Barium chlorate acid, the formal precursor to all chlorate salts, through its reaction with dilute sulfuric acid, which results in a solution of chloric acid and insoluble barium sulfate precipitate: Both the chlorate and the acid should be prepared as dilute solutions before mixing, such that the chloric acid produced is dilute, as concentrated solutions of chloric acid (above 30%) are unstable and prone to decompose, sometimes explosively. Fireworks Barium chlorate, when burned with a fuel, produces a vibrant green light. Because it is an oxidizer, a chlorine donor, and contains a metal, this compound produces a green color that is unparalleled.
Potassium chlorate chlorate and a fuel can ignite by contact with sulfuric acid, so it should be kept away from this reagent. Sulfur should be avoided in pyrotechnic compositions containing potassium chlorate, as these mixtures are prone to spontaneous deflagration. Most sulfur contains trace quantities of sulfur-containing acids, and these can cause spontaneous ignition - "Flowers of sulfur" or "sublimed sulfur", despite the overall high purity, contains significant amounts of sulfur acids. Also, mixtures of potassium chlorate with any compound with ignition promoting properties (ex. antimony(III) sulfide) are very dangerous to prepare, as they are extremely shock sensitive. Potassium chlorate Potassium chlorate