Berliner Gramophone formulations remained the standard disc record material until the first vinyl records – initially made only for radio use and other special applications – were introduced in the 1930s. Beginning in 1896, Berliner's gramophones were made by Philadelphia-based machinist Eldridge Johnson, who added a spring motor to drive the previously hand-rotated turntable. Berliner also opened an office in New York City, staffed by Frank Seaman and O. D. LaDow and organized as the National Gramophone Company. Master recordings were made onto zinc plates, which were then electroplated and a negative-image "mother" made from them to stamp discs. A major reversal
Polymer are composed of four types of nucleotide subunits. A polymer molecule containing ionizable subunits is known as a polyelectrolyte or ionomer. The microstructure of a polymer (sometimes called configuration) relates to the physical arrangement of monomer residues along the backbone of the chain. These are the elements of polymer structure that require the breaking of a covalent bond in order to change. Structure has a strong influence on the other properties of a polymer. For example, two samples of natural rubber may exhibit different durability, even though their molecules comprise the same monomers. An important microstructural feature of a polymer