Barium chlorate hazardous waste. The Environmental Protection Agency (EPA) lists barium chlorate as hazardous. Barium chlorate Barium chlorate, Ba(ClO), is a white crystalline solid, the barium salt of chloric acid. It is an irritant and toxic, as are all soluble barium compounds. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid. Barium chlorate can be produced through a double replacement reaction between solutions of barium chloride and sodium chlorate: On concentrating and chilling the resulting mixture, barium chlorate precipitates. This is perhaps the most common preparation, exploiting the lower solubility
Barium perchlorate employing gases under pressure, as the water must be removed from the air prior to the reaction taking place. Barium perchlorate is also used for the determination of small concentrations (down to 10 ppm, with an accuracy of +/- 1 ppm) of sulfate. In order for the titration to be successful, a high concentration of a nonaqueous solvent, such as ethyl alcohol, 2-propanol, or methanol, must be present. Thorin is typically used as the indicator. Barium perchlorate Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO). It is used in the pyrotechnic industry. Barium perchlorate decomposes at 505