Acid–base reaction models as theories that complement each other. For example the current Lewis model has the broadest definition of what an acid and base are, with the Bronsted-Lowry theory being a subset of what acids and bases are, and the Arrhenius theory being the most restrictive. The first scientific concept of acids and bases was provided by Lavoisier in around 1776. Since Lavoisier's knowledge of strong acids was mainly restricted to oxoacids, such as (nitric acid) and (sulfuric acid), which tend to contain central atoms in high oxidation states surrounded by oxygen, and since he was not aware of the true
Hydrazoic acid lithium) or alkaline earth metals are not explosive, but decompose in a more controlled way upon heating, releasing spectroscopically-pure gas. Solutions of hydrazoic acid dissolve many metals (e.g. zinc, iron) with liberation of hydrogen and formation of salts, which are called azides (formerly also called azoimides or hydrazoates). Dissolution in the strongest acids produces explosive salts containing the ion, for example: The ion is isoelectronic to diazomethane. The decomposition of hydrazoic acid, triggered by shock, friction, spark, etc. goes as follows: Hydrazoic acid is volatile and highly toxic. It has a pungent smell and its vapor can cause violent headaches.