Manganese(III) fluoride Manganese(III) fluoride Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives. MnF can be prepared by treating a solution of MnF in hydrogen fluoride with fluorine: It can also be prepared by the reaction of elemental fluorine with a manganese(II) halide at ~250 °C. Like vanadium(III) fluoride, MnF features octahedral metal centers with the same average M-F bond distances. In the Mn compound, however, is distorted (and hence a monoclinic unit
Manganese modern times as pyrolusite or manganese dioxide. Neither this mineral nor elemental manganese is magnetic. In the 16th century, manganese dioxide was called "manganesum" (note the two Ns instead of one) by glassmakers, possibly as a corruption and concatenation of two words, since alchemists and glassmakers eventually had to differentiate a "magnesia negra" (the black ore) from "magnesia alba" (a white ore, also from Magnesia, also useful in glassmaking). Michele Mercati called magnesia negra "manganesa", and finally the metal isolated from it became known as "manganese" (German: "Mangan"). The name "magnesia" eventually was then used to refer only to the