polymer as thermal energy. Conversely, when the polymer does work on the surroundings (such as contracting to lift an object) it converts thermal energy to work in the process and cools in the same manner as an ideal gas, expanding while doing work. In the UK during 2004, following complaints from the public about