Manganese(II) phosphate Manganese(II) phosphate Manganese(II) phosphate is an inorganic compound with the chemical formula Mn(PO). It is a rarely studied species, in contrast to the related lithium manganese phosphate, which has been investigated as a battery cathode. Manganese phosphates often combine with iron phosphates through paragenesis. In the process of paragenesis, each mineral affects the manner in which the other is crystallized. The minerals combine in isomorphic series, meaning that they crystallize in similar forms, producing a sequence of solids. Some examples of “isomorphic series” formed by Mn and Fe include heterosite (Fe,Mn)PO, purpurite (Mn,Fe)PO, and triplite (Mn,Fe)PO. The immersion method is
Manganese exists with a high spin, S = 5/2 ground state because of the high pairing energy for manganese(II). However, there are a few examples of low-spin, S =1/2 manganese(II). There are no spin-allowed d–d transitions in manganese(II), explaining why manganese(II) compounds are typically pale to colorless. The +3 oxidation state is known in compounds like manganese(III) acetate, but these are quite powerful oxidizing agents and also prone to disproportionation in solution, forming manganese(II) and manganese(IV). Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect. The oxidation