Environmental impact of shipping engines can be higher on a port-specific basis. Ultra-low sulfur diesel (ULSD) is a standard for defining diesel fuel with substantially lowered sulfur contents. As of 2006, almost all of the petroleum-based diesel fuel available in Europe and North America is of a ULSD type. In 2016 the IMO has made new sulfur regulations which must be implemented by larger ships by 2020. Of total global air emissions, shipping accounts for 18 to 30 percent of the nitrogen oxide and 9 percent of the sulphur oxides. Sulfur in the air creates acid rain which damages crops and buildings. When inhaled,
Sulfur dioxide action of hot concentrated sulfuric acid on copper turnings produces sulfur dioxide. Sulfite results from the reaction of aqueous base and sulfur dioxide. The reverse reaction involves acidification of sodium metabisulfite: Treatment of basic solutions with sulfur dioxide affords sulfite salts (e.g. sodium sulfite): Featuring sulfur in the +4 oxidation state, sulfur dioxide is a reducing agent. It is oxidized by halogens to give the sulfuryl halides, such as sulfuryl chloride: Sulfur dioxide is the oxidising agent in the Claus process, which is conducted on a large scale in oil refineries. Here, sulfur dioxide is reduced by hydrogen sulfide to