Zinc for discovering pure metallic zinc, even though Swedish chemist Anton von Swab had distilled zinc from calamine four years previously. In his 1746 experiment, Marggraf heated a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. This procedure became commercially practical by 1752. William Champion's brother, John, patented a process in 1758 for calcining zinc sulfide into an oxide usable in the retort process. Prior to this, only calamine could be used to produce zinc. In 1798, Johann Christian Ruberg improved on the smelting process by building the first horizontal retort smelter. Jean-Jacques Daniel
Group 5 element magnesium. 230,000 metric tons of niobium ore are produced yearly, with Brazil producing metric 210,000 tons, Canada producing 10000 metric tons, and Australia producing 1000 metric tons. 60000 metric tons of pure niobium are produced each year. 70000 metric tons of tantalum ore are produced yearly. Brazil produces 90% of tantalum ore, with Canada, Australia, China, and Rwanda also producing the element. The demand for tantalum is around 1200 metric tons per year. Dubnium is produced synthetically by bombarding actinides with lighter elements. Vanadium's main application is in alloys, such as vanadium steel. Vanadium alloys are used in springs, tools,