Carbonate-hosted lead-zinc ore deposits and pyrite thus form. Commonly MVT deposits form by the combination of hydrocarbon pyrolysis liberating zinc-lead ions and sulfur to form an acidic solution which dissolves the host carbonate formation and replaces it with massive sulfide accumulations. This may also take the morphology of fault-hosted stockworks, massive tabular replacements and so forth. Porous limestones may form disseminated ores, however most MVT deposits are massive sulfides with knife-like margins between carbonate and sulfide mineralogies. Ore minerals in carbonate replacement deposits are typically lead sulfide, galena, and zinc sulfide sphalerite. Weathered equivalents form anglesite, cerussite, smithsonite, hydrozincite and secondary galena and sphalerite
Primary minerals Primary minerals A primary mineral is any mineral formed during the original crystallization of the host igneous primary rock and includes the essential mineral(s) used to classify the rock along with any accessory minerals. In ore deposit geology, hypogene processes occur deep below the earth's surface, and tend to form deposits of primary minerals, as opposed to supergene processes that occur at or near the surface, and tend to form secondary minerals. The elemental and mineralogical composition of primary rocks is determined by the chemical composition of the volcanic or magmatic flow from which it is formed. Extrusive rocks (such