Manganese easy to oxidize. Manganese metal and its common ions are paramagnetic. Manganese tarnishes slowly in air and oxidizes ("rusts") like iron in water containing dissolved oxygen. Naturally occurring manganese is composed of one stable isotope, Mn. Eighteen radioisotopes have been isolated and described, ranging in atomic weight from 46 u (Mn) to 65 u (Mn). The most stable are Mn with a half-life of 3.7 million years, Mn with a half-life of 312.3 days, and Mn with a half-life of 5.591 days. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less
Manganese exists with a high spin, S = 5/2 ground state because of the high pairing energy for manganese(II). However, there are a few examples of low-spin, S =1/2 manganese(II). There are no spin-allowed d–d transitions in manganese(II), explaining why manganese(II) compounds are typically pale to colorless. The +3 oxidation state is known in compounds like manganese(III) acetate, but these are quite powerful oxidizing agents and also prone to disproportionation in solution, forming manganese(II) and manganese(IV). Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect. The oxidation