Zirconium perchlorate as cold as possible. Zirconium perchlorate is very hydroscopic forming hydrates, and it is hydrolysed by water to yield zirconyl perchlorate, ZrO(ClO). Zirconium perchlorate reacts with vaseline, methyl nitrate or acetonitrile. Zirconium perchlorate is inert towards carbon tetrachloride, chloroform, and dimethylformamide. Zirconium perchlorate reacts with benzene at 20°C, but at -10°C crystals of Zr(ClO)•CH are deposited. Zirconium perchlorate has solid state transition around 45°C, a melting point between 95.5 and 96.0°C and a decomposition point starting around 120°C. The zirconyl perchlorate formed in the heat decomposition, itself decomposes around 290°C to form zirconia, chlorine and oxygen. In the gas phase
Zirconium(IV) chloride precursor for chemical vapor deposition of zirconium dioxide and zirconium diboride. In organic synthesis zirconium tetrachloride is used as a weak Lewis acid for the Friedel-Crafts reaction, the Diels-Alder reaction and intramolecular cyclisation reactions. It is also used to make water-repellent treatment of textiles and other fibrous materials. Hydrolysis of ZrCl gives the hydrated hydroxy chloride cluster called zirconyl chloride. This reaction is rapid and virtually irreversible, consistent with the high oxophilicity of zirconium(IV). For this reason, manipulations of ZrCl typically require air-free techniques. ZrCl is the principal starting compound for the synthesis of many organometallic complexes of zirconium. Because