Calamine brass slowly phased out as zinc smelting techniques were developed in Europe, which produced metallic zinc more suitable for brass production than calamine. However, the conversion away from calamine brass manufacture was slow; a British patent was awarded to William Champion in 1738, but the alloying of metallic zinc and copper to produce brass was not patented until 1781 (by James Emerson), and calamine brass mills persisted in South Wales until as late as 1858. The slow diffusion of this technology was probably the result of economic factors. Calamine brass Calamine brass is brass produced by a particular alloying technique using
Pitinga mine By 1990 the mine directly employed 2,000 people, and indirectly perhaps as many as 40,000. Trees were cleared, the river diverted and dams and ponds built before the alluvium deposits were processed. Bucketwheel excavator dredges extracted material rich in cassiterite, which was pumped through pipes to floating processing plants that separated the tin ore. The cassiterite is concentrated on site, then shipped to Mamoré Mineração e Metalurgia in the southern state of São Paulo for casting. Columbite ore is also mined, concentrated and processed on site for use in production of FeNbTa metallic alloy. Up to 1990 a total of