Galena of Missouri and Wisconsin; the former mining communities of Galena, Kansas and Galena, Illinois take their names from deposits of this mineral. The largest documented crystal of galena is composite cubo-octahedra from the Great Laxey Mine, Isle of Man, measuring . Galena belongs to the octahedral sulfide group of minerals that have metal ions in octahedral positions, such as the iron sulfide pyrrhotite and the nickel arsenide niccolite. The galena group is named after its most common member, with other isometric members that include manganese bearing alabandite and niningerite. Divalent lead (Pb) cations and sulfur (S) anions form a close-packed
Broken Hill ore deposit hornblende schists. The ore consists of massive, recrystallised sphalerite-rich, galena-sphalerite and galena-rich sulfide lenses in folded horizons, known as No. 2 Lens Formation and No.3 Lens Formation. Both have distinctive metal ratios and gangue minerals. The ore boundaries are parallel to the bedding planes. According to Gustafson, "There is evidence that the ore has been introduced into an old, already folded, rock and has replaced certain favourable layers of that rock, particle by particle, with large tonnages of garnet, rhodonite, fluorite, marmatite (and wurtzite), galena, and other minerals that constitute the orebodies." The Potosi-Footwall Gneiss is found on both sides