Barium peroxide Barium peroxide Barium peroxide is the inorganic compound with the formula BaO. This white solid (gray when impure) is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition (as do all barium compounds), it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide. Barium peroxide is a peroxide, containing subunits. The solid is isomorphous to calcium carbide, CaC. Barium peroxide arises by the reversible reaction of O with barium oxide. The peroxide forms around 500 °C
Barium perchlorate Barium perchlorate Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO). It is used in the pyrotechnic industry. Barium perchlorate decomposes at 505 °C. Gallucci and Gerkin (1988) analyzed the structure of the hydrate isomer Barium Perclorate Trihydrate (Ba(ClO)•3HO) by X-ray crystallography. The barium ions are coordinated by six water oxygen atoms at 2.919Å and six perchlorate oxygens at 3.026Å in a distorted icosahedral arrangement. The perchlorate fails by a narrow margin to have regular tetrahedral geometry, and has an average Cl-O bond length of 1.433Å. The space-group assignment of the structure was resolved, with the centrosymmetric assignment