Barium hydroxide, it absorbs very little CO in aqueous solutions and is therefore insensitive to atmospheric fluctuations. This property is used in calibrating pH equipment. Volatile barium compounds burn with a green to pale green flame, which is an efficient test to detect a barium compound. The color results from spectral lines at 455.4, 493.4, 553.6, and 611.1 nm. Organobarium compounds are a growing field of knowledge: recently discovered are dialkylbariums and alkylhalobariums. Barium found in the Earth's crust is a mixture of seven primordial nuclides, barium-130, 132, and 134 through 138. Barium-130 undergoes very slow radioactive decay to xenon-130 by
Chlorate were once widely used in pyrotechnics for this reason, though their use has fallen due to their instability. Most pyrotechnic applications that formerly used chlorates now use the more stable perchlorates instead. The chlorate ion cannot be satisfactorily represented by just one Lewis structure, since all the Cl–O bonds are the same length (1.49 Å in potassium chlorate), and the chlorine atom is hypervalent. Instead, it is often thought of as a hybrid of multiple resonance structures: Metal chlorates can be prepared by adding chlorine to hot metal hydroxides like KOH: In this reaction, chlorine undergoes disproportionation, both reduction and