Barium chlorate in some sodium contamination, which is undesirable for pyrotechnic purposes, where the strong yellow of sodium can easily overpower the green of barium. Sodium-free barium chlorate can be produced directly through electrolysis: It can also be produced by the reaction of barium carbonate with boiling ammonium chlorate solution: The reaction initially produces barium chlorate and ammonium carbonate; boiling the solution decomposes the ammonium carbonate and drives off the resulting ammonia and carbon dioxide, leaving only barium chlorate in solution. When exposed to heat, barium chlorate alone will decompose to barium chloride and oxygen: Barium chlorate is used to produce chloric
Sodium chlorate The Chloralkali process is an industrial process for the electrolytic production of sodium hydroxide and chlorine. It can also be synthesized by passing chlorine gas through a solution of sodium hydroxide. It is then purified by crystallization. The main commercial use for sodium chlorate is for making chlorine dioxide (ClO). The largest application of ClO, which accounts for about 95% of the use of chlorate, is in bleaching of pulp. All perchlorate compounds are produced industrially by the oxidation of solutions of sodium chlorate by electrolysis. Sodium chlorate is used as a non-selective herbicide. It is considered phytotoxic to all