Calamine brass slowly phased out as zinc smelting techniques were developed in Europe, which produced metallic zinc more suitable for brass production than calamine. However, the conversion away from calamine brass manufacture was slow; a British patent was awarded to William Champion in 1738, but the alloying of metallic zinc and copper to produce brass was not patented until 1781 (by James Emerson), and calamine brass mills persisted in South Wales until as late as 1858. The slow diffusion of this technology was probably the result of economic factors. Calamine brass Calamine brass is brass produced by a particular alloying technique using
Group 11 element silver-plated copper wiring are found in some special applications. Copper occurs in its native form in Chile, China, Mexico, Russia and the USA. Various natural ores of copper are: copper pyrites (CuFeS), cuprite or ruby copper (CuO), copper glance (CuS), malachite, (Cu(OH)CuCO), and azurite (Cu(OH)2CuCO). Copper pyrite is the principal ore, and yields nearly 76% of the world production of copper. Silver is found in native form, as an alloy with gold (electrum), and in ores containing sulfur, arsenic, antimony or chlorine. Ores include argentite (AgS), chlorargyrite (AgCl) which includes horn silver, and pyrargyrite (AgSbS). Silver is extracted using the