Naphthenic acid agents, thickening agent of napalm and oil drying agents used in painting and wood surface treatment. Industrially useful naphthenates include those of aluminium, magnesium, calcium, barium, cobalt, copper, lead, manganese, nickel, vanadium, and zinc. One oft-cited study stated that "naphthenic acids are the most significant environmental contaminants resulting from petroleum extraction from oil sands deposits." However "under worst-case exposure conditions, acute toxicity is unlikely in wild mammals exposed to naphthenic acids in AOS tailings pond water, but repeated exposure may have adverse health effects." Naphthenic acids are present in Athabasca oil sands (AOL) tailings pond water (TPW) at an estimated
Copper naphthenate adhesion promoters, lubricant additives, and catalysts where oil solubility is required. Naphthenic acid is a complex group of carboxylic acids with the general formula CHO where n indicates the carbon number and z specifies the hydrogen deficiency resulting from ring formation. Naphthenic acids occur naturally in crude oil at varying concentrations, and their composition varies with the crude oil composition and the conditions during refining. Crude oils with total acid number (TAN) as little as 0.5 mg KOH/g acid or petroleum fractions greater than about 1.0 mg KOH/g oil usually qualify as a high acid crude or oil. At the