Barium sulfate groups that are sensitive to overreduction. With a low surface area, the contact time of the substrate with the catalyst is shorter and thus selectivity is achieved. Palladium on barium sulfate is also used as a catalyst in the Rosenmund reduction. As barium compounds emit a green light when burned, barium salts are often used in green pyrotechnic formulas, but the nitrate and chlorate salts are more common. Barium sulfate is commonly used as a component of "strobe" pyrotechnic compositions. As barium sulfate has high burning point and is insoluble in water, it is used as a coating material in
Calcium chlorate Calcium chlorate Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO). Like other chlorates, it is a strong oxidizer. Calcium chlorate is produced by passing chlorine gas through a hot suspension of calcium hydroxide in water, producing calcium hypochlorite, which disproportionates when heated with excess chlorine to give calcium chlorate and calcium chloride: This is also the first step of the Liebig process for the manufacture of potassium chlorate. In theory, electrolysis of hot calcium chloride solution will give chlorate, analogous to the process used for the manufacture of sodium chlorate. In practice, electrolysis is