Nitric acid rises to 1 at a temperature of 250 °C. Nitric acid can act as a base with respect to an acid such as sulfuric acid: The nitronium ion, , is the active reagent in aromatic nitration reactions. Since nitric acid has both acidic and basic properties, it can undergo an autoprotolysis reaction, similar to the self-ionization of water: Nitric acid reacts with most metals, but the details depend on the concentration of the acid and the nature of the metal. Dilute nitric acid behaves as a typical acid in its reaction with most metals. Magnesium, manganese, and zinc liberate H:
Malic acid the racemic mixture, and the (S)- enantiomer may be specifically obtained by fermentation of fumaric acid. Self-condensation of malic acid with fuming sulfuric acid gives the pyrone coumalic acid: Malic acid was important in the discovery of the Walden inversion and the Walden cycle, in which (−)-malic acid first is converted into (+)-chlorosuccinic acid by action of phosphorus pentachloride. Wet silver oxide then converts the chlorine compound to (+)-malic acid, which then reacts with PCl to the (−)-chlorosuccinic acid. The cycle is completed when silver oxide takes this compound back to (−)-malic acid. Malic acid Malic acid is an organic