Zirconium perchlorate as cold as possible. Zirconium perchlorate is very hydroscopic forming hydrates, and it is hydrolysed by water to yield zirconyl perchlorate, ZrO(ClO). Zirconium perchlorate reacts with vaseline, methyl nitrate or acetonitrile. Zirconium perchlorate is inert towards carbon tetrachloride, chloroform, and dimethylformamide. Zirconium perchlorate reacts with benzene at 20°C, but at -10°C crystals of Zr(ClO)•CH are deposited. Zirconium perchlorate has solid state transition around 45°C, a melting point between 95.5 and 96.0°C and a decomposition point starting around 120°C. The zirconyl perchlorate formed in the heat decomposition, itself decomposes around 290°C to form zirconia, chlorine and oxygen. In the gas phase
Zirconium(IV) bromide the solid state, featuring octahedral Zr centers. Zirconium(IV) bromide Zirconium(IV) bromide is the inorganic compound with the formula ZrBr. This colourless solid is the principal precursor to other Zr–Br compounds. ZrBr is prepared by the action of bromine on zirconium oxide via a carbothermic reaction: Like many related tetrahalides, it is purified by sublimation. Like related tetrabromides of Ti and Hf, ZrBr hydrolyzes readily to give oxy-bromide, with release of hydrogen bromide. No single crystal X-ray study of ZrBr has been described. Some reports suggest that it is isostructural with TiCl and TiBr, featuring tetrahedral metal centers. Other studies indicate