Zinc for discovering pure metallic zinc, even though Swedish chemist Anton von Swab had distilled zinc from calamine four years previously. In his 1746 experiment, Marggraf heated a mixture of calamine and charcoal in a closed vessel without copper to obtain a metal. This procedure became commercially practical by 1752. William Champion's brother, John, patented a process in 1758 for calcining zinc sulfide into an oxide usable in the retort process. Prior to this, only calamine could be used to produce zinc. In 1798, Johann Christian Ruberg improved on the smelting process by building the first horizontal retort smelter. Jean-Jacques Daniel
Pitinga mine By 1990 the mine directly employed 2,000 people, and indirectly perhaps as many as 40,000. Trees were cleared, the river diverted and dams and ponds built before the alluvium deposits were processed. Bucketwheel excavator dredges extracted material rich in cassiterite, which was pumped through pipes to floating processing plants that separated the tin ore. The cassiterite is concentrated on site, then shipped to Mamoré Mineração e Metalurgia in the southern state of São Paulo for casting. Columbite ore is also mined, concentrated and processed on site for use in production of FeNbTa metallic alloy. Up to 1990 a total of