Manganese(III) oxide Manganese(III) oxide Manganese(III) oxide is a chemical compound with the formula MnO. Heating MnO in air at below 800 °C produces α-MnO (higher temperatures produce MnO). γ-MnO can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline MnO have been reported, for example syntheses involving oxidation of Mn salts or reduction of MnO. Manganese (III) oxide is formed by the redox reaction in an alkaline cell: Manganese (III) oxide MnO must not be confused with MnOOH manganese (III) oxyhydroxide. Contrary to MnO, MnOOH is a compound that decomposes at about 300 °C to form MnO.
Manganese(III) fluoride octahedral, and trivalent in all of these materials. Manganese(III) fluoride fluorinates organic compounds including aromatic hydrocarbons, cyclobutenes, and fullerenes. On heating, MnF decomposes to manganese(II) fluoride. Manganese(III) fluoride Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives. MnF can be prepared by treating a solution of MnF in hydrogen fluoride with fluorine: It can also be prepared by the reaction of elemental fluorine with a manganese(II) halide at ~250 °C. Like