Ceria-zirconia oxides is thermodynamically favorable in a wide range of solid solution compositions, which means that ceria-zirconia is metastable with respect to phase separation. Ceria-zirconia is widely used as a component in current three-way catalytic converters. The ceria-based component of the converter has several functions, including promoting the dispersion of the noble metals in the catalyst, but also storing and releasing oxygen. The incorporation of zirconium in modern converters, forming ceria-zirconia, improves the performance of the catalyst by enhancing the resistance of the material to sintering, and simultaneously increasing the ability of the oxide to accommodate oxygen vacancies in its structure.
Zirconium carbide thermal chemical vapor deposition in a fluidized bed reactor. It also has high emissivity and high current capacity at elevated temperatures rendering it as a promising material for use in thermo-photovoltaic radiators and field emitter tips and arrays. It is also used as an abrasive, in cladding, in cermets, incandescent filaments and cutting tools. Zirconium carbide is made by carbo-thermal reduction of zirconia by graphite. Densified ZrC is made by sintering powder of ZrC at upwards of 2000 °C. Hot pressing of ZrC can bring down the sintering temperature and consequently helps in producing fine grained fully densified ZrC. Spark