Zinc for discovering pure metallic zinc, even though Swedish chemist Anton von Swab had distilled zinc from calamine four years previously. In his 1746 experiment, Marggraf heated a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. This procedure became commercially practical by 1752. William Champion's brother, John, patented a process in 1758 for calcining zinc sulfide into an oxide usable in the retort process. Prior to this, only calamine could be used to produce zinc. In 1798, Johann Christian Ruberg improved on the smelting process by building the first horizontal retort smelter. Jean-Jacques Daniel
Schlangenberg Nature Reserve the interest in the ore which was mostly used for weapons and vessels. The greatest interest in calamine had been in the 18th century when brass manufactures settled in Stolberg (Rhineland). For the production of the alloy they needed large amounts of calamine which was melted together with copper. Before 1800 digging small reaching only surface based ore was the only technique available to the miners. In the 19th century mining changed and more than 20 adits enabled the workers to reach calamine up to 105 m below the surface. During this time the Schlangenberg-area was perforated like a Swiss