Plovdiv municipal triangle of Plovdiv, including Maritsa municipality and Rodopi municipality. Population of Plovdiv: At the first census after the Liberation of Bulgaria in 1880 with 24,053 citizens, Plovdiv is the second largest city behind Ruse, which had 26,163 citizens then, and ahead of the capital Sofia, which had 20,501 citizens then. As of the 1887 census, Plovdiv was the largest city in the country for several years with 33,032 inhabitants compared to 30,428 for Sofia. According to the 1946 census, Plovdiv was the second largest city with 126,563 inhabitants compared to 487,000 for the capital. In its ethnic character Plovdiv
History of Plovdiv and the Day of Plovdiv. After Unification Plovdiv remained the second city in population and significance after the capital Sofia. The first railway in the city was built in 1874 and after 1888 it was linked with Sofia. In 1892 Plovdiv became host of the First Bulgarian Fair with international participation which was succeeded by the International Fair Plovdiv. After the liberation the first brewery was inaugurated in the city. In the beginning of the 20th century Plovdiv grew as a significant industrial and commercial center with well-developed light and food industry. German, French and Belgian capital was invested in