Manganese(II,III) oxide Manganese(II,III) oxide Manganese(II,III) oxide is the chemical compound with formula MnO. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO.MnO. MnO is found in nature as the mineral hausmannite. MnO formed when any manganese oxide is heated in air above 1000 °C. Considerable research has centred on producing nanocrystalline MnO and various syntheses that involve oxidation of Mn or reduction of Mn. MnO has been found to act as a catalyst for a range of reactions e.g. the oxidation of methane and carbon monoxide; the decomposition of NO, the reduction of
Manganese dioxide chlorine as a by-product. A third process involves manganese heptoxide and manganese monoxide. The two reagents combine with a 1:3 ratio to form manganese dioxide: Lastly the action of potassium permanganate over manganese sulphate crystals produces the desired oxide. Electrolytic manganese dioxide (EMD) is used in zinc–carbon batteries together with zinc chloride and ammonium chloride. EMD is commonly used in zinc manganese dioxide rechargeable alkaline (Zn RAM) cells also. For these applications, purity is extremely important. EMD is produced in a similar fashion as electrolytic tough pitch (ETP) copper: The manganese dioxide is dissolved in sulfuric acid (sometimes mixed with