Manganese(II) sulfide Manganese(II) sulfide Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite). Manganese(II) sulfide can be prepared by reacting a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide: The crystal structure of manganese(II) sulfide is similar to that of sodium chloride. The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band. Thus the lowest energy band-to-band electronic
Manganese(II) chloride batteries. It is the precursor to the antiknock compound methylcyclopentadienyl manganese tricarbonyl. Manganism, or manganese poisoning, can be caused by long-term exposure to manganese dust or fumes. Manganese(II) chloride Manganese(II) chloride describes a series of compounds with the formula MnCl(HO), where the value of x can be 0, 2, or 4. The tetrahydrate is the most common form of "manganese(II) chloride" and is the tetrahydrate with the formula MnCl·4HO. The anhydrous form and a dihydrate MnCl·2HO are also known. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with