Zirconium perchlorate as cold as possible. Zirconium perchlorate is very hydroscopic forming hydrates, and it is hydrolysed by water to yield zirconyl perchlorate, ZrO(ClO). Zirconium perchlorate reacts with vaseline, methyl nitrate or acetonitrile. Zirconium perchlorate is inert towards carbon tetrachloride, chloroform, and dimethylformamide. Zirconium perchlorate reacts with benzene at 20°C, but at -10°C crystals of Zr(ClO)•CH are deposited. Zirconium perchlorate has solid state transition around 45°C, a melting point between 95.5 and 96.0°C and a decomposition point starting around 120°C. The zirconyl perchlorate formed in the heat decomposition, itself decomposes around 290°C to form zirconia, chlorine and oxygen. In the gas phase
Zirconium is a rare water-soluble zirconium complex with the relatively complicated formula [Zr(OH)(HO)]Cl. Zirconium carbide and zirconium nitride are refractory solids. The carbide is used for drilling tools and cutting edges. Zirconium hydride phases are also known. Lead zirconate titanate (PZT) is the most commonly used piezoelectric material, with applications such as ultrasonic transducers, hydrophones, common rail injectors, piezoelectric transformers and micro-actuators. All four common halides are known, ZrF, ZrCl, ZrBr, and ZrI. All have polymeric structures and are far less volatile than the corresponding monomeric titanium tetrahalides. All tend to hydrolyse to give the so-called oxyhalides and dioxides. The corresponding