Terephthalic acid Terephthalic acid Terephthalic acid is an organic compound with formula CH(COH). This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles. Several million tonnes are produced annually. The common name is derived from the turpentine-producing tree "Pistacia terebinthus" and phthalic acid. Terephthalic acid was first isolated (from turpentine) by the French chemist Amédée Cailliot (1805–1884) in 1846. Terephthalic acid became industrially important after World War II. Terephthalic acid was produced by oxidation of "p"-xylene with dilute nitric acid. Air oxidation of "p"-xylene gives "p"-toluic acid, which resists
Sorbic acid Sorbic acid Sorbic acid, or 2,4-hexadienoic acid, is a natural organic compound used as a food preservative. It has the chemical formula CH(CH)COH. It is a colourless solid that is slightly soluble in water and sublimes readily. It was first isolated from the unripe berries of the "Sorbus aucuparia" (rowan tree), hence its name. The traditional route to sorbic acid involves condensation of malonic acid and trans-butenal. It can also be prepared from isomeric hexadienoic acids, which are available via a nickel-catalyzed reaction of allyl chloride, acetylene, and carbon monoxide. The route used commercially, however, is from crotonaldehyde and ketene.