Sulfur vulcanization had found hundreds of applications for his additive. Thus, the science of accelerators and retarders was born. An accelerator speeds up the cure reaction, while a retarder delays it. A typical retarder is cyclohexylthiophthalimide. In the subsequent century chemists developed other accelerators and ultra-accelerators, which are used in the manufacture of most modern rubber goods. Sulfur vulcanization Sulfur vulcanization or sulfur vulcanisation is a chemical process for converting natural rubber or related polymers into more durable materials by heating them with sulfur or other equivalent curatives or accelerators. Sulfur forms cross-links (bridges) between sections of polymer chain which results in
Rubber elasticity Joule published the first careful measurements of the temperature increase accompanying extension, confirming the theoretical predictions of Lord Kelvin. It was not until 1838 that the American inventor Charles Goodyear found that its properties could be immensely improved by adding a few percent sulphur. The short sulfur chains produced chemical cross-links. Before it is cross-linked, the liquid natural rubber consists of very long linear chains, containing thousands of isoprene backbone units, connected head-to-tail. Every chain follows a random path through the liquid and is in contact with thousands of other nearby chains. When heated, a cross-linker molecule (such as sulfur