Manganese(II) sulfide Manganese(II) sulfide Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite). Manganese(II) sulfide can be prepared by reacting a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide: The crystal structure of manganese(II) sulfide is similar to that of sodium chloride. The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band. Thus the lowest energy band-to-band electronic
Lithium ion manganese oxide battery made of alternating layers of lithium ions and lithium and manganese ions in a 1:2 ratio, similar to the layered structure of . Although is electrochemically inactive, it can be charged to a high potential (4.5 V v.s Li) in order to undergo lithiation/de-lithiation. However, extracting lithium from at such a high potential results in loss of oxygen from the electrode surface which leads to poor capacity and cycling stability. One of the main research efforts in the field of lithium-manganese oxide electrodes for lithium-ion batteries involves developing composite electrodes using structurally integrated layered and spinel , with a chemical