Calamine brass slowly phased out as zinc smelting techniques were developed in Europe, which produced metallic zinc more suitable for brass production than calamine. However, the conversion away from calamine brass manufacture was slow; a British patent was awarded to William Champion in 1738, but the alloying of metallic zinc and copper to produce brass was not patented until 1781 (by James Emerson), and calamine brass mills persisted in South Wales until as late as 1858. The slow diffusion of this technology was probably the result of economic factors. Calamine brass Calamine brass is brass produced by a particular alloying technique using
Metallic mean Metallic mean The metallic means or silver means (also ratios or constants) of the successive natural numbers are the continued fractions:formula_1 The golden ratio (1.618...) is the metallic mean between 1 and 2, while the silver ratio (2.414...) is the metallic mean between 2 and 3. The term "bronze ratio" (3.303...), or terms using other names of metals (such as copper or nickel), are occasionally used to name subsequent metallic means. The values of the first ten metallic means are shown at right. Notice that each metallic mean is a root of the simple quadratic equation: formula_2, where formula_3 is