Weathering release occurs of Ca and other ions into surface waters. Rainfall is acidic because atmospheric carbon dioxide dissolves in the rainwater producing weak carbonic acid. In unpolluted environments, the rainfall pH is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0. Sulfur dioxide, SO, comes from volcanic eruptions or from fossil fuels, can become sulfuric acid within rainwater, which can cause solution weathering to the rocks on which it
Nitrogen dioxide This reaction is negligibly slow at low concentrations of NO characteristic of the ambient atmosphere, although it does proceed upon NO uptake to surfaces. Such surface reaction is thought to produce gaseous HNO (often written as HONO) in outdoor and indoor environments. Nitric acid decomposes slowly to nitrogen dioxide by the overall reaction: The nitrogen dioxide so formed confers the characteristic yellow color often exhibited by this acid. is used to generate anhydrous metal nitrates from the oxides: Alkyl and metal iodides give the corresponding nitrites: is introduced into the environment by natural causes, including entry from the stratosphere, bacterial