Yttria-stabilized zirconia is known to not be completely stabilized in the pure cubic YSZ phase up to temperatures above 1000 °C (Ref. and publications therein), commonly used abbreviations in conjunction with yttria-stabilized zirconia are: The thermal expansion coefficients depends on the modification of zirconia as follows: By the addition of yttria to pure zirconia (e.g., fully stabilized YSZ) Y ions replace Zr on the cationic sublattice. Thereby, oxygen vacancies are generated due to charge neutrality: formula_4 with formula_5, meaning two Y ions generate one vacancy on the anionic sublattice. This facilitates moderate conductivity of yttrium stabilized zirconia for O ions (and thus
Zirconium zirconium to reversibly form bonds to carbon. Most complexes of Zr(II) are derivatives of zirconocene, one example being (CMe)Zr(CO). The zirconium-containing mineral zircon and related minerals (jargoon, hyacinth, jacinth, ligure) were mentioned in biblical writings. The mineral was not known to contain a new element until 1789, when Klaproth analyzed a jargoon from the island of Ceylon (now Sri Lanka). He named the new element Zirkonerde (zirconia). Humphry Davy attempted to isolate this new element in 1808 through electrolysis, but failed. Zirconium metal was first obtained in an impure form in 1824 by Berzelius by heating a mixture of potassium