Carbon the very large masses of carbonate rock (limestone, dolomite, marble and so on). Coal is very rich in carbon (anthracite contains 92–98%) and is the largest commercial source of mineral carbon, accounting for 4,000 gigatonnes or 80% of fossil fuel. As for individual carbon allotropes, graphite is found in large quantities in the United States (mostly in New York and Texas), Russia, Mexico, Greenland, and India. Natural diamonds occur in the rock kimberlite, found in ancient volcanic "necks", or "pipes". Most diamond deposits are in Africa, notably in South Africa, Namibia, Botswana, the Republic of the Congo, and Sierra Leone.
Synthesis of carbon nanotubes large scale CVD production. Nanoscale metal catalysts are important ingredients for fixed- and fluidized-bed CVD synthesis of CNTs. They allow increasing the growth efficiency of CNTs and may give control over their structure and chirality. During synthesis, catalysts can convert carbon precursors into tubular carbon structures but can also form encapsulating carbon overcoats. Together with metal oxide supports they may therefore attach to or become incorporated into the CNT product. The presence of metal impurities can be problematic for many applications. Especially catalyst metals like nickel, cobalt or yttrium may be of toxicological concern. While unencapsulated catalyst metals may be