Plovdiv municipal triangle of Plovdiv, including Maritsa municipality and Rodopi municipality. Population of Plovdiv: At the first census after the Liberation of Bulgaria in 1880 with 24,053 citizens, Plovdiv is the second largest city behind Ruse, which had 26,163 citizens then, and ahead of the capital Sofia, which had 20,501 citizens then. As of the 1887 census, Plovdiv was the largest city in the country for several years with 33,032 inhabitants compared to 30,428 for Sofia. According to the 1946 census, Plovdiv was the second largest city with 126,563 inhabitants compared to 487,000 for the capital. In its ethnic character Plovdiv
Church of the Holy Mother of God, Plovdiv 10 January 1860 the bishop of Plovdiv Paisius held a service in Bulgarian language and publicly announced that his congregation denounced the Greek Patriarch of Istanbul which became a great scandal and Plovdiv became the most radical center for the struggle of the autonomy of the Bulgarian Orthodox Church. On 30 April Paisius organized a Church and People's counsel in which the citizens were also represented in order to discuss the church question. Plovdiv sent a delegation to the Ottoman government asking officially for an autonomous Church. That Counsel was held annually until 1870 when the Bulgarian Exarchate was recognized