Copper(II) chlorate heated, giving off a yellow gas, which contains chlorine, oxygen and chlorine dioxide. A green solid is left that is a basic copper salt. Sulfur is highly reactive with copper chlorate, and it is important not to cross contaminate these chemicals, for example in pyrotechnic making. François-Marie Chertier used tetrammine copper chlorate to colour flames blue in 1843. This material was abbreviated TACC with formula Cu(NH)(ClO). TACC explodes on impact. The substance became known as Chertier'c copper for use in blue coloured pyrotechnics. However its deliquescence causes a problem. Mixtures with other metal salts can yield violet or lilac colours
Barium acetate Barium acetate Barium acetate (Ba(CHO)) is the salt of barium(II) and acetic acid. Barium acetate is generally produced by the reaction of acetic acid with barium carbonate: The reaction is performed in solution and the barium acetate crystallizes out. Alternatively, barium sulfide can be used: Again, the solvent is evaporated off and the barium acetate crystallized. Barium acetate is a white powder, which is highly soluble: at 0 °C, 55.8 g of barium acetate can be dissolved in 100 g of water. It decomposes upon heating into barium carbonate. When heated in air, barium acetate decomposes to the carbonate. It