Manganese(IV) fluoride Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream and condenses onto a cold finger. This is still the commonest method of preparation, although the sublimation can be avoided by operating at increased fluorine pressure (4.5–6 bar at 180–320 °C) and mechanically agitating the powder to avoid sintering
Methylcyclopentadienyl manganese tricarbonyl ferrocene, which has also been used as an additive to gasoline. Although of no practical value, the related compound cyclopentadienyl manganese tricarbonyl (CH)Mn(CO) is also well studied. Up to two of the CO ligands in MMT can be replaced with thiocarbonyl groups, as illustrated by the compounds (CHCH)Mn(CS)CO and (CHCH)Mn(CS)(CO). The human and environmental health impacts that may result from the use of MMT will be a function of exposure to either: (1) MMT in its original, unchanged, chemical form and/or (2) manganese combustion products emitted from vehicles operating on gasoline containing MMT as an octane improver. The general public