Spontaneous emission luminescent. And there are different forms of luminescence depending on how excited atoms are produced (electroluminescence, chemiluminescence etc.). If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission. Spontaneous emission cannot be explained by classical electromagnetic theory and is fundamentally a quantum process. The first person to derive the rate of
Stimulated emission resulting from the distribution of velocities in a gas at a certain temperature. This has a Gaussian shape and reduces the peak strength of the line shape function. In a practical problem the full line shape function can be computed through a convolution of the individual line shape functions involved. Therefore, optical amplification will add power to an incident optical field at frequency formula_17 at a rate given by The stimulated emission cross section is where Stimulated emission can provide a physical mechanism for optical amplification. If an external source of energy stimulates more than 50% of the atoms in