Barium chlorate in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis: It can also be produced by the reaction of barium carbonate with boiling ammonium chlorate solution: The reaction initially produces barium chlorate and ammonium carbonate; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution. When exposed to heat, barium chlorate alone will decompose to barium chloride and oxygen: Barium chlorate is used to produce chloric
Barium bromide and can cause severe poisoning if ingested. Barium bromide Barium bromide is the chemical compound with the formula BaBr. Like barium chloride, it dissolves well in water and is toxic in aqueous solution. BaBr crystallizes in a lead chloride motif, giving white orthorhombic crystals which are deliquescent. In aqueous solution BaBr behaves as a simple salt. Barium bromide reacts with the sulfate ion from sulfuric acid to produce a precipitate of barium sulfate. Similar reactions occur with oxalic acid, hydrofluoric acid, and phosphoric acid. Barium bromide can be prepared from barium sulfide or barium carbonate via reaction with hydrobromic acid