Ore genesis accumulation of hematite gravels called "pisolites" which form channel-iron deposits. These are preferred because they are cheap to mine. Lead-zinc deposits are generally accompanied by silver, hosted within the lead sulfide mineral galena or within the zinc sulfide mineral sphalerite. Lead and zinc deposits are formed by discharge of deep sedimentary brine onto the sea floor (termed "sedimentary exhalative" or SEDEX), or by replacement of limestone, in skarn deposits, some associated with submarine volcanoes (called volcanogenic massive sulfide ore deposits or VMS), or in the aureole of subvolcanic intrusions of granite. The vast majority of SEDEX lead and zinc deposits
Primary minerals as basalt, rhyolite, andesite and obsidian) and intrusive rocks (such as granite, granodiorite, gabbro and peridotite) contain primary minerals including quartz, feldspar, plagioclase, muscovite, biotite, amphibole, pyroxene and olivine in varying concentrations. For the classical discussions of the origin of primary ores, see the two publications "Ore Deposits" (1903 and 1913). According to W.A. Tarr (1938) the primary mineral deposits are the result of direct magmatic action; he states that the splitting of magmas results in the basic igneous rocks and their accompanying group of accessory minerals formed by the first crystallization in the magma, on the one hand, and