Barium peroxide Barium peroxide Barium peroxide is the inorganic compound with the formula BaO. This white solid (gray when impure) is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition (as do all barium compounds), it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide. Barium peroxide is a peroxide, containing subunits. The solid is isomorphous to calcium carbide, CaC. Barium peroxide arises by the reversible reaction of O with barium oxide. The peroxide forms around 500 °C
Barium hydroxide to be free of carbonate, unlike those of sodium hydroxide and potassium hydroxide, as barium carbonate is insoluble in water. This allows the use of indicators such as phenolphthalein or thymolphthalein (with alkaline colour changes) without the risk of titration errors due to the presence of carbonate ions, which are much less basic. Barium hydroxide is occasionally used in organic synthesis as a strong base, for example for the hydrolysis of esters and nitriles, and as a base in aldol condensations. It has been used to hydrolyse one of the two equivalent ester groups in dimethyl hendecanedioate. Barium hydroxide is