Pencil thereby pushing a new tip to the top. Invented by Harold Grossman for Empire Pencil Company in 1967 and subsequently improved upon by Arthur D. Little for Empire from 1969 through the early 1970s; the plastic pencil was commercialised by Empire as the "EPCON" Pencil. These pencils were co-extruded, extruding a plasticised graphite mix within a wood-composite core. Residual graphite from a pencil stick is not poisonous, and graphite is harmless if consumed. Although lead has not been used for writing since antiquity, lead poisoning from pencils was not uncommon. Until the middle of the 20th century the paint used
Lead and spontaneously decomposes to PbCl and Cl. Analogously to lead monoxide, lead dioxide is capable of forming plumbate anions. Lead disulfide and lead diselenide are only stable at high pressures. Lead tetrafluoride, a yellow crystalline powder, is stable, but less so than the difluoride. Lead tetrachloride (a yellow oil) decomposes at room temperature, lead tetrabromide is less stable still, and the existence of lead tetraiodide is questionable. Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not