Sulfur vulcanization been uncertainly as to whether it proceeds in a radical or ionic manner. The reactive sites, often referred to as 'cure sites', are unsaturated groups such as alkenes and allyls. During vulcanization, sulfur bridges are formed between these sites, crosslinking the polymer. These bridges may consist one or several sulfur atoms. Both the extent of crosslinking and the number of sulfur atoms in the crosslinks strongly influences the physical properties of the rubber produced: Sulfur, by itself, is a slow vulcanizing agent and does not vulcanize synthetic polyolefins. Even with natural rubber, large amounts of sulfur as well as high
Polymer capacitor polymer e-caps in which a solid conductive polymer forms the electrolyte, this is much more difficult to achieve, because its conductivity comes by a chemical process of polymerization. However, the benefits of a solid polymer electrolyte, the significantly lower ESR of the capacitor and the low temperature dependence of the electrical parameters, in many cases justify the additional production steps as well as higher costs. Electrolytic capacitors with the charge transfer salt tetracyanoquinodimethane TCNQ as electrolyte, formerly produced by Sanyo with the trade name "OS-CON", in the true sense of the term "polymer" were not "polymer capacitors". TCNQ electrolytic capacitors