Calamine brass slowly phased out as zinc smelting techniques were developed in Europe, which produced metallic zinc more suitable for brass production than calamine. However, the conversion away from calamine brass manufacture was slow; a British patent was awarded to William Champion in 1738, but the alloying of metallic zinc and copper to produce brass was not patented until 1781 (by James Emerson), and calamine brass mills persisted in South Wales until as late as 1858. The slow diffusion of this technology was probably the result of economic factors. Calamine brass Calamine brass is brass produced by a particular alloying technique using
Schlangenberg Nature Reserve the surface where erosion removed large amounts. About 200 million years ago aqueous metal solutions filled the cavernous rocks. Primary ores were created mostly consisting of Sphalerite, Marcasite and Galena. The process continued and the ore close to the surface decomposed due to the influence of carbon dioxide and water. In this process as a secondary ore calamine ZnCO which is known as calamine developed. Presumably the Celts had been the first digging for the calamine in the region. Ancient Celtic and Roman coins dated between 100 BC and 92/93 AD as well as remains of a Roman settlement proved