Nitric acid (HNO) greatly enhance the rate of reaction. Although chromium (Cr), iron (Fe), and aluminium (Al) readily dissolve in dilute nitric acid, the concentrated acid forms a metal-oxide layer that protects the bulk of the metal from further oxidation. The formation of this protective layer is called passivation. Typical passivation concentrations range from 20% to 50% by volume (see ASTM A967-05). Metals that are passivated by concentrated nitric acid are iron, cobalt, chromium, nickel, and aluminium. Being a powerful oxidizing acid, nitric acid reacts violently with many organic materials and the reactions may be explosive. The hydroxyl group will typically strip
Thiosulfurous acid They are immiscible in water, but dissolve in benzene or carbon tetrachloride. These species are less rigid than the thiosulfite esters. Thiosulfurous acid Thiosulfurous acid (HS−S(=O)−OH) is a low oxidation state (+1) sulfur acid. It is the equivalent acid for disulfur monoxide. Thiosulfurous acid is formed by reacting hydrogen sulfide and sulfur dioxide at room temperature. The thiosulfurous acid molecule is unstable when condensed, reacting with itself. It decomposes to polysulfane oxide or polythionic acids in water which is termed Wakenroder's liquid. Other possible isomers are dihydroxydisulfane or hypodithionous acid HOSSOH, a linear chain, and thiothionyl hydroxide (S=S(OH)) a tautomer