Zirconium tetrafluoride Zirconium tetrafluoride Zirconium(IV) fluoride (ZrF) is an inorganic chemical compound. It is a component of ZBLAN fluoride glass. It is insoluble in water. It is the main component of fluorozirconate glasses. Three crystalline phases of ZrF have been reported, α (monoclinic), β (tetragonal, Pearson symbol tP40, space group P42/m, No 84) and γ (unknown structure). β and γ phases are unstable and irreversibly transform into the α phase at 400 °C. Zirconium fluoride is used as a zirconium source in oxygen-sensitive applications, e.g. metal production. Zirconium fluoride can be purified by distillation or sublimation. Conditions/substances to avoid are: moisture, active
Zirconium(IV) bromide Zirconium(IV) bromide Zirconium(IV) bromide is the inorganic compound with the formula ZrBr. This colourless solid is the principal precursor to other Zr–Br compounds. ZrBr is prepared by the action of bromine on zirconium oxide via a carbothermic reaction: Like many related tetrahalides, it is purified by sublimation. Like related tetrabromides of Ti and Hf, ZrBr hydrolyzes readily to give oxy-bromide, with release of hydrogen bromide. No single crystal X-ray study of ZrBr has been described. Some reports suggest that it is isostructural with TiCl and TiBr, featuring tetrahedral metal centers. Other studies indicate a polymeric structure. ZrCl is polymeric in