Zinc for discovering pure metallic zinc, even though Swedish chemist Anton von Swab had distilled zinc from calamine four years previously. In his 1746 experiment, Marggraf heated a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. This procedure became commercially practical by 1752. William Champion's brother, John, patented a process in 1758 for calcining zinc sulfide into an oxide usable in the retort process. Prior to this, only calamine could be used to produce zinc. In 1798, Johann Christian Ruberg improved on the smelting process by building the first horizontal retort smelter. Jean-Jacques Daniel
Metallic color the metallic finish of such paints was added using fine aluminum powder and pigment rather than actual gold. The use of metallic colors is not limited to those colors that approximate the appearance of actual metals. In some instances, it has been noted, "[b]eetles with bright metallic colors are made up into tie pins and cuff links". One popular modern use of metallic colors is for automobiles, which use metallic paint to achieve a particular shine. Such colors "are made from a combination of different pigments and aluminum flakes that have different weights and particle sizes". Crayon-maker Crayola has manufactured