Pencil thereby pushing a new tip to the top. Invented by Harold Grossman for Empire Pencil Company in 1967 and subsequently improved upon by Arthur D. Little for Empire from 1969 through the early 1970s; the plastic pencil was commercialised by Empire as the "EPCON" Pencil. These pencils were co-extruded, extruding a plasticised graphite mix within a wood-composite core. Residual graphite from a pencil stick is not poisonous, and graphite is harmless if consumed. Although lead has not been used for writing since antiquity, lead poisoning from pencils was not uncommon. Until the middle of the 20th century the paint used
Lead of uranium-235, thorium-232, and uranium-238, respectively, so traces of all three of these lead isotopes are found naturally. Minute traces of lead-209 arise from the very rare cluster decay of radium-223, one of the daughter products of natural uranium-235, and the decay chain of neptunium-237, traces of which are produced by neutron capture in uranium ores. Lead-210 is particularly useful for helping to identify the ages of samples by measuring its ratio to lead-206 (both isotopes are present in a single decay chain). In total, 43 lead isotopes have been synthesized, with mass numbers 178–220. Lead-205 is the most stable