Barium peroxide Barium peroxide Barium peroxide is the inorganic compound with the formula BaO. This white solid (gray when impure) is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition (as do all barium compounds), it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide. Barium peroxide is a peroxide, containing subunits. The solid is isomorphous to calcium carbide, CaC. Barium peroxide arises by the reversible reaction of O with barium oxide. The peroxide forms around 500 °C
Barium hydroxide used, as well, in the decarboxylation of amino acids liberating barium carbonate in the process. It is also used in the preparation of cyclopentanone, diacetone alcohol and -Gulonic γ-lactone. Barium hydroxide decomposes to barium oxide when heated to 800 °C. Reaction with carbon dioxide gives barium carbonate. Its aqueous solution, being highly alkaline, undergoes neutralization reactions with acids. Thus, it forms barium sulfate and barium phosphate with sulfuric and phosphoric acids, respectively. Reaction with hydrogen sulfide produces barium sulfide. Precipitation of many insoluble, or less soluble barium salts, may result from double replacement reaction when a barium hydroxide aqueous solution