Zirconium nitrate of chemical suppliers. It is used as a source of zirconium for other salts, as an analytical standard, or as a preservative. Zirconium nitrate and nitronium pentanitratozirconate can be used as chemical vapour deposition precursors as they are volatile, and decompose above 100 °C to form zirconia. At 95°C zirconium nitrate sublimes with a pressure of 0.2 mm of Hg and can be deposited as zirconium dioxide on silicon at 285°C. It has the advantage in that it is a single source, meaning it does not have to be mixed with other materials like oxygen, and decomposes at a relatively
Zirconium(IV) bromide the solid state, featuring octahedral Zr centers. Zirconium(IV) bromide Zirconium(IV) bromide is the inorganic compound with the formula ZrBr. This colourless solid is the principal precursor to other Zr–Br compounds. ZrBr is prepared by the action of bromine on zirconium oxide via a carbothermic reaction: Like many related tetrahalides, it is purified by sublimation. Like related tetrabromides of Ti and Hf, ZrBr hydrolyzes readily to give oxy-bromide, with release of hydrogen bromide. No single crystal X-ray study of ZrBr has been described. Some reports suggest that it is isostructural with TiCl and TiBr, featuring tetrahedral metal centers. Other studies indicate