Manganese easy to oxidize. Manganese metal and its common ions are paramagnetic. Manganese tarnishes slowly in air and oxidizes ("rusts") like iron in water containing dissolved oxygen. Naturally occurring manganese is composed of one stable isotope, Mn. Eighteen radioisotopes have been isolated and described, ranging in atomic weight from 46 u (Mn) to 65 u (Mn). The most stable are Mn with a half-life of 3.7 million years, Mn with a half-life of 312.3 days, and Mn with a half-life of 5.591 days. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less
Methylcyclopentadienyl manganese tricarbonyl Cestoburn, by Cestoil Chemical Inc. in Canada. MMT is manufactured by reduction of bis(methylcyclopentadienyl) manganese using triethylaluminium. The reduction is conducted under an atmosphere of carbon monoxide. The reaction is exothermic, and without proper cooling, can lead to catastrophic thermal runaway. MMT is a so-called half-sandwich compound, or more specifically a piano-stool complex (since the three CO ligands are like the legs of a piano stool). The manganese atom in MMT is coordinated with three carbonyl groups as well as to the methylcyclopentadienyl ring. These hydrophobic organic ligands make MMT highly lipophilic. A variety of related complexes are known, including