Internal combustion engine the atmosphere by the reaction of and volatile organic compounds in the presence of sunlight. Ground-level ozone is harmful to human health and the environment. Though the same chemical substance, ground-level ozone should not be confused with stratospheric ozone, or the ozone layer, which protects the earth from harmful ultraviolet rays. Carbon fuels contain sulfur and impurities that eventually produce sulfur monoxides (SO) and sulfur dioxide (SO) in the exhaust, which promotes acid rain. In the United States, nitrogen oxides, PM, carbon monoxide, sulphur dioxide, and ozone, are regulated as criteria air pollutants under the Clean Air Act to levels
Nitrogen dioxide is a consequence of preferential absorption of light in the blue (400 – 500 nm), although the absorption extends throughout the visible (at shorter wavelengths) and into the infrared (at longer wavelengths). Absorption of light at wavelengths shorter than about 400 nm results in photolysis (to form NO + O, atomic oxygen); in the atmosphere the addition of O atom so formed to O results in ozone formation. Nitrogen dioxide typically arises via the oxidation of nitric oxide by oxygen in air: Nitrogen dioxide is formed in most combustion processes using air as the oxidant. At elevated temperatures nitrogen combines