Stimulated emission energy of an absorbed photon causes an identical but opposite atomic transition: from the lower level to a higher energy level. In normal media at thermal equilibrium, absorption exceeds stimulated emission because there are more electrons in the lower energy states than in the higher energy states. However, when a population inversion is present, the rate of stimulated emission exceeds that of absorption, and a net optical amplification can be achieved. Such a gain medium, along with an optical resonator, is at the heart of a laser or maser. Lacking a feedback mechanism, laser amplifiers and superluminescent sources also function
Stimulated emission an atomic or molecular resonance, the spectral line shape function is described as a Lorentzian distribution where formula_12 is the full width at half maximum or FWHM bandwidth. The peak value of the Lorentzian line shape occurs at the line center, formula_13. A line shape function can be normalized so that its value at formula_9 is unity; in the case of a Lorentzian we obtain Thus stimulated emission at frequencies away from formula_9 is reduced by this factor. In practice there may also be broadening of the line shape due to inhomogeneous broadening, most notably due to the Doppler effect