Liquefaction of gases low temperatures, using, for example, turboexpanders. The liquefaction of air is used to obtain nitrogen, oxygen, and argon and other atmospheric noble gases by separating the air components by fractional distillation in a cryogenic air separation unit. Air is liquefied by the Linde process, in which air is alternately compressed, cooled, and expanded, each expansion results in a considerable reduction in temperature. With the lower temperature the molecules move more slowly and occupy less space, so the air changes phase to become liquid. Air can also be liquefied by Claude's process in which the gas is allowed to expand isentropically
Noble gas decreases with an increasing radius because the valence electrons in the larger noble gases are farther away from the nucleus and are therefore not held as tightly together by the atom. Noble gases have the largest ionization potential among the elements of each period, which reflects the stability of their electron configuration and is related to their relative lack of chemical reactivity. Some of the heavier noble gases, however, have ionization potentials small enough to be comparable to those of other elements and molecules. It was the insight that xenon has an ionization potential similar to that of the oxygen