PH of neutrality is not exactly 7 (25 °C), although this is a good approximation in most cases. Neutrality is defined as the condition where [H] = [OH] (or the activities are equal). Since self-ionization of water holds the product of these concentration [H]×[OH] = K, it can be seen that at neutrality [H] = [OH] = , or pH = pK/2. pK is approximately 14 but depends on ionic strength and temperature, and so the pH of neutrality does also. Pure water and a solution of NaCl in pure water are both neutral, since dissociation of water produces equal numbers
Alkali soil applied as a source of Ca ions to replace the sodium at the exchange complex. Gypsum also reacts with sodium carbonate to convert into sodium sulphate which is a neutral salt and does not contribute to high pH. There must be enough natural drainage to the underground, or else an artificial subsurface drainage system must be present, to permit leaching of the excess sodium by percolation of rain and/or irrigation water through the soil profile. Calcium Chloride is also used to reclaim alkali soils. CaCl converts NaCO into NaCl precipitating CaCO. NaCl is drained off by leaching water. Spent acid