Liquefaction of gases low temperatures, using, for example, turboexpanders. The liquefaction of air is used to obtain nitrogen, oxygen, and argon and other atmospheric noble gases by separating the air components by fractional distillation in a cryogenic air separation unit. Air is liquefied by the Linde process, in which air is alternately compressed, cooled, and expanded, each expansion results in a considerable reduction in temperature. With the lower temperature the molecules move more slowly and occupy less space, so the air changes phase to become liquid. Air can also be liquefied by Claude's process in which the gas is allowed to expand isentropically
Noble gas compound exist at very low temperatures or extreme pressures. The stable cation HeH was reported in 1925. Prior to 1962, the only isolated compounds of noble gases were clathrates (including clathrate hydrates); other compounds such as coordination compounds were observed only by spectroscopic means. Clathrates (also known as cage compounds) are compounds of noble gases in which they are trapped within cavities of crystal lattices of certain organic and inorganic substances. The essential condition for their formation is that the guest (noble gas) atoms should be of appropriate size to fit in the cavities of the host crystal lattice; for instance,