Calamine (mineral) crystallographically quite distinct, the two minerals exhibit similar massive or botryoidal external form and are not readily distinguished without detailed chemical or physical analysis. The first person to separate the minerals was the British chemist and mineralogist James Smithson in 1803. In the mining industry the term calamine has been historically used to refer to both minerals indiscriminately. In mineralogy calamine is no longer considered a valid term. It has been replaced by smithsonite and hemimorphite in order to distinguish it from the pinkish mixture of zinc oxide (ZnO) and iron(III) oxide (FeO) used in calamine lotion. In the 16th
Schlangenberg Nature Reserve the interest in the ore which was mostly used for weapons and vessels. The greatest interest in calamine had been in the 18th century when brass manufactures settled in Stolberg (Rhineland). For the production of the alloy they needed large amounts of calamine which was melted together with copper. Before 1800 digging small reaching only surface based ore was the only technique available to the miners. In the 19th century mining changed and more than 20 adits enabled the workers to reach calamine up to 105 m below the surface. During this time the Schlangenberg-area was perforated like a Swiss