PH of neutrality is not exactly 7 (25 °C), although this is a good approximation in most cases. Neutrality is defined as the condition where [H] = [OH] (or the activities are equal). Since self-ionization of water holds the product of these concentration [H]×[OH] = K, it can be seen that at neutrality [H] = [OH] = , or pH = pK/2. pK is approximately 14 but depends on ionic strength and temperature, and so the pH of neutrality does also. Pure water and a solution of NaCl in pure water are both neutral, since dissociation of water produces equal numbers
PH pH measurements. The concentration of hydroxide ions in water is related to the concentration of hydrogen ions by where "K" is the self-ionisation constant of water. Taking logarithms So, at room temperature, pOH ≈ 14 − pH. However this relationship is not strictly valid in other circumstances, such as in measurements of soil alkalinity. Measurement of pH below about 2.5 (ca. 0.003 mol dm acid) and above about 10.5 (ca. 0.0003 mol dm alkaline) requires special procedures because, when using the glass electrode, the Nernst law breaks down under those conditions. Various factors contribute to this. It cannot be assumed