Fertilizer The greenhouse gases carbon dioxide, methane and nitrous oxide are produced during the manufacture of nitrogen fertilizer. The effects can be combined into an equivalent amount of carbon dioxide. The amount varies according to the efficiency of the process. The figure for the United Kingdom is over 2 kilogrammes of carbon dioxide equivalent for each kilogramme of ammonium nitrate. Nitrogen fertilizer can be converted by soil bacteria to nitrous oxide, a greenhouse gas. Through the increasing use of nitrogen fertilizer, which was used at a rate of about 110 million tons (of N) per year in 2012, adding to the
Nitrous oxide careful heating of ammonium nitrate at about 250 C, which decomposes into nitrous oxide and water vapour. The addition of various phosphate salts favours formation of a purer gas at slightly lower temperatures. This reaction may be difficult to control, resulting in detonation. The decomposition of ammonium nitrate is also a common laboratory method for preparing the gas. Equivalently, it can be obtained by heating a mixture of sodium nitrate and ammonium sulfate: Another method involves the reaction of urea, nitric acid, and sulfuric acid: Direct oxidation of ammonia with a manganese dioxide-bismuth oxide catalyst has been reported: cf. Ostwald