Manganese induce a strong green color in glass by forming less-colored iron(III) and slightly pink manganese(II), compensating for the residual color of the iron(III). Larger quantities of manganese are used to produce pink colored glass. Tetravalent manganese is used as an activator in red-emitting phosphors. While many compounds are known which show luminescence the majority is not used in commercial application due to low efficiency or deep red emission. However, several Mn aktivated fluorides were reported as potential red emitting phorshors for warm-white LEDs. But to this day, only KSiF:Mn is commercially available for use in warm-white LEDs. The manganese oxide
Methylcyclopentadienyl manganese tricarbonyl ferrocene, which has also been used as an additive to gasoline. Although of no practical value, the related compound cyclopentadienyl manganese tricarbonyl (CH)Mn(CO) is also well studied. Up to two of the CO ligands in MMT can be replaced with thiocarbonyl groups, as illustrated by the compounds (CHCH)Mn(CS)CO and (CHCH)Mn(CS)(CO). The human and environmental health impacts that may result from the use of MMT will be a function of exposure to either: (1) MMT in its original, unchanged, chemical form and/or (2) manganese combustion products emitted from vehicles operating on gasoline containing MMT as an octane improver. The general public