Triflic acid acid and its conjugate base CFSO, known as triflate, resist oxidation/reduction reactions, whereas many strong acids are oxidizing, e.g. perchloric or nitric acid. Further recommending its use, triflic acid does not sulfonate substrates, which can be a problem with sulfuric acid, fluorosulfuric acid, and chlorosulfonic acid. Below is a prototypical sulfonation, which HOTf does "not" undergo: Triflic acid fumes in moist air and forms a stable solid monohydrate, CFSOH·HO, melting point 34 °C. The triflate ligand is labile, reflecting its low basicity. Trifluoromethanesulfonic acid exothermically reacts with metal carbonates, hydroxides, and oxides. Illustrative is the synthesis of Cu(OTf). Chloride ligands
Simultaneously extracted metals and Acid-volatile sulfide the amount of HS produced by the reaction can be calculated. A few important things should be noted about this reaction: Once the quantity (in moles) of AVS has been determined in this way, it is divided by the dry mass of the sediment to obtain the AVS concentration. In addition to the gravimetric method described here, other methods, such as colorimetry, may be used. As noted above, treating metals-containing sediments with HCl liberates metal ions into the acid solution that were previously bound up with AVS. After treatment these are present in solution, along with any metals that were