Galena cubic unit cell much like the mineral halite of the halide mineral group. Zinc, cadmium, iron, copper, antimony, arsenic, bismuth and selenium also occur in variable amounts in galena. Selenium substitutes for sulfur in the structure constituting a solid solution series. The lead telluride mineral altaite has the same crystal structure as galena. Within the weathering or oxidation zone galena alters to anglesite (lead sulfate) or cerussite (lead carbonate). Galena exposed to acid mine drainage can be oxidized to anglesite by naturally occurring bacteria and archaea, in a process similar to bioleaching. One of the oldest uses of galena was
Metal subsurface mines. In some cases, the sale price of the metal/s involved make it economically feasible to mine lower concentration sources. Once the ore is mined, the metals must be extracted, usually by chemical or electrolytic reduction. Pyrometallurgy uses high temperatures to convert ore into raw metals, while hydrometallurgy employs aqueous chemistry for the same purpose. The methods used depend on the metal and their contaminants. When a metal ore is an ionic compound of that metal and a non-metal, the ore must usually be smelted—heated with a reducing agent—to extract the pure metal. Many common metals, such as iron,