Copper(II) chlorate heated, giving off a yellow gas, which contains chlorine, oxygen and chlorine dioxide. A green solid is left that is a basic copper salt. Sulfur is highly reactive with copper chlorate, and it is important not to cross contaminate these chemicals, for example in pyrotechnic making. François-Marie Chertier used tetrammine copper chlorate to colour flames blue in 1843. This material was abbreviated TACC with formula Cu(NH)(ClO). TACC explodes on impact. The substance became known as Chertier'c copper for use in blue coloured pyrotechnics. However its deliquescence causes a problem. Mixtures with other metal salts can yield violet or lilac colours
Barium carbonate barium sulfide either by treatment with sodium carbonate at 60 to 70 °C (soda ash method) or by passing carbon dioxide at 40 to 90 °C. In the soda ash process, solid or dissolved sodium carbonate is added to barium sulfide solution, and the barium carbonate precipitate is filtered, washed and dried. Barium carbonate reacts with acids such as hydrochloric acid to form soluble barium salts, such as barium chloride: However, the reaction with sulfuric acid is poor, because barium sulfate is highly insoluble. Barium carbonate is widely used in the ceramics industry as an ingredient in glazes. It acts