Spontaneous emission luminescent. And there are different forms of luminescence depending on how excited atoms are produced (electroluminescence, chemiluminescence etc.). If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission. Spontaneous emission cannot be explained by classical electromagnetic theory and is fundamentally a quantum process. The first person to derive the rate of
Stimulated emission an atomic or molecular resonance, the spectral line shape function is described as a Lorentzian distribution where formula_12 is the full width at half maximum or FWHM bandwidth. The peak value of the Lorentzian line shape occurs at the line center, formula_13. A line shape function can be normalized so that its value at formula_9 is unity; in the case of a Lorentzian we obtain Thus stimulated emission at frequencies away from formula_9 is reduced by this factor. In practice there may also be broadening of the line shape due to inhomogeneous broadening, most notably due to the Doppler effect