Group 12 element people in the 17th century. German chemist Andreas Marggraf is usually given credit for discovering pure metallic zinc in a 1746 experiment by heating a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. Experiments on frogs by the Italian doctor Luigi Galvani in 1780 with brass paved the way for the discovery of electrical batteries, galvanization and cathodic protection. In 1880, Galvani's friend, Alessandro Volta, invented the Voltaic pile. The biological importance of zinc was not discovered until 1940 when carbonic anhydrase, an enzyme that scrubs carbon dioxide from blood, was shown to
Thermo Electric Ore Reduction Corporation Mill the Hodgkinson River scattered over the surface as bunches in quartzose boulders or in drifts interspersed with coarse gravels. In 1900, 91 pounds of molybdenite was also discovered. This was said to contain some of the finest specimens of molybdenite discovered anywhere in Australia. Wolfram is composed of a heavy gray-white metallic element, with pure wolfram being used mainly in electrical applications and is also the ore from which tungsten is refined. In 1899 wolfram was returning £38 per ton. Other than along the Hodgkinson, wolfram has been located in north Queensland at Bamford Hill approximately west-south-west of Cairns in