Carbonate-hosted lead-zinc ore deposits and pyrite thus form. Commonly MVT deposits form by the combination of hydrocarbon pyrolysis liberating zinc-lead ions and sulfur to form an acidic solution which dissolves the host carbonate formation and replaces it with massive sulfide accumulations. This may also take the morphology of fault-hosted stockworks, massive tabular replacements and so forth. Porous limestones may form disseminated ores, however most MVT deposits are massive sulfides with knife-like margins between carbonate and sulfide mineralogies. Ore minerals in carbonate replacement deposits are typically lead sulfide, galena, and zinc sulfide sphalerite. Weathered equivalents form anglesite, cerussite, smithsonite, hydrozincite and secondary galena and sphalerite
Iron oxide copper gold ore deposits named as IOCG, by discovery and study of the supergiant Olympic Dam copper-gold-uranium deposit, and South American examples. IOCG deposits are classified as separate to other large intrusive related copper deposits such as porphyry copper deposits and other porphyry metal deposits primarily by their substantial accumulations of iron oxide minerals, association with felsic-intermediate type intrusives (Na-Ca rich granitoids), and lack of the complex zonation in alteration mineral assemblies commonly associated with porphyry deposits. The relatively simple copper-gold +/- uranium ore assemblage is also distinct from the wide spectrum of Cu-Au-Ag-Mo-W-Bi porphyry deposits, and there is often no metal zonation within