Group 12 element people in the 17th century. German chemist Andreas Marggraf is usually given credit for discovering pure metallic zinc in a 1746 experiment by heating a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. Experiments on frogs by the Italian doctor Luigi Galvani in 1780 with brass paved the way for the discovery of electrical batteries, galvanization and cathodic protection. In 1880, Galvani's friend, Alessandro Volta, invented the Voltaic pile. The biological importance of zinc was not discovered until 1940 when carbonic anhydrase, an enzyme that scrubs carbon dioxide from blood, was shown to
Metallic mean Metallic mean The metallic means or silver means (also ratios or constants) of the successive natural numbers are the continued fractions:formula_1 The golden ratio (1.618...) is the metallic mean between 1 and 2, while the silver ratio (2.414...) is the metallic mean between 2 and 3. The term "bronze ratio" (3.303...), or terms using other names of metals (such as copper or nickel), are occasionally used to name subsequent metallic means. The values of the first ten metallic means are shown at right. Notice that each metallic mean is a root of the simple quadratic equation: formula_2, where formula_3 is