Barium chlorate hazardous waste. The Environmental Protection Agency (EPA) lists barium chlorate as hazardous. Barium chlorate Barium chlorate, Ba(ClO), is a white crystalline solid, the barium salt of chloric acid. It is an irritant and toxic, as are all soluble barium compounds. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid. Barium chlorate can be produced through a double replacement reaction between solutions of barium chloride and sodium chlorate: On concentrating and chilling the resulting mixture, barium chlorate precipitates. This is perhaps the most common preparation, exploiting the lower solubility
Calcium chlorate with strong sulfuric acid can result in explosions due to the instability of concentrated chloric acid. Contact with ammonium compounds can also cause violent decomposition due to the formation of unstable ammonium chlorate. Calcium chlorate has been used as an herbicide, like sodium chlorate. Calcium chlorate is occasionally used in pyrotechnics, as an oxidizer and pink flame colorant. Its hygroscopic nature and incompatibility with other common pyrotechnic materials (such as sulfur) limit its utility in these applications. Calcium chlorate Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO). Like other chlorates, it is a strong