Sulfur vulcanization sulfur is not miscible in the polymer prior to vulcanization and attention is paid to prevent sulfur bloom, where it migrates to the surface of the article. Accelerators act much like catalysts allowing vulcanisation to be performed cooler yet faster and with a more efficient use of sulfur. They achieve this by reacting with and breaking the sulfur ring to form a reactive intermediate, referred to as a sulfurating agent. This in turn reacts with cure sites in the rubber to bring about vulcanization. There are two major classes of vulcanization accelerators: primary accelerators and secondary accelerators (also known as
Sulfur dioxide Sulfur dioxide Sulfur dioxide (also sulphur dioxide in British English) is the chemical compound with the formula . It is a toxic gas with a burnt match smell. It is released naturally by volcanic activity and is produced as a by-product of the burning of fossil fuels contaminated with sulfur compounds and copper extraction. SO is a bent molecule with "C" symmetry point group. A valence bond theory approach considering just "s" and "p" orbitals would describe the bonding in terms of resonance between two resonance structures. The sulfur–oxygen bond has a bond order of 1.5. There is support for