Manganese induce a strong green color in glass by forming less-colored iron(III) and slightly pink manganese(II), compensating for the residual color of the iron(III). Larger quantities of manganese are used to produce pink colored glass. Tetravalent manganese is used as an activator in red-emitting phosphors. While many compounds are known which show luminescence the majority is not used in commercial application due to low efficiency or deep red emission. However, several Mn aktivated fluorides were reported as potential red emitting phorshors for warm-white LEDs. But to this day, only KSiF:Mn is commercially available for use in warm-white LEDs. The manganese oxide
Manganese exists with a high spin, S = 5/2 ground state because of the high pairing energy for manganese(II). However, there are a few examples of low-spin, S =1/2 manganese(II). There are no spin-allowed d–d transitions in manganese(II), explaining why manganese(II) compounds are typically pale to colorless. The +3 oxidation state is known in compounds like manganese(III) acetate, but these are quite powerful oxidizing agents and also prone to disproportionation in solution, forming manganese(II) and manganese(IV). Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect. The oxidation