Zinc for discovering pure metallic zinc, even though Swedish chemist Anton von Swab had distilled zinc from calamine four years previously. In his 1746 experiment, Marggraf heated a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. This procedure became commercially practical by 1752. William Champion's brother, John, patented a process in 1758 for calcining zinc sulfide into an oxide usable in the retort process. Prior to this, only calamine could be used to produce zinc. In 1798, Johann Christian Ruberg improved on the smelting process by building the first horizontal retort smelter. Jean-Jacques Daniel
Group 3 element be reduced to their elements, meaning that the discovery of a new earth was equivalent to the discovery of the element within, which in this case would have been "yttrium". Until the early 1920s, the chemical symbol "Yt" was used for the element, after which "Y" came into common use. Yttrium metal was first isolated in 1828 when Friedrich Wöhler heated anhydrous yttrium(III) chloride with potassium to form metallic yttrium and potassium chloride. In 1869, Russian chemist Dmitri Mendeleev published his periodic table, which had empty spaces for elements directly above and under yttrium. Mendeleev made several predictions on the