Dishwashing liquid harm household silver, fine glassware, anything with gold leaf, disposable plastics, and any objects made of brass, bronze, cast iron, pewter, tin, or wood, especially when combined with hot water and the action of a dishwasher. When dishwashing liquid is used on such objects it is intended that they be washed by hand. Hand dishwashing detergents utilize surfactants to play the primary role in cleaning. The reduced surface tension of dishwashing water, and increasing solubility of modern surfactant mixtures, allows the water to run off the dishes in a dish rack very quickly. However, most people also rinse the dishes
Surface tension entropy, energy and free energy. As stated above, the mechanical work needed to increase a surface area "A" is . Hence at constant temperature and pressure, surface tension equals Gibbs free energy per surface area: where is Gibbs free energy and is the area. Thermodynamics requires that all spontaneous changes of state are accompanied by a decrease in Gibbs free energy. From this it is easy to understand why decreasing the surface area of a mass of liquid is always spontaneous (), provided it is not coupled to any other energy changes. It follows that in order to increase surface