Hydrazoic acid was originally prepared by the reaction of aqueous hydrazine with nitrous acid. Other oxidizing agents, such as hydrogen peroxide, nitrosyl chloride, trichloramine or nitric acid, can also be used. In its properties hydrazoic acid shows some analogy to the halogen acids, since it forms poorly soluble (in water) lead, silver and mercury(I) salts. The metallic salts all crystallize in the anhydrous form and decompose on heating, leaving a residue of the pure metal. It is a weak acid (p"K" = 4.75.) Its heavy metal salts are explosive and readily interact with the alkyl iodides. Azides of heavier alkali metals (excluding
Methanesulfonic acid Methanesulfonic acid Methanesulfonic acid (MsOH) is a colorless liquid with the chemical formula CHSOH. It is the simplest of the alkylsulfonic acids. Salts and esters of methanesulfonic acid are known as mesylates (or methanesulfonates, as in ethyl methanesulfonate). It is hygroscopic in its concentrated form. Methanesulfonic acid may be considered an intermediate compound between sulfuric acid (HSO), and methylsulfonylmethane ((CH)SO), effectively replacing an –OH group with a –CH group at each step. This pattern can extend no further in either direction without breaking down the –SO– group. Methanesulfonic acid can dissolve a wide range of metal salts, many of them