Gold parting valens") could be made by the distillation of saltpetre (KNO) with alum (KAl(SO)) or vitriol (FeSO) with water. 2KNO + HO + FeSO → FeO + KSO + 2HNO Nitric acid, after distillation to increase the acid strength, is capable of dissolving the silver but it will not (by itself) dissolve the gold. However, nitric acid is not able to (fully) extract silver and other impurities from an alloy with a high content of gold. Therefore, one part of scrap gold was typically alloyed with three parts of copper (quartering) before parting with nitric acid. Another method uses Sterling silver
Phosphorous acid are acidic under aqueous conditions, in contrast with HPO. On heating at 200 °C, phosphorous acid disproportionates to phosphoric acid and phosphine: This reaction is used for laboratory-scale preparations of PH. Both phosphorous acid and its deprotonated forms are good reducing agents, although not necessarily quick to react. They are oxidized to phosphoric acid or its salts. It reduces solutions of noble metal cations to the metals. When phosphorous acid is treated with a cold solution of mercuric chloride, a white precipitate of mercurous chloride forms: Mercurous chloride is reduced further by phosphorous acid to mercury on heating or on