Hydrazoic acid was originally prepared by the reaction of aqueous hydrazine with nitrous acid. Other oxidizing agents, such as hydrogen peroxide, nitrosyl chloride, trichloramine or nitric acid, can also be used. In its properties hydrazoic acid shows some analogy to the halogen acids, since it forms poorly soluble (in water) lead, silver and mercury(I) salts. The metallic salts all crystallize in the anhydrous form and decompose on heating, leaving a residue of the pure metal. It is a weak acid (p"K" = 4.75.) Its heavy metal salts are explosive and readily interact with the alkyl iodides. Azides of heavier alkali metals (excluding
Thiosulfurous acid They are immiscible in water, but dissolve in benzene or carbon tetrachloride. These species are less rigid than the thiosulfite esters. Thiosulfurous acid Thiosulfurous acid (HS−S(=O)−OH) is a low oxidation state (+1) sulfur acid. It is the equivalent acid for disulfur monoxide. Thiosulfurous acid is formed by reacting hydrogen sulfide and sulfur dioxide at room temperature. The thiosulfurous acid molecule is unstable when condensed, reacting with itself. It decomposes to polysulfane oxide or polythionic acids in water which is termed Wakenroder's liquid. Other possible isomers are dihydroxydisulfane or hypodithionous acid HOSSOH, a linear chain, and thiothionyl hydroxide (S=S(OH)) a tautomer