Zirconium perchlorate as cold as possible. Zirconium perchlorate is very hydroscopic forming hydrates, and it is hydrolysed by water to yield zirconyl perchlorate, ZrO(ClO). Zirconium perchlorate reacts with vaseline, methyl nitrate or acetonitrile. Zirconium perchlorate is inert towards carbon tetrachloride, chloroform, and dimethylformamide. Zirconium perchlorate reacts with benzene at 20°C, but at -10°C crystals of Zr(ClO)•CH are deposited. Zirconium perchlorate has solid state transition around 45°C, a melting point between 95.5 and 96.0°C and a decomposition point starting around 120°C. The zirconyl perchlorate formed in the heat decomposition, itself decomposes around 290°C to form zirconia, chlorine and oxygen. In the gas phase
Zirconium tetraalkoxides are also known. Unlike the halides, the alkoxides dissolve in nonpolar solvents. Dihydrogen hexafluorozirconate is used in the metal finishing industry as an etching agent to promote paint adhesion. Organozirconium chemistry is the study of compounds containing a carbon-zirconium bond. The first such compound was zirconocene dibromide ((CH)ZrBr), reported in 1952 by Birmingham and Wilkinson. Schwartz's reagent, prepared in 1970 by P. C. Wailes and H. Weigold, is a metallocene used in organic synthesis for transformations of alkenes and alkynes. Zirconium is also a component of some Ziegler-Natta catalysts, used to produce polypropylene. This application exploits the ability of