Internal combustion engine the atmosphere by the reaction of and volatile organic compounds in the presence of sunlight. Ground-level ozone is harmful to human health and the environment. Though the same chemical substance, ground-level ozone should not be confused with stratospheric ozone, or the ozone layer, which protects the earth from harmful ultraviolet rays. Carbon fuels contain sulfur and impurities that eventually produce sulfur monoxides (SO) and sulfur dioxide (SO) in the exhaust, which promotes acid rain. In the United States, nitrogen oxides, PM, carbon monoxide, sulphur dioxide, and ozone, are regulated as criteria air pollutants under the Clean Air Act to levels
Factors of polymer weathering hydrocarbons from automobile exhausts is another source. Ozone plays a dual role in weathering. The concentrated layer in the upper atmosphere absorbs the short wavelength (≤300 nm) ultraviolet radiation emitted by the sun and thus plays a critical role in protecting terrestrial objects from this actinic radiation. Ozone is also a powerful oxidant and reported to react rapidly with elastomers and other unsaturated polymers. Ozonolysis typically results in stiffening and cracking, particularly under mechanical stress. However, the contribution of ozonolysis reactions to the overall photooxidation process is still subject to controversy. Atmospheric pollutants (e.g., sulfur dioxide, nitrogen oxides, hydrocarbons, etc.),