Synthetic magnesium silicate Synthetic magnesium silicate Synthetic magnesium silicates are white, odorless, finely divided powders formed by the precipitation reaction of water-soluble sodium silicate (water glass) and a water-soluble magnesium salt such as magnesium chloride, magnesium nitrate or magnesium sulfate. The composition of the precipitate depends on the ratio of the components in the reaction medium, the addition of the correcting substances, and the way in which they are precipitated. The molecular formula is typically written as MgO:XSiO, where X denotes the average mole ratio of SiO to MgO. The product is hydrated and the formula is sometimes written MgO:XSiO•HO to show the
Low valent magnesium compounds Low valent magnesium compounds A number of stable low valent magnesium compounds containing a metal-metal, Mg-Mg, bond, where magnesium exhibits the formal oxidation state of +1 are known. These compounds generally have the formula LMg, where L represents a bulky ligand. The first examples of these stable magnesium(I) compounds were reported in 2007. The chemistry of Mg is dominated by the +2 oxidation state and prior to 2007 only examples of crystalline compounds with short Mg-Mg distances that may indicate an Mg-Mg bond were known, such as the ternary metal hydrides MgRuH, MgRuH, and MgIrH and magnesium diboride, Calculations had