Calamine (mineral) crystallographically quite distinct, the two minerals exhibit similar massive or botryoidal external form and are not readily distinguished without detailed chemical or physical analysis. The first person to separate the minerals was the British chemist and mineralogist James Smithson in 1803. In the mining industry the term calamine has been historically used to refer to both minerals indiscriminately. In mineralogy calamine is no longer considered a valid term. It has been replaced by smithsonite and hemimorphite in order to distinguish it from the pinkish mixture of zinc oxide (ZnO) and iron(III) oxide (FeO) used in calamine lotion. In the 16th
Pitinga mine By 1990 the mine directly employed 2,000 people, and indirectly perhaps as many as 40,000. Trees were cleared, the river diverted and dams and ponds built before the alluvium deposits were processed. Bucketwheel excavator dredges extracted material rich in cassiterite, which was pumped through pipes to floating processing plants that separated the tin ore. The cassiterite is concentrated on site, then shipped to Mamoré Mineração e Metalurgia in the southern state of São Paulo for casting. Columbite ore is also mined, concentrated and processed on site for use in production of FeNbTa metallic alloy. Up to 1990 a total of