Barium chlorate in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis: It can also be produced by the reaction of barium carbonate with boiling ammonium chlorate solution: The reaction initially produces barium chlorate and ammonium carbonate; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution. When exposed to heat, barium chlorate alone will decompose to barium chloride and oxygen: Barium chlorate is used to produce chloric
Barium carbonate barium sulfide either by treatment with sodium carbonate at 60 to 70 °C (soda ash method) or by passing carbon dioxide at 40 to 90 °C. In the soda ash process, solid or dissolved sodium carbonate is added to barium sulfide solution, and the barium carbonate precipitate is filtered, washed and dried. Barium carbonate reacts with acids such as hydrochloric acid to form soluble barium salts, such as barium chloride: However, the reaction with sulfuric acid is poor, because barium sulfate is highly insoluble. Barium carbonate is widely used in the ceramics industry as an ingredient in glazes. It acts