Witches' Sabbath (The Great He-Goat) powdered glass, orpiment and iron oxides. He likely worked with mixed materials. Technical analysis indicates that most of the Black Paintings begun with preparatory drawings. "Witches' Sabbath" is the exception; the final composition seems to have been painted directly onto the wall. Art historian Fred Licht notes that Goya's brushwork appears "clumsy, ponderous, and rough" and lacking finish compared to his earlier work. Licht believes this was a deliberate ploy to physically convey dismay at human inadequacy and his own feelings of personal doubt. Unique in the series, "Witches' Sabbath" was not significantly altered by Goya after his initial work.
Enlightenment in Spain such as La Condamine and Alexander von Humboldt, to its overseas empire, usually closed to foreigners. There were extended Royal Botanical Expeditions to Chile and Peru (1777–88), New Granada (1783–1816), and New Spain (1787–1803), which produced a huge number of detailed botanical drawings and specimens destined for the Royal Botanical Garden and the Royal Natural History Cabinet in Madrid. The Malaspina Expedition was an important scientific expedition headed by Spanish naval commander Alejandro Malaspina over five years (1789–94), with naturalists and botanical illustrators gathering information for the Spanish crown. The illustrators on the voyage included José de Pozo, trained at