Barium oxalate Barium oxalate Barium oxalate (BaCO), a barium salt of oxalic acid, is a white odorless powder that is sometimes used as a green pyrotechnic colorant generally in specialized pyrotechnic compositions containing magnesium. Though largely stable, barium oxalate can be reactive with strong acids. A mild skin irritant, the substance is considered toxic when ingested, causing nausea, vomiting, renal failure, and injury to the gastrointestinal tract. It is different from most pyrotechnic colorants in that it is a reducing agent and not an oxidizing agent. It is extremely insoluble in water and converts to the oxide form when heated. The raw
Calcium chlorate complicated by calcium hydroxide depositing on the cathode, preventing the flow of current. When concentrated solutions of calcium chlorate and potassium chloride are combined, potassium chlorate precipitates: This is the second step of the Liebig process for the manufacture of potassium chlorate. Solutions of calcium chlorate react with solutions of alkali carbonates to give a precipitate of calcium carbonate and the alkali chlorate in solution: On strong heating, calcium chlorate decomposes to give oxygen and calcium chloride: Cold, dilute solutions of calcium chlorate and sulfuric acid react to give a precipitate of calcium sulfate and chloric acid in solution: Contact