Hydrazoic acid was originally prepared by the reaction of aqueous hydrazine with nitrous acid. Other oxidizing agents, such as hydrogen peroxide, nitrosyl chloride, trichloramine or nitric acid, can also be used. In its properties hydrazoic acid shows some analogy to the halogen acids, since it forms poorly soluble (in water) lead, silver and mercury(I) salts. The metallic salts all crystallize in the anhydrous form and decompose on heating, leaving a residue of the pure metal. It is a weak acid (p"K" = 4.75.) Its heavy metal salts are explosive and readily interact with the alkyl iodides. Azides of heavier alkali metals (excluding
Phosphorous acid concentrating the solution and precipitations with alcohols, the pure acid can be separated from the salt. Phosphorous acid is a strong acid with a p"K" in the range 1.26–1.3. It is a diprotic acid, the hydrogenphosphite ion, HP(O)(OH) is a moderately strong acid: The conjugate base HP(O)(OH) is called hydrogen phosphite, and the second conjugate base, , is the phosphite ion. (Note that the IUPAC recommendations are hydrogen phosphonate and phosphonate respectively). The hydrogen atom bonded directly to the phosphorus atom is not readily ionizable. Chemistry examinations often test students' appreciation of the fact that "not" all three hydrogen atoms