Nitric acid (HNO) greatly enhance the rate of reaction. Although chromium (Cr), iron (Fe), and aluminium (Al) readily dissolve in dilute nitric acid, the concentrated acid forms a metal-oxide layer that protects the bulk of the metal from further oxidation. The formation of this protective layer is called passivation. Typical passivation concentrations range from 20% to 50% by volume (see ASTM A967-05). Metals that are passivated by concentrated nitric acid are iron, cobalt, chromium, nickel, and aluminium. Being a powerful oxidizing acid, nitric acid reacts violently with many organic materials and the reactions may be explosive. The hydroxyl group will typically strip
Simultaneously extracted metals and Acid-volatile sulfide be determined. In initial versions of the SEM-AVS approach, six metals were measured: nickel, zinc, cadmium, copper, lead, and mercury. More current methods call for the measurement of silver in addition to these metals. In applying the SEM-AVS approach, two concentrations are determined: the total concentrations of all toxic heavy metals of interest, represented as [SEM], and the acid-volatile sulfide concentration, represented as [AVS]. From these concentrations, the [SEM]/[AVS] ratio can be obtained, summarizing the results in a single value. Based on the extremely low K values for heavy metal sulfides, if [SEM]/[AVS] is less than 1 ([SEM < [AVS]),