Manganese(IV) fluoride hydrofluoric acid. The pentafluoromanganate(1−) salts of potassium, rubidium and caesium, MMnF, can be prepared by fluorination of MMnF or by the reaction of [MnF(py)(HO)] with MF. The lemon-yellow heptafluoromanganate(3−) salts of the same metals, MMnF, have also been prepared. Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream
Manganese heptoxide Manganese heptoxide Manganese(VII) oxide (manganese heptoxide) is an inorganic compound with the formula MnO. This volatile liquid is highly reactive and more often discussed than intentionally prepared. It is a dangerous oxidizer and was first described in 1860. It is the acid anhydride of permanganic acid. The crystalline form of this chemical compound is dark green. The liquid is green by reflected light and red by transmitted light. It is soluble in carbon tetrachloride, and decomposes when in contact with water. It melts at only 5.9 °C, and sublimes at −10 °C. These properties indicate a nonpolar molecular species, which