Rotational Brownian motion Rotational Brownian motion Rotational Brownian motion is the random change in the orientation of a polar molecule due to collisions with other molecules. It is an important element of theories of dielectric materials. The polarization of a dielectric material is a competition between torques due to the imposed electric field, which tend to align the molecules, and collisions, which tend to destroy the alignment. The theory of rotational Brownian motion allows one to calculate the net result of these two competing effects, and to predict how the permittivity of a dielectric material depends on the strength and frequency of the
Brownian excursion Brownian excursion In probability theory a Brownian excursion process is a stochastic process that is closely related to a Wiener process (or Brownian motion). Realisations of Brownian excursion processes are essentially just realizations of a Wiener process selected to satisfy certain conditions. In particular, a Brownian excursion process is a Wiener process conditioned to be positive and to take the value 0 at time 1. Alternatively, it is a Brownian bridge process conditioned to be positive. BEPs are important because, among other reasons, they naturally arise as the limit process of a number of conditional functional central limit theorems. A