Climate change in Washington related emissions are the dominant source of GHG emissions and have increased from 61.2 MMT CO-equivalent (CO-e) in 1990 (excluding residual fuel for transportation) to 74.6 MMT CO-e in 2004, while their share has increased from 79% of total emissions to 85% over the past fourteen years. Carbon dioxide is the dominant GHG followed by methane, nitrous oxide, perfluorocarbon and sulfur hexafluoride. Non-energy industrial global greenhouse gas emissions have lowered from 14% to 9%, mainly due to reduced emissions from aluminum production. This has been the result of two key elements: process changes that reduced CO and PFC emissions per
Sulfur hexafluoride also the method used by the discoverers Henri Moissan and Paul Lebeau in 1901. Some other sulfur fluorides are cogenerated, but these are removed by heating the mixture to disproportionate any (which is highly toxic) and then scrubbing the product with NaOH to destroy remaining . Alternatively, utilizing bromine, sulfur hexafluoride can be synthesized from SF and CoF at lower temperatures (e.g. 100 °C), as follows: There is virtually no reaction chemistry for . A main contribution to the inertness of SF is the steric hindrance of the sulfur atom, whereas its heavier group 16 counterparts, such as SeF are