Manganese induce a strong green color in glass by forming less-colored iron(III) and slightly pink manganese(II), compensating for the residual color of the iron(III). Larger quantities of manganese are used to produce pink colored glass. Tetravalent manganese is used as an activator in red-emitting phosphors. While many compounds are known which show luminescence the majority is not used in commercial application due to low efficiency or deep red emission. However, several Mn aktivated fluorides were reported as potential red emitting phorshors for warm-white LEDs. But to this day, only KSiF:Mn is commercially available for use in warm-white LEDs. The manganese oxide
Manganese(II) carbonate Manganese(II) carbonate Manganese carbonate is a compound with the chemical formula MnCO. Manganese carbonate occurs naturally as the mineral rhodochrosite but it is typically produced industrially. It is a pale pink, water-insoluble solid. Approximately 20,000 metric tonnes were produced in 2005. MnCO adopts a structure like calcite, consisting of manganese(II) ions in an octahedral coordination geometry. Treatment of aqueous solutions of manganese(II) nitrate with ammonia and carbon dioxide leads to precipitation of this faintly pink solid. The side product, ammonium nitrate is used as fertilizer. The carbonate is insoluble in water but, like most carbonates, hydrolyses upon treatment with acids