Weathering release occurs of Ca and other ions into surface waters. Rainfall is acidic because atmospheric carbon dioxide dissolves in the rainwater producing weak carbonic acid. In unpolluted environments, the rainfall pH is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0. Sulfur dioxide, SO, comes from volcanic eruptions or from fossil fuels, can become sulfuric acid within rainwater, which can cause solution weathering to the rocks on which it
Lead chamber process Sulfuric acid produced in the reaction chambers is limited to about 35% concentration. At higher concentrations, nitrosylsulfuric acid precipitates on the lead walls as chamber crystals and is no longer able to catalyze the oxidation reactions. Sulfur dioxide is generated by burning elemental sulfur or by roasting pyritic ore in a current of air: Nitrogen oxides are produced by decomposition of niter in the presence of sulfuric acid or hydrolysis of nitrosylsulfuric acid: In the reaction chambers, sulfur dioxide and nitrogen dioxide dissolve in the reaction liquor. Nitrogen dioxide is hydrated to produce nitrous acid which then oxidizes the sulfur