Calamine brass slowly phased out as zinc smelting techniques were developed in Europe, which produced metallic zinc more suitable for brass production than calamine. However, the conversion away from calamine brass manufacture was slow; a British patent was awarded to William Champion in 1738, but the alloying of metallic zinc and copper to produce brass was not patented until 1781 (by James Emerson), and calamine brass mills persisted in South Wales until as late as 1858. The slow diffusion of this technology was probably the result of economic factors. Calamine brass Calamine brass is brass produced by a particular alloying technique using
Christopher Schutz to mine and process the ore, being joined in some of their licences with Thomas Smythe, William Williams and Humfrey Cole. Only a few months later, in early 1566, William Humfrey and Schutz found calamine in the Mendip Hills, and Daniel Hoechstetter designed a refining process by which it could be used in Schutz' furnace at Tintern. As a reward for his work at Tintern, Schutz was granted denization on 9 April 1568, but the extraction of calamine ore at Worle Hill proved prohibitively expensive for the production of brass, and on 28 May the Company of Mineral and Battery