Manganese(IV) fluoride Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream and condenses onto a cold finger. This is still the commonest method of preparation, although the sublimation can be avoided by operating at increased fluorine pressure (4.5–6 bar at 180–320 °C) and mechanically agitating the powder to avoid sintering
Manganese modern times as pyrolusite or manganese dioxide. Neither this mineral nor elemental manganese is magnetic. In the 16th century, manganese dioxide was called "manganesum" (note the two Ns instead of one) by glassmakers, possibly as a corruption and concatenation of two words, since alchemists and glassmakers eventually had to differentiate a "magnesia negra" (the black ore) from "magnesia alba" (a white ore, also from Magnesia, also useful in glassmaking). Michele Mercati called magnesia negra "manganesa", and finally the metal isolated from it became known as "manganese" (German: "Mangan"). The name "magnesia" eventually was then used to refer only to the