Manganese(II) oxide that the Mn ions form a face centered cubic magnetic sub-lattice where there are ferromagnetically coupled sheets that are anti-parallel with adjacent sheets. Manganese(II) oxide undergoes the chemical reactions typical of an ionic oxide. Upon treatment with acids, it converts to the corresponding manganese(II) salt and water. Oxidation of manganese(II) oxide gives manganese(III) oxide. MnO occurs in nature as the rare mineral manganosite. Commercially it is prepared by reduction of MnO with hydrogen, carbon monoxide or methane, e.g.: MnO can also be prepared by decarbonation of the carbonate: This calcining process is conducted anaerobically, lest MnO form. An alternative route,
Manganese(II) carbonate Manganese(II) carbonate Manganese carbonate is a compound with the chemical formula MnCO. Manganese carbonate occurs naturally as the mineral rhodochrosite but it is typically produced industrially. It is a pale pink, water-insoluble solid. Approximately 20,000 metric tonnes were produced in 2005. MnCO adopts a structure like calcite, consisting of manganese(II) ions in an octahedral coordination geometry. Treatment of aqueous solutions of manganese(II) nitrate with ammonia and carbon dioxide leads to precipitation of this faintly pink solid. The side product, ammonium nitrate is used as fertilizer. The carbonate is insoluble in water but, like most carbonates, hydrolyses upon treatment with acids