Zirconium tetrafluoride reactors.) Zirconium tetrafluoride Zirconium(IV) fluoride (ZrF) is an inorganic chemical compound. It is a component of ZBLAN fluoride glass. It is insoluble in water. It is the main component of fluorozirconate glasses. Three crystalline phases of ZrF have been reported, α (monoclinic), β (tetragonal, Pearson symbol tP40, space group P42/m, No 84) and γ (unknown structure). β and γ phases are unstable and irreversibly transform into the α phase at 400 °C. Zirconium fluoride is used as a zirconium source in oxygen-sensitive applications, e.g. metal production. Zirconium fluoride can be purified by distillation or sublimation. Conditions/substances to avoid are: moisture,
Zirconium(II) hydride Zirconium(II) hydride Zirconium(II) hydride, ZrH is a molecular chemical compound which has been prepared by laser ablation and isolated at low temperature. Zirconium(II) hydride has repeatedly been the subject of Dirac–Hartree–Fock relativistic calculation studies, which investigate the stabilities, geometries, and relative energies of hydrides of the formula MH, MH, MH, or MH. Zirconium(II) hydride has a dihedral (C) structure. In zirconium(II) hydride, the formal oxidation states of hydrogen and zirconium are −1 and +2, respectively, because the electronegativity of zirconium is lower than that of hydrogen. The stability of metal hydrides with the formula MH (M = Ti-Hf) decreases as