Hydrazoic acid was originally prepared by the reaction of aqueous hydrazine with nitrous acid. Other oxidizing agents, such as hydrogen peroxide, nitrosyl chloride, trichloramine or nitric acid, can also be used. In its properties hydrazoic acid shows some analogy to the halogen acids, since it forms poorly soluble (in water) lead, silver and mercury(I) salts. The metallic salts all crystallize in the anhydrous form and decompose on heating, leaving a residue of the pure metal. It is a weak acid (p"K" = 4.75.) Its heavy metal salts are explosive and readily interact with the alkyl iodides. Azides of heavier alkali metals (excluding
Sulfuric acid gas and salts (the metal sulfate). It attacks reactive metals (metals at positions above copper in the reactivity series) such as iron, aluminium, zinc, manganese, magnesium, and nickel. However, concentrated sulfuric acid is a strong oxidizing agent and does not react with metals in the same way as other typical acids. Sulfur dioxide, water and ions are evolved instead of the hydrogen and salts. It can oxidize non-active metals such as tin and copper, depending upon the temperature. Lead and tungsten, however, are resistant to sulfuric acid. Hot concentrated sulfuric acid oxidizes non-metals such as carbon (as bituminous coal) and