Manganese(III) oxide Manganese(III) oxide Manganese(III) oxide is a chemical compound with the formula MnO. Heating MnO in air at below 800 °C produces α-MnO (higher temperatures produce MnO). γ-MnO can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline MnO have been reported, for example syntheses involving oxidation of Mn salts or reduction of MnO. Manganese (III) oxide is formed by the redox reaction in an alkaline cell: Manganese (III) oxide MnO must not be confused with MnOOH manganese (III) oxyhydroxide. Contrary to MnO, MnOOH is a compound that decomposes at about 300 °C to form MnO.
Manganese(III) acetate Manganese(III) acetate Manganese(III) acetate describes a family of coordination complexes with the approximate formula Mn(OCCH). All are brown solids, which are soluble in acetic acid and water. These compounds are used in organic synthesis as oxidizing agents. Compounds with the formula Mn(OCCH) have not been verified. Instead manganese(III) acetate adopts the structure reminiscent of those of basic chromium acetate and basic iron acetate. For this reason, manganese(III) acetate is sometimes referred to as basic manganese acetate. The formula is [MnO(OCCH)L]X where L is a ligand and X is an anion. The coordination polymer [MnO(OCCH)]OCCHHOCCH has been crystallized. It is usually