Manganese(II) phosphate Manganese(II) phosphate Manganese(II) phosphate is an inorganic compound with the chemical formula Mn(PO). It is a rarely studied species, in contrast to the related lithium manganese phosphate, which has been investigated as a battery cathode. Manganese phosphates often combine with iron phosphates through paragenesis. In the process of paragenesis, each mineral affects the manner in which the other is crystallized. The minerals combine in isomorphic series, meaning that they crystallize in similar forms, producing a sequence of solids. Some examples of “isomorphic series” formed by Mn and Fe include heterosite (Fe,Mn)PO, purpurite (Mn,Fe)PO, and triplite (Mn,Fe)PO. The immersion method is
Manganese(II) sulfate highly characteristic. Typically, manganese ores are purified by their conversion to manganese(II) sulfate. Treatment of aqueous solutions of the sulfate with sodium carbonate leads to precipitation of manganese carbonate, which can be calcined to give the oxides MnO. In the laboratory, manganese sulfate can be made by treating manganese dioxide with sulfur dioxide: It can also be made by mixing potassium permanganate with sodium bisulfate and hydrogen peroxide. Manganese sulfate is a by-product of various industrially significant oxidations that use manganese dioxide, including the manufacture of hydroquinone and anisaldehyde. Electrolysis of manganese sulfate yields manganese dioxide, which is called EMD