Barium chlorate in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis: It can also be produced by the reaction of barium carbonate with boiling ammonium chlorate solution: The reaction initially produces barium chlorate and ammonium carbonate; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution. When exposed to heat, barium chlorate alone will decompose to barium chloride and oxygen: Barium chlorate is used to produce chloric
Barium perchlorate employing gases under pressure, as the water must be removed from the air prior to the reaction taking place. Barium perchlorate is also used for the determination of small concentrations (down to 10 ppm, with an accuracy of +/- 1 ppm) of sulfate. In order for the titration to be successful, a high concentration of a nonaqueous solvent, such as ethyl alcohol, 2-propanol, or methanol, must be present. Thorin is typically used as the indicator. Barium perchlorate Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO). It is used in the pyrotechnic industry. Barium perchlorate decomposes at 505