Quaternions and spatial rotation of a circle representing a particular rotation angle will be half of the angle represented by that rotation, since as the point is moved from the north to south pole, the latitude ranges from zero to 180 degrees, while the angle of rotation ranges from 0 to 360 degrees. (the "longitude" of a point then represents a particular axis of rotation.) Note however that this set of rotations is not closed under composition. Two successive rotations with axes in the "xy" plane will not necessarily give a rotation whose axis lies in the "xy" plane, and thus cannot be represented
Degrees of freedom (physics and chemistry) for 3 degrees of freedom. In addition, the molecule has two rotational degrees of motion and one vibrational mode. The rotations occur around the two axes perpendicular to the line between the two atoms. The rotation around the atom–atom bond is not a physical rotation. This yields, for a diatomic molecule, a decomposition of: For a general, non-linear molecule, all 3 rotational degrees of freedom are considered, resulting in the decomposition: which means that an -atom molecule has vibrational degrees of freedom for . In special cases, such as adsorbed large molecules, the rotational degrees of freedom can be limited