María Cayetana de Silva, 13th Duchess of Alba María Cayetana de Silva, 13th Duchess of Alba María del Pilar Teresa Cayetana de Silva-Álvarez de Toledo y Silva, 13th Duchess of Alba, GE (full name, see infobox; 10 June 1762 – 23 July 1802), was a Spanish aristocrat and a popular subject of the painter Francisco de Goya y Lucientes. María del Pilar Teresa Cayetana de Silva Alvarez de Toledo became the 13th Duchess of Alba in 1776. Her marriage to José Álvarez de Toledo, 11th Marquis of Villafranca, made her and her husband the wealthiest couple in the Kingdom of Spain; their only rivals to this title were
María Cayetana de Silva, 13th Duchess of Alba was poisoned (this theory was dramatized in the film "The Naked Maja"). She had no biological issue although she did have an adoptive daughter, known as María de la Luz. After her death, the title Duke of Alba passed to a relative, Carlos Miguel Fitz-James Stuart (1794–1835), who became the 14th Duke of Alba. María Cayetana de Silva, 13th Duchess of Alba María del Pilar Teresa Cayetana de Silva-Álvarez de Toledo y Silva, 13th Duchess of Alba, GE (full name, see infobox; 10 June 1762 – 23 July 1802), was a Spanish aristocrat and a popular subject of the painter