Carbonate-hosted lead-zinc ore deposits and pyrite thus form. Commonly MVT deposits form by the combination of hydrocarbon pyrolysis liberating zinc-lead ions and sulfur to form an acidic solution which dissolves the host carbonate formation and replaces it with massive sulfide accumulations. This may also take the morphology of fault-hosted stockworks, massive tabular replacements and so forth. Porous limestones may form disseminated ores, however most MVT deposits are massive sulfides with knife-like margins between carbonate and sulfide mineralogies. Ore minerals in carbonate replacement deposits are typically lead sulfide, galena, and zinc sulfide sphalerite. Weathered equivalents form anglesite, cerussite, smithsonite, hydrozincite and secondary galena and sphalerite
Schlangenberg Nature Reserve the surface where erosion removed large amounts. About 200 million years ago aqueous metal solutions filled the cavernous rocks. Primary ores were created mostly consisting of Sphalerite, Marcasite and Galena. The process continued and the ore close to the surface decomposed due to the influence of carbon dioxide and water. In this process as a secondary ore calamine ZnCO which is known as calamine developed. Presumably the Celts had been the first digging for the calamine in the region. Ancient Celtic and Roman coins dated between 100 BC and 92/93 AD as well as remains of a Roman settlement proved