Copying pencil Copying pencil A copying pencil, also indelible pencil or chemical pencil, is pencil whose lead contains a dye. The lead is fabricated by adding a dry water-soluble permanent dye to powdered graphite—used in standard graphite pencils—before binding the mixture with clay. Copying pencils were introduced in the 1870s and were originally marketed for copying documents, especially for making permanent copies of a permanent original. This was achieved by creating a hand-written document using a copying pencil, laying a moist tissue paper over the document and pressing down with a mechanical press. The water-soluble dye in the writing would be transferred
Lead of lead exceeds that of tin, contrary to what periodic trends would predict. Relativistic effects, which become significant in heavier atoms, contribute to this behavior. One such effect is the inert pair effect: the 6s electrons of lead become reluctant to participate in bonding, making the distance between nearest atoms in crystalline lead unusually long. Lead's lighter carbon group congeners form stable or metastable allotropes with the tetrahedrally coordinated and covalently bonded diamond cubic structure. The energy levels of their outer s- and p-orbitals are close enough to allow mixing into four hybrid sp orbitals. In lead, the inert pair