Emissions trading market in pollution-licenses is more widely applicable than the market in emission-licenses. The international community began the long process towards building effective international and domestic measures to tackle GHG emissions (carbon dioxide, methane, nitrous oxide, hydroflurocarbons, perfluorocarbons, sulphur hexafluoride) in response to the increasing assertions that global warming is happening due to man-made emissions and the uncertainty over its likely consequences. That process began in Rio in 1992, when 160 countries agreed the UN Framework Convention on Climate Change (UNFCCC). The UNFCCC is, as its title suggests, simply a framework; the necessary detail was left to be settled by the
Sulfur hexafluoride also the method used by the discoverers Henri Moissan and Paul Lebeau in 1901. Some other sulfur fluorides are cogenerated, but these are removed by heating the mixture to disproportionate any (which is highly toxic) and then scrubbing the product with NaOH to destroy remaining . Alternatively, utilizing bromine, sulfur hexafluoride can be synthesized from SF and CoF at lower temperatures (e.g. 100 °C), as follows: There is virtually no reaction chemistry for . A main contribution to the inertness of SF is the steric hindrance of the sulfur atom, whereas its heavier group 16 counterparts, such as SeF are