Group 12 element people in the 17th century. German chemist Andreas Marggraf is usually given credit for discovering pure metallic zinc in a 1746 experiment by heating a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. Experiments on frogs by the Italian doctor Luigi Galvani in 1780 with brass paved the way for the discovery of electrical batteries, galvanization and cathodic protection. In 1880, Galvani's friend, Alessandro Volta, invented the Voltaic pile. The biological importance of zinc was not discovered until 1940 when carbonic anhydrase, an enzyme that scrubs carbon dioxide from blood, was shown to
Metallic fiber also produces metallic yarns; the city Dongyang contains more than 100 factories, though some of these are home based production sites rather than conventional factories. Two of the more popular factories are Salu Metallic Yarn and Aoqi Textile. The most popular company in Europe is the company Wagner-Tech-Textile GmbH with the brand name Rexess, this company is probably the last company which is able to produce metallic yarn in EU. They have still machinery for production of supported and unsupported metallic yarn. The Lurex Company has manufactured metallic fibers in Europe for over fifty years. They produce a wide variety