Manganese(II) nitrate Manganese(II) nitrate Manganese(II) nitrate are the inorganic compounds with formula Mn(NO)(HO). Each formula unit is composed of one Mn cation and two NO anions and varying amounts of water. Most common is the tetrahydrate Mn(NO)·4HO, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese. Manganese(II) nitrate is prepared by dissolving manganese(II) oxide in nitric acid: It can also be prepared from manganese dioxide and nitrogen dioxide: On heating to 300 °C, aqueous solutions of manganese(II) nitrate thermally decompose to form MnO and NO. Manganese(II)
Manganese(III) fluoride octahedral, and trivalent in all of these materials. Manganese(III) fluoride fluorinates organic compounds including aromatic hydrocarbons, cyclobutenes, and fullerenes. On heating, MnF decomposes to manganese(II) fluoride. Manganese(III) fluoride Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives. MnF can be prepared by treating a solution of MnF in hydrogen fluoride with fluorine: It can also be prepared by the reaction of elemental fluorine with a manganese(II) halide at ~250 °C. Like