Nitric acid (HNO) greatly enhance the rate of reaction. Although chromium (Cr), iron (Fe), and aluminium (Al) readily dissolve in dilute nitric acid, the concentrated acid forms a metal-oxide layer that protects the bulk of the metal from further oxidation. The formation of this protective layer is called passivation. Typical passivation concentrations range from 20% to 50% by volume (see ASTM A967-05). Metals that are passivated by concentrated nitric acid are iron, cobalt, chromium, nickel, and aluminium. Being a powerful oxidizing acid, nitric acid reacts violently with many organic materials and the reactions may be explosive. The hydroxyl group will typically strip
Phosphorous acid are acidic under aqueous conditions, in contrast with HPO. On heating at 200 °C, phosphorous acid disproportionates to phosphoric acid and phosphine: This reaction is used for laboratory-scale preparations of PH. Both phosphorous acid and its deprotonated forms are good reducing agents, although not necessarily quick to react. They are oxidized to phosphoric acid or its salts. It reduces solutions of noble metal cations to the metals. When phosphorous acid is treated with a cold solution of mercuric chloride, a white precipitate of mercurous chloride forms: Mercurous chloride is reduced further by phosphorous acid to mercury on heating or on