Zirconium tetrafluoride Zirconium tetrafluoride Zirconium(IV) fluoride (ZrF) is an inorganic chemical compound. It is a component of ZBLAN fluoride glass. It is insoluble in water. It is the main component of fluorozirconate glasses. Three crystalline phases of ZrF have been reported, α (monoclinic), β (tetragonal, Pearson symbol tP40, space group P42/m, No 84) and γ (unknown structure). β and γ phases are unstable and irreversibly transform into the α phase at 400 °C. Zirconium fluoride is used as a zirconium source in oxygen-sensitive applications, e.g. metal production. Zirconium fluoride can be purified by distillation or sublimation. Conditions/substances to avoid are: moisture, active
Zirconia Toughened Alumina offers several key properties. The mechanical robustness compared to alumina is attributed to the displacive phase transformation of the metastable tetragonal ziroconia grains when the material is stressed. The stress concentration at a crack tip can cause a transformation from a tetragonal crystal structure to a monoclinic one, which has an associated volume expansion of ziroconia. This volume expansion effectively pushes back the propagation of the crack and results in higher toughness and strength. A common specimen of Zirconia Toughened Alumina will have 10-20% zirconium oxides. The 20-30% increase in strength often meets the design criteria needed at a much