Manganese(IV) fluoride Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream and condenses onto a cold finger. This is still the commonest method of preparation, although the sublimation can be avoided by operating at increased fluorine pressure (4.5–6 bar at 180–320 °C) and mechanically agitating the powder to avoid sintering
Chemical looping combustion in operation include monometallic oxides of nickel, copper, manganese and iron, as well as various combined oxides including manganese oxides.combined with calcium, iron and silica. Also natural ores have been in use, especially for solid fuels, including iron ores, manganese ores and ilmenite. A detailed technology assessment of chemical-looping combustion of solid fuel, i.e. coal, for a 1000 MW power plant shows that the added CLC reactor costs as compared to a normal circulating fluidized bed boiler are small, because of the similarities of the technologies. Major costs are instead CO compression, needed in all CO capture technologies, and oxygen