Manganese(II) nitrate Manganese(II) nitrate Manganese(II) nitrate are the inorganic compounds with formula Mn(NO)(HO). Each formula unit is composed of one Mn cation and two NO anions and varying amounts of water. Most common is the tetrahydrate Mn(NO)·4HO, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese. Manganese(II) nitrate is prepared by dissolving manganese(II) oxide in nitric acid: It can also be prepared from manganese dioxide and nitrogen dioxide: On heating to 300 °C, aqueous solutions of manganese(II) nitrate thermally decompose to form MnO and NO. Manganese(II)
Manganese dioxide chlorine as a by-product. A third process involves manganese heptoxide and manganese monoxide. The two reagents combine with a 1:3 ratio to form manganese dioxide: Lastly the action of potassium permanganate over manganese sulphate crystals produces the desired oxide. Electrolytic manganese dioxide (EMD) is used in zinc–carbon batteries together with zinc chloride and ammonium chloride. EMD is commonly used in zinc manganese dioxide rechargeable alkaline (Zn RAM) cells also. For these applications, purity is extremely important. EMD is produced in a similar fashion as electrolytic tough pitch (ETP) copper: The manganese dioxide is dissolved in sulfuric acid (sometimes mixed with