Manganese(III) oxide a structure related to the spinel structure of MnO where the oxide ions are cubic close packed. This is similar to the relationship between γ-FeO and FeO. γ-MnO is ferrimagnetic with a Néel temperature of 39 K. Manganese(III) oxide Manganese(III) oxide is a chemical compound with the formula MnO. Heating MnO in air at below 800 °C produces α-MnO (higher temperatures produce MnO). γ-MnO can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline MnO have been reported, for example syntheses involving oxidation of Mn salts or reduction of MnO. Manganese (III) oxide is formed
Manganese heptoxide with sulfuric acid to give the remarkable manganyl(VII) cation , which is isoelectronic with CrO MnO decomposes near room temperature, explosively so above 55 °C. The explosion can be initiated by striking the sample or by its exposure to oxidizable organic compounds. The products are MnO and O. Ozone is also produced, giving a strong smell to the substance. The ozone can spontaneously ignite a piece of paper impregnated with an alcohol solution. The production of manganese heptoxide is an undesirable byproduct in many situations. Manganese heptoxide Manganese(VII) oxide (manganese heptoxide) is an inorganic compound with the formula MnO. This