Manganese(II) sulfide transition requires very high energy (ultraviolet) photons. Manganese(II) sulfide Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite). Manganese(II) sulfide can be prepared by reacting a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide: The crystal structure of manganese(II) sulfide is similar to that of sodium chloride. The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized
Manganese(II) carbonate to give water-soluble salts. Manganese carbonate decomposes with release of carbon dioxide, i.e. calcining, at 200 °C to give MnO: This method is sometimes employed in the production of manganese dioxide, which is used in dry-cell batteries and for ferrites. Manganese carbonate is widely used as an additive to plant fertilizers to cure manganese deficient crops. It is also used in health foods, in ceramics as a glaze colorant and flux, and in concrete stains. It is used in medicine as a hematinic. Manganese poisoning, also known as manganism, may be caused by long-term exposure to manganese dust or fumes.