Heat pump the brand name Freon, a trademark of DuPont. Its manufacture is now banned or severely restricted by the Montreal Protocol of August 1987 because of the damage that CFCs cause to the ozone layer if released into the atmosphere. One widely adopted replacement refrigerant is the hydrofluorocarbon (HFC) known as R-134a (1,1,1,2-tetrafluoroethane). Heat pumps using R-134a replaced R-12 (dichlorodifluoromethane) and have similar thermodynamic properties but with insignificant ozone depletion potential and a somewhat lower global warming potential. Other substances such as liquid R-717 ammonia are widely used in large-scale systems, or occasionally the less corrosive but more flammable propane or
Montreal Protocol Antarctic Survey scientists Joe Farman, Brian Gardiner and Jonathan Shanklin published results of abnormally low ozone concentrations above Halley Bay near the South Pole. They speculated that this was connected to increased levels of CFCs in the atmosphere. It took several other attempts to establish the Antarctic losses as real and significant, especially after NASA had retrieved matching data from its satellite recordings. The impact of these studies, the metaphor 'ozone hole', and the colourful visual representation in a time lapse animation proved shocking enough for negotiators in Montreal, Canada to take the issue seriously. Also in 1985, 20 nations,