Barium chlorate in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis: It can also be produced by the reaction of barium carbonate with boiling ammonium chlorate solution: The reaction initially produces barium chlorate and ammonium carbonate; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution. When exposed to heat, barium chlorate alone will decompose to barium chloride and oxygen: Barium chlorate is used to produce chloric
Calcium chlorate complicated by calcium hydroxide depositing on the cathode, preventing the flow of current. When concentrated solutions of calcium chlorate and potassium chloride are combined, potassium chlorate precipitates: This is the second step of the Liebig process for the manufacture of potassium chlorate. Solutions of calcium chlorate react with solutions of alkali carbonates to give a precipitate of calcium carbonate and the alkali chlorate in solution: On strong heating, calcium chlorate decomposes to give oxygen and calcium chloride: Cold, dilute solutions of calcium chlorate and sulfuric acid react to give a precipitate of calcium sulfate and chloric acid in solution: Contact