Manganese(IV) fluoride hydrofluoric acid. The pentafluoromanganate(1−) salts of potassium, rubidium and caesium, MMnF, can be prepared by fluorination of MMnF or by the reaction of [MnF(py)(HO)] with MF. The lemon-yellow heptafluoromanganate(3−) salts of the same metals, MMnF, have also been prepared. Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream
Manganese(II) oxide Manganese(II) oxide Manganese(II) oxide is an inorganic compound with chemical formula MnO. It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives. Like many monoxides, MnO adopts the rock salt structure, where cations and anions are both octahedrally coordinated. Also like many oxides, manganese(II) oxide is often nonstoichiometric: its composition can vary from MnO to MnO. Below 118 K MnO is antiferromagnetic. MnO has the distinction of being one of the first compounds to have its magnetic structure determined by neutron diffraction, the report appearing in 1951. This study showed