Manganese(IV) fluoride Manganese(IV) fluoride Manganese tetrafluoride, MnF, is the highest fluoride of manganese. It is a powerful oxidizing agent and is used as a means of purifying elemental fluorine. Manganese tetrafluoride was first unequivocally prepared in 1961 by the reaction of manganese(II) fluoride (or other Mn compounds) with a stream of fluorine gas at 550 °C: the MnF sublimes into the gas stream and condenses onto a cold finger. This is still the commonest method of preparation, although the sublimation can be avoided by operating at increased fluorine pressure (4.5–6 bar at 180–320 °C) and mechanically agitating the powder to avoid sintering
Manganese peroxidase the presence of O, can oxidize lignin or react with water to form HO. The Mn3+ ion itself can degrade lignin by catalyzing alkyl-aryl cleavages and α-carbon oxidation in phenols. MnP activity is controlled via transcriptional regulation. MnP is up-regulated by increases in extracellular Mn(II) and HO concentrations. It has been found that increased O concentration and heat stress also activate MnP. Manganese peroxidase In enzymology, a manganese peroxidase () is an enzyme that catalyzes the chemical reaction The 3 substrates of this enzyme are Mn(II), H, and HO, whereas its two products are Mn(III) and HO. This enzyme belongs