Copper(II) chlorate heated, giving off a yellow gas, which contains chlorine, oxygen and chlorine dioxide. A green solid is left that is a basic copper salt. Sulfur is highly reactive with copper chlorate, and it is important not to cross contaminate these chemicals, for example in pyrotechnic making. François-Marie Chertier used tetrammine copper chlorate to colour flames blue in 1843. This material was abbreviated TACC with formula Cu(NH)(ClO). TACC explodes on impact. The substance became known as Chertier'c copper for use in blue coloured pyrotechnics. However its deliquescence causes a problem. Mixtures with other metal salts can yield violet or lilac colours
Sodium chlorate The Chloralkali process is an industrial process for the electrolytic production of sodium hydroxide and chlorine. It can also be synthesized by passing chlorine gas through a solution of sodium hydroxide. It is then purified by crystallization. The main commercial use for sodium chlorate is for making chlorine dioxide (ClO). The largest application of ClO, which accounts for about 95% of the use of chlorate, is in bleaching of pulp. All perchlorate compounds are produced industrially by the oxidation of solutions of sodium chlorate by electrolysis. Sodium chlorate is used as a non-selective herbicide. It is considered phytotoxic to all