Copper(II) chlorate heated, giving off a yellow gas, which contains chlorine, oxygen and chlorine dioxide. A green solid is left that is a basic copper salt. Sulfur is highly reactive with copper chlorate, and it is important not to cross contaminate these chemicals, for example in pyrotechnic making. François-Marie Chertier used tetrammine copper chlorate to colour flames blue in 1843. This material was abbreviated TACC with formula Cu(NH)(ClO). TACC explodes on impact. The substance became known as Chertier'c copper for use in blue coloured pyrotechnics. However its deliquescence causes a problem. Mixtures with other metal salts can yield violet or lilac colours
Barium manganate Barium manganate Barium manganate is an inorganic compound with the formula BaMnO. It is used as an oxidant in organic chemistry. It belongs to a class of compounds known as manganates in which the manganese resides in a +6 oxidation state. Manganate should not to be confused with permanganate in which contains manganese(VII). Barium manganate is a powerful oxidant, popular in organic synthesis and can be used in a wide variety of oxidation reactions. The manganate(VI) ion is a d ion and is tetrahedral with bond angles of approximately 109.5°. The Mn-O bond lengths in BaMnO and KMnO are identical