Gouache tubes and a "Chinese white" tube was added to boxes for this purpose. Later that century, for decorative uses "poster paint" was mass-produced, based on the much cheaper dextrin binder. It was sold in cans or as a powder to be mixed with water. The dextrin replaced older paint types based on hide glue or size. During the twentieth century, gouache began to be specially manufactured in tubes for more refined artistic purposes. Initially, gum arabic was used as a binder but soon cheaper brands were based on dextrin, as is most paint for children. A relatively new variation in
Gum arabic insoluble in water upon exposure to ultraviolet light. In the final print, the acacia gum permanently binds the pigments onto the paper. Gum arabic is also used to protect and etch an image in lithographic processes, both from traditional stones and aluminum plates. In lithography, gum by itself may be used to etch very light tones, such as those made with a number five crayon. Phosphoric, nitric or tannic acid is added in varying concentrations to the acacia gum to etch the darker tones up to dark blacks. The etching process creates a gum adsorb layer within the matrix that