Carbon the very large masses of carbonate rock (limestone, dolomite, marble and so on). Coal is very rich in carbon (anthracite contains 92–98%) and is the largest commercial source of mineral carbon, accounting for 4,000 gigatonnes or 80% of fossil fuel. As for individual carbon allotropes, graphite is found in large quantities in the United States (mostly in New York and Texas), Russia, Mexico, Greenland, and India. Natural diamonds occur in the rock kimberlite, found in ancient volcanic "necks", or "pipes". Most diamond deposits are in Africa, notably in South Africa, Namibia, Botswana, the Republic of the Congo, and Sierra Leone.
History of the iron and steel industry in the United States when coke from coal started replacing charcoal as the fuel and reducing agent. Coke has a higher crushing strength than charcoal, allowing larger smelting furnaces. Because iron and steel-making at the time consumed more coal than iron ore, the steel mills moved closer to the coal mines to minimize transportation costs. A problem of coke was that it carried impurities such as sulfur, which degraded the quality of the steel. Although coke quickly became the dominant fuel for iron-smelting, in 1884 charcoal was still used to make ten percent of iron and steel in the US. The use of charcoal