Yttria-stabilized zirconia is known to not be completely stabilized in the pure cubic YSZ phase up to temperatures above 1000 °C (Ref. and publications therein), commonly used abbreviations in conjunction with yttria-stabilized zirconia are: The thermal expansion coefficients depends on the modification of zirconia as follows: By the addition of yttria to pure zirconia (e.g., fully stabilized YSZ) Y ions replace Zr on the cationic sublattice. Thereby, oxygen vacancies are generated due to charge neutrality: formula_4 with formula_5, meaning two Y ions generate one vacancy on the anionic sublattice. This facilitates moderate conductivity of yttrium stabilized zirconia for O ions (and thus
Zirconium perchlorate synthesized by reacting Zr(OH) with HClO, then the colorless crystals are formed by slow evaporation. Zirconium perchlorate Zirconium perchlorate is a molecular substance containing zirconium and perchlorate groups with formula Zr(ClO). Zr(ClO) is a volatile crystalline product. It can be formed by reacting zirconium tetrachloride with dry perchloric acid at liquid nitrogen temperatures. Zr(ClO) sublimes slowly in a vacuum at 70°C showing that the molecule is covalently bound rather than being ionic. The reaction also forms some zirconyl perchlorate (or zirconium oxyperchlorate) ZrO(ClO) as even apparently pure perchloric acid is in equilibrium with dichlorine heptoxide, hydronium ions and perchlorate ions.