Zirconium perchlorate as cold as possible. Zirconium perchlorate is very hydroscopic forming hydrates, and it is hydrolysed by water to yield zirconyl perchlorate, ZrO(ClO). Zirconium perchlorate reacts with vaseline, methyl nitrate or acetonitrile. Zirconium perchlorate is inert towards carbon tetrachloride, chloroform, and dimethylformamide. Zirconium perchlorate reacts with benzene at 20°C, but at -10°C crystals of Zr(ClO)•CH are deposited. Zirconium perchlorate has solid state transition around 45°C, a melting point between 95.5 and 96.0°C and a decomposition point starting around 120°C. The zirconyl perchlorate formed in the heat decomposition, itself decomposes around 290°C to form zirconia, chlorine and oxygen. In the gas phase
Zirconium dioxide coatings; it is a high-index material usable from the near-UV to the mid-IR, due to its low absorption in this spectral region. In such applications, it is typically deposited by PVD. In jewelry making, some watch cases are advertised as being "black zirconium oxide". In 2015 Omega released a fully ZrO watch named "The Dark Side of The Moon" with ceramic case, bezel, pushers and clasp, advertising it as four times harder than stainless steel and therefore much more resistant to scratches during everyday use. Single crystals of the cubic phase of zirconia are commonly used as diamond simulant in