Magnesium chloride salts is rare in healthy individuals with a normal diet, because excess magnesium is readily excreted in urine by the kidneys. A few cases of oral magnesium toxicity have been described in persons with normal renal function ingesting large amounts of magnesium salts, but it is rare. If a large amount of magnesium chloride is eaten, it will have effects similar to magnesium sulfate, causing diarrhea, although the sulfate also contributes to the laxative effect in magnesium sulfate, so the effect from the chloride is not as severe. Chloride (Cl) and magnesium (Mg) are both essential nutrients important for normal
Magnesium chloride made from solar evaporation of seawater. Anhydrous magnesium chloride is the principal precursor to magnesium metal, which is produced on a large scale. Hydrated magnesium chloride is the form most readily available. MgCl crystallizes in the cadmium chloride motif, which features octahedral Mg centers. Several hydrates are known with the formula MgCl(HO), and each loses water at higher temperatures: x = 12 (−16.4 °C), 8 (−3.4 °C), 6 (116.7 °C), 4 (181 °C), 2 (about 300 °C). In the hexahydrate, the Mg is also octahedral, but is coordinated to six water ligands. The thermal dehydration of the hydrates MgCl(HO) (x