Spontaneous emission luminescent. And there are different forms of luminescence depending on how excited atoms are produced (electroluminescence, chemiluminescence etc.). If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission. Spontaneous emission cannot be explained by classical electromagnetic theory and is fundamentally a quantum process. The first person to derive the rate of
Stimulated emission difference in energies between the two states as a photon. The photon will have frequency "ν" and energy "hν", given by: where "h" is Planck's constant. Alternatively, if the excited-state atom is perturbed by an electric field of frequency "ν", it may emit an additional photon of the same frequency and in phase, thus augmenting the external field, leaving the atom in the lower energy state. This process is known as stimulated emission. In a group of such atoms, if the number of atoms in the excited state is given by "N", the rate at which stimulated emission occurs is