Calamine (mineral) crystallographically quite distinct, the two minerals exhibit similar massive or botryoidal external form and are not readily distinguished without detailed chemical or physical analysis. The first person to separate the minerals was the British chemist and mineralogist James Smithson in 1803. In the mining industry the term calamine has been historically used to refer to both minerals indiscriminately. In mineralogy calamine is no longer considered a valid term. It has been replaced by smithsonite and hemimorphite in order to distinguish it from the pinkish mixture of zinc oxide (ZnO) and iron(III) oxide (FeO) used in calamine lotion. In the 16th
Christopher Schutz to mine and process the ore, being joined in some of their licences with Thomas Smythe, William Williams and Humfrey Cole. Only a few months later, in early 1566, William Humfrey and Schutz found calamine in the Mendip Hills, and Daniel Hoechstetter designed a refining process by which it could be used in Schutz' furnace at Tintern. As a reward for his work at Tintern, Schutz was granted denization on 9 April 1568, but the extraction of calamine ore at Worle Hill proved prohibitively expensive for the production of brass, and on 28 May the Company of Mineral and Battery