Manganese(IV) fluoride Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream and condenses onto a cold finger. This is still the commonest method of preparation, although the sublimation can be avoided by operating at increased fluorine pressure (4.5–6 bar at 180–320 °C) and mechanically agitating the powder to avoid sintering
Manganese Manganese compounds where manganese is in oxidation state +7, which are mostly restricted to the unstable oxide MnO, compounds of the intensely purple permanganate anion MnO, and a few oxyhalides (MnOF and MnOCl), are powerful oxidizing agents. Compounds with oxidation states +5 (blue) and +6 (green) are strong oxidizing agents and are vulnerable to disproportionation. The most stable oxidation state for manganese is +2, which has a pale pink color, and many manganese(II) compounds are known, such as manganese(II) sulfate (MnSO) and manganese(II) chloride (MnCl). This oxidation state is also seen in the mineral rhodochrosite (manganese(II) carbonate). Manganese(II) most commonly