Chemical element of an element to exist in one of many structural forms is known as 'allotropy'. The standard state, also known as the reference state, of an element is defined as its thermodynamically most stable state at a pressure of 1 bar and a given temperature (typically at 298.15 K). In thermochemistry, an element is defined to have an enthalpy of formation of zero in its standard state. For example, the reference state for carbon is graphite, because the structure of graphite is more stable than that of the other allotropes. Several kinds of descriptive categorizations can be applied broadly to
Chemical substance regard. A chemical substance may well be defined as "any material with a definite chemical composition" in an introductory general chemistry textbook. According to this definition a chemical substance can either be a pure chemical element or a pure chemical compound. But, there are exceptions to this definition; a pure substance can also be defined as a form of matter that has both definite composition and distinct properties. The chemical substance index published by CAS also includes several alloys of uncertain composition. Non-stoichiometric compounds are a special case (in inorganic chemistry) that violates the law of constant composition, and for